JPS60220140A - 脱硫剤 - Google Patents

脱硫剤

Info

Publication number: JPS60220140A
Authority: JP; Japan
Prior art keywords: iron oxide; desulfurization agent; regeneration; adsorbent; adsorption
Prior art date: 1984-04-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP7504984A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0363427B2 (de

Inventor

Yoshiaki Obayashi

良昭尾林

Hiroshi Ogawa

弘小川

Toru Seto

徹瀬戸

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Heavy Industries Ltd

Original Assignee

Mitsubishi Heavy Industries Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-04-16

Filing date

1984-04-16

Publication date

1985-11-02

1984-04-16 Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd

1984-04-16 Priority to JP7504984A priority Critical patent/JPS60220140A/ja

1985-11-02 Publication of JPS60220140A publication Critical patent/JPS60220140A/ja

1991-10-01 Publication of JPH0363427B2 publication Critical patent/JPH0363427B2/ja

Status Granted legal-status Critical Current

Links

238000006477 desulfuration reaction Methods 0.000 title claims abstract description 15
230000023556 desulfurization Effects 0.000 title claims abstract description 15
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 36
239000003795 chemical substances by application Substances 0.000 claims abstract description 19
150000001785 cerium compounds Chemical class 0.000 claims abstract description 9
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 6
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 4
230000008929 regeneration Effects 0.000 abstract description 17
238000011069 regeneration method Methods 0.000 abstract description 17
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 7
HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 abstract description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
239000000377 silicon dioxide Substances 0.000 abstract description 2
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 1
229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
238000001179 sorption measurement Methods 0.000 description 18
239000003463 adsorbent Substances 0.000 description 16
238000000034 method Methods 0.000 description 11
239000007789 gas Substances 0.000 description 9
230000000052 comparative effect Effects 0.000 description 8
230000003009 desulfurizing effect Effects 0.000 description 6
229910052717 sulfur Inorganic materials 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 4
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
239000010779 crude oil Substances 0.000 description 3
239000000446 fuel Substances 0.000 description 3
229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
239000002994 raw material Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000003245 coal Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003464 sulfur compounds Chemical class 0.000 description 2
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
238000012360 testing method Methods 0.000 description 2
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
241000270708 Testudinidae Species 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
-1 ethylene, propylene, acetic acid Chemical class 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000011056 performance test Methods 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
238000004904 shortening Methods 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
229910052815 sulfur oxide Inorganic materials 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
238000004065 wastewater treatment Methods 0.000 description 1

Landscapes

Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Hydrogen, Water And Hydrids (AREA)

JP7504984A 1984-04-16 1984-04-16 脱硫剤 Granted JPS60220140A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP7504984A JPS60220140A (ja)	1984-04-16	1984-04-16	脱硫剤

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7504984A JPS60220140A (ja)	1984-04-16	1984-04-16	脱硫剤

Publications (2)

Publication Number	Publication Date
JPS60220140A true JPS60220140A (ja)	1985-11-02
JPH0363427B2 JPH0363427B2 (de)	1991-10-01

Family

ID=13564954

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP7504984A Granted JPS60220140A (ja)	1984-04-16	1984-04-16	脱硫剤

Country Status (1)

Country	Link
JP (1)	JPS60220140A (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6393347A (ja) *	1986-10-07	1988-04-23	Mitsubishi Heavy Ind Ltd	脱硫剤
JPH0781901A (ja) *	1993-09-16	1995-03-28	Taiyo Sanso Co Ltd	気状水素化物またはそれを稀釈したガスの精製方法
CN1061633C (zh) *	1997-07-23	2001-02-07	湖北省化学研究所	多功能氧化铁精脱硫剂及制备

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6871396B2 (en)	2000-02-09	2005-03-29	Matsushita Electric Industrial Co., Ltd.	Transfer material for wiring substrate

1984
- 1984-04-16 JP JP7504984A patent/JPS60220140A/ja active Granted

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6393347A (ja) *	1986-10-07	1988-04-23	Mitsubishi Heavy Ind Ltd	脱硫剤
JPH0781901A (ja) *	1993-09-16	1995-03-28	Taiyo Sanso Co Ltd	気状水素化物またはそれを稀釈したガスの精製方法
CN1061633C (zh) *	1997-07-23	2001-02-07	湖北省化学研究所	多功能氧化铁精脱硫剂及制备

Also Published As

Publication number	Publication date
JPH0363427B2 (de)	1991-10-01

Publication	Publication Date	Title
CA1290552E (en)	1991-10-15	Selective removal of hydorgen sulfide over zinc titanate and alumina
US4001375A (en)	1977-01-04	Process for the desulfurization of flue gas
KR20020080331A (ko)	2002-10-23	탈황 및 이를 위한 신규 흡착제
US4725417A (en)	1988-02-16	Process for removing sulfur oxides from a gas by means of an absorption mass regenerable by reaction with hydrogen sulfide
JPS61216735A (ja)	1986-09-26	ＦＣＣ装置のＳＯｘ排出量を低減するための触媒及びＳＯｘ低減方法
US5227351A (en)	1993-07-13	Sorbent for use in hot gas desulfurization
JPS594175B2 (ja)	1984-01-28	被覆触媒を使用する窒素酸化物除去
CN114502277A (zh)	2022-05-13	复合材料及其在脱硫方面的应用
US4325926A (en)	1982-04-20	Process for removing sulfur dioxide from a gas
JPS60220140A (ja)	1985-11-02	脱硫剤
CN112642397A (zh)	2021-04-13	复合材料及其制备方法和应用
CN86103858A (zh)	1987-01-21	用于使c3烃和c4烃转化的物质组成及转化方法
JPS62500083A (ja)	1987-01-16	硫黄化合物を除去するためのガスの精製法
JP2005029466A (ja)	2005-02-03	直接的酸化による含硫黄化合物の除去方法
JP3486756B2 (ja)	2004-01-13	炭化水素中の砒素を予備硫化された捕獲物質上への通過によって除去する方法
CN109718663B (zh)	2022-06-28	一种脱除烟气中硫氧化物和/或氮氧化物的方法及装置
BRPI0619396A2 (pt)	2011-10-04	processos para regenerar catalisadores de fcc em um regenerador e para craquear uma alimentação de hidrocarboneto em uma zona de craqueamento catalìtico, e, composição de catalisador para redução de emissão de nox
JPS60102935A (ja)	1985-06-07	脱硫剤
JPS63134028A (ja)	1988-06-06	乾式脱硫方法
JPS6393347A (ja)	1988-04-23	脱硫剤
USRE33393E (en)	1990-10-16	Selective removal of hydrogen sulfide over zinc titanate and alumina
JPS59139934A (ja)	1984-08-11	乾式脱硫剤
CN106492797A (zh)	2017-03-15	一种Ag2O@Ti‑Ce‑O双功能催化吸附脱硫剂及其制备方法和应用
JPS6265744A (ja)	1987-03-25	Ｃ↓３及びｃ↓４炭化水素の転化用触媒組成物ならびに転化方法
JPS59166241A (ja)	1984-09-19	脱硫剤

JPS60220140A - 脱硫剤 - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=13564954

Family Applications (1)

Country Status (1)

Cited By (3)

Families Citing this family (1)

Cited By (3)

Also Published As

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