JPS60263151A - Treatment of silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To prevent yellow stains immediately after processing unexposed parts from increasing in stabilization treatment substantially free from a water rinse step by processing a photosensitive material, after a fixing step, and bringing a stabilizing soln. into contact with a specified substance during this stabilization treatment. CONSTITUTION:After a step for fixing the photosensitive material, the stabilization treatment is directly executed substantially without a water rinse step. In this treatment, the stabilization soln. is brought into contact with at least one of the following substances; activated carbon, clay, polyamide type resins, polyurethane type resins, phenol type resins, epoxy resins, polymers having hydrazide groups, polymers contg. polytetrafluoroethylene, and a copolymer of univalent - multivalent alcohol methacrylate monoester-polyalcohol methacrylate polyester. The stabilizing soln. is kept in a pH of 3.2-8.9 and if it is kept out of this range, removal of these stains become extremely difficult.

Description

Detailed Description of the Invention (Industrial Application Field) The present invention relates to a method for processing silver halide color photographic light-sensitive materials (hereinafter abbreviated as light-sensitive materials), and particularly relates to a method for processing silver halide color photographic materials (hereinafter referred to as light-sensitive materials), and in particular, a method for stabilizing silver halide color photographic materials (hereinafter abbreviated as light-sensitive materials) without the need for a washing step following a desilvering step. Regarding processing method.

[Prior art]

In recent years, environmental conservation and water resource issues have become important in photofininers, which automatically and continuously process photosensitive materials. It is desired to reduce or eliminate the large amount of washing water used. For this reason, after processing with fixer or bleach-fixer, do not wash with water.
! A technique for stabilizing the contact has been proposed. For example, JP-A-57-8542, JP-A-57-132146, JP-A-57
No. 14834 and No. 58-18631 describe a technique of processing with a stabilizing solution containing an inteazoline conductor, a pentwinthiazoline conductor, a soluble iron complex salt, a polycarboxylic acid, and an organic phosphonic acid.

These techniques relate to methods for suppressing or preventing problems caused by fixing or bleach-fixing components introduced by photosensitive materials into the stabilizing solution; It has been found that if the processing is carried out continuously over a long period of time when the amount of photosensitive material is small, a stain (% yellow stain) is generated after processing due to eluates from the photosensitive material.

Therefore, there is a strong desire for a low-pollution, economical treatment method that does not have these drawbacks.

[Purpose of the invention]

The first object of the present invention is to process a photosensitive material in which yellow stain does not increase in the stain percentage of unexposed areas immediately after processing even if continuous processing is performed over a long period of time in stabilization processing that does not substantially require a water washing step. K provides a method, the second
The purpose of this is to reduce the amount of replenishment of the stabilizer by removing the stain components in the stabilizer, and to provide a method that can be reused. To provide a processing method with improved storage durability.

(Summary of the Invention) As a result of intensive research, the present inventors have developed a photosensitive material with a standard 7I
In a method of directly performing a stabilizing treatment without substantially a water washing step following a treatment step with r north, the stabilizing solution is brought into contact with at least one of the substances shown in (a) to (1) below. The inventors have discovered that the above object can be achieved by processing the above-mentioned materials, leading to the present invention.

(Contact substance) (al activated carbon (b) ft!i earth substance fc) polyamide-based product molecular compound kl) -triurethane-based polymer compound (, +7.nol resin (f) epoxy resin (g) hydra, 'do group A polymer compound (hl
Polymer compound containing polytetrafluoroethylene (111-hydric or polyhydric alcohol methacrylic monoester-polyhydric alcohol methacrylic polyester copolymer) In a preferred embodiment of the present invention, the auto-flow liquid of the stabilizing liquid and the above ( After contacting the substances shown in a) to (1), at least a part of the substance is reused as a stabilizing liquid, and the stabilizing liquid is treated in steps 32 to 8.9. It has been found that the above objective can be achieved more effectively by including K, a chelating agent and/or an ammonium compound in the stabilizing solution.

[Structure of the invention]

The present invention will be explained in detail below.

In conventional processing, most of the components such as dyes eluted from the light-sensitive material are washed away because the final step is washing with water, and the material is thoroughly washed.

However, in a method in which the water washing step is removed and the image is stabilized by stabilization treatment, the components eluted from these light-sensitive materials and the components brought in from the pre-bath are added to the Kl in the stabilizing solution.
Some of them are adsorbed onto photosensitive materials, causing stains and other contamination.

As a result of extensive research, the inventors of the present invention found that the causes of such staining are the things shown in (a) to (i) above.
It has been discovered that this can be completely prevented by bringing jk (hereinafter referred to as the substance of the present invention 5) into contact with a stabilizing solution. The present invention can be carried out using the final process treatment solution in
It was a surprising discovery that the effect is more fully exhibited and that the substance of the present invention acts extremely effectively against contamination caused by eluates from photosensitive materials.

The replenishment amount of the stabilizing solution of the present invention in continuous processing is extremely effective when it is less than 30 sheets per 100 Qll of photographic material to be processed, and more effective JK processing is achieved when it is less than 20 times. The stability of the stabilizer is closely related to the efficiency of adsorption and removal of contaminants eluted from photosensitive materials, and is preferably L-<? , l p
i(:(, 2 to 89). If βl is less than 32 or -1 exceeds 89, it will be extremely difficult to remove the stain even if the substance of the present invention and the stabilizing solution are brought into contact Δ.

The particularly preferred pH of the stabilizing solution is 35 to 8.5, and the most preferred pH of the stabilizing solution is 42 to 80.

The activated carbon (a) in the substance of the present invention may be any activated carbon having adsorption ability. Unfavorable raw materials for activated carbon: sawdust, coconut shell, lignin, cow bone, blood, lignite,
Any of carbon charcoal, peat, filtered charcoal, etc. may be used. Although powdered activated carbon and granular activated carbon are available in terms of form, the present invention may use either of them. K manufactures powdered activated carbon
After pulverizing the raw material, it is activated by carbonizing it under high heat.

In some cases, activation can be carried out by passing water vapor under high heat, or by soaking in a solution of zinc chloride, phosphoric acid, sulfuric acid, alkali, etc., followed by firing and carbonization. Other methods include igniting the charcoal under paper pressure, or heating it in air, carbon dioxide, or chlorine gas to oxidize and activate a portion of the charcoal. Activated products are usually washed to remove ash and chemicals.
It is crushed and dried to produce powdered activated carbon. Granular activated carbon is made by molding crushed charcoal powder into single-grain particles using tar, pitch, etc. as a binder, drying, sintering, and activating it.Also, when using coconut shells or coal, crush it. After separation, it is carbonized and activated under high heat to obtain granular activated carbon. In the present invention, any raw material or activation method can be used, and either powder or granular activated carbon can be used, preferably granular activated carbon, and particularly preferred are coconut shell activated carbon and activated carbon with molecular sieving ability. Here, the activated carbon having molecular sieving ability has slit-like pores, and the pore size is preferably 6A or more and the width is 15A or less. Regarding activated carbon having such molecular sieving ability, reference can be made to the contents published in HC of Japanese Patent Application Laid-Open No. 14831/1983 by the present applicant.

The clay material (b) in the unexploded lily material has silica and alumina as essential components and is a must! Inorganic materials containing other components depending on the material, such as silica gel, bettonite, activated clay, acid clay, kaolin, zeolite, etc., are included. Bentonite is a clay acid based on hydrous aluminum silicate whose main ore is montmorillonite.

Activated clay is a clay material whose main ore is montmorillonite...rosite. Acid clay is a similar clay material. Kaolin is a clay material consisting of naturally hydrated aluminum silicate. Fluorine group 6, such as zeolite, is a natural or synthetic fluorite, which is a clay material that has a uniform pore size and acts as a molecular sieve.

Other than zeodyte, there are soda 7 stones, chabasite, etc.

The polyamide-based polymer compound (C) in the substance of the present invention is a polymer having an acid amide bond such as 6-nylon, 6,6-nylon, 6,10-nylon, etc.

The polyurethane-based polymer compound (d) in the substance of the present invention has a urethane bond -NHOO in the repeating unit of the main chain.
It is a polymer compound with O-.

The phenolic resin (e) in the substance of the present invention is a resin obtained from phenols such as phenol, cresol, xylenol, and resorcin and aldehydes such as formaldehyde, acetaldehyde, and furfural, and modified resins thereof, preferably phenol. It is a formaldehyde resin, and commercially available products include, for example, Duolite S-761 resin manufactured by Sumitomo Chemical Co., Ltd.

Examples of the polymer compound (g) in the substance of the present invention that supports a hydrazide group include a sulfohydrazide group, a carbonylhydrazide group, and a methyl acrylate-divinylbenzene copolymer, a styrene-divinylbenzene copolymer, etc. It is a polymer compound added to.

In the substance of the present invention, (h) a polymer compound containing polytetrafluoroethylene, a mixture of polyethylene, polyglobylene, polypylene chloride, etc. and polytetrafluoroethylene or pure polytetrafluoroethylene is used, preferably. The content of polytetrafluoroethylene is 50% or more.

What kind of methacrylate copolymer is used as the monohydric or polyhydric alcohol methacrylic acid monoester that is the monohydric or polyhydric alcohol methacrylic acid monoester-polyhydric alcohol methacrylic acid polyester copolymer component in (1) in the substance of the present invention? Although a combination may be used, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, 2-hydroxy-ethyl methacrylate, 2-hydroxy-globil methacrylate, etc. are preferred. As the polyhydric alcohol methacrylic acid polyester for crosslinking, ethylene glycol dimethacrylate is most preferable, and polyethylene glycols such as diethylene glycol dimethacrylate and triethylene glycol dimethacrylate (n = 1 = 10
) Dimethacrylate is also preferred. Furthermore, trimethylolpronotrimethacrylate, pentaerythritol tetramethacrylate, etc. can also be used. Preferably, the porous methacrylate copolymer used has a composition of 10 to 90% by weight of monohydric or polyhydric alcohol methacrylic acid monoester. Among these, those containing 50% or less of polyhydric alcohol methacrylic acid polyester are preferred. Specifically, Amberlite XAD-7, 8, and 9 manufactured by Rohm and Haas Co., Ltd. are preferred.

Moreover, these substances of the present invention are preferably porous with a large surface state, and have a specific surface area of about 1 to 000n? /
A range of g is preferred and I! preferably 100 to 100
It has a specific surface area of 0♂/g. Further, the pore radius is preferably 4 to 200 OA.

Among the substances of the present invention, (a) activated carbon, (b) clay material, (
Particularly preferred are e) phenolic resins and (i) monohydric or polyhydric alcohol methacrylic acid monoester-polyhydric alcohol methacrylic acid polyester copolymers.

In order to help the stain prevention effect of the present invention, a chelating agent is used to suppress the occurrence of stain due to residual bleach-fixing components, and a chelating agent is used to reduce the surface density of the photosensitive material during the drying process.
The addition of ammonium compounds to the stabilizing solution to better prevent staining is preferred.

Preferred stabilizers that can be added to the stabilizer of the present invention
1111Kt'i, organic carboxylic acid chelating agents, organic phosphoric acid chelating agents, polyhydroxy compounds, and condensed phosphates, among which preferred chelating agents include ethylenediamine diorthohydroxyphenylacetic acid, nitrilotriacetic acid ER, and hydroquinoethylenediamine. Triacetic acid, diethylenetriaminepentaacetic acid, hydroxyethyliminodiacetic acid, diaminoglobanoltetraacetic acid, transcyclohexanediaminetetraacetic acid, ethylenediaminetetrakismethylenephosphonic acid, nitrilotrimethylenephosphonic acid, l-
Hydroxyethylidene-1,1'-diphosphonic acid, 1.
1'-diphosphonoethane-2-carboxylic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, l-hydroxy-1-phosphonoprono-1,2,3-tricarboxylic acid, catechol-3,5-disulfone acid, sodium birophosphate, sodium tetrapolyphosphate, and sodium hexametaphosphate, and for the effect of the present invention, VC%K
Ff is preferably diethylenetriaminepentaacetic acid, l-hydroxyethylidene-1,1'-diphosphonic acid, or salts thereof. These may be used alone or in combination of two or more. The amount of these chelating agents added is 0.01 per stabilizer solution + fi.
．． A range of 9-100g is preferred, F! preferably 0
．． The range is 1 to 50y.

In addition to the above-mentioned chelating agents, ammonium compounds are desirable compounds to be added to the stabilizing solution containing the compound of the present invention. These are supplied by ammonium salts of various inorganic compounds, including KFi ammonium hydroxide, ammonium bromide, ammonium carbonate, ammonium chloride, ammonium hypophosphite, ammonium phosphate, ammonium phosphite, and ammonium fluoride. , acidic ammonium fluoride, ammonium fluoroborate,
Ammonium arsenate, ammonium carbonate, ammonium hydrogen fluoride, ammonium hydrogen sulfate, ammonium sulfate, ammonium iodide, ammonium nitrate, ammonium pentaborate, ammonium acetate? ”, 7) e>$
7y-e='y''・7'''IJy)! I: ammonium a carboxylate, ammonium benzoate, ammonium carbamate, ammonium citrate, ammonium diethyldithiocarbamate, ammonium oxalate, ammonium hydrogen malate, ammonium hydrogen oxalate, ammonium hydrogen phthalate, ammonium hydrogen tartrate, lactic acid Ammonium, ammonium malate, ammonium maleate, ammonium oxalate, ammonium phthalate, ammonium picrate, ammonium pyrrolidine dithiocarbamate, ammonium salicylate, ammonium succinate, ammonium sulfanilate, ammonium tartrate, ammonium thioglycolate, 2, 4
．． 6-) +7 Nitrophenolammonium etc. These may be used alone or in combination of two or more.

For details of these ammonium addition techniques, reference may be made to the content described in Japanese Patent Application No. 58-58693 filed by the present applicant.

Furthermore, preferred compounds to be added to the stabilizing solution of the present invention include acetic acid, sulfuric acid, hydrochloric acid, nitric acid, sulfanilic acid, potassium hydroxide, sodium hydroxide, ammonium hydroxide, etc. , butyl hydroxybenzoate, antibiotics, tehydroacetic acid, potassium sorbate, thiapendazole, anti-inflammatory agents such as ortho-phenylphenol, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-octyl- 4-inthiazoline-
3-one, l,2-benzisothiazolin-3-one,
Preservatives such as water-soluble metal salts, dispersants such as ethylene glycol, polyethylene glycol, polyvinylpyrrolidone,
Examples include hardening agents such as formalin, fluorescent brighteners, and the like.

The treatment temperature during the stabilization treatment is preferably in the range of 15°C to 60°C, preferably 20°C to 45°C. In addition, from the viewpoint of rapid processing, the shorter the treatment time, the better, but usually 20 seconds to 10 minutes, most preferably 1 minute to 5 minutes, and in the case of multiple tank stabilization treatment, the previous tank should be shortened. It is preferable that the treatment time is longer in the latter tank.In particular, it is desirable to perform the treatment sequentially with a treatment time that is 20% to 50% longer than that of the previous tank.Also, the stabilization treatment process is performed in multi-stage tanks, and replenishment is performed in multiple stages. It is preferable to use a backflow system in which the liquid is replenished from the last stage tank and sequentially overflows to the previous stage tank.

The treatment step with fixing ability of the present invention is for the purpose of desilvering, and specifically, the bleach-fixing bath and the fixing bath are used to remove silver, and the bleaching agent used for such treatment is not particularly limited. It is particularly effective when using organic acid ferric complex salts, although it is not limited to organic acid ferric complex salts, and it is particularly effective when using thiosulfates, although it is not limited to fixing agents. It is more effective when using a fixing bath or a whitening-fixing bath containing a diiron complex salt and a thiosulfate.

Following the fixing process of the present invention, performing a direct stabilization process without substantially going through a water washing process means to perform a water washing alternative stabilization process following the fixing process, and substantially without a water washing process. It means not. Depending on the requirements, a short-time complex recovery bath, rinsing, etc. may be provided between the fixing bath or bleach-fixing bath and the stabilization treatment bath, or a rinse after the stabilization treatment may be provided. A draining bath containing a surfactant may also be provided, but it is preferable not to provide a silver recovery bath, a rinsing bath, a draining bath, etc.

In the present invention, the method of bringing the stabilizing liquid into contact with the photosensitive material is as follows:
It is best to immerse the photosensitive material in the solution (bath) in the same way as a general processing solution, but it may also be applied to the emulsion surface of the photosensitive material, both sides of the transport leader, and the transport belt using equal pressure with a sponge or synthetic fiber cloth. Alternatively, it may be applied by spraying or the like.

In the present invention, processing while bringing the stabilizing solution into contact with the substances of the present invention shown in (a) to (1) means the stabilizing treatment tank (hereinafter referred to as stabilizing bath or stabilizing tank) in which the photosensitive material is being processed. ) K directly put the material of the present invention in a cloth, etc. and bring it into contact with it, or
Alternatively, it is indicated that a resin column or filter case directly connected to the stabilizing tank is placed in a container made of chemical fiber or the like and brought into contact with the stabilizing liquid. Furthermore, after contacting the overflow liquid of the stabilizing liquid of the present invention with the substance of the present invention, using at least a part of it as a stabilizing liquid means that the stabilizing liquid is removed from the stabilizing tank and separated from the stabilizing tank. Indicates that after contacting the substance by a column method, a mixing method, etc., at least a part of it is placed in a stabilizing tank. In this case, K can be added to the stabilizing tank as a replenisher, but it is preferably added to the stabilizing tank itself, regardless of the replenishment system, and it is desirable to add at least twice the amount of replenishment.

The substance of the present invention may be brought into contact with any cypress in the case of multiple stabilization tanks (stabilizing baths), but it is preferably carried out in V12 or more cypresses, and more preferably in all the tanks. Of course, this does not apply to single-phase stabilization treatment.Also, in the method of the present invention, the substance of the present invention is brought into contact with a stabilizing solution, but other than this, for example, an ion exchange resin such as an anion exchange resin or a cation exchange resin may be brought into contact. It is also preferable to use electrodialysis treatment or reverse osmosis treatment together.

In the present invention, it is most preferable to bring the substance of the present invention into contact with the stabilizing solution by directly connecting it to the stabilizing bath.
If space for installing a filter case is not available, the stabilizer solution taken out from the stabilizing bath by overflow or forcibly may be brought into contact with the substance of the present invention and returned to the stabilizing bath.

It should be noted that, prior to the processing method of the present invention, the light-sensitive material is subjected to a color development process, and a color image is formed by a coupling reaction between an oxidant of the color development process and a color coupler. Regarding this, reference can be made to known techniques. Furthermore, if necessary, it is also possible to perform a conditioner treatment after the color development pretreatment.

〔Example〕

EXAMPLES Next, the present invention will be explained in detail with reference to Examples, but the present invention is not limited to these Examples.

Example-1 Using silver chlorobromide (30 mol% silver chloride), color sensitization was carried out using Regieler sensitizing dye, ortho sensitizing dye, and pancreatic sensitizing dye, and yellow, magenta, and cyan 3s couplers were produced. Photographic emulsions were prepared using each of these in accordance with conventional methods.

This emulsion was coated on polyethylene coated paper to prepare a color paper sample. This color paper was used for continuous replenishment after being printed using an automatic aircraft. The treatment steps and composition of the treatment liquid at this time are as follows.

Standard treatment process [υ Color development 38°C 3 minutes 30 seconds (2) Bleach-fixing 33°C 1 minute 30 seconds (3) Stabilization treatment 25°C to 30°C 3 minutes [mu] Drying 75°C to 80°C approximately 2 minutes Liquid composition: Color developer tank solution Color developer replenisher solution Bleach-fix tank solution Bleach-fix replenisher Bleach-fix replenisher B Stabilizer and stable replenisher Add the above color developer tank to the automatic processor Fill the bleach-fixing tank solution, bleach-fixing tank solution, and stabilizing solution, and replenish the above-mentioned color developer replenisher and bleach-fixing solution in predetermined amounts every 3 minutes while processing the paper. I did a running test.

The amount of replenishment is 2゜0Ir11 per 1001 color papers to the color development tank! , bleach-fix replenisher A2B o, s respectively as the replenishment amount to the bleach-fix tank
d. 2.8 tons of stabilizing solution was replenished into the stabilizing tank.

The stabilizing tanks of the automatic developing machine are the first to third tanks in the direction of the flow of the photosensitive material, and the final tank is replenished, and the overflow from the i & final tank is allowed to flow into the paddle in the previous stage. Furthermore, this overflow liquid was further flowed into the preceding tank, and overflowed from the foremost tank, resulting in a multi-tank countercurrent system.

The total replenishment amount of stabilizing liquid is 10 of the total stabilizing tank capacity of tanks 1 to 3.
Continuous processing was performed until the amount doubled.

Experiment-1 191 pieces of the continuous treated stable liquid were collected from each of the first to third tanks, mixed, and the treated stable liquid was sampled. This sampling stable solution was divided into 19 parts E1, one of which was left as it was (processing style 2), and 10g of the present invention substance shown in Table IK was added to each of the other 18 stable solutions, and the mixture was stirred for 2 hours using Star 2-. Then, the substance of the present invention was removed from each treated stabilizer by filtration.9. The self-made color paper was processed using each treated stabilizer solution of P solution. At this time, the processing liquid other than the processing step and stabilizing liquid is the same as above.
The stabilization treatment was performed sequentially for 1 minute with the first cypress stabilizer, 1 minute with the second cypress stabilizer, and 1 minute with the third cypress stabilizer. For comparison, the case of washing with running water is also shown (processing No. 1).

Furthermore, a portion of each sample treated with the stabilizing solution in the TS3 tank was stored at 60℃ and 60% HK for 2 weeks, and the stain was measured as a white light density along with the treated sample. As is clear from the results of the comparison, stabilization treatment (treatment No. 2) F compared to running water washing (treatment Nal) VC
Due to i-delivery processing, the number of same-day stays increases significantly.

On the other hand, the stabilizer was treated with the substance of the present invention (treatment air 3-20
), it is found that same-day staining is reduced and is extremely preferable. It is also found that the present invention is effective against staining after storage.

Example-2 Using the third cypress liquid of the treated stabilizer obtained by the treatment in Example-1, the stabilizer was prepared at 2.6, 3.9, 6, 9, 8.
．． 0.9.6 t change, processing NQ3~2o is the above-mentioned light-
Each of the self-made color paper was treated in the same manner as in Example 1 using the substance of the present invention corresponding to the treated teeth in Example 1. The stain astringency of the colored vapor after treatment was measured using white light, and the results are shown in Table 2.

Margin table below -2 Note 1 Processing NCLI ~ 20 is processing wind 1 ~ 2 of light-1 above
0 respectively, and the treated ml corresponds to water washing treatment, NCL2
The sample was treated with a stabilizing solution and was not brought into contact with the substance of the present invention.

As is clear from the results in Table 2, in the present invention, the stabilizer with a stabilizer of 39 to 8.0 has less stain, a higher reflectance on a white background, and a higher degree of white discoloration when visually observed, giving particularly favorable results. I understand. In addition, additional tests confirmed that the effect of the present invention was remarkable at a special K pH of 3.2 to 8.9.

Example-3 By replacing the stabilizing solution of Example-1 with the following formulation, Example-
Perform continuous processing in the same manner as in 1.9.

After the continuous treatment, as in Example-1, 4 parts of the stable liquid were collected from each of the first to third tanks, mixed, and the treated stable liquid was sampled, which was divided into four parts. One of them was left as it was, and the other compounds shown in Table 3 were added, 7.5 Klll JIL was added with sulfuric acid and potassium hydroxide, and 1 ρ of synthetic zeolite (Moleki Seeve 13X, beret-like) was added.
Added 5y per serving, stirred for 2 hours, filtered, and washed the same day with Example-1 and rF3#! The results are shown in Table 3.

As is clear from Table 3, it can be seen that yellow stain can be more effectively prevented on the same day by using in addition to the present invention a method of incorporating a chelating agent or an ammonium compound into the stabilizing solution.

Patent i,! Ehito Roku Konishi Photo Industry Co., Ltd. Representative
Person Patent Attorney Nobuaki Sakaguchi (and 1 other person) 354-

Claims (6)

[Claims] (1) Silver halide power 2-Processing process with fixing ability for photographic light-sensitive materials 1iVCIn a method of directly stabilizing a photographic light-sensitive material with a stabilizing solution without substantially going through a water washing process, the stabilizing solution and the following (a) A method for processing a silver halide color photographic light-sensitive material, which comprises processing a silver halide color photographic material in contact with at least one of the substances shown in ) to (1). (Contact substances) (a) Active material (b) Clay material (c) Polyamide-based polymer compound (e.g. Polyurethane-based polymer compound (e) Phenol resin (f) Epoxy resin (g) Polymer compound with hydrazide group ( h) Polymer compound containing polytetrafluoroethylene (1) Monohydric or polyhydric alcohol methacrylic acid monoester-polyhydric alcohol methacrylic acid polyester copolymer (2) After contacting the contact substance with the overflow liquid of the stabilizing liquid,
A method for processing a silver halide color photographic material according to claim 1, characterized in that at least a part of the material is used again as a stabilizing liquid. (3) A method for processing a silver halide color photographic light-sensitive material according to claim 1 or 2, wherein the stabilization treatment is a final treatment step. (4) A method for processing a silver halide color photographic light-sensitive material according to claim 1, 2 or 3, wherein the stabilizer has a voice of 3.2 to 89. (5) A method for processing a silver halide color photographic material as set forth in claim 1, 2, 3, or 4, wherein the stabilizer contains a chelating agent. (6) A silver halide color photographic light-sensitive material according to claim 1, 2, 3, 4 or 5, wherein the stabilizer contains ammonium ions. Processing method.