JPS6099056A - Production of heat resistant high strength nonwoven fabric - Google Patents
Production of heat resistant high strength nonwoven fabricInfo
- Publication number
- JPS6099056A JPS6099056A JP58205340A JP20534083A JPS6099056A JP S6099056 A JPS6099056 A JP S6099056A JP 58205340 A JP58205340 A JP 58205340A JP 20534083 A JP20534083 A JP 20534083A JP S6099056 A JPS6099056 A JP S6099056A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- resistant
- fibers
- fiber
- nonwoven fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nonwoven Fabrics (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、強度、耐熱性並びに寸法安定性が共に優れた
不織布の製造法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing a nonwoven fabric having excellent strength, heat resistance, and dimensional stability.
不織布は従来、芯地、使い捨て衣料2合成皮革基4′、
A等の衣料用拐料、壁装利、カーテン等の室内装飾品、
フェルト、フィルター、断熱材、吸音材。Conventionally, non-woven fabrics include interlining, disposable clothing 2 synthetic leather base 4',
Clothing materials such as A, wall decorations, interior decoration items such as curtains, etc.
Felt, filters, insulation and sound absorbing materials.
バッテリーセパレータ等の工業用材料等に広く用いられ
、近時その用途は益々拡大多様化され、電気被覆拐等の
電気絶縁4′A料、プリント配線用積層板、LL布、ベ
ルト基材、防弾衣服等の特殊IF RP J41補強布
等、特に薄層でありながら大きい耐熱性。It is widely used in industrial materials such as battery separators, and its applications have recently become increasingly expanded and diversified. Special IF RP J41 reinforcement cloth for clothing, etc., especially thin layer but with great heat resistance.
強度および寸法安定性を要求される分野にまで利用され
つつある。It is now being used in fields that require strength and dimensional stability.
一般に不織布は合成繊組:、半合成繊維、天然繊、un
+ 、無機g!8維等、用途に応じて任意の繊糸1仁か
ら作られ、それらの短線糸11:からなるウェブをニー
ドルパンチングによる交絡、接着剤の作用あるいは構成
繊維ゐ浴)r7等により繊組相互を結合させる方法が多
用されている。上記ウェブの形成は通常カーディングま
たはエア・レイ方式によって行なわれ、それに使用され
る繊維は作業性向上のため多少に拘らず捲縮又は屈曲を
予めN°与されている。またカーディング直後のウェブ
即ちパラレルウェブは()η成繊糾:が可成りの方向性
を以って配列しているため、それから得られた不織布は
無配向の所謂、ランダムウェブからの不織布に較べて配
向軸方向の強度が大である。しかし乍ら、パラレルウェ
ブにおいても尚、製造過程に゛おける繊維の揺動や残存
捲縮等のため、繊維は互いに完全に並行になっていると
は云えず、従って、それから得られた不織布に構成繊維
の強度が充分に具現されなかった。In general, nonwoven fabrics are made of synthetic fibers:, semi-synthetic fibers, natural fibers, unwoven fibers,
+, inorganic g! 8 fibers, etc., depending on the purpose, and the web consisting of these short filaments 11 is interlaced by needle punching, the action of an adhesive or the constituent fiber bath) R7, etc. Combining methods are often used. The formation of the above-mentioned web is usually carried out by carding or air-laying, and the fibers used therein are crimped or bent to a certain degree in advance to improve workability. In addition, in the web immediately after carding, that is, the parallel web, ()η synthetic fibers: are arranged with considerable directionality, so the nonwoven fabric obtained therefrom is a nonwoven fabric from a non-oriented, so-called random web. In comparison, the strength in the orientation axis direction is large. However, even in parallel webs, it cannot be said that the fibers are completely parallel to each other due to oscillation of the fibers and residual crimping during the manufacturing process, and therefore, the nonwoven fabric obtained from it The strength of the constituent fibers was not sufficiently realized.
一方、素拐面から見ると、通常汎用されている合成線部
、例えばポリエチレンテレフタレート。On the other hand, from a material perspective, synthetic wire parts that are commonly used, such as polyethylene terephthalate.
ナイロン66、ナイロン6、ポリオレフィン等よりなる
繊ホ1「はその融点が約270℃以下であり、それらを
用いた不織布は約120℃〜200℃において軟化収縮
すると共に強度を失い実用に耐えられなくなる。また、
無機繊維、例えばガラス繊維、セラミック繊維、シリカ
繊維、炭化珪素繊維。Fibers made of nylon 66, nylon 6, polyolefin, etc. have melting points of about 270°C or lower, and nonwoven fabrics made from them soften and shrink at about 120°C to 200°C, lose strength, and become unusable. .Also,
Inorganic fibers, such as glass fibers, ceramic fibers, silica fibers, and silicon carbide fibers.
窒化珪素繊維等は、一般に剛直であり屈折強度が小さい
ため、カーディング工程において困漣に遭遇し、特に1
」付の小なる薄葉シート材料を乾式法で製造することは
至難とされるのみならず、ガラス繊糸11を除くと概し
て高価であり実用上好ましくない。更に、天然繊維は強
度並びに寸法安定性の曲で用途が著しく制限される。Silicon nitride fibers, etc. are generally rigid and have low refractive strength, so they encounter difficulties in the carding process.
It is not only extremely difficult to produce a small thin sheet material with "" by a dry method, but also it is generally expensive except for the glass fiber thread 11, which is not preferred in practice. Additionally, natural fibers are severely limited in their use due to their strength and dimensional stability.
更に寸だ、近時、耐熱性高強度繊維として芳香族ポリア
ミド繊維即ちアラミド繊維や、炭素繊維が開発され実用
化されるに及んで、例えばアラミド繊維とポリエステル
繊維とよりなる耐熱性の不織布は既に公知である。しか
しながら、そのものの強度並びに寸法安定性は、不x、
成布に固有の構造特性の故に、ポリエステル繊w、10
0%からなる不織布と余り差の認められないものであり
、裂断長は5,000 m未満程度に過ぎず、破断伸度
は約20%以上にも及び、簿層品としてT)iJ述の特
定の用途に適合すべきものとは程遠い。Furthermore, in recent years, aromatic polyamide fibers (aramid fibers) and carbon fibers have been developed and put into practical use as heat-resistant, high-strength fibers. For example, heat-resistant nonwoven fabrics made of aramid fibers and polyester fibers have already been developed. It is publicly known. However, its strength and dimensional stability are
Due to the inherent structural properties of the fabric, polyester fibers w, 10
There is no discernible difference from nonwoven fabric made of 0%, the breaking length is only about less than 5,000 m, and the breaking elongation is about 20% or more. is far from what it should be suitable for a specific use.
このような現状の技術的背景の中で、本発明者等は、電
気絶縁AA料、フレキシブル銅張積磨板(00L)基布
、ベルト基材、防弾衣服等の多層FRP用補強布等に特
に好適に用いることのできる耐熱性7強度9寸法安定性
並びに可撓性において共に優れた薄葉シート拐料を経済
的有利に提供する目的を以って鋭意研究の結果、本発明
に到達したものである。Against this current technical background, the present inventors have developed electrical insulating AA materials, flexible copper-clad laminated board (00L) base fabrics, belt base materials, reinforcing fabrics for multilayer FRP such as bulletproof clothing, etc. The present invention was arrived at as a result of intensive research aimed at economically advantageously providing a thin sheet material that is particularly advantageous in terms of heat resistance, strength, dimensional stability, and flexibility. It is.
すなわち本発明に係る耐〃も性高強度不織布は、ステー
ブル状耐熱性繊糾と該耐熱性繊維の熱変形温度未満の粘
着温度を有するステーブル状熱nJ塑性繊維とが1%0
〜9才。の重量比を以って均一に混合されてなるソート
材料であって、前記耐熱性繊維は捲縮・屈曲等を除かれ
た実質的直線状をなして」二記シート材刺の拡がり方向
の1ji−軸に沿って配向した骨格材を形成すると共に
、前記熱可塑性繊維は少なくとも部分的にnいに接着し
た状態で1111記骨格4Aと一体的なマトリックス全
形成してなり、該シート桐材は少なくとも約a、ooo
mの裂断長と、たかだか約5%の破断伸度と′f:有す
ることを特徴とし、更にかかるシートイオ料と、そのH
I成織繊維表面に付着した全繊維重量の5〜50%の繊
維用樹脂加工剤とよりなる樹脂加工繊維構造物の揚台は
、少なくとも約12,000 、nの裂断長と、たかだ
か約3%の破断伸度とを有することを特徴とするもので
ある。That is, the moisture-resistant high-strength nonwoven fabric according to the present invention has stable heat-resistant fibers and stable thermo-NJ plastic fibers having a cohesive temperature lower than the heat deformation temperature of the heat-resistant fibers.
~9 years old. The heat-resistant fibers are uniformly mixed in a weight ratio of The thermoplastic fibers are at least partially adhered to form a matrix integral with the skeleton 4A of No. 1111, and the sheet paulownia material is at least about a,ooo
It is characterized by having a breaking length of m and a breaking elongation of at most about 5%, and further comprising such a sheet ion material and its H
The lifting platform of a resin-treated fiber structure consisting of a fiber resin finishing agent of 5 to 50% of the total fiber weight attached to the surface of the woven fibers has a tearing length of at least about 12,000, n, and at most about It is characterized by having a breaking elongation of 3%.
また上述のシート桐材は、ステーブル状耐熱性繊糾と、
該耐熱性繊維の熱変形温度未満の粘着温度を有するステ
ーブル状熱可塑性繊維とを4゜〜宵。好ましくは2*o
〜8*oの重量比を以って均一に混合してなるパラレル
ウェブを前記熱可塑性繊維の粘着ff1i度以」二に加
熱すると共に、−軸方向に5〜100%、好ましくは1
5〜35%延伸し、かくして軟化乃至溶融状態にある熱
可塑性繊維、によって結合、保持された耐熱性繊維をそ
の捲縮。In addition, the above-mentioned sheet paulownia material is made of stable heat-resistant fiber,
Stable thermoplastic fibers having a sticking temperature below the heat distortion temperature of the heat-resistant fibers are heated at 4° to overnight. Preferably 2*o
A parallel web formed by uniformly mixing the thermoplastic fibers at a weight ratio of ~8*o is heated to a temperature higher than the adhesiveness of the thermoplastic fibers, and at the same time the web is heated to a temperature of 5 to 100% in the -axial direction, preferably 1
The heat-resistant fibers are stretched by 5 to 35% and thus bonded and held by the thermoplastic fibers in a softened or molten state, and the heat-resistant fibers are crimped.
屈曲を伸長しつつ延伸方向に配向させ、しかる後冷却固
化して前記熱可塑性繊維を、それらが少なくとも部分的
に相互に接着し且つ前記伸、長配向した耐熱性繊維を一
体的に包絡してなるシート状マトリックスとなすことを
特徴とする製造法によって取得することができ、更に物
性値がより改良された前述の樹脂加工tJA維構造物は
、上記シート桐材に繊細、用樹脂加工を施して全繊維重
量の5〜50%(固形分換算)の樹脂を付与することを
特徴とする製法によって製造することができる。The thermoplastic fibers are oriented in the stretching direction while being stretched, and then cooled and solidified so that the thermoplastic fibers are at least partially adhered to each other and integrally envelop the stretched and long-oriented heat-resistant fibers. The above-mentioned resin-treated tJA fiber structure, which can be obtained by a manufacturing method characterized by forming a sheet-like matrix and has further improved physical properties, is obtained by subjecting the sheet paulownia material to delicate resin processing. It can be manufactured by a manufacturing method characterized by applying resin in an amount of 5 to 50% (in terms of solid content) of the total fiber weight.
本発明に適用される耐熱性tJAillは、少なくとも
約300℃の熱変形湿度を有する有機または無機繊維が
好ましく、また、本発明不織布の骨格材となるものであ
るから少なくとも約10’7の引張強度を有するものが
好適である。The heat-resistant tJAill applied to the present invention is preferably an organic or inorganic fiber having a heat deformation humidity of at least about 300°C, and also has a tensile strength of at least about 10'7 since it becomes the skeleton material of the nonwoven fabric of the present invention. It is preferable to have the following.
ここに熱変形温度とはvA紐を形成する材料が実質的な
熱収縮乃至は塑性流動を起こすか、熱分解を生ずる温度
を云い、熱溶融性材料からなる繊維においては、その組
成、繊維径等によっても相違するが、固有の融点以下2
0〜80℃程度の温度であるといわれる。Here, the heat deformation temperature refers to the temperature at which the material forming the vA string undergoes substantial thermal contraction, plastic flow, or thermal decomposition. etc., but below the specific melting point 2
It is said that the temperature is about 0 to 80°C.
かかる耐熱性繊維としては、例えばポリパラフェニレン
テレ7タルアミド、ポリメタフェニレンイソフタルアミ
ド等のアラミド繊維、炭素繊維。Examples of such heat-resistant fibers include aramid fibers such as polyparaphenylenetere-7-talamide and polymetaphenylene isophthalamide, and carbon fibers.
フェノール繊維および例えば金属繊維、ガラス繊維、セ
ラミックファイバー、炭化珪異繊維、窒化珪素繊維等の
無機繊維が挙げられるが、就中、価格9入手可能性およ
び他の特性例えば耐折性1作業性等の観点からポリパラ
フェニレンテレフタルアミドおよび炭素繊維が特に有利
である。Mention may be made of phenolic fibers and inorganic fibers such as metal fibers, glass fibers, ceramic fibers, silicon carbide fibers, silicon nitride fibers, among others, with particular emphasis on price, availability and other properties such as folding resistance, workability, etc. From this point of view, polyparaphenylene terephthalamide and carbon fibers are particularly advantageous.
かかる耐熱性繊維は本発明の不織布の耐熱性、高強度9
寸法安定性を高水準に維持するための骨格材となる。Such heat-resistant fibers have high heat resistance and high strength 9 of the nonwoven fabric of the present invention.
It serves as a framework material to maintain a high level of dimensional stability.
また本発明に用いられる熱可塑性繊維はその粘ス°’I
7AM度が上述の耐熱性繊維の熱変形温度未満である
ことを要し、例えばポリエチレン、ポリプロピレン等の
ポリオレフィンtaAI[i:ポリビニルクロライド、
ポリビニリデンクロライド、ポリアクリロニトリル等の
ビニル系繊維;ポリエチレンテレフタレート、ポリプロ
ピレンテレフタレート、ポリブチレンテレフタレート、
ポリエチレン−P、P′−ジフェニルジカルボキシレー
ト等のポリエステル;ナイロン61ナイロン66、ナイ
ロン6101ナイロン7、ナイロン210.ナイロン4
6.ナイロン56.ナイロン58等のポリアミド等から
形成されたm 維が挙げられ、特にポリエステル繊維と
ポリアミド繊維は好ましく、中でも前記耐熱性繊維とし
てアラミド繊維を選択した場合は、ボIJ xステル、
特にポリエチレンテレフタレート繊維を組合わせ使用す
ることが最も適当である。これらの繊糺ヲ形成する重縮
合体は他の共重合成分若しくは添加物を含有することが
できる。かかる熱iJ塑性繊維は後述の加熱処理によっ
てマ) IJソックス形成する際に極端な収縮を起こさ
ぬよう、未延伸繊維の状態で適用する−ことが好ましい
。In addition, the thermoplastic fiber used in the present invention has a viscosity of
7AM degree is required to be lower than the heat distortion temperature of the above-mentioned heat-resistant fiber, for example, polyolefin taAI such as polyethylene, polypropylene [i: polyvinyl chloride,
Vinyl fibers such as polyvinylidene chloride and polyacrylonitrile; polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate,
Polyesters such as polyethylene-P, P'-diphenyldicarboxylate; nylon 61, nylon 66, nylon 6101, nylon 7, nylon 210. nylon 4
6. Nylon 56. Examples include m fibers formed from polyamides such as nylon 58, and polyester fibers and polyamide fibers are particularly preferred.Among them, when aramid fibers are selected as the heat-resistant fibers, BoIJ x stell,
In particular, it is most suitable to use polyethylene terephthalate fibers in combination. These fiber-forming polycondensates may contain other copolymer components or additives. Such thermal IJ plastic fibers are preferably applied in the state of undrawn fibers so as not to cause extreme shrinkage when forming an IJ sock by the heat treatment described below.
上述の耐熱性繊維および熱可塑性繊維は共にステーブル
状で用いられ、繊維長は15〜loo+nm程度が望ま
しい。これらの繊維は夫々単独で、あるいは2種以上を
混合して用いてもよいが、耐熱性繊維と、熱可塑性繊維
との混合比率は重hk比で1O/6o〜9害。の間であ
り、望1しくけ24〜85%4oのの範囲である。調合
率が上記範囲を外れて耐熱性繊維の量が過少となると、
得られたシート材料の強伸度特性、熱安定性が損なわれ
、通に過大となると熱可塑性繊維が形成する後述のマ)
IJソックス組織が粗となり過ぎて耐熱性繊維の包絡
力が劣り、シート材料の幅方向の引張強度が著しく小さ
くなるため不可である。Both the above-mentioned heat-resistant fiber and thermoplastic fiber are used in stable form, and the fiber length is preferably about 15 to loo+nm. These fibers may be used alone or in a mixture of two or more, but the mixing ratio of the heat-resistant fibers and the thermoplastic fibers is 1O/6O to 9% in weight hk ratio. It is preferably in the range of 24 to 85% 4o. If the blending ratio falls outside the above range and the amount of heat-resistant fiber becomes too small,
The strength and elongation characteristics and thermal stability of the obtained sheet material will be impaired, and if it becomes too large, thermoplastic fibers will form (see below).
This is not acceptable because the IJ sock structure becomes too coarse, the enveloping force of the heat-resistant fibers is poor, and the tensile strength of the sheet material in the width direction becomes extremely low.
上記の繊維はそれぞれギヤクリンパまたはスタッファボ
ックス等により捲縮または屈曲を付与され、あるいはフ
ンシュゲート繊糺の場合は内部歪の解放によって捲縮が
顕在化された状態で、前述の範囲の調合率を以ってオー
プナ−ミキサー等の混合機に投入され、充分に混合解繊
されて混合フリースとなる。The above-mentioned fibers are crimped or bent using a gear crimper or stuffer box, or in the case of Funshugate fibers, crimps are made apparent by releasing internal strain, and then the blending ratio within the above range is applied. The fibers are then put into a mixer such as an opener mixer, where they are sufficiently mixed and defibrated to form a mixed fleece.
混合フリースは更にローラーカード、フラットカード等
のカーディングマシンに供給され、常法によりカーディ
ングを施して目何約60り以下、好ましくは542〜3
0諮に調整しつつパラレルウニブとなす。The mixed fleece is further fed to a carding machine such as a roller card or a flat card, and is carded in a conventional manner to obtain a mesh size of about 60 or less, preferably 542 to 3.
While adjusting to 0 consultation, it will be made into a parallel sea bream.
パラレルウェブの目イ」は特にマルチレイヤまlこはフ
レキシブルのOOL用途等においては極端に小さいもの
が要求される傾向があり、本発明が意図する用途に対し
ては、前記数値を超えたシート相打は可撓性が損なわれ
ることがあるため不向きである。There is a tendency for parallel web webs to be extremely small, especially in multi-layer web applications such as flexible OOL applications, and for the intended use of the present invention, sheets exceeding the above-mentioned values are required. Trading is not suitable because flexibility may be impaired.
このようにして作られたパラレルウェブは長尺形態をな
しており、その長手方向の軸に沿って構成繊維は一応配
向しているが、その・ト行度は低く夫々の捲縮、屈曲等
により交絡凝集している。The parallel web made in this way has a long shape, and the constituent fibers are oriented along the longitudinal axis, but the degree of torsion is low and there are crimps, bends, etc. Confounding and aggregating due to
かくして作られたパラレルウェブは、直ちに後述の加熱
延伸工程にイ」シて本発明の不織布とすることもできる
が、予め加熱処理または加熱加[1:、処理によって、
耐熱性繊維が熱Of塑性繊糾の融着によって形成された
マトリックス中に一体的に接X1包絡された中間体不織
布となした後に加熱延伸処理を施すことが、安定した工
程1品質を確保する上で最も好ましい。かかる中間体不
織布は、前記のパラレルウェブを必要に応じて複数枚積
層し、熱可塑性繊維の接着温度以上且つ耐熱性繊維の熱
変形湿度未満の温度で加熱処理することによって得られ
る。また加熱処理は必要とあらばパラレルウェブの厚さ
方向における圧力の作用下に行なってもよく、かかる圧
力は設定温度や加熱時間その他の条件とも密接な関連が
あるが、約0.5η〜150ち、好ましくは約50ち〜
100シの範囲が好適であり、上記圧力範囲に達しない
場合は熱可塑性繊維の融着が不足してマ) IJソック
ス満足すべき形成が行なわれずに後述の延伸配向が充分
に達成されないことがあり、一方、前記範囲を超えて過
大となると、中間体不織布は不織布本来の性状を失ない
、甚しい場合は損傷することがある。The thus-produced parallel web can be immediately subjected to the heating and stretching process described below to form the nonwoven fabric of the present invention, but it can be prepared by heat treatment or heating [1: treatment] in advance.
After forming an intermediate nonwoven fabric in which heat-resistant fibers are integrally wrapped in a matrix formed by fusion of heat-of-plastic fibers, heating and stretching treatment is performed to ensure stable process 1 quality. Most preferred above. Such an intermediate nonwoven fabric can be obtained by laminating a plurality of parallel webs as necessary and heat-treating the web at a temperature higher than the bonding temperature of the thermoplastic fibers and lower than the heat deformation humidity of the heat-resistant fibers. Further, if necessary, the heat treatment may be performed under the action of pressure in the thickness direction of the parallel web, and the pressure is closely related to the set temperature, heating time, and other conditions, but it is approximately 0.5η to 150Ω. Preferably about 50 cm
A range of 100 mm is preferable, and if the above pressure range is not reached, the thermoplastic fibers may not be sufficiently fused and the IJ sock may not be formed satisfactorily and the stretching orientation described below may not be fully achieved. On the other hand, if the amount exceeds the above range, the intermediate nonwoven fabric will not lose its original properties, and in severe cases may be damaged.
加熱の行なわれる時間は、圧力、温度、ウェブの目付、
熱可塑性繊維の直径等により異なるが、約0.5秒〜1
0秒の範聞内で適宜選定される。加熱処理はホットフル
ーを、また加圧併用の場合は2本または3本ロールカレ
ンダ若しくはホットプレス装置等、公知慣用の機械を用
いて行なわれるが、特にカレンダ装置による連続工程は
有利である。The heating time depends on the pressure, temperature, web weight,
Although it varies depending on the diameter of the thermoplastic fiber, about 0.5 seconds to 1
It is appropriately selected within the range of 0 seconds. The heat treatment is carried out using a hot flue or, in the case of combined use of pressure, a known and commonly used machine such as a two or three roll calender or a hot press machine, but a continuous process using a calender machine is particularly advantageous.
かかる加熱処理によってパラレルウェブ中の熱可塑性繊
維はその接着温度以上に加熱され、塑性変形乃至は塑性
流動を起こし、繊維相互の接触部分において少なくとも
部分的に接着し、シート状マトリックスとなる。この際
、熱可塑性繊維の含有量が大きい場合は実質的に連続し
た緻密組織のマ) IJソックスなり、又、含有量が比
較的小さい場合であっても特に未延伸繊維を使用した場
合は延伸繊維の如き極端な熱収縮を生ずることなく、接
着部分が全体に均一に分散して存在する多孔質または網
状マトリックスとなる。By such heat treatment, the thermoplastic fibers in the parallel web are heated to a temperature higher than their bonding temperature, causing plastic deformation or plastic flow, and the fibers are at least partially bonded at the mutually contacting portions to form a sheet-like matrix. In this case, if the content of thermoplastic fibers is large, it will become an IJ sock with a substantially continuous dense structure, and even if the content is relatively small, especially if unstretched fibers are used, stretched fibers will be formed. The result is a porous or reticulated matrix in which the bonded parts are uniformly distributed throughout, without causing extreme heat shrinkage as with fibers.
熱可塑性繊維は、その接着温度が耐熱性絆111の熱変
形温度未満のものを選定したのであるから、上記加熱処
理によってもウェブ中において実質的に変質変形するこ
とがない。Since the thermoplastic fibers were selected to have an adhesion temperature lower than the heat deformation temperature of the heat-resistant bond 111, they are not substantially altered or deformed in the web even by the heat treatment described above.
しかして耐熱性繊維はカーディングにより、ウェブの拡
がり方向の単一軸、即ち、長尺ウェブにおいてはその長
手方向の軸に沿っである程度配向されているが、尚その
平行度は低く、捲縮、屈曲を残したままで、熱可塑性繊
維の相互融着によって形成されたマトリックス中に一体
的に接着包絡された状態となる。However, due to carding, the heat-resistant fibers are oriented to some extent along a single axis in the spreading direction of the web, that is, along the longitudinal axis in the case of a long web, but the degree of parallelism is still low, and crimping, The fibers remain bent and are integrally adhesively enveloped in a matrix formed by mutual fusion of thermoplastic fibers.
パラレルウェブは上述の加熱処理または加熱加圧処理を
施すかまたは施すことなく加熱延伸工程に付される。加
熱延伸工程は、2組のニップロールまたはエプロンロー
ルとそれらの間に設けられた加熱手段とよりなる公知の
熱延伸装置によって行なわれる。The parallel web is subjected to a heating stretching process with or without the above-mentioned heating treatment or heating and pressure treatment. The hot stretching step is carried out using a known hot stretching device comprising two sets of nip rolls or apron rolls and heating means provided between them.
加熱手段は、ウェブの進行方向を横切って横架された棒
状ヒーターにウェブを接触させるか、ウェブ通路に沿っ
て横設されたプレートヒーター等によるなど、適宜公知
慣用の手段を適用し得るが走行中のウェブをその熱可塑
性繊維の粘着温度以上、即ち軟化溶融温度にまで加熱す
るに充分な容量に設n1されることが肝要である。The heating means may be any known and commonly used means, such as bringing the web into contact with a rod-shaped heater placed horizontally across the web's traveling direction, or using a plate heater placed horizontally along the web path. It is important that the capacity n1 is sufficient to heat the web therein above the sticking temperature of the thermoplastic fibers, ie, to the softening melting temperature.
また、延伸は、5〜100%、好ましくは15〜35%
の延伸率を以って行なわれる。延伸率が上記範囲より過
小であると繊維の捲縮、屈曲の伸長及び配向が不充分と
なり、一方、過大となると厚さ斑が生じ、極端な場□合
には破断の惧れがあるため不可である。かかる加熱延伸
工程により、パラレルウェブまたは中間体不織布中の熱
可塑性繊維は軟化溶融し、その粘着力によって互い、に
融着して粘性マトリックスを形成すると同時に、耐熱
。In addition, the stretching is 5 to 100%, preferably 15 to 35%.
The stretching ratio is as follows. If the stretching ratio is less than the above range, the crimp, bending, elongation and orientation of the fibers will be insufficient, while if it is too much, uneven thickness will occur, and in extreme cases there is a risk of breakage. Not possible. Through this heated stretching process, the thermoplastic fibers in the parallel web or intermediate nonwoven fabric are softened and melted, and their adhesive strength causes them to fuse together to form a viscous matrix, while at the same time providing heat-resistant properties.
.
性繊維をも一体的に粘着保持し、その状態で延伸される
と耐熱性繊維は粘性マトリックスに保持されたまま、そ
の捲縮、屈曲等が伸張除去され、1(i線状となり、更
に延伸方向に高度の配向度をもって配向し骨格側となる
。その後適宜冷却すれば熱可塑性繊維の粘着力は失われ
て、上記マ) IJラックスシート状に固化し、実質的
に直線状で高度に配向した耐熱性繊維よりなる骨格側を
一体的に包絡した、本発明のシート材料、即ち、耐熱性
高強度不織布が得られるのである。When the heat-resistant fibers are adhesively held together and stretched in that state, the crimps, bends, etc. are removed by stretching while the heat-resistant fibers are held in the viscous matrix, and the heat-resistant fibers become 1 (i-linear) and are further stretched. The thermoplastic fibers are oriented with a high degree of orientation in the direction and become the skeleton side.After that, when appropriately cooled, the adhesive force of the thermoplastic fibers is lost and solidified into the above-mentioned M) IJ Lux sheet form, which is substantially linear and highly oriented. The sheet material of the present invention, ie, the heat-resistant high-strength nonwoven fabric, is obtained in which the skeleton side made of the heat-resistant fibers is integrally wrapped.
上述の如くして得られたシート相別はそのままでも優れ
た特性を具備しており有用であるが、必要に応じて更に
加熱、加圧することにより更に高強度とすることができ
る。この加熱、加圧処理は既述の延伸前に適用する加熱
、加圧処理に準じた方法で行なわれる。The sheet phased sheet obtained as described above has excellent properties and is useful as it is, but it can be further strengthened by further heating and pressurizing if necessary. This heating and pressure treatment is carried out in a manner similar to the heating and pressure treatment applied before stretching as described above.
本発明におけるシート材料は」二連の説明から明らかな
通す、シート状マトリックスとそれに一体的に接着包絡
された実質的に直線状で且つ高度に配向した骨格材とよ
りなるものであり、骨格材はシート材料に作用する荷重
を支え、シート材料に大なる引張強度、小さい破断伸度
、大きい耐熱性および小さい熱収縮率を与える作用をす
る。−1だ本発明になるシート材料は目付6o諮以下、
好ましくは30卦という極く薄層に形成されているから
大半の繊維が一体的に融着していても良好な可撓性を呈
する。又、骨格材となる耐熱性繊維に高強度のアラミド
繊維を用い、マトリックスにポリエステル繊組を適用す
ると、両型合体は互いに親和性に乏しいため、骨格材と
マトリックスとの間は機械的応力により容易に剥離して
ルーズとなり従ってシート材料の可撓性は損なわれるこ
とがない。The sheet material in the present invention is made up of a sheet-like matrix and a substantially linear and highly oriented skeleton integrally adhesively enveloped therein, as is clear from the above description. acts to support the load acting on the sheet material and provide the sheet material with high tensile strength, low elongation at break, high heat resistance and low thermal shrinkage. -1 The sheet material according to the present invention has a basis weight of 6 o's or less,
Since it is preferably formed into an extremely thin layer of 30 trigrams, it exhibits good flexibility even if most of the fibers are fused together. In addition, if high-strength aramid fibers are used as the heat-resistant fibers that form the framework material, and polyester fibers are used as the matrix, the two types of combination have poor affinity for each other, so the relationship between the framework material and the matrix is caused by mechanical stress. It peels off easily and becomes loose, so that the flexibility of the sheet material is not impaired.
かくして得られるシート材料は、その長軸方向に測定し
て、少なくとも約8,00 o’mの裂断長と、たかだ
か約5%の破断伸度を示す。即ち骨格材は既に実質的に
直線状で高度に配向しているため、伸長力が作用した場
合、応力の増大に伴なう伸度が極めて小さく、優れた寸
法安定性を示、すのである。かように本発明に係る不織
布は、その構成繊維である耐熱性繊維が直線状で、かつ
冒度に配向した骨格材となり、それと混在する熱可塑性
繊維より形成されたシート状マトリックスによって上記
骨格材を一体的に結合包絡してなるものであるから、直
線状骨格材に由来する大なる引張強度と繊維固有の擾れ
た耐熱性とを具えると共に、薄層に形成されたから可撓
性に富み、また骨格材として剛直な材料を選択した場合
と鎚もマ) IJラックスよって包絡保護されているた
め耐折性に富み、更に小なる破断伸度に象徴される良好
なτノ法安定性を具備し、F’RP@の補強利料として
最適である0
本発明になる不織布の有する上記の好ましい特性を更に
向上させるには、シート材f′Fの重はの5〜50%(
−形分換算)に相当する繊維用、りd脂加工剤、好まし
くは例えば、メラミン樹1指、フェノール樹脂およびエ
ポキシ樹脂よりなる群より選ばれた少なくとも1つの有
機高分子化合物を主剤とする樹脂加工剤をシート材料構
成繊維の表面に41着せしめた樹脂加工繊維構造物とな
すことが頗る有効である。The sheet material thus obtained exhibits a breaking length of at least about 8,00 ohm and an elongation at break of no more than about 5%, measured along its longitudinal axis. In other words, since the framework material is already substantially linear and highly oriented, when an elongation force is applied, the elongation associated with the increase in stress is extremely small, and it exhibits excellent dimensional stability. . As described above, in the nonwoven fabric according to the present invention, the heat-resistant fibers that are its constituent fibers form a linear and highly oriented skeleton material, and the sheet-like matrix formed from the thermoplastic fibers mixed with the heat-resistant fibers serves as a skeleton material. Because it is made by integrally bonding and enveloping the fibers, it has the high tensile strength derived from the linear skeleton material and the distorted heat resistance inherent to the fiber, and is flexible because it is formed into a thin layer. In addition, when a rigid material is selected as the frame material, it has excellent bending durability because it is enveloped and protected by IJ Lux, and also has good τ method stability, symbolized by a small elongation at break. In order to further improve the above-mentioned favorable properties of the nonwoven fabric of the present invention, the weight of the sheet material f'F is 5 to 50% (
- Resin processing agent for fibers corresponding to (in terms of shape), preferably a resin whose main ingredient is at least one organic polymer compound selected from the group consisting of melamine resin, phenol resin, and epoxy resin. It is extremely effective to form a resin-processed fiber structure in which the processing agent is applied to the surface of the fibers constituting the sheet material.
また、かかる樹脂加工繊維構造物は、本発明不織布の用
途に応じて適宜な種類の樹脂加工を選択することにより
、FRP製造時の樹脂との親和性を増大し高品質のFR
Pを製造することができる。In addition, by selecting an appropriate type of resin processing depending on the use of the nonwoven fabric of the present invention, such a resin-processed fiber structure can increase its affinity with the resin during FRP production and produce high-quality FR.
P can be produced.
例えば、フェノール樹脂成形体の補強材に用いる場合は
フェノール樹脂加工を、エポキシ樹脂成形体の補強利用
にはエポキシ樹脂加工を、またポリアミド、ポリイミド
メラミン樹脂成形体に対してはメラミン樹脂加工を行な
うとよい。これらの樹脂加工は通常繊維製品に適用され
ている公知慣用の方法で行なわれ、付;tjIIfが「
′Jil記範囲未満であると樹脂加工の効果が実質的に
顕出せず、反面、過大であると不織布が粗硬とな9、可
撓性が低下するので好ましくない。For example, phenol resin processing is used for reinforcing phenolic resin moldings, epoxy resin processing is used for reinforcing epoxy resin moldings, and melamine resin processing is used for polyamide and polyimide melamine resin moldings. good. These resin treatments are carried out using known and commonly used methods that are normally applied to textile products.
If it is less than the above range, the effect of the resin processing will not be realized substantially, while if it is too large, the nonwoven fabric will be coarse and hard9 and its flexibility will be reduced, which is not preferable.
上記樹脂加工を施すことによって、本発明の不織布は、
耐熱性繊組の配向方向に測定して、少なく七も約12.
Q Ooff+の裂UIt長と、たがだが約3%の破断
伸度とを具えるに至り、その引張強度と寸法安定性は一
段と増大する。By applying the above resin processing, the nonwoven fabric of the present invention can be
At least 7 and about 12.
It has a tear UIt length of QOoff+ and a breaking elongation of about 3%, and its tensile strength and dimensional stability are further increased.
以上のようにして得られた本発明になる薄層不織布はそ
の優れた耐熱性、高強度、低伸度1寸法安定性、耐折性
、可撓性等の特性を併有するため電気絶縁薄葉材料の含
浸基材、フレギシブルaaL、マルチレイヤOOLの基
布、特殊P R,Pの補強用布帛、ベルト基材、マグネ
ットワイヤー、テーピング、マイカ裏打袖!i’ii拐
等に特に優れた効果を発揮する。The thin-layer nonwoven fabric of the present invention obtained as described above has properties such as excellent heat resistance, high strength, low elongation, one-dimensional stability, bending durability, and flexibility, so it can be used as an electrically insulating thin nonwoven fabric. Impregnated base material, flexible aaL, multilayer OOL base fabric, special PR, P reinforcing fabric, belt base material, magnet wire, taping, mica-lined sleeves! It is particularly effective against i'ii kidnapping.
以下に本発明の実施例を示す。Examples of the present invention are shown below.
実施例1
単繊維繊度1.5d、平均繊維長38M、!vL変形温
度(炭化温度)450℃のポリパラフェニレンテレフタ
ルアミド繊維(米国デュポン社製、商品名「ケブラー」
)ステーブル60重量部と、単繊イ41.繊度5.Od
、平均繊維長38fil、融点温度265℃の未延伸ポ
リエチレンテレフタレート繊糾ステーブル(東し製ホ“
リエステルl′T・211 ” )40重量部とをオー
プナ−ミキサーで混合解繊しり後、ローラーカーディン
グマシンでカーディングし、ウェブの坪量を35りに調
整1得られたパラレルウェブを3本ロールカレンダ機に
通し、200℃、80ちの条件で加熱加圧し、中間体不
織布を作製した。中間体不織布中のポリパラフェニレン
テレフタルアミド繊維はその捲縮を保持したま1不織布
の長手方向に低い配向度で一応配向し、ポリエチレンテ
レフタレート繊維が融着して形成されたシート状マ)
IJラックス中に一体的に包絡埋設されていた。このも
のを対照品(1)とした。Example 1 Single fiber fineness 1.5d, average fiber length 38M! vL polyparaphenylene terephthalamide fiber with a deformation temperature (carbonization temperature) of 450°C (manufactured by DuPont, USA, product name: “Kevlar”)
) 60 parts by weight of stable and 41. Fineness 5. Od
, an undrawn polyethylene terephthalate fiber stable with an average fiber length of 38 fil and a melting point temperature of 265°C (Toshi Co., Ltd.)
After mixing and fibrillating 40 parts by weight of Lyester l'T. An intermediate nonwoven fabric was produced by passing it through a roll calender machine and heating and pressurizing it at 200°C and 80°C.The polyparaphenylene terephthalamide fibers in the intermediate nonwoven fabric maintained their crimps and were lowered in the longitudinal direction of the nonwoven fabric. A sheet-like material formed by fusing polyethylene terephthalate fibers with some degree of orientation)
It was buried integrally in IJ Lux. This product was designated as control product (1).
対照品(1)にエポキシ樹脂(東部化成(株)製。The control product (1) was an epoxy resin (manufactured by Tobu Kasei Co., Ltd.).
商品名「エボトニト」)を用いて常法によりエポキシ樹
脂加工を行なって、繊緋総爪1iの約28%のエポキシ
樹脂を繊維表面に平均に伺着させ、得られた不織I′I
iを対照品(2)とした。The non-woven material I'I was processed by epoxy resin processing using a conventional method using the product (trade name "Evotonito") to deposit about 28% of the epoxy resin on the fiber surface on average on the fiber surface.
i was used as a control product (2).
次いで1」1j記対照品(1)を直列に配設された2組
のニップロールの間で、260℃に加熱した棒状ヒータ
ーに接触させながら30%の延伸を連続的に施した。そ
の後、得られたシート桐材を210℃。Next, the comparative product (1) in Item 1''1j was continuously stretched by 30% between two sets of nip rolls arranged in series while being brought into contact with a rod-shaped heater heated to 260°C. Thereafter, the obtained paulownia wood sheet was heated to 210°C.
80(至)の温度、圧力条件で再びロールカレンダ機に
よって処理し、得られた不織布を本発明、品(1)とし
た。The nonwoven fabric was treated again using a roll calender at a temperature and pressure of 80°C (up to 80°C), and the obtained nonwoven fabric was designated as product (1) of the present invention.
本発明品(1)に前記同様のエポキシ樹脂加工を行ない
、繊維総組fftの約28%のエポキシ樹脂を繊維表面
に平均に付着させ、得られた樹脂加工繊糸1「構造物を
本発明品(2)とした。The product (1) of the present invention is subjected to the same epoxy resin processing as described above, and about 28% of the epoxy resin of the total fiber set fft is adhered to the fiber surface on average, and the resulting resin-treated fiber 1 "structure of the present invention is Product (2).
これら対照品と本発明品との物性を対比して第実施例2
耐熱性繊糸1Fとして実施例1と同じポリバラフェニレ
ンテレフタルアミドta 維ステーブ/l/ f用い、
熱可塑性繊細として、単繊維繊度5.5d、乎均繊崩1
長40 TnIn(バイアスカッ+、)、4点WIM度
225℃のナイロン6繊維ステーブルを用いて、混合比
を種々に変えて坪m 30 f!/n?のパラレルウェ
ブを作った。The physical properties of these control products and the product of the present invention were compared in Example 2. As the heat-resistant fiber 1F, the same polybara phenylene terephthalamide ta fiber stave/l/f as in Example 1 was used.
As a thermoplastic delicate, single fiber fineness 5.5d, uniform fiber breakdown 1
Using a 4-point WIM 225°C nylon 6-fiber stable with a length of 40 TnIn (bias cut +), the mixing ratio was varied to obtain a 30 f! /n? created a parallel web.
それらを2本ロールカレンダ機によって205℃、50
ηの条件で加熱加圧し、中間体不織布を得、そのものを
更に、加熱温度を215℃とする他は実施例1と同様に
加熱延伸処理にイ」シ、シート桐材とした。They were heated to 205℃ and 50℃ using a two-roll calender machine.
This was heated and pressed under the conditions of η to obtain an intermediate nonwoven fabric, which was further subjected to heat stretching treatment in the same manner as in Example 1 except that the heating temperature was 215° C. to form a sheet of paulownia wood.
上記シートkA料にゴム系バインダとして慣用されてい
るメチルメタクリレート−ブタジェン共重合ラテックス
(MBR)処理を施し5 flay?のMBRを(’=
J着させた。The above-mentioned sheet kA material is treated with methyl methacrylate-butadiene copolymer latex (MBR), which is commonly used as a rubber binder. MBR of ('=
I made him wear J.
得られた不織布について繊維配向方向(長手方向)とそ
れを横切る方向(幅方向)にそれぞれ測定した裂断長と
、破断伸度とを第2表に示す。Table 2 shows the breaking length and breaking elongation of the obtained nonwoven fabric, which were measured in the fiber orientation direction (longitudinal direction) and in the direction crossing it (width direction).
(以下 余白)
第 2 表
第2表から明らかな通り、耐熱性繊維と熱可塑性繊維の
混合比が過小であると、不織布の長手方向の引張強度が
不足し、又、過大であると幅方向の引張強度が著しく小
さくなり、何れにしても不可であシ、上記混合重量比は
10/9o〜9才。、好ましくは席。〜8*oの範囲内
にあることが判る。(Margins below) Table 2 As is clear from Table 2, if the mixing ratio of heat-resistant fibers and thermoplastic fibers is too small, the tensile strength in the longitudinal direction of the nonwoven fabric will be insufficient, and if it is too large, the tensile strength in the width direction will be insufficient. The tensile strength of the mixture becomes extremely small, which is unacceptable in any case, and the above mixing weight ratio is 10/9 to 9 years. , preferably a seat. It can be seen that it is within the range of ~8*o.
実施例3
単繊維繊度1.7cl、平均繊維長42M、熱変形温度
350℃のホ゛リメタフエニレンイソフタルアミド繊組
ステーブル(米国デュポン社製、商品名1ノーメツクス
」)65爪量部と、単繊維繊度7.5d、平均繊糸11
長44 tnm +融点温度170℃のアイツタクチイ
ックポリプロピレン繊維ステーブル35重量部とを充分
に混繊し、ローラーカーディングマシンで坪(il 4
0 t/H?のパラレルウェブを形成した。このものを
、ヒータ一温度を150℃とする他は実施例1と同様の
延伸装置を用い、延伸率を種々に変えて、各種不織布を
作製した。Example 3 Polymetaphenylene isophthalamide fiber stabilizer (manufactured by DuPont, USA, trade name 1 Nomex) with a single fiber fineness of 1.7 cl, average fiber length of 42 M, and heat deformation temperature of 350° C. was used with 65 claws. Fiber fineness 7.5d, average yarn 11
44 tnm in length + 35 parts by weight of tactical polypropylene fiber stable with a melting point temperature of 170°C.
0t/H? A parallel web was formed. Various nonwoven fabrics were produced using the same stretching apparatus as in Example 1 except that the temperature of the heater was 150° C., and by varying the stretching ratio.
その結果を第3表に示した。The results are shown in Table 3.
第 3 表
第3表の結果から、延伸率5%未満では破断伸度が過大
となり、又、裂断長も小さく補強用基布としては不適で
あり 一方、延伸率が100%を超えると、延伸床が大
きくカリ、破損に至ることがあるため不適であることが
理解される。Table 3 From the results shown in Table 3, if the stretching ratio is less than 5%, the elongation at break will be excessive, and the tearing length will also be small, making it unsuitable as a reinforcing base fabric.On the other hand, if the stretching ratio exceeds 100%, It is understood that this method is unsuitable because the stretched bed is large and can lead to breakage.
Claims (1)
形温度未満の粘着温度を有するステープル状熱口■塑性
繊維とを1%0〜9躍。の重量比を以って均種1合して
なるパラレルウェブf:前記熱可塑性繊維の粘着温度以
上に加熱すると共に一軸方向に5〜100%延伸し、か
くして軟化乃至溶融状態にある熱可塑性繊維によって結
合・保持された耐熱性繊維をその捲縮、屈曲を伸長しつ
つ延伸方向に配向させ、しかる後、冷却固化して前記熱
可塑性繊維全、それらが少なくとも部分的に相互に接着
し且つ前記伸長配向した耐熱性繊維を一体的に包絡して
なるシート状マトリックスとなすことを特徴とする耐熱
性高強度不織布の製造法。 2、 耐熱性繊維がアラミド繊維である特J′r請求の
範囲第1項記載の耐熱性高強度不織布の製造法。 8、 アラミド繊維がポリパラフェニレンテレ7り耐熱
性高強度不織布の製造法。 4、 耐熱性繊維が炭素繊維である特許請求の範囲第1
項記載の耐熱性高強度不織布の製造法。 5、 熱可塑性繊維がポリエステル繊維である特許請求
の範囲第1〜4項の何れかの項に記載の耐熱性高強度不
織布の製造法。 6、 ポリエステル繊維がポリエチレンテレフタレート
繊維である特許請求の範囲第5項記載の耐熱性高強度不
織布の製造法。 7、 熱可塑性繊維が未延伸繊維である特許請求の範囲 度不織布の製造法。 8、 延伸が15〜35%の延沖率で行なわれる特許請
求の範囲第1〜7項の何れかの項に記・1&の耐熱性高
強度不織布の製造法。 9、 耐熱性繊維と熱可塑性繊維との混合型;1を比が
”Xo ” 憧oである前記特許請求の範囲第1〜8項
の何れかの項に記載の耐熱性高強度不織布の製造法。 10、ステーブル状耐熱性繊維と、該耐熱性繊維の熱変
形温度未満の粘着温度を有するステーブル状熱可塑性繊
維とを1%〇〜9%の重数比を以って均一に混合してな
るパラレルウェブを前記熱可塑性繊維の粘着温度以上に
加熱すると共に一軸方向に5〜100%延伸し、かくし
て軟化乃至溶融状態にある熱可塑性ti i++によっ
て結合・保持された耐熱性繊維をその捲縮、屈曲を伸長
しつつ延伸方向に配向させ、しかる後冷却固化して前記
熱可塑性繊維を、それらが少なくとも部分的に相Uに接
着し且つ前記延伸配向した耐熱性繊維を一体的に包絡し
てなるシート状マトリックスとなし、次いで繊細用樹脂
加工を施して全繊維重量の5〜50%(固形分換算)の
樹脂を(J与することを特徴とする耐熱性高強度不織布
の製造法。 11 繊維用樹脂加工が、メラミン樹脂、フェノール樹
脂、不飽和ポリエステル樹脂、ポリイミド樹脂およびエ
ポキシ樹脂よりなる群より選げれた少なくとも1つの有
機高分子化合物皮膜を繊維表面に形成することからなる
特許請求の範囲第10項記載の耐熱性高強度不織布の製
造法。 12、耐熱性繊維がアラミド繊維である特許請求の範囲
第10項又は第11項記載の耐熱性高強度不織布の製造
法。 18、アラミド繊維がポリパラフェニレンテレフタルア
ミド繊維である特許請求の範囲第12項記載の耐熱性高
強度不織布の製造法。 14、耐熱性線41I′が炭素繊維である特111:請
求の範囲第10〜13項の何れかの項に記載の耐熱性高
強度不織布の製造法。 15、熱可塑性繊維がポリエステル繊維である特許請求
の範囲第10〜14項の何れかの項に記載の耐熱性高強
度不織布の製造法。 16、熱可塑性繊維が未延伸繊細である特許請求の範囲
第10〜15項の何れかの項に記載の耐熱性高強度不織
布の製造法。 17、延伸が15〜35%の延伸率で行なわれる特許請
求の範囲第10〜16項の何れかの項に記載の耐熱性高
強度不織布の製造法。 18、耐熱性繊維と熱可塑性繊維との混合型ifk比が
1゜〜憧。である前記特許請求の範囲第10〜17項の
何れかの項に記載の耐熱性高強度不織布の製造法。[Claims] (1) A staple-shaped heat-resistant fiber and a staple-shaped hot-open plastic fiber having a sticking temperature lower than the heat deformation temperature of the heat-resistant fiber (1% 0 to 9%). Parallel web f made of homogeneous fibers with a weight ratio of: thermoplastic fibers that are heated to a temperature higher than the adhesive temperature of the thermoplastic fibers and stretched 5 to 100% in a uniaxial direction, thus softening or melting the fibers. The heat-resistant fibers bonded and held by the thermoplastic fibers are crimped and bent and oriented in the stretching direction while being stretched, and then cooled and solidified so that all of the thermoplastic fibers are at least partially bonded to each other and A method for producing a heat-resistant, high-strength nonwoven fabric characterized by forming a sheet-like matrix formed by integrally enveloping elongated and oriented heat-resistant fibers. 2. The method for producing a heat-resistant, high-strength nonwoven fabric according to claim 1, wherein the heat-resistant fiber is an aramid fiber. 8. A method for producing a heat-resistant, high-strength nonwoven fabric in which aramid fibers are made of polyparaphenylenetere. 4. Claim 1 in which the heat-resistant fiber is carbon fiber
A method for producing a heat-resistant, high-strength nonwoven fabric as described in Section 1. 5. The method for producing a heat-resistant high-strength nonwoven fabric according to any one of claims 1 to 4, wherein the thermoplastic fiber is a polyester fiber. 6. The method for producing a heat-resistant, high-strength nonwoven fabric according to claim 5, wherein the polyester fiber is a polyethylene terephthalate fiber. 7. A method for producing a nonwoven fabric as claimed in the claims, wherein the thermoplastic fibers are undrawn fibers. 8. A method for producing a heat-resistant high-strength nonwoven fabric according to any one of claims 1 to 7, wherein the stretching is carried out at a stretching ratio of 15 to 35%. 9. Production of the heat-resistant high-strength nonwoven fabric according to any one of claims 1 to 8, which is a mixed type of heat-resistant fiber and thermoplastic fiber; Law. 10. Stable heat-resistant fibers and stable thermoplastic fibers having a sticking temperature lower than the heat deformation temperature of the heat-resistant fibers are uniformly mixed at a weight ratio of 1% to 9%. The parallel web made of the thermoplastic fibers is heated to a temperature higher than the adhesive temperature of the thermoplastic fibers and stretched 5 to 100% in the uniaxial direction, and the heat-resistant fibers bonded and held by the thermoplastic fibers in a softened or molten state are wound. The thermoplastic fibers are oriented in the stretching direction while being stretched and bent, and then cooled and solidified so that the thermoplastic fibers are at least partially adhered to the phase U and integrally envelop the stretch-oriented heat-resistant fibers. A process for producing a heat-resistant, high-strength nonwoven fabric, which is characterized by forming a sheet-like matrix consisting of a fiber, and then subjecting it to a delicate resin treatment to provide resin in an amount of 5 to 50% (in terms of solid content) of the total fiber weight. 11 A patent claim in which the resin processing for fibers comprises forming on the fiber surface a film of at least one organic polymer compound selected from the group consisting of melamine resin, phenol resin, unsaturated polyester resin, polyimide resin, and epoxy resin. A method for producing a heat-resistant high-strength nonwoven fabric according to claim 10. 12. A method for producing a heat-resistant high-strength nonwoven fabric according to claim 10 or 11, wherein the heat-resistant fiber is an aramid fiber. A method for producing a heat-resistant high-strength nonwoven fabric according to claim 12, wherein the aramid fiber is polyparaphenylene terephthalamide fiber. 14. Feature 111: Claims 10 to 14, wherein the heat-resistant wire 41I' is carbon fiber. 15. The heat-resistant high-strength nonwoven fabric according to any one of claims 10 to 14, wherein the thermoplastic fiber is a polyester fiber. A method for producing a nonwoven fabric. 16. A method for producing a heat-resistant high-strength nonwoven fabric according to any one of claims 10 to 15, wherein the thermoplastic fibers are unstretched and delicate. 17. Stretching is 15 to 35%. A method for producing a heat-resistant high-strength nonwoven fabric according to any one of claims 10 to 16, which is carried out at a stretching ratio of 18. The mixed ifk ratio of heat-resistant fibers and thermoplastic fibers is 1°. A method for producing a heat-resistant, high-strength nonwoven fabric according to any one of claims 10 to 17.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58205340A JPS6099056A (en) | 1983-10-31 | 1983-10-31 | Production of heat resistant high strength nonwoven fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58205340A JPS6099056A (en) | 1983-10-31 | 1983-10-31 | Production of heat resistant high strength nonwoven fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6099056A true JPS6099056A (en) | 1985-06-01 |
| JPH0138903B2 JPH0138903B2 (en) | 1989-08-17 |
Family
ID=16505278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58205340A Granted JPS6099056A (en) | 1983-10-31 | 1983-10-31 | Production of heat resistant high strength nonwoven fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6099056A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62171961U (en) * | 1986-04-22 | 1987-10-31 | ||
| WO1999013150A1 (en) * | 1997-09-11 | 1999-03-18 | Toray Industries, Inc. | Fabric |
| JP2010539340A (en) * | 2007-09-14 | 2010-12-16 | エボニック デグサ ゲーエムベーハー | Fiber composite and use of the fiber composite in a vacuum insulation system |
| JP2017053065A (en) * | 2015-09-10 | 2017-03-16 | シンワ株式会社 | Manufacturing method of sheet-like semi-finished product for FRP manufacturing |
| JP2023084400A (en) * | 2021-12-07 | 2023-06-19 | 東洋紡せんい株式会社 | sheet |
-
1983
- 1983-10-31 JP JP58205340A patent/JPS6099056A/en active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62171961U (en) * | 1986-04-22 | 1987-10-31 | ||
| WO1999013150A1 (en) * | 1997-09-11 | 1999-03-18 | Toray Industries, Inc. | Fabric |
| JP2010539340A (en) * | 2007-09-14 | 2010-12-16 | エボニック デグサ ゲーエムベーハー | Fiber composite and use of the fiber composite in a vacuum insulation system |
| JP2017053065A (en) * | 2015-09-10 | 2017-03-16 | シンワ株式会社 | Manufacturing method of sheet-like semi-finished product for FRP manufacturing |
| JP2023084400A (en) * | 2021-12-07 | 2023-06-19 | 東洋紡せんい株式会社 | sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0138903B2 (en) | 1989-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1124499A (en) | Multi-layered, needle-punched, felt-like cushioning material and production method thereof | |
| TW382642B (en) | Hybrid yarn, textile sheet material, permanent deformation capable textile sheet material and fiber reinforced shaped article and their production processes | |
| JPS59163458A (en) | Reinforcing of polyethylene fiber reticulated texture | |
| JPH026867B2 (en) | ||
| JP2935864B2 (en) | Flame-retardant high heat-resistant polyimide fiber and molded article comprising the fiber | |
| KR100523312B1 (en) | Cardable Blends of Dual Glass Fibers, a Coherent Web Made From the Same, a Felt made from the Same, and a Process for forming a Felt Containing a Dual Glass Fiber | |
| US5229184A (en) | Heat shrinkable fibres and products therefrom | |
| JPS6099056A (en) | Production of heat resistant high strength nonwoven fabric | |
| US3317335A (en) | Fibrous, non-woven sheet materials and the production thereof | |
| JPS6316504B2 (en) | ||
| US6133171A (en) | Mechanically compacted non-woven material for use in the production of dimensionally stable mouldings | |
| JPH0316427B2 (en) | ||
| JP3856972B2 (en) | Split type composite short fiber having heat shrinkability and short fiber nonwoven fabric using the same | |
| JPS6071754A (en) | Heat resistant high strength nonwoven fabric and its production | |
| JP2007197891A (en) | Spun-bond nonwoven fabric | |
| JPH11117163A (en) | Heat resistant nonwoven fabric and its production | |
| JPH06200460A (en) | Fiber composite product | |
| JPH073598A (en) | Nonwoven fabrics and fabric lamination | |
| JP3283320B2 (en) | Manufacturing method of laminated molded products | |
| JP4298589B2 (en) | Nonwoven fabric for protecting inner and outer surfaces of pipes | |
| JPH05116161A (en) | Heat resistant cushion material for molding press | |
| JP6458589B2 (en) | Sheet material, integrated molded product, and integrated molded product manufacturing method | |
| JPH0544147A (en) | Composite fiber material | |
| JPH07145569A (en) | Method for producing smooth leather-like sheet | |
| JP4381904B2 (en) | Method for producing fibrous base material for artificial leather |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |