JPS60244363A - Coating apparatus - Google Patents
Coating apparatusInfo
- Publication number
- JPS60244363A JPS60244363A JP10137084A JP10137084A JPS60244363A JP S60244363 A JPS60244363 A JP S60244363A JP 10137084 A JP10137084 A JP 10137084A JP 10137084 A JP10137084 A JP 10137084A JP S60244363 A JPS60244363 A JP S60244363A
- Authority
- JP
- Japan
- Prior art keywords
- coating
- cylindrical body
- ring
- liquid
- cylindrical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Photoreceptors In Electrophotography (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Apparatus (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
囚 産業上の利用分野
本発明は、塗布装置に関し、荷に円筒形状体の外周面に
電子写真感光体を連続的に塗布するに通した塗布装置に
関するものでめる〇(B) 従来技術及びその間4点
円筒形状体のような被塗布基材の円外周面上に塗布材を
被覆する方法としては、スプレー法、浸漬法、リング状
液体容器を用いる手直型塗布法、カーテン塗布法、ブレ
ードa布法、ロール塗布法、エクストルジ胃ン法等の種
々の方法が知られている。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a coating device, and more particularly, to a coating device for continuously coating an outer peripheral surface of a cylindrical body with an electrophotographic photoreceptor on a load. 〇(B) Conventional technology and four-point method for coating the outer circumferential surface of a substrate to be coated, such as a cylindrical body, with a spray method, a dipping method, and a manual method using a ring-shaped liquid container. Various methods are known, such as a coating method, a curtain coating method, a blade coating method, a roll coating method, and an extrusion method.
しかし、スプレー法は量産性に優れている反面、1回当
9の塗布量が少ないこと、また表面平滑性が劣るという
欠点がるり、1μm〜数十μmの広い範囲の膜厚と極め
て高い表面平滑性のの塗布層が必要な電子写真感光体の
塗布法としては適していない。浸漬法は、比較的手軽な
方法であるが、円筒形状体の上部と下部とで膜厚の差が
大きいこと、また2層以上の塗布を行う場合に各層の塗
布を同一溶剤系で行うと下層が2かされるという欠点が
生じ易く、更に量産性に劣っている。However, while the spray method is excellent in mass production, it has the drawbacks of a small amount of coating per application, poor surface smoothness, and a wide range of film thickness from 1 μm to several tens of μm and an extremely high surface finish. It is not suitable as a coating method for electrophotographic photoreceptors that require a smooth coating layer. The dipping method is a relatively simple method, but there is a large difference in film thickness between the upper and lower parts of the cylindrical body, and when coating two or more layers, it is difficult to coat each layer with the same solvent system. The disadvantage is that the lower layer is likely to be doubled, and furthermore, mass productivity is poor.
特開昭53−22544、同昭56−101149、同
昭58−11064、同昭58−180261などに示
されるリング塗布法は、塗布層の表面平滑性に優れ、ま
た塗布液との接触時間が短かいため多層塗布にも適して
いる利点がめる。リング塗布法は、円筒形状体の外径よ
シ僅かに小さい内径の弾性リングと液体容器外筒とを一
体となし、このリングの中に円筒形状体を貫通させて円
筒形状体の外表面とで形成された塗布室に塗布液を供給
し、円筒形状休めるいはリングのいずれか又は両方を移
動冷せることによって円筒形状体の外表面に塗布するも
のでるる。しかし、このリング塗布法は、多数の円筒形
状体を連続して塗布することは装置の構造上から困難な
ことでめった。たとえば、第1の円筒形状体と第2の円
筒形状体とを隙間なく完全に接合してリング中を通さな
ければ、塗布室が形成されず、塗布液が漏れ出て第2の
円筒形状休を汚してしまう結果になる。さらに、円筒形
状体を下部昇降手段により供給し、塗布リングを貫通し
上部昇降手段により円筒形状休を排出する場合に2いて
、下部昇降手段から上部昇降手段への受渡し中は、両昇
降手段の速度が完全に一致しなければならない。また、
第1の円筒形状体と第2の円筒形状体とが接合する時に
も両日筒形状体の速度は完全に一致する必要があり、さ
もなければ接合時に衝撃が発生し、塗布面の乱れとなる
からである。また、その接合部は、一体の円筒形状体と
みなせる程度に正確でないと、接合部の不一致部分に液
の溜りが発生し、その液溜りが第2の円筒形状体の外表
面にタレとなって塗布面を乱したり、接合部の内面に浸
透し第2の円筒形状体の内面を汚したりするのでおる。The ring coating method shown in JP-A-53-22544, JP-A-56-101149, JP-A-58-11064, JP-A-58-180261, etc. has excellent surface smoothness of the coating layer, and also shortens the contact time with the coating liquid. Because it is short, it has the advantage of being suitable for multilayer coating. In the ring coating method, an elastic ring with an inner diameter slightly smaller than the outer diameter of a cylindrical body is integrated with an outer cylinder of a liquid container, and the cylindrical body is passed through this ring to coat the outer surface of the cylindrical body. The coating solution is supplied to the coating chamber formed by the above method, and is applied to the outer surface of the cylindrical body by moving and cooling either the cylindrical chamber or the ring, or both. However, this ring coating method was unsuccessful because it was difficult to coat a large number of cylindrical bodies in succession due to the structure of the apparatus. For example, unless the first cylindrical body and the second cylindrical body are completely joined without any gaps and passed through the ring, the coating chamber will not be formed and the coating liquid will leak out and cause the second cylindrical body to pass through the ring. This results in contamination. Furthermore, when the cylindrical body is supplied by the lower lifting means and the cylindrical body is passed through the application ring and discharged by the upper lifting means, during the transfer from the lower lifting means to the upper lifting means, both lifting means are The speeds must match exactly. Also,
When the first cylindrical body and the second cylindrical body are joined, the speeds of the two cylindrical bodies must be perfectly matched, otherwise an impact will occur during joining, resulting in disturbance of the coated surface. It is from. In addition, if the joint is not precise enough to be considered as a single cylindrical body, liquid will accumulate at the mismatched part of the joint, and this pool will drip onto the outer surface of the second cylindrical body. This may disturb the coated surface or penetrate into the inner surface of the joint and stain the inner surface of the second cylindrical body.
さらに、積層感光体を塗布する際に丁場がおかされるの
を防止する目的で第1の円筒形状体と第2の円筒形状休
め間に中間リングを設けることも知られているが、やは
9上述したと同様の難点がめる◇
また、リング塗布法は、弾性リング先端よりも上にある
塗布液だけで塗布するため塗布液が少なく(反面、前述
したように円筒形状休との接触時間が短かい利点がるる
)、連続塗布するためには塗布液を断続的に供給しなけ
ればならず、泡の発生や液面の変動により均斉な塗布面
が得られなからたり、生産効率を低下したりするO
(Q 発明の目的
本発明の目的は、前述したような欠点か々く、円筒形状
休の外周面上に均斉な塗布層を効率よく連続的に形成す
ることができる電子写真感光体を塗布するに適した塗布
装置を提供することである。Furthermore, it is known to provide an intermediate ring between the first cylindrical body and the second cylindrical rest for the purpose of preventing the coating from being disturbed when coating the laminated photoreceptor, but this 9. It has the same drawbacks as mentioned above ◇ In addition, the ring coating method uses only the coating liquid above the tip of the elastic ring, so the amount of coating liquid is small (on the other hand, as mentioned above, the contact time with the cylindrical shape is short). In order to perform continuous coating, the coating liquid must be supplied intermittently, making it impossible to obtain a uniform coating surface due to the generation of bubbles and fluctuations in the liquid level, and reducing production efficiency. (Q. Purpose of the Invention The purpose of the present invention is to provide an electrophotographic photosensitive material that is capable of efficiently and continuously forming a uniform coating layer on the outer peripheral surface of a cylindrical shape, despite the drawbacks mentioned above. An object of the present invention is to provide a coating device suitable for coating the body.
(D) 発明の構成
本発明は、被塗布基材としての円筒形状休を上昇させる
だめの昇降手段、昇降手段に設けられた外周円体の載置
台2よび外周円体の外周を保持する係止手段を含み外周
円体の両側は円筒゛形状体の内面に装着したとき連続的
な外周面を形成する構造を有していることを特徴とする
リング塗布法に用いる塗布装置である〇
本発明の塗布装置は、上記した特徴に加えて外周円体が
係止手段によって停止している間も塗布液をリング状液
体容器に連続して供給できるように容器中の塗布液がオ
ーバーフローするように構成した装置を包含するもので
るる。(D) Structure of the Invention The present invention comprises an elevating means for elevating a cylindrical base material to be coated, a mounting table 2 for an outer circular body provided in the elevating means, and a member for holding the outer circumference of the outer circular body. This is a coating device used in a ring coating method, characterized in that both sides of the outer circular body including a stop means form a continuous outer circumferential surface when attached to the inner surface of a cylindrical body. In addition to the above-mentioned characteristics, the coating device of the present invention has a feature that allows the coating liquid in the container to overflow so that the coating liquid can be continuously supplied to the ring-shaped liquid container even while the outer circular body is stopped by the locking means. This includes devices configured as follows.
(B) 実施例
以下に本発明の塗布装置の動作、機構を図面によシ詳細
に説明する。(B) Example The operation and mechanism of the coating apparatus of the present invention will be explained in detail below with reference to the drawings.
第1図(、)〜(、)は、本発明の塗布装置を用いて円
筒形状体の外周面に塗布している状態を経時的に示す断
面図でるる。円筒形状体7が弾性リングを有する液体容
器4を貫通し、昇降装置(ロッド6のみ図示)により一
定速度で上昇しながら塗布される。リング状液体容器4
には塗布液供給管lが設けられ、塗布層がポンプ(図示
せず)により自動的に液体容器4に塗布液供給管から送
られ塗布されるようになっている◇しかし、第1図に2
いては、リング状液体容器4とは別個に貯液槽2が連通
管3(塗布液供給管とも言いうる)で連結され、この貯
液槽2に塗布液供給管1及びオーバーフロー管5が設け
ている。オーバーフロー管5をもり貯液槽2を液体容器
4とは別個に設けることは、装置の製作が容易であるこ
と、円筒形状体への塗布近傍ではオーバーフロー管への
塗布液の流れ込みによる液面の乱れによって局部的な重
布ムラを防止すること等によるが、液体容器4の外径を
大きくすれば、別個の貯液槽を設けることなく、液体容
器4の中にオーバーフロー管5を設けてもよいO
円筒形状体7の外周表面上への塗布は、弾性の
リングの先端より上にるる塗布版#液面で行なわれ、そ
の液面の高さは任意に設定することができる。本発明の
図示した塗布装置では、その液面の高さはオーバーフロ
ー管によって決別されるが、弾性リングの先端より僅か
の上にオーバーフロー管5の流入口が位置するようにし
て。FIGS. 1(a) to 1(a) are cross-sectional views showing over time the state in which the outer circumferential surface of a cylindrical body is coated using the coating apparatus of the present invention. The cylindrical body 7 passes through the liquid container 4 having an elastic ring and is applied while being raised at a constant speed by means of a lifting device (only the rod 6 is shown). Ring-shaped liquid container 4
is provided with a coating liquid supply pipe l, and the coating layer is automatically sent from the coating liquid supply pipe to the liquid container 4 by a pump (not shown) for coating. 2
In this case, a liquid storage tank 2 is connected to the ring-shaped liquid container 4 separately through a communication pipe 3 (also referred to as a coating liquid supply pipe), and a coating liquid supply pipe 1 and an overflow pipe 5 are provided in this liquid storage tank 2. ing. Providing the overflow pipe 5 and the liquid storage tank 2 separately from the liquid container 4 makes it easy to manufacture the device, and prevents the liquid level from flowing into the overflow pipe in the vicinity of coating a cylindrical body. This is to prevent localized unevenness due to turbulence, etc., but if the outer diameter of the liquid container 4 is increased, the overflow pipe 5 can be provided inside the liquid container 4 without providing a separate liquid storage tank. Coating onto the outer circumferential surface of the cylindrical body 7 is carried out at the liquid level of the coating plate # above the tip of the elastic ring, and the height of the liquid level can be set arbitrarily. In the illustrated coating device of the present invention, the liquid level is determined by the overflow tube, and the inlet of the overflow tube 5 is located slightly above the tip of the elastic ring.
も可能である。is also possible.
塗布液供給管lからは円筒形状体での消費型(塗布量)
よりもある程度多い量の塗布液が連続して供給されるが
、円筒形状体の移動によっても塗布液液面は変動せず、
常に同一の条件で塗布することができる。また、外周円
体9がそれを保持するための係止手段lOによってリン
グ容器内に停止している間も同様に塗布液供給を続ける
ことができる。第1図(&)は、円筒形状体7に塗布す
る前の状態を示しておシ、連続塗布作業は外周円体9I
をリング容器内で係止手段10により停止させた状態で
開始することが好ましい。Consumption type (coating amount) in a cylindrical shape from the coating liquid supply pipe l
Although a somewhat larger amount of coating liquid is continuously supplied, the level of the coating liquid does not fluctuate even when the cylindrical body moves.
It can be applied under the same conditions all the time. Further, even while the outer circumferential circular body 9 is stopped in the ring container by the locking means 1O for holding it, the application liquid can be similarly supplied. Figure 1 (&) shows the state before coating on the cylindrical body 7, and continuous coating work is performed on the outer circular body 9I.
It is preferable to start with the ring container stopped by the locking means 10.
昇降装置には外周円体9の載置台8が設けられ、外周円
体9を保持している。外周円体9は、円筒形状体と等し
い外径を有し、かつ外周が円形になっていれば、中空の
ものでも中空でないものでもよい。載置台8に保持され
た外周円体9の上側(第1図(a) ) Id、被塗布
基材としての円筒形状体7の内面に挿入、装着され、そ
の際に円筒形状体7と外周円体9の外周が連続した外周
面となるように、円筒形状体7の外壁厚みに等しい分だ
け外径が小さくなっている。但し、その部分はエンドレ
スになっている必要はない。The lifting device is provided with a mounting table 8 for the outer circular body 9, and holds the outer circular body 9. The outer circular body 9 may be hollow or non-hollow as long as it has the same outer diameter as the cylindrical body and has a circular outer periphery. The upper side of the outer circumferential body 9 held on the mounting table 8 (FIG. 1(a)) Id is inserted and attached to the inner surface of the cylindrical body 7 as a substrate to be coated, and at that time, the cylindrical body 7 and the outer circumference The outer diameter is reduced by an amount equal to the outer wall thickness of the cylindrical body 7 so that the outer circumference of the circular body 9 forms a continuous outer circumferential surface. However, that part does not need to be endless.
外周円体9は、円筒形状体7の塗布完了後に外周円体9
Iと同じ状態に々るから、その下側(第1図(a))も
上述した上側と同様の構造を有している必要がめる0外
周円体9の両側は既述した構造のものに限られることは
なく、円筒形状体に挿入したときその内面に拡張バネ方
式で装着するようにしてもよい。載置台8は、外周円体
9を保持するものである。従って、載置台8は第1図(
&)で示すように外周円体9の下側の外径よシも僅かに
大きい内径の円筒体とする(外径は任意でるる。)
また、載置台の別の例は、外周円体9の内径より僅かに
小さい外径の円筒体または円柱体であるとともできる。The outer circumferential circular body 9 is formed after the application of the cylindrical body 7 is completed.
Since it is in the same state as I, its lower side (Fig. 1(a)) must also have the same structure as the upper side described above.Both sides of the outer circular body 9 have the structure described above. The present invention is not limited to this, and when inserted into a cylindrical body, it may be attached to the inner surface of the body using an expansion spring method. The mounting table 8 holds the outer circular body 9. Therefore, the mounting table 8 is as shown in Fig. 1 (
As shown by &), the outer diameter of the lower side of the outer circular body 9 is also a cylindrical body with a slightly larger inner diameter (the outer diameter can be set arbitrarily). It can also be a cylindrical body or a cylindrical body with an outer diameter slightly smaller than the inner diameter of 9.
昇降装置は、一定速度で昇降する手段を備えている。昇
降の手段については公知の方法でよく、モーターによる
もの、油圧シリンダー、空気圧シリンダー等によるもの
でよい。The lifting device includes means for lifting and lowering at a constant speed. The means for raising and lowering may be any known method, such as a motor, a hydraulic cylinder, a pneumatic cylinder, or the like.
第1図(、)に2いて、上昇した円筒形状体7に係止手
段10によシ保持されている外周円体9Iが装着される
。装着と同時もしくはその後に係止手段lOは、外周円
体9Tの保持を解除するようKそれから離間される。円
筒形状体7は、一定速度で上昇を続けながら塗布される
(第1図(b))。At 2 in FIG. 1(,), the outer circular body 9I held by the locking means 10 is attached to the raised cylindrical body 7. Simultaneously with or after mounting, the locking means 1O is separated from the outer circumferential body 9T so as to release its holding. The cylindrical body 7 is applied while continuing to rise at a constant speed (FIG. 1(b)).
外周円体9が第1図(a)の外周円体9・の位置に来た
とき昇降装置の上昇が停止され、同時に係止手段10が
作動して外周円体9を保持する(第1図(C))。When the outer circular body 9 reaches the position of the outer circular body 9 in FIG. Figure (C)).
円筒形状体9は、その上の外周円体9Iからの塗液の流
れがあり、それらが連続的な外周面を形成しているから
、全長にわたって均一な膜厚の塗布が可能でろる。Since the cylindrical body 9 has a flow of coating liquid from the outer circular body 9I above it and forms a continuous outer circumferential surface, it is possible to coat the cylindrical body 9 with a uniform film thickness over the entire length.
一方、塗布が完了した円筒形状体7は、排出手段として
の昇降装置11によって、外周円体9′とともに排出さ
れ、また載置台8を有する昇降手段は次の円筒形状体の
準備に下降する(第1図(C))。排出手段は公知のも
のでよい◎第2図は、係止手段10について、第1図(
b)の上方から見た断面図でめp1係止手段が4つのも
のを示している0係止手譚は少なくとも2つめればよい
。On the other hand, the cylindrical body 7 that has been coated is discharged together with the outer circular body 9' by the elevating device 11 serving as a discharging means, and the elevating means having the mounting table 8 is lowered to prepare the next cylindrical body ( Figure 1 (C)). The ejection means may be of any known type. ◎ Fig. 2 shows the locking means 10 compared to Fig. 1 (
In the sectional view seen from above in b), there are four locking means (0 locking means), but it is sufficient to have at least two locking means.
載置台8、外周円体9、係止手段10の材質は、金属、
プラスチックス等任意のものでよい。The materials of the mounting table 8, the outer circular body 9, and the locking means 10 are metal,
Any material such as plastic may be used.
外周円体は塗膜を除去して再使用できる。昇降装置の昇
降、係止手段の作動などを公知の検知手段を用いること
によって、自動的に連続塗布することができる。The outer circle can be reused by removing the paint film. Continuous coating can be performed automatically by using known detection means for raising and lowering the lifting device, operating the locking means, etc.
本発明の塗布装置を用いて塗布される液の粘度は、広い
範囲にわたって選択することができるが通常は0.5〜
1,000センチボイズ(OP)程度、好ましくは1〜
5000Fである。The viscosity of the liquid applied using the coating device of the present invention can be selected over a wide range, but is usually 0.5 to
Approximately 1,000 centivoise (OP), preferably 1~
It is 5000F.
第1図に示す塗布装置のリング状液体容器を使用し、1
16111のアルミニウム管(長さ33m)の外周面上
へ下記処方の分散液を塗布した〇塗布速度I Q NI
L / secで既述した方法により連続的に30本の
アルミニウム管に塗布し乾燥した。塗膜厚みは20μm
でめった。塗布液供給管1からは3 d7 secで常
時送液した・乾燥後に電位を測定したところ、円周方向
および長さ方向に2いて2%以内の電位のフレがあるだ
けでsb、多数の円筒形状体について同じ品質が再現性
よく確保できることが確認された。Using the ring-shaped liquid container of the coating device shown in Fig. 1,
A dispersion liquid with the following formulation was applied onto the outer peripheral surface of a 16111 aluminum pipe (length 33 m). Coating speed I Q NI
L/sec was applied continuously to 30 aluminum tubes by the method described above and dried. Coating film thickness is 20μm
I failed. The coating liquid was constantly fed from the coating liquid supply pipe 1 at a rate of 3 d7 sec. When the potential was measured after drying, there was only a variation in potential within 2% in the circumferential direction and length direction. It was confirmed that the same quality could be ensured with good reproducibility for the shaped bodies.
CF) 発明の効果
本発明によれば、円筒形状体の全長にわたって極めて均
斉な塗布層を形成することができる〇また外周円体2よ
びその係止手段の採用によって、昇降手段と排出手段の
動作を分離して確実で能率のよい連続塗布が可能になり
、且つ塗布液の連続供給も可能になった。CF) Effects of the Invention According to the present invention, an extremely uniform coating layer can be formed over the entire length of the cylindrical body. Also, by employing the outer circumferential circular body 2 and its locking means, the operation of the elevating means and the discharging means is controlled. It has become possible to separate reliable and efficient continuous coating, and it has also become possible to continuously supply the coating liquid.
第1図(a)〜(、)は、本発明に2ける塗布装置の一
具体例を用いて塗布している状態を示す主要部の断面図
である〇
第2図は、係止手段の一具体例を示す正断面図でめる◎
l・・・・・・塗布液供給管
2・・・・・・貯 赦 槽
3・・・・・・連通管
4・・・・・・リング塗布容器
5・・・・・・オーバーフロー管
6・・・・・・ロ ツ・ ド
ア・・・・・・円筒形状体
8・・・・・・載置台
9及び9″・・・・・・外周円体
10・・・・・・係止手段
11・・・・・・排出手段
館1聞Figures 1 (a) to (,) are cross-sectional views of the main parts showing a state in which coating is performed using a specific example of the coating device according to the second aspect of the present invention. Figure 2 shows the locking means. A front sectional view showing a specific example is shown below. ◎ l...Coating liquid supply pipe 2...Storage tank 3...Communication pipe 4...Ring Coating container 5... Overflow pipe 6... Rotsu door... Cylindrical body 8... Placement table 9 and 9''... Outer circumference circular body 10...Locking means 11...Ejection means building 1
Claims (2)
の昇降手段、昇降手段に設けられた外周円体の載置台お
よび外周円体の外周を保持する係止手段を含み、外周円
体の両側は円筒形状体の内面に装着したとき連続的な外
周面を形成する構造を有していることを脣峨とするリン
グ塗布法に用いる塗布装置。(1) A lifting means for raising a cylindrical body as a substrate to be coated, a mounting table for the outer circular body provided in the lifting means, and a locking means for holding the outer circumference of the outer circular body, A coating device used in a ring coating method having a structure in which both sides of the ring form a continuous outer circumferential surface when attached to the inner surface of a cylindrical body.
求の範囲第1項記載の塗布装置。(2) The coating device according to claim 1, further comprising means for overflowing the coating liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10137084A JPS60244363A (en) | 1984-05-18 | 1984-05-18 | Coating apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10137084A JPS60244363A (en) | 1984-05-18 | 1984-05-18 | Coating apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60244363A true JPS60244363A (en) | 1985-12-04 |
| JPH043271B2 JPH043271B2 (en) | 1992-01-22 |
Family
ID=14298929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10137084A Granted JPS60244363A (en) | 1984-05-18 | 1984-05-18 | Coating apparatus |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60244363A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58132569U (en) * | 1982-03-02 | 1983-09-07 | 三菱化学株式会社 | Coating equipment |
-
1984
- 1984-05-18 JP JP10137084A patent/JPS60244363A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58132569U (en) * | 1982-03-02 | 1983-09-07 | 三菱化学株式会社 | Coating equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH043271B2 (en) | 1992-01-22 |
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