JPS6071224A - Coating method for resin molded article having deep- drawn portion - Google Patents

Coating method for resin molded article having deep- drawn portion

Info

Publication number
JPS6071224A
JPS6071224A JP17967983A JP17967983A JPS6071224A JP S6071224 A JPS6071224 A JP S6071224A JP 17967983 A JP17967983 A JP 17967983A JP 17967983 A JP17967983 A JP 17967983A JP S6071224 A JPS6071224 A JP S6071224A
Authority
JP
Japan
Prior art keywords
mold
molded article
deep
molded product
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17967983A
Other languages
Japanese (ja)
Other versions
JPH0424212B2 (en
Inventor
Yoshio Tanimoto
谷本 義雄
Takeshi Furukawa
武司 古川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mazda Motor Corp
Original Assignee
Mazda Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mazda Motor Corp filed Critical Mazda Motor Corp
Priority to JP17967983A priority Critical patent/JPS6071224A/en
Publication of JPS6071224A publication Critical patent/JPS6071224A/en
Publication of JPH0424212B2 publication Critical patent/JPH0424212B2/ja
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/08—Deep drawing or matched-mould forming, i.e. using mechanical means only
    • B29C51/082—Deep drawing or matched-mould forming, i.e. using mechanical means only by shaping between complementary mould parts

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To coat a resin molded article having a deep-drawn portion, by spraying a coating material onto the projection of a mold for forming the deep-drawn portion, and by applying the coating material on the surfasce of the molded article after resin is molded monolithically. CONSTITUTION:In the state that a mold composed of a mold 2 in which a projection 5 for forming a deep-drawn portion is formed on a cavity 4 forming side and a mold 3 corresponding to the mold 2 is opened, a coating material is sprayed on the projection of the mold. Then, said mold is closed and a resin is introduced into it to form a molded article 19. Next, the molded article 19 is taken out of the mold and a coating material of synthetic resin is applied on the surface of the molded article. The surface of the molded article is coated in the following process, after the deep-drawn portion is masked with a masking tape 22, a primer is applied thereon, and then, after the masking is removed, a topcoat is applied on the surface.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、探しぼり部を有する樹脂成形品の特に該探し
ぼり部の表面に、塗料を均一に塗布するための塗装方法
に関するものである。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a coating method for uniformly applying paint to the surface of a resin molded article having a recessed part, particularly the recessed part. .

(従来技術) 最近、自動車の燃料消費量を節減する対策のなかで車体
の軽量化が採り上げられ、車体各部の金属製部品を可能
な限り合成樹脂成形品で代用することが進められている
。そのなかで合成樹脂成形品カ断面で示した第7図のよ
うなソフトフェイシャSなどに適用される場合は、この
ソフトフェイシャSは自動車の車体の表面に取付けられ
、しかも、素材の色が多くの場合、車体の仕上げ色と同
じでないために、その表面に塗料pを塗布して車体°と
同じ色調【こ仕上げるのが通例である。したがって、ソ
フトフェイシャSの表面形状がなだらかであれば塗料p
をムラな(塗布することができるが、塗装すべき表面に
探しぼり部nがあるものは、この探しぼり部nに対して
塗料pを満遍なく塗布することが難しいために、その塗
膜が不均一になって表−7の「従来方法」の欄に示すよ
うな外観を損なう不具合があり、とりわけ、メタリック
塗装においてはメタルずれを生じる。
(Prior Art) Recently, weight reduction of car bodies has been adopted as a measure to reduce the fuel consumption of automobiles, and efforts are being made to replace metal parts in various parts of car bodies with synthetic resin molded products as much as possible. Among them, when applied to soft facia S as shown in Figure 7, which shows a cross section of a synthetic resin molded product, this soft facia S is attached to the surface of the car body, and the material is available in many colors. In this case, since the finish color is not the same as the car body, it is customary to paint the surface with paint P to finish it in the same color as the car body. Therefore, if the surface shape of Soft Facial S is smooth, the paint p
It is possible to apply the paint p unevenly (but if the surface to be painted has a hollowed-out area n, it is difficult to apply the paint p evenly to the hollowed-out area n, so the coating film may be defective). There is a problem in that the coating becomes uniform and impairs the appearance as shown in the column of "Conventional method" in Table 7, and in particular, in the case of metallic coating, metal misalignment occurs.

そこで、合成樹脂成形品を金型で成形したのち、金型を
少し開いて金型とこの成形品の闇に僅かの隙間をつくり
、金型に設けた塗料口からこの隙間に塗料を注入したの
ち加圧するインモールドコートの一方法が知られている
が、この方法は探しぼり部nが形成されたものでは塗料
の流れが悪(均一な塗膜が形成されないから、上記従来
の欠点を解消するものではない。
Therefore, after molding a synthetic resin molded product in a mold, the mold was slightly opened to create a small gap between the mold and the molded product, and paint was injected into this gap from the paint port provided in the mold. One method of in-mold coating is known, in which pressure is applied afterwards, but this method eliminates the above-mentioned drawbacks of the conventional method, as the paint does not flow well (a uniform coating film is not formed) if the searched portion n is formed. It's not something you do.

(発明の目的) 本発明はかかる従来の上記問題点に鑑み、樹脂成形品の
探しぼり部の塗装]よ、種々の実験の結果。
(Object of the Invention) In view of the above-mentioned conventional problems, the present invention is based on the results of various experiments such as "painting of the searched portion of a resin molded product".

該成形品の成形工程に先行せしめることによって好結果
を得られることが判明したので、成形金型を開放状態に
したまま該成形金型あ一方の金型のキャビティ形成面に
形成された突出部に対して、予じめ塗料の吹付けを行な
い、探しぼり部の塗膜を均一に形成することを目的とす
る。
It has been found that good results can be obtained by preceding the molding process of the molded product, so the protrusion formed on the cavity forming surface of the other mold while the mold is in an open state. The purpose of this is to spray paint in advance on the area to form a uniform coating on the searched area.

(発明の構成) 本発明の構成は、成形金型を開いた状態で成形金型の一
半をなす金型のキャビティ形成面に形成された探しぼり
部を形成するための突出部の全面に対して合成樹脂成形
品こよる吹付けを行なう吹付は工程と、成形金型を型締
めして該成形金型内に合成樹脂を導入して前記塗料と一
体の成形品を成形する工程と、該成形品を成形金型から
取り出して前記探しぼり都を有する成形品の表面に合成
樹脂塗料を塗布する製品表面塗装工程とを順次行なうこ
とを特徴とするものである。
(Structure of the Invention) The structure of the present invention is such that when the molding die is opened, the entire surface of the protruding part for forming the recessed part formed on the cavity forming surface of the mold forming one half of the molding die is Spraying is a process in which a synthetic resin molded product is sprayed, a process in which a mold is clamped and a synthetic resin is introduced into the mold to form a molded product that is integrated with the paint; The method is characterized in that the molded product is removed from the molding die, and a product surface coating step of applying a synthetic resin paint to the surface of the molded product having the above-mentioned search marks is sequentially performed.

(実施例) 以下、本発明の構成を実施側にりいて詳述する。(Example) Hereinafter, the configuration of the present invention will be explained in detail from the implementation side.

第1図はソフトフェイシャ等の合成樹脂製品の成形に適
用される成形金型1を示しており、該成形金型は凹型2
と該凹型に対する金型3とでなっている。凹型2のキャ
ビティ4内Eこは、後述する成形品19の探しぼり部1
8に相当する突出部5が形成され、前記金型乙のコア6
には突出部5に対する深溝部7が形成されている。
Fig. 1 shows a molding die 1 that is applied to molding synthetic resin products such as soft fascias, and the molding die has a concave shape 2.
and a mold 3 for the concave mold. Inside the cavity 4 of the concave mold 2 is a search section 1 for a molded product 19, which will be described later.
A protrusion 5 corresponding to 8 is formed, and the core 6 of the mold B
A deep groove portion 7 is formed in the protrusion portion 5 .

本発明方法は上記成形金型1を適用してなされるもので
あり、離型剤塗布工程8、吹付は工程9゜射出成形工程
10、洗浄工程11および製品表面塗装工程12が順に
行なうことを主要部として構成される。
The method of the present invention is carried out by applying the above-mentioned molding die 1, and the mold release agent application step 8, the spraying step 9, the injection molding step 10, the cleaning step 11, and the product surface coating step 12 are carried out in this order. It is constructed as the main part.

前記離型剤塗布工程8は、第1図に示すように成形金型
1を開いた状態で、凹型2のキャビティ4および金型6
のコア6の各型面に対して噴霧、塗装器13でワックス
離型剤14を塗布する。
In the mold release agent application step 8, with the mold 1 open as shown in FIG.
A wax mold release agent 14 is applied to each mold surface of the core 6 using a spray coating device 13.

前記吹付は工程9は、離型剤塗布工程8に引続き成形金
型1を開いた状態で第2図に示すように、凹型2の突出
部5に対して乙θ〜g0°Cに調節された2液ウレタン
塗料による被覆層15を噴霧塗装器16で塗装し、塗膜
の厚さを70〜30μに形成したのち、7〜5分間放置
して硬化させる。
In step 9 of the spraying process, following the mold release agent application step 8, with the mold 1 open, as shown in FIG. A coating layer 15 made of a two-component urethane paint is applied using a spray coater 16 to form a coating film with a thickness of 70 to 30 μm, and then left to cure for 7 to 5 minutes.

前記射出成形工程10は、吹付は工程9のあと第3図に
示すように、前記成形金型1を型締めしたのち、該成形
金型内に乙O−♂00 Cの反応射出成形用ウレタン等
の合成樹脂17を導入してソフトフェイシャ等の探しぼ
り部18を有する成形品19を前記被覆層15と一体に
成形し、2〜グ分間放置して硬化させる。
In the injection molding step 10, after the spraying step 9, as shown in FIG. A molded article 19 having a cut-out portion 18 such as a soft fascia is molded integrally with the coating layer 15, and left for 2 to 3 minutes to harden.

前記洗浄工程11は、射出成形工程101こ次いで成形
金型1から成形品19を取り出したのち、第3図の成形
時における堰20およびその他の不用部分を除いて第7
図に示すように成形品19の製品形状を整え、/、/、
/−トリクロルエタンによる蒸気洗浄を60〜720秒
間続けて成形品19の脱脂、洗浄を行なう。
In the cleaning step 11, after the injection molding step 101, the molded product 19 is taken out from the molding die 1, and then the weir 20 and other unnecessary parts are removed from the molding step 7 as shown in FIG.
Arrange the product shape of the molded product 19 as shown in the figure, /, /,
The molded article 19 is degreased and cleaned by continuing steam cleaning with /-trichloroethane for 60 to 720 seconds.

前記製品表面塗装工程12は下塗り工程12aと上塗り
工、ff1l 2bとを行なうものであって、下塗り工
程12aは洗浄工程11のあと第66に示すように、成
形品19の表面21を上側に向けておき、被覆層15を
施した部分の外端にマスキングテープ22を貼付してマ
スキングしたのち、成形品19の表面21に対して、2
液ウレタン塗料によるプライマー26を噴霧塗装器24
で塗装し、塗膜の厚さを75〜30μに形成したのち、
/2θ0Cに加熱して20分間で硬化させる。前記上塗
り工程12bは下塗り工程12alこ続いて第3図に示
すように、上記のマスキングテープ22を取り除いたの
ち、成形品19の表側の全面に対して、/液つレタン塗
料によるトップコート25を噴霧塗装器26で塗装し、
塗膜の厚さを20〜グθμに形成したのち、/2θ0C
に加熱して30分間で硬化させる。
The product surface painting step 12 includes an undercoat step 12a and a top coat, ff1l 2b.The undercoat step 12a is performed after the cleaning step 11, as shown in No. 66, by turning the surface 21 of the molded product 19 upward. Then, masking tape 22 is applied to the outer edge of the part to which the coating layer 15 has been applied, and then the surface 21 of the molded product 19 is covered with 2
A paint device 24 sprays a primer 26 using liquid urethane paint.
After coating to form a coating film thickness of 75 to 30μ,
/2θ0C and harden for 20 minutes. The top coating step 12b is followed by the undercoating step 12al, and as shown in FIG. Paint with a spray paint machine 26,
After forming a coating film with a thickness of 20 to θμ, /2θ0C
Heat to harden for 30 minutes.

上記の実施例方法において、塗装しにくい成形品19の
探しぼり部18は、成形品19の射出成形工程10に先
行せしめた吹付は工程9によって、容易かつ均一に塗装
されるものであり、製品表面塗装工程12においてトッ
プコート25が深シホり部18の奥部に屈かないことが
あっても、該トップコートと被覆層15とを同色にして
おけば仕上りの外観美を損うことはない。ちなみに、上
記実施例方法に基づいて探しぼり部を有する合成樹脂成
形品の塗装を試みたところ、表−/の「本発明方法」の
欄に示す好ましい結果を得た。
In the method of the above embodiment, the locating portion 18 of the molded product 19 that is difficult to paint is easily and uniformly coated by spraying step 9, which is performed prior to the injection molding step 10 of the molded product 19. Even if the top coat 25 does not bend into the deep part of the deep scarf part 18 in the surface painting process 12, if the top coat and the coating layer 15 are made the same color, the appearance of the finished product will not be impaired. . Incidentally, when an attempt was made to paint a synthetic resin molded article having a searched portion based on the above-mentioned method of the example, favorable results were obtained as shown in the column of "Method of the present invention" in Table 2.

なお、上記実施例の洗浄工程11と下塗り工程12a・
のマスキングテープ22の貼付とは塗装仕様によって省
略してもよく、また本例に代えて、吹付は工程9はトッ
プコート25を適用し、製品表面塗装工程12は上塗り
工程12bのみにすることもできる。
Note that the cleaning step 11 and the undercoating step 12a of the above embodiment
The application of the masking tape 22 may be omitted depending on the coating specifications, and instead of this example, the top coat 25 may be applied in the spraying step 9, and the product surface painting step 12 may be performed only in the top coating step 12b. can.

(発明の効果) 本発明は上記の構成により、探しぼり部を有する樹脂成
形品は吹付は工程において探しぼり部の塗膜が均一に形
成され、該探しぼり部の塗膜とともに一体に形成される
成形工程を経たのち、製品表面塗装工程において前記探
しぼり部を有する成形品の表面に均一な塗膜が形成され
るから整った塗装外観に仕上げることができ、とりわけ
メタリック塗装の場合には優れた効果かある。
(Effects of the Invention) According to the above configuration of the present invention, a resin molded product having a search part is formed with a uniform coating film on the search part during the spraying process, and is formed integrally with the coating film on the search part. After going through the molding process, a uniform coating film is formed on the surface of the molded product having the above-mentioned cut-out parts in the product surface painting process, so it can be finished with a uniform painted appearance, and is especially excellent in the case of metallic paint. There is some effect.

表−/ 探しぼり部への被覆層の有無による樹脂成形品
の塗装部外観の比較 ※NBS単位 J I S Zj?730色差表示によ
る00.s以下 目視で識別難 /、2〜2.0 目視で識別可能、クレーム限界3.0
以上 目視で識別容易、クレームレベル
Table - Comparison of appearance of painted parts of resin molded products with and without coating layer on searched parts *NBS unit J I S Zj? 00.00 with 730 color difference display. s or less Difficult to visually identify/, 2 to 2.0 Visually identifiable, claim limit 3.0
Easy to visually identify, complaint level

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明方法の実施態様を例示し、第1図は離型剤
塗布工程を示す成形金型を開いた状態の縦断面図、第2
図は吹付は工程を示す凹型の縦断面図、第3図は射出成
形工程を示す成形金型の縦断面図、第7図は洗浄工程を
示す成形品の縦断面図、第5図および第3図はそれぞれ
製品表面塗装工程の下塗り工程および上塗り工程を示す
成形品の縦断面図、第7図は探しほり部塗装の従来例を
説明する成形品の縦断面図、第2図は各工程を示すブロ
ック図である。 1・・・・・・成形金型、2−・・・・・凹型、6・・
・ 金型、4・・・・・キャビティ、5・・・・・・突
出部、8・・・・・・離型剤塗布工程、9・・・・・イ
ンモールドコート吹付は工程、10・・・・・射出成形
工程、11・・・・・・洗浄工程、12・・・・・・製
品表面塗装工程、12a・・・・・・下塗り工程、12
b・・・・・上塗り工程、14・・・・・・ワックス離
型剤、15・・・・・・被覆層517・・・−・・合成
樹脂、19・・・・・・成形品、21・・・・・・表面
、22・・・・・・マスキングテープ、23・・・・・
・プライマー、25・・・・・トツブコートJ&、 廠
 〜 餘
The drawings illustrate embodiments of the method of the present invention, and FIG. 1 is a longitudinal sectional view of the mold in an open state showing the process of applying a mold release agent, and FIG.
The figure is a vertical cross-sectional view of the concave mold showing the spraying process, Figure 3 is a vertical cross-sectional view of the molding die showing the injection molding process, Figure 7 is a vertical cross-sectional view of the molded product showing the cleaning process, and Figures 5 and 3 are vertical cross-sectional views of the molded product showing the cleaning process. Figure 3 is a vertical cross-sectional view of a molded product showing the undercoating and top-coating processes of the product surface coating process, Figure 7 is a vertical cross-sectional view of a molded product illustrating a conventional example of coating the searched areas, and Figure 2 is a diagram showing each process. FIG. 1...Molding mold, 2-...Concave mold, 6...
・Mold, 4...Cavity, 5...Protrusion, 8...Mold release agent application process, 9...In-mold coat spraying process, 10. ...Injection molding process, 11...Cleaning process, 12...Product surface painting process, 12a...Undercoating process, 12
b...Top coating step, 14...Wax release agent, 15...Coating layer 517...Synthetic resin, 19...Molded product, 21...Surface, 22...Masking tape, 23...
・Primer, 25...Totsubu Coat J&, Factory ~ 餘

Claims (2)

【特許請求の範囲】[Claims] (1) キャビティ形成面に探しほり部を形成するため
の突出部が形成された金型と、該金型に対する金型とで
なる成形金型を準備し、該成形金型を開いた状態で、前
記金型の突出部に塗料の吹付けを行う吹付は工程と、前
記成形金型を型締めして該成形金型内に合成樹脂を導入
して成形品を成形する工程と、該成形品を成形金型から
取り出して前記探しぼり部を有する成形品の表面に合成
樹脂塗料を塗布する製品表面塗装工程とを順に行なうこ
とを特徴とする探しぼり部を有する樹脂成形品の塗装方
法。
(1) Prepare a mold consisting of a mold in which a protrusion is formed on the cavity forming surface and a mold for the mold, and open the mold. , a spraying step for spraying paint onto the protruding portion of the mold; a step of clamping the molding mold and introducing a synthetic resin into the molding mold to mold a molded product; A method for painting a resin molded article having a search section, comprising sequentially performing a product surface coating step of removing the article from a molding die and applying a synthetic resin paint to the surface of the molded article having the search section.
(2)製品表面塗装工程は、探しぼり部にマスキングし
たのち、プライマーを塗布する子塗り工程と、前記マス
キングを取り除いたのち、トップコートを塗布する上塗
り工程とを行なう特許請求の範囲第1項記載の探しぼり
部を有する樹脂成形品の塗装方法。
(2) The product surface painting process includes a sub-coating process in which a primer is applied after masking the searched areas, and a top-coating process in which a top coat is applied after the masking is removed. A method of painting a resin molded product having the described searching part.
JP17967983A 1983-09-27 1983-09-27 Coating method for resin molded article having deep- drawn portion Granted JPS6071224A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17967983A JPS6071224A (en) 1983-09-27 1983-09-27 Coating method for resin molded article having deep- drawn portion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17967983A JPS6071224A (en) 1983-09-27 1983-09-27 Coating method for resin molded article having deep- drawn portion

Publications (2)

Publication Number Publication Date
JPS6071224A true JPS6071224A (en) 1985-04-23
JPH0424212B2 JPH0424212B2 (en) 1992-04-24

Family

ID=16069973

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17967983A Granted JPS6071224A (en) 1983-09-27 1983-09-27 Coating method for resin molded article having deep- drawn portion

Country Status (1)

Country Link
JP (1) JPS6071224A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007260939A (en) * 2006-03-27 2007-10-11 Komatsu Ltd Molding method and molded product
JP2013233773A (en) * 2012-05-11 2013-11-21 Panasonic Corp Thickness control method for synthetic resin sheet
CN108943575A (en) * 2018-06-28 2018-12-07 北京小米移动软件有限公司 Double-material injection-molding method and terminal shell

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007260939A (en) * 2006-03-27 2007-10-11 Komatsu Ltd Molding method and molded product
JP2013233773A (en) * 2012-05-11 2013-11-21 Panasonic Corp Thickness control method for synthetic resin sheet
CN108943575A (en) * 2018-06-28 2018-12-07 北京小米移动软件有限公司 Double-material injection-molding method and terminal shell
CN108943575B (en) * 2018-06-28 2020-07-21 北京小米移动软件有限公司 Double-material injection molding method and terminal shell

Also Published As

Publication number Publication date
JPH0424212B2 (en) 1992-04-24

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