JPS60262937A - Aluminum alloy for photosensitive drum having superior suitability to vapor deposition of amorphous silicon - Google Patents
Aluminum alloy for photosensitive drum having superior suitability to vapor deposition of amorphous siliconInfo
- Publication number
- JPS60262937A JPS60262937A JP11943684A JP11943684A JPS60262937A JP S60262937 A JPS60262937 A JP S60262937A JP 11943684 A JP11943684 A JP 11943684A JP 11943684 A JP11943684 A JP 11943684A JP S60262937 A JPS60262937 A JP S60262937A
- Authority
- JP
- Japan
- Prior art keywords
- amorphous silicon
- aluminum alloy
- vapor deposition
- photosensitive drum
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910021417 amorphous silicon Inorganic materials 0.000 title claims abstract description 21
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 17
- 238000007740 vapor deposition Methods 0.000 title claims abstract description 6
- 239000012535 impurity Substances 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 abstract description 4
- 239000000956 alloy Substances 0.000 abstract description 4
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 238000003754 machining Methods 0.000 abstract description 2
- 230000008021 deposition Effects 0.000 description 13
- 239000000463 material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 108091008695 photoreceptors Proteins 0.000 description 2
- 229910018084 Al-Fe Inorganic materials 0.000 description 1
- 229910021365 Al-Mg-Si alloy Inorganic materials 0.000 description 1
- 229910018192 Al—Fe Inorganic materials 0.000 description 1
- 229910019064 Mg-Si Inorganic materials 0.000 description 1
- 229910019406 Mg—Si Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Photoreceptors In Electrophotography (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野1
本発明はアモルファスシリコン蒸着性に優れた感光ドラ
ム用アルミニウム合金に関し、さらに詳しくは、Al−
Mg−Si合金にZnを微量含有させることにより、不
純物含有量の規制をゆるくすることができ、かつ、精密
切削時の表面仕上り性およびアモルファスシリコンの蒸
着性を改善した感光ドラム用のアルミニウム合金に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field 1] The present invention relates to an aluminum alloy for photosensitive drums that has excellent amorphous silicon deposition properties, and more specifically,
Relating to an aluminum alloy for photosensitive drums in which regulations on impurity content can be loosened by containing a small amount of Zn in an Mg-Si alloy, and the surface finish during precision cutting and the deposition of amorphous silicon are improved. .
[従来技術1
従来において、電子写真用感光体の光導電材料としては
、Se、CdS、Zn○、有機感光体(OPC)等が、
その特性、用途を考慮して使用されてきているが、近年
になって、アモルファスシリコンの使用が注目されるよ
うになってきた。[Prior Art 1 Conventionally, photoconductive materials for electrophotographic photoreceptors include Se, CdS, Zn○, organic photoreceptor (OPC), etc.
Amorphous silicon has been used in consideration of its characteristics and uses, but in recent years, the use of amorphous silicon has been attracting attention.
その理由は、このアモルファスシリコンは従来材に比較
して、耐熱性、耐摩耗性、環境汚染性等において優れた
特性を有しているからでかる。The reason for this is that this amorphous silicon has superior properties such as heat resistance, wear resistance, and environmental pollution resistance compared to conventional materials.
しかしながら、アモルファスシリコンは成膜速度が遅い
こと等の理由から、蒸着膜厚が15〜20μlと従来の
Se、CdS等の40〜70.1711に比較して薄く
、また、アモルファスシリコンの表面硬度が高いために
基盤の影響を受け易く、従来の基盤よりさらに高精度の
表面が要求されるようになってきている。However, due to the slow deposition rate of amorphous silicon, the evaporated film thickness is 15 to 20 μl, which is thinner than that of conventional Se, CdS, etc., which is 40 to 70.1711 μl, and the surface hardness of amorphous silicon is low. Due to its high height, it is easily affected by the substrate, and a surface with even higher precision than the conventional substrate is required.
即ち、例えば、幾何学的な表面粗さは従来よす1段高い
精度が必要であり、一つの目標としてRmax= 0
、05μ−の表面仕上りが要求され、また、切削時に基
盤表面に形成される加工変質層も膜特性に影響するとし
て、その程度の低いことが要求される。このため、通常
の切削では満足する表面が得られないため、天然ダイア
モンド工兵を使用して特殊な精密旋盤により11面を得
ているのが現状である。That is, for example, geometric surface roughness requires a level of precision higher than that of conventional methods, and one goal is to set Rmax = 0.
A surface finish of 0.05μ- is required, and a process-affected layer formed on the substrate surface during cutting is also required to be of a low level since it affects the film properties. For this reason, it is not possible to obtain a satisfactory surface by ordinary cutting, so at present 11 surfaces are obtained using a special precision lathe using natural diamond sappers.
また、基盤材料としては従来より、一般にアルミニウム
合金が使用されており、主に、JIS3003およびJ
ISA6063合金が多用されてきているが、これらの
材料においては、マトリックス中に微細に分散した多数
の金属間化合物が存在し、このため、切削時の表面粗さ
を充分満足することが困難であった。In addition, aluminum alloys have conventionally been generally used as base materials, mainly in accordance with JIS3003 and JIS.
ISA6063 alloy has been widely used, but these materials have a large number of finely dispersed intermetallic compounds in the matrix, making it difficult to achieve sufficient surface roughness during cutting. Ta.
また、アモルファスシリコン蒸着用感光ドラム用のアル
ミニウム合金としては、いままでは、不純物含有量を極
端に規制したAl−Mg−Si合金(例えば、99,9
9wt%A1をベースとしたJISA6063合金)が
用いられていたが、高純度地金のために素材コストが極
めて高いという欠点があった。Furthermore, as aluminum alloys for photosensitive drums for amorphous silicon deposition, Al-Mg-Si alloys with extremely restricted impurity content (for example, 99,9
JISA6063 alloy (based on 9wt% A1) was used, but it had the disadvantage that the material cost was extremely high due to the high purity metal.
[発明が解決しようとする問題点]
本発明は上記に説明したような、従来使用されてきてい
る感光ドラム用のアルミニウム合金の欠点および問題点
を解消すべくなされたものであり、アモルファスシリコ
ンの蒸着性に極めて優れ、かつ、表面仕上り性に優れて
いる、アモルファスシリコン蒸着性に優れた感光ドラム
用アルミニウム合金を提供することにある。[Problems to be Solved by the Invention] The present invention has been made to solve the above-mentioned drawbacks and problems of the conventionally used aluminum alloy for photosensitive drums. It is an object of the present invention to provide an aluminum alloy for photosensitive drums which has extremely excellent vapor deposition properties and excellent surface finishing properties, and is excellent in amorphous silicon vapor deposition properties.
1問題点を解決するための手段1
本発明に係るアモルファスシリコン蒸着性に優れた感光
ドラム用アルミニウム合金の特徴とするところは、
Si 0.2−1,0wt%(0,2wt%、1.0w
t%を含まず)、Mg O,1−1,5wt%(1,5
wt%を含1ず)、Zn O,05−1,0wt%(1
,0wt%を含まず)を含有し、不純物として、
Fe O,35wL%以下、Mn 0010wt%以下
、Cr O,10wt%以下
に規制し、残部A1よりなることにある。1 Means for Solving Problem 1 The aluminum alloy for photosensitive drums having excellent amorphous silicon deposition properties according to the present invention is characterized by: Si 0.2-1.0 wt% (0.2 wt%, 1.0 wt%) 0w
t%), MgO, 1-1,5 wt% (1,5
(wt% not included), ZnO,05-1,0wt% (1
, 0 wt%), and the impurities are restricted to Fe 2 O, 35 wt% or less, Mn 0,0010 wt% or less, Cr 2 O, 10 wt% or less, and the remainder consists of A1.
本発明に係るアモルファスシリコン蒸着性に優れた感光
ドラム用アルミニウム合金について詳細に説明する。The aluminum alloy for photosensitive drums having excellent amorphous silicon deposition properties according to the present invention will be described in detail.
先ず、本発明に係るアモルファスシリコン蒸着性に優れ
た感光ドラム用アルミニウム合金の含有成分および成分
割合について説明する。First, the components and component ratios of the aluminum alloy for photosensitive drums having excellent amorphous silicon deposition properties according to the present invention will be explained.
Si、Mgは強度を向上させるための必須の元素であり
、切削加工時の撓み等による寸法精度等不良防止に必要
な強度を付与するものであり、Si含有量が0.2wt
%未満、Mg含有量が0,1wt%未満ではこの効果が
充分ではなく、また、Sil、0wt%、MB 1.5
wt%を夫々越えて含有されると、MB2Siの晶出物
を作り易くなるため切削面積度Rmax5/100μ−
以下を満足することかで外ない。よって、Si含有量は
0.2〜1.0wt%(0,2wL%、1、Oat%を
含まず)、Mg含有量は0.1−1.5mt%(1゜5
wt%を含まず)とする。Si and Mg are essential elements for improving strength, and they provide the strength necessary to prevent defects such as dimensional accuracy due to bending during cutting, and the Si content is 0.2wt.
%, Mg content is less than 0.1 wt%, this effect is not sufficient, and Sil, 0 wt%, MB 1.5
If the content exceeds each wt%, it becomes easy to form crystallized MB2Si, so the cutting area degree Rmax5/100μ-
All you have to do is satisfy the following. Therefore, the Si content is 0.2 to 1.0 wt% (not including 0.2 wL%, 1, Oat%), and the Mg content is 0.1 to 1.5 mt% (1°5
(wt% not included).
Znは低融点金属であり、切削時に潤滑効果により表面
仕上り性を改善する効果が著しく、がっ、工具のチッピ
ングを起り難くする元素であり、含有量が0,05wt
%未満ではこの効果が充分でなく、また、1,0wt%
を越えて含有されると耐蝕性を劣化させる。よって、Z
n含有量は0.05〜1,0wt%(1,0wt%は含
まず)とする。Zn is a low melting point metal that has a remarkable effect of improving surface finish through lubrication during cutting, and is an element that makes it difficult for tools to chip, with a content of 0.05wt.
If it is less than 1.0 wt%, this effect is not sufficient, and if it is less than 1.0 wt%
If the content exceeds this amount, corrosion resistance will deteriorate. Therefore, Z
The n content is 0.05 to 1.0 wt% (excluding 1.0 wt%).
Fe、Mn、 Crは結晶粒微細化のため1こ含有させ
ることがあるが、含有量がFe O,35wt%、Mn
O,10wt%、Cr 0.10wt%を夫々越えると
A I 7 Cr、Al−Fe系、A16(MnFe)
等の晶出物の量および寸法共に大きくなり切削面精度を
悪化させる。よって、Fe含有量0,35wt%以下、
Mn含有量 0.10wt%以下、Cr含有量0.10
wt%以下に規制する必要がある。Fe, Mn, and Cr may be included in one quantity to refine grains, but the content is FeO, 35wt%, Mn
When O, 10 wt% and Cr exceed 0.10 wt%, respectively, A I 7 Cr, Al-Fe system, A16 (MnFe)
Both the amount and size of crystallized substances increase, deteriorating the precision of the cut surface. Therefore, the Fe content is 0.35 wt% or less,
Mn content 0.10wt% or less, Cr content 0.10
It is necessary to regulate it below wt%.
上記の含有成分以外に、鋳塊の結晶粒微細化のためにT
iを0.03wt%以下含有させることは許容される。In addition to the above-mentioned ingredients, T is added for grain refinement of the ingot.
It is permissible to contain 0.03 wt% or less of i.
[実施例1
次に、本発明に係るアモルファスシリコン蒸着性に優れ
た感光ドラム用アルミニウム合金の実施例を説明する。[Example 1] Next, an example of an aluminum alloy for photosensitive drums having excellent amorphous silicon deposition properties according to the present invention will be described.
実施例
第1表に示す含有成分および成分割合のアルミニウム合
金を常法に従って溶解し、200φの鋳塊に舞遺し、5
20℃の温度で4時間の灼熱処理を行なった後、押出お
よび抽伸加工により直径123mm、肉厚4.8+mの
管を作成し供試材とした。Example An aluminum alloy having the components and proportions shown in Table 1 was melted according to a conventional method, poured into a 200φ ingot, and
After performing a scorching treatment at a temperature of 20° C. for 4 hours, a tube with a diameter of 123 mm and a wall thickness of 4.8+ m was prepared by extrusion and drawing and used as a test material.
◎切削条件は次の通りである。◎Cutting conditions are as follows.
(1)粗切削(NC旋盤)
工具:焼結ダイアモンド工兵(市販品)切削速度: 6
00m/sin
切込:0.25u+
送り 二0.11II+1/rev
(2)仕上切削(超精密旋盤)
工14::天然ダイアモンド製工兵(市販品)切削速度
: 600+/win
切込: 0,01 S−輸
送り : 0.03mm/rev
切削した全長30011Imの製品の中央部で表面粗さ
計により最大粗さくRmax)をめその結果を第1表に
示す。(1) Rough cutting (NC lathe) Tool: Sintered diamond engineer (commercial product) Cutting speed: 6
00m/sin Depth of cut: 0.25u+ Feed 20.11II+1/rev (2) Finish cutting (ultra-precision lathe) Machining 14: Natural diamond engineer (commercial product) Cutting speed: 600+/win Depth of cut: 0.01 S-Transportation: 0.03 mm/rev Table 1 shows the maximum roughness (Rmax) determined by a surface roughness meter at the center of the cut product with a total length of 30011 Im.
切削した後アモルファスシリコンの蒸着を行ないテープ
テストにより蒸着性を判定した結果を第1表に示す。After cutting, amorphous silicon was deposited, and the deposition properties were determined by a tape test. Table 1 shows the results.
この第1表から、本発明に係るアモルファスシリコン蒸
着性に優れた感光ドラム用アルミニウム合金は、切削表
面仕上り精度Re+axO,05μ−以下を容易に得る
ことができ、さらに、切削後のアモルファスシリコン蒸
着性についても、テープテストの結果剥離せず優れた蒸
着性が得られた。From this Table 1, it is clear that the aluminum alloy for photosensitive drums according to the present invention, which has excellent amorphous silicon deposition properties, can easily obtain a cutting surface finish accuracy of Re+axO,05 μ- or less, and also has amorphous silicon deposition properties after cutting. Also, as a result of the tape test, excellent vapor deposition properties were obtained without peeling.
[発明の効果1
以上説明したように、本発明に係るアモルファスシリコ
ン蒸着性に優れた感光ドラム用アルミニウム合金は上記
の構成を有しているものであるから、精密切削時の表面
仕上り性が極めて良好であり、かつ、アモルファスシリ
コン蒸着性が極めて優れている感光ドラム用のアルミニ
ウム合金である。[Effect of the invention 1 As explained above, since the aluminum alloy for photosensitive drums according to the present invention which has excellent amorphous silicon deposition properties has the above-mentioned structure, the surface finish during precision cutting is extremely high. This is an aluminum alloy for photosensitive drums that has excellent amorphous silicon deposition properties.
Claims (1)
%を含まず)、Mg O,1−1,5wt%(1,5w
t%を含まず)、Zn O,05−1,ht%(1,O
mt%を含まず)を含有し、不純物として、 Fe O,35wt%以下、Mn O,10wt%以下
、Cr O,10wt%以下 に規制し、残部A1よりなることを特徴とするアモルフ
ァスシリコン蒸着性に優れた感光ドラム用アルミニウム
合金。[Claims] SiO,2-1,0wt% (0,2wt%, 1.kt
%), Mg O, 1-1,5wt% (1,5w
(excluding t%), ZnO,05-1,ht% (1,O
Amorphous silicon vapor deposition property characterized by containing impurities FeO, 35wt% or less, MnO, 10wt% or less, CrO, 10wt% or less, and the balance being A1. Aluminum alloy for photosensitive drums with excellent properties.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11943684A JPS60262937A (en) | 1984-06-11 | 1984-06-11 | Aluminum alloy for photosensitive drum having superior suitability to vapor deposition of amorphous silicon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11943684A JPS60262937A (en) | 1984-06-11 | 1984-06-11 | Aluminum alloy for photosensitive drum having superior suitability to vapor deposition of amorphous silicon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60262937A true JPS60262937A (en) | 1985-12-26 |
| JPS6232258B2 JPS6232258B2 (en) | 1987-07-14 |
Family
ID=14761371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11943684A Granted JPS60262937A (en) | 1984-06-11 | 1984-06-11 | Aluminum alloy for photosensitive drum having superior suitability to vapor deposition of amorphous silicon |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60262937A (en) |
-
1984
- 1984-06-11 JP JP11943684A patent/JPS60262937A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6232258B2 (en) | 1987-07-14 |
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