JPS6077143A - Silicate laser glass - Google Patents
Silicate laser glassInfo
- Publication number
- JPS6077143A JPS6077143A JP18440583A JP18440583A JPS6077143A JP S6077143 A JPS6077143 A JP S6077143A JP 18440583 A JP18440583 A JP 18440583A JP 18440583 A JP18440583 A JP 18440583A JP S6077143 A JPS6077143 A JP S6077143A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- thermal expansion
- laser
- nd2o3
- sio2
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000087 laser glass Substances 0.000 title claims abstract description 18
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 229910052745 lead Inorganic materials 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- 239000011521 glass Substances 0.000 abstract description 19
- 238000010791 quenching Methods 0.000 abstract description 5
- 230000000171 quenching effect Effects 0.000 abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052593 corundum Inorganic materials 0.000 abstract description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 abstract 3
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 230000006698 induction Effects 0.000 abstract 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 2
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 1
- 229910019714 Nb2O3 Inorganic materials 0.000 abstract 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 1
- 230000035939 shock Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 3
- 239000005365 phosphate glass Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910011763 Li2 O Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/068—Glass compositions containing silica with less than 40% silica by weight containing boron containing rare earths
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はガラス形成成分としてＰ、０．と５ｉ０２ヲ併
有したレーザーガラスに関する。DETAILED DESCRIPTION OF THE INVENTION The present invention uses P, 0.5% as glass-forming components. Regarding laser glass that has both 5i02 and 5i02.
比較的多量のアルカリ成分を含有する燐酸塩レーザーガ
ラスは、誘導放出断面積が大きいという長所を具えてい
るものの、機械的強度及び化学的耐久性が貧弱であるこ
とに加えて、熱膨張係数が大きい故に耐熱衝撃性が小さ
いことが欠点とじてた欠点は、そのガラス組成にＲ’、
０３（Ｒ’はＹ、Ｌａ。Phosphate laser glass, which contains a relatively large amount of alkaline components, has the advantage of a large stimulated emission cross section, but has poor mechanical strength and chemical durability, as well as a low coefficient of thermal expansion. The drawback is that the thermal shock resistance is low due to the large size, but the glass composition has R',
03 (R' is Y, La.
Ｂ％ＡＩを示す）やＲ１０（Ｒ’はＭｇ、 Ｃａ、 ８
ｒ。B%AI) and R10 (R' is Mg, Ca, 8
r.
Ｂａ、Ｚｎ％ｐｂを示す。以下同じ）を配合することで
改善することができる。しかし、Ｂ′２０３やＲ’０の
配合はレーザーガラスの誘導放出断面積を低下させる不
都合がある。一方、珪酸塩レーザーガラスは一般に機械
的強度と耐熱衝撃性が大きい反面、誘導放出断面積が小
さい。Shows Ba, Zn%pb. This can be improved by adding (the same applies hereinafter). However, the combination of B'203 and R'0 has the disadvantage of reducing the stimulated emission cross section of the laser glass. On the other hand, silicate laser glasses generally have high mechanical strength and thermal shock resistance, but have a small stimulated emission cross section.
本発明は燐酸塩レーザーガラスと珪酸塩レーザーガラス
のそれぞれの長所を兼ね備えた、具体的には誘導放出断
面積が大きいうえに耐熱衝撃性も大きい、従って熱膨張
係数がホブいレーザーガラスを提供するものである。The present invention provides a laser glass that combines the respective advantages of phosphate laser glass and silicate laser glass, specifically, has a large stimulated emission cross section and high thermal shock resistance, and therefore has a high coefficient of thermal expansion. It is something.
本発明者等が得た知見によれば、従来燐酸塩レーザーガ
ラスの欠点を改善する目的でガラス組成に配合されてい
たＡＩ、０３とＲ１０の一部又は全部を８ ｘ ０２で
置換することにより、＊酸塩レーザーガラス本央の誘導
放出断面積を客質的に損うことな（熱膨張係数を小さく
、従って耐熱衝撃性を大きくすることができる。しかも
燐酸塩ガラスへの８ｉ０２の多量添加は、一般に分相乃
至結晶化を招くとされているにも拘らず、本発明のガラ
ス組成にはそうした傾向が認められないばかりか、螢光
の濃度消光が小さいガラスが得られることを本発明者等
は確認した。According to the knowledge obtained by the present inventors, by replacing part or all of AI, 03 and R10, which were mixed in the glass composition with 8 x 02, in order to improve the drawbacks of conventional phosphate laser glass. ,*Without objectively damaging the stimulated emission cross-section of the phosphate laser glass (the coefficient of thermal expansion can be reduced, and therefore the thermal shock resistance can be increased), a large amount of 8i02 can be added to the phosphate glass. Although it is generally believed that this causes phase splitting or crystallization, the glass composition of the present invention not only does not exhibit such a tendency, but also provides a glass with low concentration quenching of fluorescence. The parties have confirmed.
而して本発明の珪燐酸塩レーザーガラスは、Ｐ、０．−
５ｉ０２− Ｒ，０（几はＬｉ％Ｎａ％Ｋを示す）−Ｎ
ｄ、０．を基本組成とし、モルチ表示でＰ、０．４５〜
７０．８ｉ０．８〜３０、Ｐ２Ｏ，−）−８ｉ０２６５
〜９５、Ｌ １２０＋ Ｎａ 、！０ ＋Ｋ ｔ ０
４〜２０、Ｎｄ２Ｏ，０，０１〜１２、Ａｌ２Ｏ。The silicate phosphate laser glass of the present invention has P, 0. −
5i02-R,0 (几 indicates Li%Na%K)-N
d, 0. The basic composition is P, 0.45 to 0.45 in molti
70.8i0.8~30,P2O,-)-8i0265
~95, L 120+ Na,! 0 + K t 0
4-20, Nd2O, 0.01-12, Al2O.
Ｏ〜１０、 Ｌａ、０３−１−Ｙ、Ｏ５−１−Ｂ、Ｏ８
Ｏ〜５、 Ｒ２Ｏ０〜１０、Ｎｂ２０６−）−ＣｅＯ，
０〜１の組成を有することを特徴とする。そしてこのガ
ラスのレーザーガラスとしての特長点は、螢光の濃度消
光が小さく、誘導放出断面積が犬で熱膨張係数が小さい
ことにある。O~10, La, 03-1-Y, O5-1-B, O8
O~5, R2O0~10, Nb206-)-CeO,
It is characterized by having a composition of 0 to 1. The advantages of this glass as a laser glass are that the concentration quenching of fluorescent light is small, the stimulated emission cross section is large, and the coefficient of thermal expansion is small.
本発明のガラス組成（モルチ表示）に於て、Ｐ２Ｏ，は
４５〜７０％存在していることが必要であって、この範
囲を逸脱した場合にはガラスの安定性が悪化する。５ｉ
０２１ｉ８〜３０％の範囲で誘導放出断面積を大幅に低
下させることなく、熱膨張係数を小さくするが、３０チ
を越えると誘導放出断面積が所望値より低下する。また
、誘導放出断面積を高水準に保持したまま、熱膨張係数
を小さくするためには、Ｐ２０Ｈ＋Ｓ ＋ Ｏｔの合量
は６５〜９５％の範囲になければならない。In the glass composition of the present invention (in molten representation), it is necessary that P2O is present in an amount of 45 to 70%, and if it deviates from this range, the stability of the glass will deteriorate. 5i
In the range of 021i from 8 to 30%, the coefficient of thermal expansion is reduced without significantly reducing the stimulated emission cross section, but when it exceeds 30%, the stimulated emission cross section decreases from the desired value. Further, in order to reduce the coefficient of thermal expansion while maintaining the stimulated emission cross section at a high level, the total amount of P20H+S + Ot must be in the range of 65 to 95%.
Ｌ１２０＋Ｎａ、Ｏ＋に２０の合量が４チ未満ではガラ
ス化が困難になり、２０チを越えると熱膨張係数が大き
くなるので、本発明では４〜２０％の範囲が選ばれてい
る。ちなみに、熱膨張係数を小さくするうえではＬｉ２
Ｏが有利でめるが、誘導放出断面積を犬きくする点では
に、０が有利である。Ｎｄ、０３はレーザーガラスの必
須成分であって、レーザーガラスとしての特性を発揮さ
せるには、少なくとも０．０１％のＮｄ２Ｏ，が必要で
あり、本発明のガラス組成では１２％（Ｎｄ３＋イオン
として３０ Ｘ １０２゜イオン／ＣＣ）まで導入可能
である。If the total amount of L120+Na, O+ and 20 is less than 4 inches, vitrification becomes difficult, and if it exceeds 20 inches, the coefficient of thermal expansion increases, so in the present invention, a range of 4 to 20% is selected. By the way, in order to reduce the coefficient of thermal expansion, Li2
O is advantageous, but 0 is particularly advantageous in terms of increasing the stimulated emission cross section. Nd,03 is an essential component of laser glass, and in order to exhibit its properties as a laser glass, at least 0.01% of Nd2O, is required, and in the glass composition of the present invention, it is 12% (30% as Nd3+ ions). It is possible to introduce up to X 102° ions/CC).
任意成分について言えば、Ａｌ２Ｏ３は０〜１０％の範
囲で誘導放出断面積に著しい悪影響を及ぼすことなく、
熱膨張係数を小さくする。そして化学的耐久性を向上略
せるためには５％以上含まれていることが望ましい。Ｌ
”ｔＯｓ＋Ｙｚ ｏ３＋ Ｂ２Ｏ３は０〜５チの範囲で
ＡＩ、０．に置換して使用することができる。几１０（
Ｒ２Ｍｇ、Ｃａ、 Ｓｒ、 Ｂａ％Ｚｎ、 Ｐｂ）は０
〜１０％の範囲でＬｉ、０、Ｎａ２Ｏ、Ｋ、Ｏｖｃ置換
して用いることができ、熱膨張係数の低下、化学的耐久
性の向上に有効である。また、Ｎｂ、Ｕ、 −１−Ｃｅ
Ｏ。Regarding optional ingredients, Al2O3 can be used in the range of 0-10% without any significant negative effect on the stimulated emission cross section.
Reduce the coefficient of thermal expansion. In order to improve chemical durability, it is desirable that the content be 5% or more. L
"tOs+Yz o3+ B2O3 can be used by replacing AI with 0. in the range of 0 to 5.
R2Mg, Ca, Sr, Ba%Zn, Pb) is 0
It can be used by replacing Li, 0, Na2O, K, and Ovc in a range of 10% to 10%, and is effective in lowering the coefficient of thermal expansion and improving chemical durability. Also, Nb, U, -1-Ce
O.
は０〜１％の範囲でソー２リゼーシヨン防止剤として有
効に働く成分である。is a component that effectively works as a saw resorption inhibitor in the range of 0 to 1%.
本発明の珪燐酸塩レーザーガラスは、上記したガラス組
成が得られるようガラス原料を配合して浴融し、常法通
り乾燥ガスによるノ々シリング等のされる。The silicate phosphate laser glass of the present invention is prepared by blending glass raw materials to obtain the glass composition described above, melting the glass in a bath, and subjecting the glass to a conventional method such as sintering with a dry gas.
次に実施例を示して本発明に係るレーザーガラスの性状
を具体的に説明する。Next, the properties of the laser glass according to the present invention will be specifically explained with reference to Examples.
実施例１
実施例２
Ｎｄ３イオン濃度を変化式せた以外は実施例１のｔＪｎ
８の組成で５種の珪燐酸塩ガラスを調製し、各ガラスの
螢光寿命を測定した。結果を表２に示す。Example 1 Example 2 tJn of Example 1 except that the Nd3 ion concentration was changed by the formula
Five types of silicate phosphate glasses were prepared with composition No. 8, and the fluorescence lifetime of each glass was measured. The results are shown in Table 2.
尚、螢光寿命はガラス中に含まれる水の量に影響される
ため、３．３μ付近に生ずる０−Ｈ振動に基づく赤外吸
収の吸収係数を水の量の尺度として表２に併記した。In addition, since the fluorescence lifetime is affected by the amount of water contained in the glass, the absorption coefficient of infrared absorption based on the 0-H vibration that occurs around 3.3μ is also listed in Table 2 as a measure of the amount of water. .
表２から明らかな如く、本発明の珪燐酸塩ガラスは螢光
の濃度消光が小さく、Ｎｄ、０．を高濃度域までドープ
することが可能なため、小さなサイズで高効率、高出力
のガラスレーザーを構成することが期待できる。As is clear from Table 2, the silicate phosphate glass of the present invention has a small concentration quenching of fluorescence, and Nd, 0. Since it is possible to dope up to a high concentration range, it is expected that a small-sized, highly efficient, high-output glass laser can be constructed.
Claims (1)
３０、Ｐ、Ｏ，＋８ｉ０，６５〜９５、Ｌ ｔ ＊ Ｏ
＋Ｎａ ！Ｏ＋ Ｋ ｔ Ｏ４〜２．０、Ｎｄ、０３０
．０１〜１２、ＡＩ、０．０〜１０％Ｌａ、０．＋Ｙ、
０３−）−Ｂ、０．０〜５、Ｒ２Ｏ（但し、ＫはＭｇ、
Ｃａ％Ｓｒ。 Ｂａ％Ｚｎ％Ｐｂを示す） Ｏ％ １０ 、 Ｎｂ、０
．−１−Ｃｅ０゜θ〜１の組成を有する珪燐酸塩レーザ
ーガラス。[Claims] 1. P in molti, 0.45-70.1liio, 8-
30, P, O, +8i0, 65-95, L t * O
+Na! O+ Kt O4~2.0, Nd, 030
．． 01-12, AI, 0.0-10% La, 0. +Y,
03-)-B, 0.0-5, R2O (however, K is Mg,
Ca%Sr. Ba%Zn%Pb) O% 10, Nb, 0
．． -1-Ce A silicate phosphate laser glass having a composition of 0° θ to 1.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18440583A JPS6077143A (en) | 1983-10-04 | 1983-10-04 | Silicate laser glass |
| DE19843435133 DE3435133A1 (en) | 1983-10-04 | 1984-09-25 | Silicophosphate laser glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18440583A JPS6077143A (en) | 1983-10-04 | 1983-10-04 | Silicate laser glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6077143A true JPS6077143A (en) | 1985-05-01 |
| JPS6319451B2 JPS6319451B2 (en) | 1988-04-22 |
Family
ID=16152590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18440583A Granted JPS6077143A (en) | 1983-10-04 | 1983-10-04 | Silicate laser glass |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS6077143A (en) |
| DE (1) | DE3435133A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012102002A (en) * | 2010-09-13 | 2012-05-31 | Schott Corp | Aluminophosphate glass composition |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61215233A (en) * | 1985-03-19 | 1986-09-25 | Hoya Corp | Silicophosphate laser glass |
| US4661284A (en) * | 1985-09-25 | 1987-04-28 | The United States Of America As Represented By The United States Department Of Energy | Silica and boron-containing ultraphosphate laser glass with low concentration quenching and improved thermal shock resistance |
| US4929387A (en) * | 1988-08-31 | 1990-05-29 | Schott Glass Technologies, Inc. | Phosphate glass useful in high power lasers |
| US5032315A (en) * | 1989-04-03 | 1991-07-16 | Schott Glass Technologies, Inc. | Phosphate glass useful in high power lasers |
| US6636347B1 (en) * | 2000-11-08 | 2003-10-21 | Corning Incorporated | Phosphorus-silicate fibers suitable for extended band amplification |
| EP4524117A1 (en) * | 2023-09-12 | 2025-03-19 | The Penn State Research Foundation | Low-melting glass compositions, articles, and methods of making the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4075120A (en) * | 1975-05-14 | 1978-02-21 | Kogre, Inc. | Laser phosphate glass compositions |
-
1983
- 1983-10-04 JP JP18440583A patent/JPS6077143A/en active Granted
-
1984
- 1984-09-25 DE DE19843435133 patent/DE3435133A1/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012102002A (en) * | 2010-09-13 | 2012-05-31 | Schott Corp | Aluminophosphate glass composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6319451B2 (en) | 1988-04-22 |
| DE3435133A1 (en) | 1985-04-11 |
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