JPS60209033A - 連続炭素繊維と連続熱可塑繊維のブレンド、その製法と用途 - Google Patents

連続炭素繊維と連続熱可塑繊維のブレンド、その製法と用途

Info

Publication number: JPS60209033A
Authority: JP; Japan
Prior art keywords: fiber; tow; fibers; thermoplastic polymer; polymer
Prior art date: 1984-03-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP4946685A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0536525B2 (de

Inventor

ポール・イー・マクマーン

タイシヤン・チヤン

リンカーン・イン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Celanese Corp

Original Assignee

Celanese Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-03-15

Filing date

1985-03-14

Publication date

1985-10-21

1985-03-14 Application filed by Celanese Corp filed Critical Celanese Corp

1985-10-21 Publication of JPS60209033A publication Critical patent/JPS60209033A/ja

1993-05-31 Publication of JPH0536525B2 publication Critical patent/JPH0536525B2/ja

Status Granted legal-status Critical Current

Links

239000000835 fiber Substances 0.000 title claims description 202
229920000049 Carbon (fiber) Polymers 0.000 title claims description 90
239000004917 carbon fiber Substances 0.000 title claims description 90
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 60
229920001169 thermoplastic Polymers 0.000 title claims description 58
239000002131 composite material Substances 0.000 title claims description 34
239000000203 mixture Substances 0.000 title claims description 28
239000004416 thermosoftening plastic Substances 0.000 title description 22
238000000034 method Methods 0.000 claims description 72
238000002156 mixing Methods 0.000 claims description 38
-1 polyethylene Polymers 0.000 claims description 32
125000003118 aryl group Chemical group 0.000 claims description 30
229920000728 polyester Polymers 0.000 claims description 30
229920000642 polymer Polymers 0.000 claims description 25
238000004519 manufacturing process Methods 0.000 claims description 16
229920000106 Liquid crystal polymer Polymers 0.000 claims description 15
239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims description 15
229920001577 copolymer Polymers 0.000 claims description 12
238000002844 melting Methods 0.000 claims description 12
230000008018 melting Effects 0.000 claims description 12
239000002759 woven fabric Substances 0.000 claims description 10
239000004696 Poly ether ether ketone Substances 0.000 claims description 9
229920002530 polyetherether ketone Polymers 0.000 claims description 9
238000010438 heat treatment Methods 0.000 claims description 8
239000004743 Polypropylene Substances 0.000 claims description 6
239000004962 Polyamide-imide Substances 0.000 claims description 5
239000004695 Polyether sulfone Substances 0.000 claims description 5
239000004697 Polyetherimide Substances 0.000 claims description 5
239000004698 Polyethylene Substances 0.000 claims description 5
238000009730 filament winding Methods 0.000 claims description 5
229920002239 polyacrylonitrile Polymers 0.000 claims description 5
229920002312 polyamide-imide Polymers 0.000 claims description 5
229920001225 polyester resin Polymers 0.000 claims description 5
239000004645 polyester resin Substances 0.000 claims description 5
229920006393 polyether sulfone Polymers 0.000 claims description 5
229920001601 polyetherimide Polymers 0.000 claims description 5
229920000573 polyethylene Polymers 0.000 claims description 5
229920001155 polypropylene Polymers 0.000 claims description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
239000004677 Nylon Substances 0.000 claims 4
229920001778 nylon Polymers 0.000 claims 4
229920005594 polymer fiber Polymers 0.000 claims 2
239000007789 gas Substances 0.000 description 32
239000000047 product Substances 0.000 description 19
239000000463 material Substances 0.000 description 15
229920001707 polybutylene terephthalate Polymers 0.000 description 9
239000000178 monomer Substances 0.000 description 7
229920001187 thermosetting polymer Polymers 0.000 description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
229910002804 graphite Inorganic materials 0.000 description 6
239000010439 graphite Substances 0.000 description 6
239000010410 layer Substances 0.000 description 6
FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
238000000576 coating method Methods 0.000 description 5
229920003023 plastic Polymers 0.000 description 5
239000004033 plastic Substances 0.000 description 5
229920001279 poly(ester amides) Polymers 0.000 description 5
229920001634 Copolyester Polymers 0.000 description 4
239000002253 acid Substances 0.000 description 4
125000001246 bromo group Chemical group Br* 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
150000001875 compounds Chemical group 0.000 description 4
125000004122 cyclic group Chemical group 0.000 description 4
239000004744 fabric Substances 0.000 description 4
229910052736 halogen Inorganic materials 0.000 description 4
150000002367 halogens Chemical class 0.000 description 4
238000009736 wetting Methods 0.000 description 4
125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 3
125000004959 2,6-naphthylene group Chemical group [H]C1=C([H])C2=C([H])C([*:1])=C([H])C([H])=C2C([H])=C1[*:2] 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
239000002243 precursor Substances 0.000 description 3
238000012545 processing Methods 0.000 description 3
239000002994 raw material Substances 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000012783 reinforcing fiber Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
238000011282 treatment Methods 0.000 description 3
XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 description 2
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
NGSWKAQJJWESNS-UHFFFAOYSA-N 4-coumaric acid Chemical compound OC(=O)C=CC1=CC=C(O)C=C1 NGSWKAQJJWESNS-UHFFFAOYSA-N 0.000 description 2
229940090248 4-hydroxybenzoic acid Drugs 0.000 description 2
KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
239000004952 Polyamide Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
125000003277 amino group Chemical group 0.000 description 2
239000002585 base Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
238000003763 carbonization Methods 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
125000001309 chloro group Chemical group Cl* 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
239000002657 fibrous material Substances 0.000 description 2
239000012530 fluid Substances 0.000 description 2
125000001153 fluoro group Chemical group F* 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
238000000465 moulding Methods 0.000 description 2
239000011087 paperboard Substances 0.000 description 2
IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachloro-phenol Natural products OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
229920002647 polyamide Polymers 0.000 description 2
238000006068 polycondensation reaction Methods 0.000 description 2
230000003014 reinforcing effect Effects 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
238000010561 standard procedure Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
238000009941 weaving Methods 0.000 description 2
KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 description 1
OHBQPCCCRFSCAX-UHFFFAOYSA-N 1,4-Dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1 OHBQPCCCRFSCAX-UHFFFAOYSA-N 0.000 description 1
XIWRQEFBSZWJTH-UHFFFAOYSA-N 2,3-dibromobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Br)=C1Br XIWRQEFBSZWJTH-UHFFFAOYSA-N 0.000 description 1
DBCKMJVEAUXWJJ-UHFFFAOYSA-N 2,3-dichlorobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Cl)=C1Cl DBCKMJVEAUXWJJ-UHFFFAOYSA-N 0.000 description 1
REFDOIWRJDGBHY-UHFFFAOYSA-N 2-bromobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Br)=C1 REFDOIWRJDGBHY-UHFFFAOYSA-N 0.000 description 1
AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
GTIIZGAMOLIVIE-UHFFFAOYSA-N 3-methyl-2-prop-2-enoyloxybenzoic acid Chemical compound CC1=CC=CC(C(O)=O)=C1OC(=O)C=C GTIIZGAMOLIVIE-UHFFFAOYSA-N 0.000 description 1
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
LABJFIBQJFPXHZ-UHFFFAOYSA-N 4-(carboxymethoxy)benzoic acid Chemical compound OC(=O)COC1=CC=C(C(O)=O)C=C1 LABJFIBQJFPXHZ-UHFFFAOYSA-N 0.000 description 1
GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
229920013683 Celanese Polymers 0.000 description 1
241000723438 Cercidiphyllum japonicum Species 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
239000002841 Lewis acid Chemical class 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
239000004642 Polyimide Substances 0.000 description 1
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
125000002252 acyl group Chemical group 0.000 description 1
125000004423 acyloxy group Chemical group 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000012790 adhesive layer Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
QEZIKGQWAWNWIR-UHFFFAOYSA-N antimony(3+) antimony(5+) oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[Sb+3].[Sb+5] QEZIKGQWAWNWIR-UHFFFAOYSA-N 0.000 description 1
238000000149 argon plasma sintering Methods 0.000 description 1
230000000386 athletic effect Effects 0.000 description 1
238000005452 bending Methods 0.000 description 1
WXBLLCUINBKULX-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 WXBLLCUINBKULX-UHFFFAOYSA-N 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
238000010000 carbonizing Methods 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
HLVCZTOFOWHIJZ-UHFFFAOYSA-N chembl2204744 Chemical compound C1=CC(C(=O)O)=CC=C1N=NC1=CC=C(O)C=C1 HLVCZTOFOWHIJZ-UHFFFAOYSA-N 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
229940114081 cinnamate Drugs 0.000 description 1
239000011280 coal tar Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
125000000950 dibromo group Chemical group Br* 0.000 description 1
JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
125000003963 dichloro group Chemical group Cl* 0.000 description 1
BXJGUBZTZWCMEX-UHFFFAOYSA-N dimethylhydroquinone Natural products CC1=C(C)C(O)=CC=C1O BXJGUBZTZWCMEX-UHFFFAOYSA-N 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002168 ethanoic acid esters Chemical class 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 description 1
235000001785 ferulic acid Nutrition 0.000 description 1
229940114124 ferulic acid Drugs 0.000 description 1
KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
239000002241 glass-ceramic Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
230000001788 irregular Effects 0.000 description 1
239000010985 leather Substances 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000010128 melt processing Methods 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
125000004957 naphthylene group Chemical group 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
235000012771 pancakes Nutrition 0.000 description 1
YNWDKZIIWCEDEE-UHFFFAOYSA-N pantoprazole sodium Chemical compound [Na+].COC1=CC=NC(CS(=O)C=2[N-]C3=CC=C(OC(F)F)C=C3N=2)=C1OC YNWDKZIIWCEDEE-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
239000011301 petroleum pitch Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
229920002492 poly(sulfone) Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001230 polyarylate Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920006149 polyester-amide block copolymer Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000002990 reinforced plastic Substances 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000010129 solution processing Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1

Landscapes

Reinforced Plastic Materials (AREA)
Artificial Filaments (AREA)
Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

JP4946685A 1984-03-15 1985-03-14 連続炭素繊維と連続熱可塑繊維のブレンド、その製法と用途 Granted JPS60209033A (ja)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US58982384A	1984-03-15	1984-03-15
US589823		1984-03-15
US589825		1984-03-15
US589817		1990-09-27

Publications (2)

Publication Number	Publication Date
JPS60209033A true JPS60209033A (ja)	1985-10-21
JPH0536525B2 JPH0536525B2 (de)	1993-05-31

Family

ID=24359694

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP4946685A Granted JPS60209033A (ja)	1984-03-15	1985-03-14	連続炭素繊維と連続熱可塑繊維のブレンド、その製法と用途

Country Status (1)

Country	Link
JP (1)	JPS60209033A (de)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62135537A (ja) *	1985-12-09	1987-06-18	Fuji Standard Res Kk	柔軟性複合材料及びその製造方法
JPH01102161A (ja) *	1987-10-14	1989-04-19	Nippon Oil Co Ltd	補強用構造材
JPH01266232A (ja) *	1988-04-12	1989-10-24	Toyobo Co Ltd	抗張力体成形用糸条及び抗張力体
WO1990007024A1 (fr) *	1988-12-15	1990-06-28	Asahi Kasei Kogyo Kabushiki Kaisha	Feuille composite pour materiau renforce par des fibres
JP2004504502A (ja) *	2000-07-13	2004-02-12	ソシエテ　アノニム　シヤープ	複合材から作られた一方向性シート
US7344667B2 (en)	2002-04-23	2008-03-18	Toray Industries, Inc.	Prepreg, production process thereof, and molded article
WO2008105225A1 (ja) *	2007-02-27	2008-09-04	Nec Corporation	炭素繊維ロービング、これを用いた長繊維ペレット及び繊維強化樹脂成形体
WO2010144134A1 (en)	2009-06-11	2010-12-16	Spunfab, Ltd	Method of delivering a thermoplastic and/or crosslinking resin to a composite laminate structure
JP2013517162A (ja) *	2010-01-22	2013-05-16	ダイムラー・アクチェンゲゼルシャフト	サンドイッチコンポーネント及びその製造方法
WO2017094633A1 (ja)	2015-12-01	2017-06-08	新日鉄住金マテリアルズ株式会社	現場重合型熱可塑性プリプレグ、熱可塑性コンポジット及びその製造方法

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JPS58215343A (ja) *	1982-06-09	1983-12-14	リグナイト株式会社	合成樹脂成形品の製造方法
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Cited By (13)

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Publication number	Priority date	Publication date	Assignee	Title
JPS62135537A (ja) *	1985-12-09	1987-06-18	Fuji Standard Res Kk	柔軟性複合材料及びその製造方法
JPH01102161A (ja) *	1987-10-14	1989-04-19	Nippon Oil Co Ltd	補強用構造材
JPH01266232A (ja) *	1988-04-12	1989-10-24	Toyobo Co Ltd	抗張力体成形用糸条及び抗張力体
WO1990007024A1 (fr) *	1988-12-15	1990-06-28	Asahi Kasei Kogyo Kabushiki Kaisha	Feuille composite pour materiau renforce par des fibres
JP2004504502A (ja) *	2000-07-13	2004-02-12	ソシエテ　アノニム　シヤープ	複合材から作られた一方向性シート
US7344667B2 (en)	2002-04-23	2008-03-18	Toray Industries, Inc.	Prepreg, production process thereof, and molded article
WO2008105225A1 (ja) *	2007-02-27	2008-09-04	Nec Corporation	炭素繊維ロービング、これを用いた長繊維ペレット及び繊維強化樹脂成形体
WO2010144134A1 (en)	2009-06-11	2010-12-16	Spunfab, Ltd	Method of delivering a thermoplastic and/or crosslinking resin to a composite laminate structure
JP2013517162A (ja) *	2010-01-22	2013-05-16	ダイムラー・アクチェンゲゼルシャフト	サンドイッチコンポーネント及びその製造方法
US8945327B2 (en)	2010-01-22	2015-02-03	Daimler Ag	Sandwich component and method for the production thereof
WO2017094633A1 (ja)	2015-12-01	2017-06-08	新日鉄住金マテリアルズ株式会社	現場重合型熱可塑性プリプレグ、熱可塑性コンポジット及びその製造方法
KR20180089413A (ko)	2015-12-01	2018-08-08	신닛테츠스미킹 마테리알즈 가부시키가이샤	현장 중합형 열가소성 프리프레그, 열가소성 컴포지트 및 그 제조 방법
EP4108714A1 (de)	2015-12-01	2022-12-28	NIPPON STEEL Chemical & Material Co., Ltd.	Verfahren zur herstellung eines in-situ polymerisierten thermoplastischen prepregs

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Publication number	Publication date
JPH0536525B2 (de)	1993-05-31

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