JPS6064409A - Permanent magnet material - Google Patents
Permanent magnet materialInfo
- Publication number
- JPS6064409A JPS6064409A JP58172838A JP17283883A JPS6064409A JP S6064409 A JPS6064409 A JP S6064409A JP 58172838 A JP58172838 A JP 58172838A JP 17283883 A JP17283883 A JP 17283883A JP S6064409 A JPS6064409 A JP S6064409A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- rare earth
- permanent magnet
- alloy
- magnet material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/047—Alloys characterised by their composition
- H01F1/053—Alloys characterised by their composition containing rare earth metals
- H01F1/055—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
- H01F1/057—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Hard Magnetic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は希土類元素を含有する新規な永久磁石用材料に
関するものである。これまでに希土類元素と遷移金属元
素からなる合金系に関して数多くの研究がなされており
、その中でも希土類元素（２）とＣＯよりなる合金系が
今啼実用材料となっている。具体的にはＲＣＯ，系なら
びにＣｕ添加Ｒ鵞ｃｏｔｙ系合金であり、組成式で褒わ
すならばＲＣＯ８％ＲＣＯ７の範囲である。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel permanent magnet material containing rare earth elements. Many studies have been carried out on alloy systems consisting of rare earth elements and transition metal elements, and among these, alloy systems consisting of rare earth elements (2) and CO are currently being used as practical materials. Specifically, it is an RCO type alloy and a Cu-added Rcoty type alloy, and its compositional formula is in the range of RCO8%RCO7.
Ｒ−Ｃｏ系合金は、Ｒに対するＣＯの比重が高くなる程
飽和磁化の強さく４πＩｓ ）が大きくなり、また磁石
の代表的な特性である吊天エネルギーで上昇する。それ
ゆえ、具体的ＫｔｉＲＣＯｓ系からより飽和磁化の高い
Ｉｊｓｃｏｔｙ 系へと研究が推移してきたわけである
。さらにＣｏ ｒｉｃｌｌ 側組成にすれば飽和磁化が
大きくなるわけであるが、一方保磁力に影響を与える異
方性磁界が低下するためか高い保磁力が得られず、現在
まで磁石材料としての可能性は見出されていない。そこ
で本発明省等は飽和磁化のより高いＣｏｒｉｃｈ側組成
系において磁石材料としての基本物性値を満足させうる
ようなＲ−Ｃｏ−Ｘ系およびＲ−ＣＧ−Ｆｅ−Ｘ系につ
いて鋭意研究した結果、Ｘとしてポロンの）を添加する
ことによって飽和磁化（４π！ｇ）が高い組成で異方性
磁場（ＨＡ）が改良されえることを発見し充分磁石材料
となり得ることを見出したものである。In R-Co alloys, as the specific gravity of CO to R increases, the saturation magnetization strength (4πIs) increases, and the magnetization increases with hanging energy, which is a typical characteristic of magnets. Therefore, research has shifted from the specific KtiRCOs system to the Ijscoty system, which has higher saturation magnetization. Furthermore, if the composition is set to the Coricll side, the saturation magnetization increases, but on the other hand, a high coercive force cannot be obtained, perhaps because the anisotropic magnetic field that affects the coercive force decreases, and so far, the possibility of using it as a magnetic material has been limited. has not been found. Therefore, the Ministry of the Invention and others conducted intensive research on the R-Co-X system and R-CG-Fe-X system that can satisfy the basic physical property values as a magnet material in the Corich side composition system with higher saturation magnetization. They discovered that the anisotropic magnetic field (HA) can be improved in compositions with high saturation magnetization (4π!g) by adding poron as X, and found that it can be used as a sufficient magnetic material.
すなわち本発明は、Ｒ−Ｃｏ、Ｂ系およびＲ−ＣＯ−Ｆ
ｅ−Ｂ系に関するものであ石、組成式で表現すれば
■ Ｒ（ＢｘＣｏｓ−ｘ）ｚ：（但し、ＲはＹを含む希
土類元素Ｌａｔ ＣＯｅ Ｐｒｏ Ｎｄａ Ｓｍの１種
又は２種以上の組合せ）０．００２≦Ｘ≦ｃＬｘ、 ７
≦２≦１６■ Ｒ（ＢｘＦｅｙＣｏｔ−ｘ−ｙ）ｚ ：
（但し、ＲはＹを含む希土類元素Ｌａｇ Ｃｅ、 Ｐ
７ｓｅ Ｎｃｔ、 Ｓｍ ｏ １種又は２種以上の胡合
せ）ＣＬ００２≦Ｘ≦［ｌｓ、 ｏ＜ｙ≦α４．７≦２
≦１６
なる組成を有することを特徴とするものである。That is, the present invention provides R-Co, B-based and R-CO-F
It is related to the e-B system, and expressed in the compositional formula ■ R (BxCos-x)z: (However, R is one type or a combination of two or more of the rare earth elements Lat COe Pro Nda Sm including Y) 0.002≦X≦cLx, 7
≦2≦16■ R(BxFeyCot-x-y)z:
(However, R is a rare earth element containing Y, Lag Ce, P
7se Nct, Sm o 1 type or 2 or more types) CL002≦X≦[ls, o<y≦α4.7≦2
It is characterized by having a composition of ≦16.
これらの組成合金は高周波溶解、アーク溶解等で得た溶
湯を金型等に鋳込んで作成したもので結晶質の合金であ
る。又非晶質状態のものを結晶化してもよい。又Ｂの・
代わシにＣ２入Ｊ＃ ＳＬ ＰｔＧｅｔ Ｓｂ＃ Ｓｎ
＃ Ｂｉｔ ＴＬ Ｖｅ Ｚｒａ Ｎｂｅ Ｍｏｌ Ｈ
ｆｅ Ｔａｐ Ｗ＃ＣらＭｎｌ Ｃｕの１種又は２種以
上およびＢとの複合添加を行なっても効果を示す。These compositional alloys are crystalline alloys made by casting molten metal obtained by high-frequency melting, arc melting, etc. into a mold or the like. Alternatively, an amorphous state may be crystallized. Also B's...
Enter C2 instead J# SL PtGet Sb# Sn
# Bit TL Ve Zra Nbe Mol H
Even if one or more types of fe Tap W#C, Mnl Cu, and B are added in combination, the effect is shown.
本発明において個々の成分および成分量範囲を限定した
理由は下記の通りである。すなわちＢｆｌ：（１がα０
０２以下となると異方性磁界が小さくなる。又Ｂｆｉが
０．３以上になると飽和磁化の大きさが低下する。この
ため、Ｂｔはａ００２≦Ｘ≦１１５となるが、好ましく
は０，０１≦Ｘ≦α２．より好ましくは、α０２≦ｘ（
［Ｌ１５となるとより良好なら・性を示すようになる。The reasons for limiting the individual components and component amount ranges in the present invention are as follows. That is, Bfl: (1 is α0
02 or less, the anisotropic magnetic field becomes small. Moreover, when Bfi becomes 0.3 or more, the magnitude of saturation magnetization decreases. Therefore, Bt satisfies a002≦X≦115, but preferably 0,01≦X≦α2. More preferably, α02≦x(
[If it becomes L15, it will show better characteristics.]
このよりなりとしてはフエロボ日ンをもちいてもよい。For this purpose, you may use Ferobo Sun.
Ｆｅの添加は必ずしも必要ではないが、Ｆｅの添加によ
り飽和磁束密度が上昇する。Ｆｅの添加量が１０５以上
となるとより良好な結果を得ることが出来る。Although the addition of Fe is not necessarily necessary, the addition of Fe increases the saturation magnetic flux density. When the amount of Fe added is 105 or more, better results can be obtained.
一方、（Ｂ＋Ｃｏ ） ！あるいは（Ｂ＋Ｃｏ＋Ｆｅ
） ＠とＲμ・のモル比（ｚｌについて７≦２≦１６と
した理由は、モル比２が７以下になると飽和磁化の強さ
が低下し、モル比２が１６よりも大きくなると異方性磁
界の大きさが低下してしまう。この場合、ＩＢましくに
７≦２≦１４ よ抄好まし、くは８≦２≦１５になると
、比較的飽和磁化の大きな組成領域で高い異方性磁場を
得ることか出来る。On the other hand, (B+Co)! Or (B+Co+Fe
) The reason why the molar ratio of @ and Rμ (zl is set to 7≦2≦16 is that when the molar ratio 2 becomes 7 or less, the strength of saturation magnetization decreases, and when the molar ratio 2 becomes larger than 16, the anisotropy In this case, if IB is exactly 7≦2≦14, or 8≦2≦15, a high anisotropic magnetic field will occur in a composition region with relatively large saturation magnetization. It is possible to obtain.
以下実施例罠ついて示す。Examples are shown below.
５ＡＩＭ例Ｉ Ｓｍ（ＣＯｅ、ｕ Ｂ ｏｓｓ ）―
の組成式で示される合金を作成し物性値として飽和磁化
の強さく４π■）および異方性磁界の大きさくＨＡ）に
ついて測定した結果、４πＩ＝１２ＫＧ、ＨＡ＝１１０
ＫＯｅであった。一方比較例としてＳｍＣｏ＊の合金を
作成し同様に測定した。その結果４７ｒｌ＝＝１２ＫＧ
、Ｈ人＝９５ＫＯｅであった。この結果に示されるよう
、にＢの効果は明らかである。5AIM Example I Sm (COe, u B oss ) -
An alloy with the composition formula was prepared and the physical properties were measured for the strength of saturation magnetization (4π■) and the magnitude of anisotropic magnetic field (HA), and the results were as follows: 4πI = 12KG, HA = 110
It was KOe. On the other hand, as a comparative example, an alloy of SmCo* was prepared and measured in the same manner. As a result 47rl==12KG
, H people = 95 KOe. As shown in this result, the effect of B is clear.
実施例２ ８ｍ（Ｃ０１１，Ｑ ＢＩＬＩ ｈｏの組成
式で示される合金を作成し物性値として飽和磁化の強さ
く４π■）および異方性磁界の大きさくＨＡ）ｉｃつい
て測定した結果４πＩ＝１２−８ＫＧ、 ＨＡ＝６５Ｋ
Ｏｅであった。一方比較例として５ｍＣｏ５ｏの合金を
作成し同様に測定した。４πＩ＝１２．９ＫＧ。Example 2 An alloy shown by the composition formula of 8m (C011,Q BILI ho) was prepared, and the physical properties were measured for the strength of saturation magnetization (4π■) and the magnitude of anisotropic magnetic field (HA)ic; the results were 4πI = 12- 8KG, HA=65K
It was Oe. On the other hand, as a comparative example, an alloy of 5mCo5o was prepared and measured in the same manner. 4πI=12.9KG.
Ｈａ＝５ΩＫＯｅ で６つた。Ha = 5ΩKOe, 6.
実施例Ｓ Ｓｍ（Ｃｏｏ、ｙｓＦｅｏ、寓Ｂｏ、ｅｓ）
ｅ の組成で示な
される合金を作成、し物性眞として飽紹磁化の強さく４
π！）および異方性磁界の大きさくＴ（Ａ）について測
定した結果、ａ ｗｌ ＝ １１５ＫＧ−ＨＡ＝８０Ｋ
Ｏｅであった。Example S Sm (Coo, ysFeo, Bo, es)
An alloy with a composition of e was prepared, and its physical properties were 4
Pi! ) and the magnitude of the anisotropic magnetic field T(A), a wl = 115KG-HA = 80K
It was Oe.
一方比較例としてＳｍ（Ｃｏｓｏ、ａ Ｆｅｏ、ｓ）ｓ
の合金を作成し同様に測定した。その結果４πｉ−，１
３，４ＴＣＧｅ Ｈｈ＝６０ ＫＯｃであった。On the other hand, as a comparative example, Sm(Coso, a Feo, s)s
An alloy was prepared and measured in the same manner. The result is 4πi−,1
3,4TCGe Hh=60 KOc.
なお希土類元素ＲとしてＹ＊ Ｌａｙ Ｃ，ｅｓ Ｐｒ
ｏ Ｎｄ の１譚又は２ａ以上の組合せおよびＳｍとの
組合せを用いても有効なり添加効果を示す。In addition, as the rare earth element R, Y* Lay C, es Pr
o A combination of 1 tan or 2a or more of Nd and a combination with Sm are also effective and exhibit an additive effect.
以上述べたように本願発明は従来永久石喜石合金利料と
しての可能性について否定的であったＣｏｒｉｃｈＲ−
Ｃｏ系にＢを加えることにより新しく高性能な永久磁石
合金材料を提供することを可能にしカーものである。As mentioned above, the present invention can be applied to CorichR-
By adding B to the Co-based material, it is possible to provide a new high-performance permanent magnet alloy material.
Claims (1)
≦α３゜７≦２≦１６）なる組成式で表わされ、上記組
成式においてＲは、Ｙを含む希土類元素ＬａｐＰす ｃム噴ｄ、 Ｓｍの１種又は２ｍ以上の組合せであるこ
とを特徴とする永久磁石用材料。 ■ Ｒ（ＢｚＦ６ｙ Ｃｏｔ−ｘ−ｙ） ｚ （ただし
α００２≦Ｘ≦αＳ、Ｏ（ｙ≦（１４，７≦２≦１６）
なる組成式で表わされ、上記組成式においてＲは、Ｙを
含む希土類元素Ｌａｐ Ｃｅｅ Ｐｒｙ Ｎｄｔ Ｓｍ
の１種又は２種以上の胡合せであ本ことを特徴とする永
久磁石用材料。[Claims] ■ R(BxCot-x)z (provided that LOO2≦X
≦α3゜7≦2≦16), and in the above composition formula, R is one type or a combination of 2 or more of the rare earth elements LapP, Sm, and Sm containing Y. Materials for permanent magnets. ■ R(BzF6y Cot-x-y) z (However, α002≦X≦αS, O(y≦(14,7≦2≦16)
In the above composition formula, R is a rare earth element containing Y. Lap Cee Pry Ndt Sm
A material for a permanent magnet, characterized in that it is made of one or more of the following.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58172838A JPS6064409A (en) | 1983-09-19 | 1983-09-19 | Permanent magnet material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58172838A JPS6064409A (en) | 1983-09-19 | 1983-09-19 | Permanent magnet material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6064409A true JPS6064409A (en) | 1985-04-13 |
Family
ID=15949269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58172838A Pending JPS6064409A (en) | 1983-09-19 | 1983-09-19 | Permanent magnet material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6064409A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03260018A (en) * | 1990-03-09 | 1991-11-20 | Fuji Elelctrochem Co Ltd | Manufacture of anisotropic rare earth metal permanent magnet |
| JPH03261104A (en) * | 1990-03-09 | 1991-11-21 | Fuji Elelctrochem Co Ltd | Manufacture of anisotropic rare earth permanent magnet |
-
1983
- 1983-09-19 JP JP58172838A patent/JPS6064409A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03260018A (en) * | 1990-03-09 | 1991-11-20 | Fuji Elelctrochem Co Ltd | Manufacture of anisotropic rare earth metal permanent magnet |
| JPH03261104A (en) * | 1990-03-09 | 1991-11-21 | Fuji Elelctrochem Co Ltd | Manufacture of anisotropic rare earth permanent magnet |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6032306A (en) | Permanent magnet | |
| RU2003122788A (en) | NANOCOMPOSITE MAGNET FROM CONTAINING RARE EARTH ALLOY ELEMENT ON THE BASIS OF IRON AND METHOD OF ITS MANUFACTURE | |
| Ishikawa et al. | Hard magnetic phase in rapidly quenched Zr-Co-B alloys | |
| JPH11307328A5 (en) | ||
| JPH1053844A (en) | (rare earth)-iron-boron magnetic alloy and its production and bond magnet using the (rare earth)-iron-boron magnetic alloy | |
| Ghemawat et al. | New microcrystalline hard magnets in a Co-Zr-B alloy system | |
| JPH0316761B2 (en) | ||
| JPH04129203A (en) | permanent magnet powder | |
| Burzo et al. | Magnetic properties of Nd2Fe14− x− yCoxAlyB alloys | |
| EP0594309A1 (en) | Non-uniaxial permanent magnet material | |
| JP3073807B2 (en) | Iron-rare earth permanent magnet material and method for producing the same | |
| JPH0474426B2 (en) | ||
| JPH1064710A (en) | Isotropic permanent magnet having high magnetic flux density and manufacture thereof | |
| JPH06231917A (en) | Permanent magnet of rare earth-transition metal base and its manufacture | |
| Arai et al. | High-energy isotropic resin bonded magnets produced from (Nd, Dy)-(Fe, Co)-B nanocomposite alloys | |
| JPS60187662A (en) | Ferromagnetic alloy | |
| JPS63241142A (en) | Ferromagnetic alloy | |
| JPH0549741B2 (en) | ||
| Hirosawa et al. | Effects of Cu-Nb/Zr addition on magnetic properties of Fe/sub 3/B/(Nd-Dy)/sub 2/Fe/sub 14/B nanocomposite magnets | |
| JPS60106108A (en) | Material for permanent magnet | |
| JPH0474425B2 (en) | ||
| Fujii et al. | Crystallography and magnetism of zirconium-doped (Sm, Pr) 2Co17 alloys | |
| JPH116038A (en) | Rare earth permanent magnet material | |
| JPH06172937A (en) | Permanent magnet material | |
| JPH024939A (en) | Rare earth-transition metallic magnetic alloy |