JPS6081179A - ニトロエテニルチオフエン系化合物 - Google Patents

ニトロエテニルチオフエン系化合物

Info

Publication number: JPS6081179A
Authority: JP; Japan
Prior art keywords: absorption; thiophene; group; water; ring
Prior art date: 1983-10-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP19158883A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6119631B2 (da

Inventor

Hajime Satonaka

里中　初

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

KANAGAWAKEN CHIJI

Original Assignee

KANAGAWAKEN CHIJI

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-10-13

Filing date

1983-10-13

Publication date

1985-05-09

1983-10-13 Application filed by KANAGAWAKEN CHIJI filed Critical KANAGAWAKEN CHIJI

1983-10-13 Priority to JP19158883A priority Critical patent/JPS6081179A/ja

1985-05-09 Publication of JPS6081179A publication Critical patent/JPS6081179A/ja

1986-05-17 Publication of JPS6119631B2 publication Critical patent/JPS6119631B2/ja

Status Granted legal-status Critical Current

Links

150000001875 compounds Chemical class 0.000 title claims abstract description 11
UTPOWFFIBWOQRK-UHFFFAOYSA-N 2-(2-nitroethenyl)thiophene Chemical compound [O-][N+](=O)C=CC1=CC=CS1 UTPOWFFIBWOQRK-UHFFFAOYSA-N 0.000 title 1
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical group C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims abstract description 39
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims description 3
YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims 1
125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
229930192474 thiophene Natural products 0.000 abstract description 16
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
125000001424 substituent group Chemical group 0.000 abstract description 5
230000000843 anti-fungal effect Effects 0.000 abstract description 4
229940121375 antifungal agent Drugs 0.000 abstract description 4
-1 nitro, carboxyl Chemical group 0.000 abstract description 3
239000000126 substance Substances 0.000 abstract description 3
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract description 2
125000000217 alkyl group Chemical group 0.000 abstract description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
RBIGKSZIQCTIJF-UHFFFAOYSA-N 3-formylthiophene Chemical compound O=CC=1C=CSC=1 RBIGKSZIQCTIJF-UHFFFAOYSA-N 0.000 abstract 1
YFHYTCZRPGXHCF-UHFFFAOYSA-N 3-methyl-2-(2-nitroethenyl)thiophene Chemical compound CC=1C=CSC=1C=C[N+]([O-])=O YFHYTCZRPGXHCF-UHFFFAOYSA-N 0.000 abstract 1
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 abstract 1
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 abstract 1
125000003545 alkoxy group Chemical group 0.000 abstract 1
239000003429 antifungal agent Substances 0.000 abstract 1
239000004599 antimicrobial Substances 0.000 abstract 1
CNUDBTRUORMMPA-UHFFFAOYSA-N formylthiophene Chemical compound O=CC1=CC=CS1 CNUDBTRUORMMPA-UHFFFAOYSA-N 0.000 abstract 1
239000000463 material Substances 0.000 abstract 1
LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 abstract 1
239000002904 solvent Substances 0.000 abstract 1
238000010521 absorption reaction Methods 0.000 description 71
230000015572 biosynthetic process Effects 0.000 description 11
238000003786 synthesis reaction Methods 0.000 description 11
238000005481 NMR spectroscopy Methods 0.000 description 10
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
238000000921 elemental analysis Methods 0.000 description 9
238000005259 measurement Methods 0.000 description 8
238000000034 method Methods 0.000 description 8
239000000243 solution Substances 0.000 description 6
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
241000534944 Thia Species 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000000844 anti-bacterial effect Effects 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
CXOFVDLJLONNDW-UHFFFAOYSA-N Phenytoin Chemical group N1C(=O)NC(=O)C1(C=1C=CC=CC=1)C1=CC=CC=C1 CXOFVDLJLONNDW-UHFFFAOYSA-N 0.000 description 2
125000004989 dicarbonyl group Chemical group 0.000 description 2
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
BQQXUGGTSVMBLL-UHFFFAOYSA-N methyl 2-sulfanylidene-1h-pyridine-3-carboxylate Chemical compound COC(=O)C1=CC=CNC1=S BQQXUGGTSVMBLL-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
238000001953 recrystallisation Methods 0.000 description 2
DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
UFSBFMDTWVPCIA-UHFFFAOYSA-N 2-(2-chloro-2,2-diphenylacetyl)oxyethyl-diethylazanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1C(Cl)(C(=O)OCC[NH+](CC)CC)C1=CC=CC=C1 UFSBFMDTWVPCIA-UHFFFAOYSA-N 0.000 description 1
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
235000017166 Bambusa arundinacea Nutrition 0.000 description 1
235000017491 Bambusa tulda Nutrition 0.000 description 1
241001330002 Bambuseae Species 0.000 description 1
241000723346 Cinnamomum camphora Species 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical class OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
235000015334 Phyllostachys viridis Nutrition 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
239000002253 acid Substances 0.000 description 1
125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000011425 bamboo Substances 0.000 description 1
229960000846 camphor Drugs 0.000 description 1
229930008380 camphor Natural products 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
239000001307 helium Substances 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
JMBPWMGVERNEJY-UHFFFAOYSA-N helium;hydrate Chemical compound [He].O JMBPWMGVERNEJY-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000002689 soil Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
210000002784 stomach Anatomy 0.000 description 1
125000001544 thienyl group Chemical group 0.000 description 1

Landscapes

Heterocyclic Compounds Containing Sulfur Atoms (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

JP19158883A 1983-10-13 1983-10-13 ニトロエテニルチオフエン系化合物 Granted JPS6081179A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP19158883A JPS6081179A (ja)	1983-10-13	1983-10-13	ニトロエテニルチオフエン系化合物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP19158883A JPS6081179A (ja)	1983-10-13	1983-10-13	ニトロエテニルチオフエン系化合物

Publications (2)

Publication Number	Publication Date
JPS6081179A true JPS6081179A (ja)	1985-05-09
JPS6119631B2 JPS6119631B2 (da)	1986-05-17

Family

ID=16277136

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP19158883A Granted JPS6081179A (ja)	1983-10-13	1983-10-13	ニトロエテニルチオフエン系化合物

Country Status (1)

Country	Link
JP (1)	JPS6081179A (da)

1983
- 1983-10-13 JP JP19158883A patent/JPS6081179A/ja active Granted

Also Published As

Publication number	Publication date
JPS6119631B2 (da)	1986-05-17

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