JPS6033348A - Acrylic resin product having gold vapor deposition layer with perspective property and preparation thereof - Google Patents
Acrylic resin product having gold vapor deposition layer with perspective property and preparation thereofInfo
- Publication number
- JPS6033348A JPS6033348A JP14006683A JP14006683A JPS6033348A JP S6033348 A JPS6033348 A JP S6033348A JP 14006683 A JP14006683 A JP 14006683A JP 14006683 A JP14006683 A JP 14006683A JP S6033348 A JPS6033348 A JP S6033348A
- Authority
- JP
- Japan
- Prior art keywords
- acrylic resin
- vapor deposition
- resin product
- deposition layer
- vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 42
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 42
- 229910052737 gold Inorganic materials 0.000 title claims description 35
- 239000010931 gold Substances 0.000 title claims description 35
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims description 34
- 238000007740 vapor deposition Methods 0.000 title abstract description 27
- 238000002360 preparation method Methods 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 14
- 238000000151 deposition Methods 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 235000014676 Phragmites communis Nutrition 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 7
- 229910052681 coesite Inorganic materials 0.000 abstract 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract 3
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract 3
- 229910052682 stishovite Inorganic materials 0.000 abstract 3
- 229910052905 tridymite Inorganic materials 0.000 abstract 3
- 239000010410 layer Substances 0.000 description 34
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- 230000008602 contraction Effects 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002343 gold Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000001883 metal evaporation Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
【発明の詳細な説明】
〔技術分野〕
本発明は、各種機器のカバー、のぞき窓等に用いられる
透視性を備えた金蒸着／１′Ｍを有するアクリル樹脂製
品およびその製造方法に関するものである。[Detailed Description of the Invention] [Technical Field] The present invention relates to an acrylic resin product having gold vapor deposition/1'M with transparency and used for covers of various equipment, observation windows, etc., and a method for manufacturing the same. .
透視性を備えかつ導電住葡もった合成樹脂板ｔユ、内部
透視が可能であって導電性能を有し、かつ電磁遮蔽性能
を有しているノζめ、最近は各種機２汁カ１０カバー等
として注目されるようになってきている。このような４
ＩＩ１１ｊぼ１反としては、合成樹脂板の表面に金属蒸
着膜を形成することが行なわれている。ところで、合成
樹脂板に金属蒸着膜を形成する場合、イ１几して密看強
度が低いため、下地層としてのアンダーコートあるいは
保護層としてのトップコートｙｉ施すのが一般的であっ
たが、アンターコートやトップコートは斑が生じたシ、
異物が付着することがあって、これらの形成に熟練を要
す難点がめった。Synthetic resin plates with see-through properties and conductive properties, which can be seen through inside, have conductive properties, and have electromagnetic shielding properties, have recently been used for various types of equipment. It is starting to attract attention as a cover, etc. 4 like this
As for II11j, a metal vapor deposition film is formed on the surface of a synthetic resin plate. By the way, when forming a metal vapor deposited film on a synthetic resin board, it has been common practice to apply an undercoat as a base layer or a topcoat as a protective layer because the adhesive strength is low. The undercoat and top coat are mottled,
Foreign matter sometimes adheres to this method, and the formation of these materials often requires skill.
このため、例えば特公昭５５−３０５３号公す６等の改
善がなされている。ところが、金を合成樹脂就中アクリ
ル樹脂に蒸着しようとすると、この発明に示された方法
で形成しても、十分な密着強度は得られず、実用に耐え
る製品は得られなかった。金の蒸着に際して密着がよく
ない理由の１つとしては、金は空気中でば化されること
がないため、アルミニウムーやクロム等のように表面に
酸化被膜をつくることがなく、この酸化被膜による密着
性向上が期待できないことが挙げられる。またアクリル
樹脂を対象とした場合には、該樹脂が所定の表面硬反を
有し、他の樹脂と比較して含水率、線膨張係数が大きく
、しかも残留応力も大きいことに起因すると考えられる
。すなわちアクリル樹脂板を真空蒸着する際には、加熱
され乾燥されるが、この状態から蒸着後に冷却、吸湿を
受けると、樹脂板が伸縮し、これに伴なって金属にヘア
ークラックが生じ、殆んど密着性を示芒ないこととなる
。For this reason, improvements have been made, for example, as disclosed in Japanese Patent Publication No. 55-3053 No. 6. However, when trying to deposit gold onto a synthetic resin, especially an acrylic resin, even if formed by the method shown in this invention, sufficient adhesion strength could not be obtained, and a product that could withstand practical use could not be obtained. One of the reasons why adhesion is not good when gold is vapor-deposited is that since gold does not oxidize in the air, it does not form an oxide film on the surface like aluminum or chromium. For example, it is difficult to expect an improvement in adhesion due to In addition, in the case of acrylic resin, this is thought to be due to the fact that the resin has a certain surface hardness, has a higher water content and linear expansion coefficient than other resins, and also has a large residual stress. . In other words, when an acrylic resin plate is vacuum-deposited, it is heated and dried, but when it is cooled and absorbs moisture after being vapor-deposited, the resin plate expands and contracts, which causes hair cracks in the metal. However, the adhesion cannot be demonstrated.
したがって、アクリル樹脂板に密着性の高い金蒸着膜全
形成するためにＱ」：、真空蒸着時のアクリル樹脂の膨
張、収縮ｒ十分考慮した蒸着膜ないしは蒸着の方法′ｆ
ｆ：佃：立する磨管かある。Therefore, in order to fully form a gold vapor deposited film with high adhesion on an acrylic resin plate, a vapor deposition film or vapor deposition method that takes into account the expansion and contraction of acrylic resin during vacuum vapor deposition.
f: Tsukuda: There is a standing pipe.
不発明は上記従来の問題点に鑑み、事実上困難視さＩし
ていた金蒸着を施したアクリル樹脂製品おユびその効率
的な＃全方法を提供せんとするものである。SUMMARY OF THE INVENTION In view of the above-mentioned conventional problems, it is an object of the present invention to provide an acrylic resin product coated with gold vapor deposition, which has been considered difficult in practice, and an efficient method thereof.
本発明は上記の目的を達成するためになされたもので、
その要旨とラーるところは、アクリル樹脂製品の表面に
、酸化ケイ素および該１波化ケイ素と合金可能な金属ま
たは金属酸化物との混合蒸着層および銅、チタン、銀か
ら選ばれた１つの金属蒸着層を形成した上に、さらに金
蒸着層を形成したことを特徴とする透視性を備えた金蒸
着層を鳴するアクリル樹脂製品′？Ｉ：第１の発明とし
、アクリル樹脂製品を真空槽内に装填して所定の真窒度
とすると共に、アクリル樹脂製品を熱変形温度以下の温
度で予熱し、次に酸化ケイ素および酸化ケイ素と合金可
能な金属または金属酸化物との混合物を蒸着し、引続き
鋼、チタン、銀から選はノシた１つの金満を蒸着し、さ
らに金を蒸着させることを特徴とする透視性を備えた金
蒸着層を有するアクリル樹脂製品の製造方法を第２の発
明とするところにある。The present invention has been made to achieve the above objects,
The main point is that a mixed vapor deposition layer of silicon oxide and a metal or metal oxide that can be alloyed with the single-wave silicon and one metal selected from copper, titanium, and silver are applied to the surface of the acrylic resin product. An acrylic resin product with a transparent gold vapor-deposited layer, which is characterized by having a gold vapor-deposited layer formed on top of the vapor-deposited layer. I: As the first invention, an acrylic resin product is loaded into a vacuum chamber to reach a predetermined true nitrogen temperature, and the acrylic resin product is preheated at a temperature below the heat distortion temperature, and then silicon oxide and silicon oxide are heated. Transparent gold deposition characterized by depositing an alloyable metal or a mixture with metal oxides, followed by depositing one gold layer selected from steel, titanium, silver, and further depositing gold. A second invention is a method for manufacturing an acrylic resin product having layers.
以下本発明を実施例の図面に従ってさらに詳細に説明す
る。The present invention will be described in more detail below with reference to drawings of embodiments.
図中（１）はアクリル樹脂製品で、このアクリル樹脂製
品（１）は、一般的に用いられているアクリル樹脂の板
状晶、成形品が使用できる。そして、この表面に最終的
に金の蒸着層が形成されるが、通常この蒸着膜は一方の
表面に設けられる。勿論両面に設けても差支えない。In the figure, (1) is an acrylic resin product, and the acrylic resin product (1) can be a plate-like crystal or a molded product of acrylic resin that is commonly used. A gold vapor deposited layer is finally formed on this surface, but this vapor deposited film is usually provided on one surface. Of course, it may be provided on both sides.
（２）は、酸化）１イ素および該酸化ケイ素と合金可能
な金属また嬢；金属酸化物との混合蒸着層で、この場合
の金属としてはチタン、クロム、ニッケルが使用でき、
また金属酸化物としては酸化チタン、酸化セリウム、＋
９化タンクステン、酸化イノジュムが使用できる。この
混合類Ｍ 層（２）ｅよ、ＣＢ２図に示すように例えば
酸化ケイ素と酸化チタンを用い／ζ場合には、−まず酸
化ケイ素の年独趨しＶ、１反化ケイ素と酸化チタンとり
（１１５合層（２々、さらに酸化チタンの単独層Ｖ、、
３１の如く形成すると蒸崩〕戻が透明となりしかもＩ・
話メ１力が強固とな、５ので、φ合が良い。(2) is a mixed vapor deposition layer of 1iron oxide and a metal that can be alloyed with the silicon oxide; titanium, chromium, or nickel can be used as the metal in this case;
In addition, metal oxides include titanium oxide, cerium oxide, +
Tanksten 9ide and inodium oxide can be used. For example, if silicon oxide and titanium oxide are used as shown in Fig. CB2, for example, if silicon oxide and titanium oxide are used in this mixture M layer (2) e, (115 combined layers (2, and a single layer of titanium oxide V,
When formed as shown in 31, the vaporization] return becomes transparent and I.
The speaking force is strong and the 5 is strong, so the φ match is good.
（３）Ｑよ、上記晶合蒸漸ノ（至）（２）とイ、灸述す
る金蒸着層（４）との間に形成する金属蒸＊層で、鋼、
チタン、銀７１）ら選ばｎだ１つの金属の蒸着層で形成
されている。この金属蒸着ノ脅（３）は、金の蒸着層の
密着性を高めるために役立つものである。(3) Q, the metal vapor * layer formed between the above-mentioned crystal synthesis (to) (2) and A, the gold vapor deposited layer (4) described in moxibustion, and the steel,
It is formed of a vapor-deposited layer of one metal selected from titanium and silver71). This metal deposition threat (3) is useful for increasing the adhesion of the gold deposition layer.
（４）は金蒸着層で、本発明の最外層全形成するもので
ある。この金蒸着層は、目的とする金層全構成するもの
であり、金の透明曲、導電性をオリ用せんとするもので
ある。(4) is a gold vapor-deposited layer, which is entirely formed as the outermost layer of the present invention. This gold vapor deposition layer constitutes the entire gold layer, and is intended to improve the transparency and conductivity of gold.
こ７しらの蒸着層は、透視性を損ねない程度の厚さに形
成されるが、混合蒸着層（２）としては３０〜１００Ａ
程度、銅、チタン、銀から選ばれた１つの金属蒸着層（
３）としては、１０〜６０度とするのが好ましい。These seven vapor deposition layers are formed to a thickness that does not impair transparency, but the mixed vapor deposition layer (2) has a thickness of 30 to 100A.
grade, one metal vapor deposition layer selected from copper, titanium, and silver (
As for 3), it is preferable to set it as 10-60 degrees.
以上のように各蒸着層が重層として形成されり本ｉ Ｑ
ＩＪのアクリル樹脂製品は、アンターコートやトップコ
ートを施すことなく密着性が優れており、十分に実用性
のあることが判す」シた。As described above, each vapor deposited layer is formed as a multilayer.
IJ's acrylic resin products have excellent adhesion without the need for an undercoat or topcoat, and are found to be fully practical.
次に本発明の最適な製造方法についで説明するが、本発
明の製造方法も金属蒸着の技術に基づいて行なわれるも
のである。Next, the optimum manufacturing method of the present invention will be explained, and the manufacturing method of the present invention is also performed based on metal vapor deposition technology.
まず対象となるアクリル樹脂ｓ品（１）ハ、被処理面が
洗浄され、真空槽具体的にはベルジャ内に装填される。First, the surface of the acrylic resin product (1) to be treated is cleaned, and the product is loaded into a vacuum tank, specifically, a bell jar.
ベルジャは閉じられ、内部は真空ポンプ等によｐ徐々に
真空度を高め、所定の真空度に保持される。一般的には
この状態に至ると、蒸発源となる金属等が加熱、溶融烙
れ、金属等が微粉末状となって飛散し、被処理面に刺着
して蒸着層が形成される。このときアクリル樹脂製品（
１）は、真空による水分の離脱にょる収縮現象、金属の
溶融による熱の影響による膨張現象さらには蒸着終了後
の大気導入による吸湿による膨張現象ケ起し、しかもこ
れらの現象が微妙に入シ乱れて発生づ−ることＱこより
、アクリル樹脂製品（１）は畿雑な膨張、収縮忙起しで
いる。したがってこのような現象がｆｆ−なっているす
・シ処理面に、蒸発した金１・−ｔｉ等が（；］看して
も十分な密層強度がイＪらｉｔないこととなる。The bell jar is closed, and the degree of vacuum inside is gradually increased using a vacuum pump or the like to maintain a predetermined degree of vacuum. Generally, when this state is reached, the metal or the like serving as the evaporation source is heated, melted and roasted, and the metal or the like becomes a fine powder and scatters, which sticks to the surface to be treated and forms a vapor deposited layer. At this time, the acrylic resin product (
In 1), contraction phenomena occur due to the removal of moisture due to vacuum, expansion phenomena due to the influence of heat due to melting of metal, and expansion phenomena due to moisture absorption due to the introduction of atmospheric air after the completion of evaporation. Due to the disturbance caused by this, the acrylic resin product (1) undergoes rough expansion and contraction. Therefore, even if evaporated gold 1.-ti, etc. are present on the treated surface where such a phenomenon is ff-, there will not be sufficient dense layer strength.
そこで不発明Ｖこおいては、その第１の発明に金蒸着層
（４）の密着性を高めるようにしたものであるが、第２
ｖ発明においてはアクリル樹脂製品（１）の膨張、収縮
する現象を極力抑える処理を併用して、一層密着の高い
アクリル樹脂製品を提供しようとするものである。Therefore, in the invention V, the adhesion of the gold vapor deposited layer (4) is improved in the first invention, but the second invention is
v The invention aims to provide an acrylic resin product with even higher adhesion by using a treatment that suppresses the phenomenon of expansion and contraction of the acrylic resin product (1) as much as possible.
このため第２の発明においでは、ベルジャ内に装填され
て所定の真壁度に置かれているアクリル樹脂製品（１）
を、蒸着前の段階で予熱し、膨張、収縮現象の緩ｇ−ｕ
ないし抑制ｔぜんとするものである。すなわち、アクリ
ル樹脂製品を熱変形温度以下、好ましくは５０〜５０℃
程度で、０．５〜１分間程度加熱する。この予熱を行な
った後は、前述し７と酸化ケイ素および酸化ケイ素と合
金可能な金属祉たは金属酸化物との混合物２第２して混
合蒸Ｍ ＪＶｉ （２） ｋ形成し、引続き鋼、チタン
、銀から選ばれた１つの金Ａ”Ｊ’４ ｋ蒸着して７金
属蒸着層（３）を形成し、さらに金を蒸着して最終的に
金蒸着層（４ンを形成するととＶこよって製造される。Therefore, in the second invention, an acrylic resin product (1) loaded in a bell jar and placed at a predetermined wall thickness.
is preheated before vapor deposition to slow the expansion and contraction phenomena.
It is completely suppressed. That is, the temperature of the acrylic resin product is below the heat distortion temperature, preferably 50 to 50°C.
Heat for about 0.5 to 1 minute. After this preheating, a mixture of 7 and silicon oxide and a metal or metal oxide that can be alloyed with silicon oxide is formed as a mixture 2, and then the steel, One piece of gold selected from titanium and silver is evaporated to form 7 metal evaporation layers (3), and then gold is further evaporated to form a final gold evaporation layer (4k). This is how it is manufactured.
この個々の金属等の蒸着条件は、側管特別なものではな
く、一般的な条件が採用しうる。The vapor deposition conditions for each metal, etc. are not specific to the side tube, and general conditions can be adopted.
〔実施例」
アクリル樹脂製品として、板厚２間、縦×横１０１００
Ｘ１００の透明アクリル樹脂板を用意し、この被処理面
をメタノールと水で洗浄した。[Example] As an acrylic resin product, board thickness is 2 meters, length x width 10100
A X100 transparent acrylic resin plate was prepared, and the surface to be treated was washed with methanol and water.
そしてこの透明アクリル樹脂板を、被処理面が蒸発源に
向うようにベルジャ内に装填し、真空度がＩ Ｘ １０
−’ ｔｏｒｒになるように準備する。次に透明アクリ
ル樹脂板を基板加熱用フィラメントによって４０℃で１
分間予熱した上で、酸化ケイ素と酸化チタンの混合物２
第２図の如き層となるよう、すなわち１ずｌ液化ケイ素
を蒸発させ次に酸化チタンも併せて蒸うれさせ最後に酸
化チタンのみ蒸発させた。このときの酸化ケイ素と酸化
チタンの使用量はｏ、１７．０．０５１７ｍ２であった
。引続き銅ケ［Ｊ、 ０５ ｆ蒸着させ、さらに金を０
．１２蒸冶させた。なおアクリル樹脂板４！：蒸着用フ
ィラメントとの間隔は５０ｃｍとした。Then, this transparent acrylic resin plate was loaded into a bell jar with the surface to be treated facing the evaporation source, and the degree of vacuum was 1 x 10.
-' Prepare for torr. Next, the transparent acrylic resin plate was heated to 40℃ using a substrate heating filament.
After preheating for a minute, the mixture of silicon oxide and titanium oxide 2
To obtain a layer as shown in FIG. 2, 1 liter of liquefied silicon was evaporated, then titanium oxide was also evaporated, and finally only titanium oxide was evaporated. The amount of silicon oxide and titanium oxide used at this time was 17.0.0517 m2. Subsequently, copper film [J, 05 f] was evaporated, and gold was further deposited.
．． It was steamed for 12 minutes. In addition, acrylic resin board 4! : The distance from the filament for deposition was 50 cm.
得られた金蒸着Ｎｋ有する透明アクリル樹脂板の性能を
評価したところ、第１表に示す如く良好なものであった
。なお、比較品ｔよ透明アクリル（Ｉ２１脂板に直接金
蒸着を行なったものである。When the performance of the obtained transparent acrylic resin plate with gold vapor deposited Nk was evaluated, it was found to be good as shown in Table 1. Comparative product t is made of transparent acrylic (gold vapor-deposited directly on I21 resin plate).
第 １ 表
※密着テストは、金蒸着層に１問間隔の１０１０Ｘ１０
のコ゛パン目をけがき、これにセロハンテープを貼シ剥
したときの剥は落ちた個数による（なお分子は残ってい
る数である）。Table 1 *Adhesion test is 1010 x 10 with one question interval on the gold vapor deposited layer.
This is based on the number of pieces that fall off when you mark out the squares of the square, paste cellophane tape on it, and peel it off (the number of molecules is the number that remains).
※くミ摩耗テストは、ガーゼで往復５０回こすったのち
の表面状態を観察した。*In the Kumi wear test, the surface condition was observed after rubbing back and forth with gauze 50 times.
（発り」の効果」
本発明は以上の如き構成からなるものであるから、密着
性の高い金蒸着層を肩するアクリル樹脂製品を提供でき
、しかも他に特別な装置を要することがなく密着性の高
いこの種アクリル樹脂製品を効率よく製造することがで
きる利点がある。(Effect of starting point) Since the present invention has the above-described structure, it is possible to provide an acrylic resin product that supports a gold vapor deposited layer with high adhesion, and also to achieve adhesion without requiring any other special equipment. This type of acrylic resin product with high properties can be efficiently manufactured.
第１図は本発明の一実施例を示すアクリル樹脂製品の部
分的な拡大断面図、第２図は第１図■部分の拡大断面図
である。
（１）・・・透明アクリル樹脂製品
（２）−・・混合蒸着層
（３）−・・金属蒸着層
（４）・・・金蒸着層FIG. 1 is a partially enlarged cross-sectional view of an acrylic resin product showing an embodiment of the present invention, and FIG. 2 is an enlarged cross-sectional view of the portion (■) in FIG. (1)...Transparent acrylic resin product (2)...Mixed vapor deposited layer (3)...Metal vapor deposited layer (4)...Gold vapor deposited layer
Claims (1)
酸化ケイ素と合金可能な金属葦たは金属敵化合物との混
合蒸着層、および銅、チタン、銀から選はれた１つの金
属蒸着層を形成した上に、さらに金蒸着層を形成したこ
とを特徴とする透視性を備えた金蒸着層を有するアクリ
ル樹脂製品。 ２ アクリル樹脂製品を真空槽内に装具して所定の真空
度とすると共に、アクリル樹脂製品を熱変形温度以下の
温度で予熱し、次に酸化ケイ素および酸化ケイ素と合金
可能な金属または金属酸化物との混合物を蒸着し、引続
き銅、チタン、銀から選ばれた１つの金属を蒸着し、さ
らに金を蒸着させることを特徴とする透視性を備えた金
蒸着層を有するアクリル樹脂製品の製造方法。[Claims] 1. On the surface of the acrylic resin product, a mixed vapor deposited layer of silicon oxide and a metal reed or metal compound that can be alloyed with the silicon oxide, and 1 selected from copper, titanium, and silver. An acrylic resin product having a gold vapor-deposited layer with transparency, characterized in that a gold vapor-deposited layer is further formed on top of two metal vapor-deposited layers. 2. Place the acrylic resin product in a vacuum chamber to achieve a predetermined degree of vacuum, preheat the acrylic resin product at a temperature below the heat distortion temperature, and then add silicon oxide and a metal or metal oxide that can be alloyed with silicon oxide. A method for producing an acrylic resin product having a transparent gold vapor-deposited layer, characterized by vapor-depositing a mixture of copper, titanium, and silver, followed by vapor-depositing gold, and further vapor-depositing gold. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14006683A JPS6033348A (en) | 1983-07-30 | 1983-07-30 | Acrylic resin product having gold vapor deposition layer with perspective property and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14006683A JPS6033348A (en) | 1983-07-30 | 1983-07-30 | Acrylic resin product having gold vapor deposition layer with perspective property and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6033348A true JPS6033348A (en) | 1985-02-20 |
| JPS6250551B2 JPS6250551B2 (en) | 1987-10-26 |
Family
ID=15260178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14006683A Granted JPS6033348A (en) | 1983-07-30 | 1983-07-30 | Acrylic resin product having gold vapor deposition layer with perspective property and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6033348A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6394839A (en) * | 1986-10-09 | 1988-04-25 | シ−アイ化成株式会社 | Metal-like decorative sheet |
| US6128155A (en) * | 1997-12-16 | 2000-10-03 | Mitsubishi Denki Kabushiki Kaisha | High density magnetic recording apparatus including a hologram type magnetic head positioning system |
| JP2018051818A (en) * | 2016-09-27 | 2018-04-05 | Ｂｂｓジャパン株式会社 | Vapor deposition emblem and manufacturing method thereof |
-
1983
- 1983-07-30 JP JP14006683A patent/JPS6033348A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6394839A (en) * | 1986-10-09 | 1988-04-25 | シ−アイ化成株式会社 | Metal-like decorative sheet |
| US6128155A (en) * | 1997-12-16 | 2000-10-03 | Mitsubishi Denki Kabushiki Kaisha | High density magnetic recording apparatus including a hologram type magnetic head positioning system |
| JP2018051818A (en) * | 2016-09-27 | 2018-04-05 | Ｂｂｓジャパン株式会社 | Vapor deposition emblem and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6250551B2 (en) | 1987-10-26 |
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