JPS6025514B2 - 延性ある光沢性亜鉛メッキ用光沢剤 - Google Patents
延性ある光沢性亜鉛メッキ用光沢剤Info
- Publication number
- JPS6025514B2 JPS6025514B2 JP54047161A JP4716179A JPS6025514B2 JP S6025514 B2 JPS6025514 B2 JP S6025514B2 JP 54047161 A JP54047161 A JP 54047161A JP 4716179 A JP4716179 A JP 4716179A JP S6025514 B2 JPS6025514 B2 JP S6025514B2
- Authority
- JP
- Japan
- Prior art keywords
- brightener
- mol
- polycondensate
- epihalohydrin
- galvanizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005246 galvanizing Methods 0.000 title description 9
- -1 2-hydroxypropyl group Chemical group 0.000 claims description 9
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000002168 alkylating agent Substances 0.000 claims description 5
- 229940100198 alkylating agent Drugs 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical group CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000000565 5-membered heterocyclic compounds Chemical class 0.000 claims description 2
- 150000000644 6-membered heterocyclic compounds Chemical class 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 238000009713 electroplating Methods 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000011630 iodine Chemical group 0.000 claims 1
- 229910052740 iodine Chemical group 0.000 claims 1
- 238000007747 plating Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 6
- 238000005804 alkylation reaction Methods 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000002152 alkylating effect Effects 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000003934 aromatic aldehydes Chemical class 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920002557 polyglycidol polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QWENRTYMTSOGBR-UHFFFAOYSA-N 1H-1,2,3-Triazole Chemical compound C=1C=NNN=1 QWENRTYMTSOGBR-UHFFFAOYSA-N 0.000 description 1
- PGARRYOTCVOJQR-UHFFFAOYSA-N 2-ethoxynaphthalen-1-ol Chemical compound C1=CC=CC2=C(O)C(OCC)=CC=C21 PGARRYOTCVOJQR-UHFFFAOYSA-N 0.000 description 1
- RQMWVVBHJMUJNZ-UHFFFAOYSA-N 4-chloropyridin-2-amine Chemical group NC1=CC(Cl)=CC=N1 RQMWVVBHJMUJNZ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- GKIPXFAANLTWBM-UHFFFAOYSA-N epibromohydrin Chemical compound BrCC1CO1 GKIPXFAANLTWBM-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US897979 | 1978-04-20 | ||
| US05/897,979 US4169771A (en) | 1978-04-20 | 1978-04-20 | Ductile bright zinc electroplating bath and process and additive therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54141345A JPS54141345A (en) | 1979-11-02 |
| JPS6025514B2 true JPS6025514B2 (ja) | 1985-06-18 |
Family
ID=25408744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54047161A Expired JPS6025514B2 (ja) | 1978-04-20 | 1979-04-17 | 延性ある光沢性亜鉛メッキ用光沢剤 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4169771A (fr) |
| JP (1) | JPS6025514B2 (fr) |
| AR (1) | AR220750A1 (fr) |
| AU (1) | AU526759B2 (fr) |
| BE (1) | BE875758A (fr) |
| BR (1) | BR7902419A (fr) |
| CA (1) | CA1121098A (fr) |
| DE (1) | DE2914866C2 (fr) |
| ES (1) | ES8205886A1 (fr) |
| FR (1) | FR2423557A1 (fr) |
| GB (1) | GB2020298B (fr) |
| HK (1) | HK66186A (fr) |
| IT (1) | IT1164112B (fr) |
| MX (1) | MX152324A (fr) |
| NL (1) | NL7903138A (fr) |
| SE (1) | SE7903446L (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4397717A (en) * | 1981-02-10 | 1983-08-09 | Elektro-Brite Gmbh & Co. Kg. | Alkaline zinc electroplating bath with or without cyanide content |
| US4536261A (en) * | 1984-08-07 | 1985-08-20 | Francine Popescu | Alkaline bath for the electrodeposition of bright zinc |
| US4730022A (en) * | 1987-03-06 | 1988-03-08 | Mcgean-Rohco, Inc. | Polymer compositions and alkaline zinc electroplating baths |
| US5182006A (en) * | 1991-02-04 | 1993-01-26 | Enthone-Omi Inc. | Zincate solutions for treatment of aluminum and aluminum alloys |
| US5435898A (en) * | 1994-10-25 | 1995-07-25 | Enthone-Omi Inc. | Alkaline zinc and zinc alloy electroplating baths and processes |
| US5578187A (en) * | 1995-10-19 | 1996-11-26 | Enthone-Omi, Inc. | Plating process for electroless nickel on zinc die castings |
| GB2344069B (en) * | 1998-07-27 | 2002-05-15 | Eastman Kodak Co | Imaging and printing methods to form fingerprint protected imaging member |
| US6143160A (en) * | 1998-09-18 | 2000-11-07 | Pavco, Inc. | Method for improving the macro throwing power for chloride zinc electroplating baths |
| WO2005093132A1 (fr) * | 2004-03-04 | 2005-10-06 | Taskem, Inc. | Agent de brillance polyamine |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3954575A (en) * | 1972-11-10 | 1976-05-04 | Dipsol Chemicals Co., Ltd. | Zinc electroplating |
| US3853718A (en) * | 1973-01-05 | 1974-12-10 | Oxy Metal Finishing Corp | Method to improve zinc deposition employing multi-nitrogen quaternaries |
| JPS5332771B2 (fr) * | 1973-12-10 | 1978-09-09 | ||
| US3972789A (en) * | 1975-02-10 | 1976-08-03 | The Richardson Company | Alkaline bright zinc plating and additive composition therefore |
| DE2525264C2 (de) * | 1975-06-04 | 1984-02-16 | Schering AG, 1000 Berlin und 4709 Bergkamen | Alkalisches cyanidfreies Zinkbad und Verfahren zur galvanischen Abscheidung von Zinküberzügen unter Verwendung dieses Bades |
| US4188271A (en) * | 1975-12-15 | 1980-02-12 | Rohco, Inc. | Alkaline zinc electroplating baths and additive compositions therefor |
-
1978
- 1978-04-20 US US05/897,979 patent/US4169771A/en not_active Expired - Lifetime
-
1979
- 1979-04-12 DE DE2914866A patent/DE2914866C2/de not_active Expired
- 1979-04-16 AR AR276193A patent/AR220750A1/es active
- 1979-04-17 MX MX177330A patent/MX152324A/es unknown
- 1979-04-17 JP JP54047161A patent/JPS6025514B2/ja not_active Expired
- 1979-04-18 AU AU46180/79A patent/AU526759B2/en not_active Expired
- 1979-04-18 CA CA000325734A patent/CA1121098A/fr not_active Expired
- 1979-04-18 IT IT48769/79A patent/IT1164112B/it active
- 1979-04-18 FR FR7909796A patent/FR2423557A1/fr active Granted
- 1979-04-19 BR BR7902419A patent/BR7902419A/pt unknown
- 1979-04-19 SE SE7903446A patent/SE7903446L/ not_active Application Discontinuation
- 1979-04-19 ES ES479750A patent/ES8205886A1/es not_active Expired
- 1979-04-19 GB GB7913601A patent/GB2020298B/en not_active Expired
- 1979-04-20 BE BE0/194760A patent/BE875758A/fr not_active IP Right Cessation
- 1979-04-20 NL NL7903138A patent/NL7903138A/xx not_active Application Discontinuation
-
1986
- 1986-09-11 HK HK661/86A patent/HK66186A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES479750A0 (es) | 1982-06-16 |
| NL7903138A (nl) | 1979-10-23 |
| ES8205886A1 (es) | 1982-06-16 |
| BR7902419A (pt) | 1979-10-23 |
| CA1121098A (fr) | 1982-03-30 |
| HK66186A (en) | 1986-09-18 |
| AU4618079A (en) | 1979-10-25 |
| FR2423557A1 (fr) | 1979-11-16 |
| AU526759B2 (en) | 1983-01-27 |
| JPS54141345A (en) | 1979-11-02 |
| GB2020298B (en) | 1983-02-02 |
| IT1164112B (it) | 1987-04-08 |
| DE2914866A1 (de) | 1979-10-25 |
| AR220750A1 (es) | 1980-11-28 |
| GB2020298A (en) | 1979-11-14 |
| SE7903446L (sv) | 1979-10-21 |
| IT7948769A0 (it) | 1979-04-18 |
| FR2423557B1 (fr) | 1983-06-03 |
| US4169771A (en) | 1979-10-02 |
| DE2914866C2 (de) | 1982-06-09 |
| MX152324A (es) | 1985-06-27 |
| BE875758A (fr) | 1979-10-22 |
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