JPS61129008A - 気体分離用複合膜および製造法 - Google Patents

気体分離用複合膜および製造法

Info

Publication number: JPS61129008A
Authority: JP; Japan
Prior art keywords: polymer; composite membrane; thickness; polymers; siloxane compound
Prior art date: 1984-11-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP25229084A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0451218B2 (fr

Inventor

Jiro Nagarego

流郷　治朗

Hidehiko Matsuka

松家　英彦

Koichi Takada

耕一高田

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sanyo Chemical Industries Ltd

Original Assignee

Sanyo Chemical Industries Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-11-28

Filing date

1984-11-28

Publication date

1986-06-17

1984-11-28 Application filed by Sanyo Chemical Industries Ltd filed Critical Sanyo Chemical Industries Ltd

1984-11-28 Priority to JP25229084A priority Critical patent/JPS61129008A/ja

1986-06-17 Publication of JPS61129008A publication Critical patent/JPS61129008A/ja

1992-08-18 Publication of JPH0451218B2 publication Critical patent/JPH0451218B2/ja

Status Granted legal-status Critical Current

Links

239000012528 membrane Substances 0.000 title claims abstract description 46
239000002131 composite material Substances 0.000 title claims abstract description 36
238000002360 preparation method Methods 0.000 title description 2
229920000642 polymer Polymers 0.000 claims abstract description 75
-1 siloxane compound Chemical class 0.000 claims abstract description 59
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
238000000926 separation method Methods 0.000 claims abstract description 26
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims abstract description 20
230000035699 permeability Effects 0.000 claims abstract description 20
239000010409 thin film Substances 0.000 claims abstract description 15
229920002678 cellulose Polymers 0.000 claims abstract description 9
239000001913 cellulose Substances 0.000 claims abstract description 8
229920000098 polyolefin Polymers 0.000 claims abstract description 6
239000004711 α-olefin Substances 0.000 claims abstract description 5
125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims abstract 5
239000007789 gas Substances 0.000 claims description 38
238000004519 manufacturing process Methods 0.000 claims description 11
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
229910052760 oxygen Inorganic materials 0.000 claims description 7
150000003512 tertiary amines Chemical class 0.000 claims description 3
239000003960 organic solvent Substances 0.000 claims 2
125000001302 tertiary amino group Chemical group 0.000 claims 1
238000000034 method Methods 0.000 abstract description 35
238000006116 polymerization reaction Methods 0.000 abstract description 4
238000010030 laminating Methods 0.000 abstract description 3
238000000108 ultra-filtration Methods 0.000 abstract description 3
229920002554 vinyl polymer Polymers 0.000 abstract description 3
238000005266 casting Methods 0.000 abstract 1
125000000217 alkyl group Chemical group 0.000 description 16
239000010408 film Substances 0.000 description 15
238000004132 cross linking Methods 0.000 description 13
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
229920001577 copolymer Polymers 0.000 description 12
125000005677 ethinylene group Chemical class [*:2]C#C[*:1] 0.000 description 11
238000003892 spreading Methods 0.000 description 11
229920002492 poly(sulfone) Polymers 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
239000000203 mixture Substances 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
GDWZLADUGAKASM-UHFFFAOYSA-N 2-chloroethynylbenzene Chemical group ClC#CC1=CC=CC=C1 GDWZLADUGAKASM-UHFFFAOYSA-N 0.000 description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
238000005259 measurement Methods 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000000020 Nitrocellulose Substances 0.000 description 3
238000000149 argon plasma sintering Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000000178 monomer Substances 0.000 description 3
229920001220 nitrocellulos Polymers 0.000 description 3
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
239000000047 product Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
DCGLONGLPGISNX-UHFFFAOYSA-N trimethyl(prop-1-ynyl)silane Chemical compound CC#C[Si](C)(C)C DCGLONGLPGISNX-UHFFFAOYSA-N 0.000 description 3
UZNOMHUYXSAUPB-UNZYHPAISA-N (2e,6e)-2,6-bis[(4-azidophenyl)methylidene]cyclohexan-1-one Chemical compound C1=CC(N=[N+]=[N-])=CC=C1\C=C(/CCC\1)C(=O)C/1=C/C1=CC=C(N=[N+]=[N-])C=C1 UZNOMHUYXSAUPB-UNZYHPAISA-N 0.000 description 2
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
239000001856 Ethyl cellulose Substances 0.000 description 2
ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 2
229940081735 acetylcellulose Drugs 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229920002301 cellulose acetate Polymers 0.000 description 2
238000005345 coagulation Methods 0.000 description 2
230000015271 coagulation Effects 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 description 2
229920001249 ethyl cellulose Polymers 0.000 description 2
235000019325 ethyl cellulose Nutrition 0.000 description 2
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
239000004417 polycarbonate Substances 0.000 description 2
229920000515 polycarbonate Polymers 0.000 description 2
239000004810 polytetrafluoroethylene Substances 0.000 description 2
229920001343 polytetrafluoroethylene Polymers 0.000 description 2
229920002635 polyurethane Polymers 0.000 description 2
239000004814 polyurethane Substances 0.000 description 2
239000004800 polyvinyl chloride Substances 0.000 description 2
229920000915 polyvinyl chloride Polymers 0.000 description 2
GHUURDQYRGVEHX-UHFFFAOYSA-N prop-1-ynylbenzene Chemical group CC#CC1=CC=CC=C1 GHUURDQYRGVEHX-UHFFFAOYSA-N 0.000 description 2
239000004627 regenerated cellulose Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
DMIYMHYUMINMFK-UHFFFAOYSA-N 1-(2-chloroethynyl)-2-methylbenzene Chemical group CC1=CC=CC=C1C#CCl DMIYMHYUMINMFK-UHFFFAOYSA-N 0.000 description 1
HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
UZIBPOIXTCIHBH-UHFFFAOYSA-N 1-chlorohex-1-ene Chemical compound CCCCC=CCl UZIBPOIXTCIHBH-UHFFFAOYSA-N 0.000 description 1
CGHIBGNXEGJPQZ-UHFFFAOYSA-N 1-hexyne Chemical compound CCCCC#C CGHIBGNXEGJPQZ-UHFFFAOYSA-N 0.000 description 1
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 description 1
125000005916 2-methylpentyl group Chemical group 0.000 description 1
PLHJCCHSCFNKCC-UHFFFAOYSA-N 3-methylpent-1-yne Chemical compound CCC(C)C#C PLHJCCHSCFNKCC-UHFFFAOYSA-N 0.000 description 1
125000005917 3-methylpentyl group Chemical group 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
229920002284 Cellulose triacetate Polymers 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004642 Polyimide Substances 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
239000004734 Polyphenylene sulfide Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
235000010724 Wisteria floribunda Nutrition 0.000 description 1
NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000004103 aminoalkyl group Chemical group 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
125000004181 carboxyalkyl group Chemical group 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
125000004965 chloroalkyl group Chemical group 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000013256 coordination polymer Substances 0.000 description 1
RWDDSTHSVISBEA-UHFFFAOYSA-N dec-2-yne Chemical compound CCCCCCCC#CC RWDDSTHSVISBEA-UHFFFAOYSA-N 0.000 description 1
239000004205 dimethyl polysiloxane Substances 0.000 description 1
OIKHZBFJHONJJB-UHFFFAOYSA-N dimethyl(phenyl)silicon Chemical compound C[Si](C)C1=CC=CC=C1 OIKHZBFJHONJJB-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
HBWGDHDXAMFADB-UHFFFAOYSA-N ethenyl(triethyl)silane Chemical compound CC[Si](CC)(CC)C=C HBWGDHDXAMFADB-UHFFFAOYSA-N 0.000 description 1
GTBGHTLFBQMXTN-UHFFFAOYSA-N ethenyl(tripropyl)silane Chemical compound CCC[Si](CCC)(CCC)C=C GTBGHTLFBQMXTN-UHFFFAOYSA-N 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
125000003709 fluoroalkyl group Chemical group 0.000 description 1
125000005417 glycidoxyalkyl group Chemical group 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
MELUCTCJOARQQG-UHFFFAOYSA-N hex-2-yne Chemical compound CCCC#CC MELUCTCJOARQQG-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
239000003999 initiator Substances 0.000 description 1
125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
238000003475 lamination Methods 0.000 description 1
125000005358 mercaptoalkyl group Chemical group 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000001471 micro-filtration Methods 0.000 description 1
GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
QCQALVMFTWRCFI-UHFFFAOYSA-N oct-2-yne Chemical compound CCCCCC#CC QCQALVMFTWRCFI-UHFFFAOYSA-N 0.000 description 1
WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
229920006380 polyphenylene oxide Polymers 0.000 description 1
229920000069 polyphenylene sulfide Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003566 sealing material Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003206 sterilizing agent Substances 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000003799 water insoluble solvent Substances 0.000 description 1
CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1

Landscapes

Separation Using Semi-Permeable Membranes (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Laminated Bodies (AREA)

JP25229084A 1984-11-28 1984-11-28 気体分離用複合膜および製造法 Granted JPS61129008A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP25229084A JPS61129008A (ja)	1984-11-28	1984-11-28	気体分離用複合膜および製造法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP25229084A JPS61129008A (ja)	1984-11-28	1984-11-28	気体分離用複合膜および製造法

Publications (2)

Publication Number	Publication Date
JPS61129008A true JPS61129008A (ja)	1986-06-17
JPH0451218B2 JPH0451218B2 (fr)	1992-08-18

Family

ID=17235196

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP25229084A Granted JPS61129008A (ja)	1984-11-28	1984-11-28	気体分離用複合膜および製造法

Country Status (1)

Country	Link
JP (1)	JPS61129008A (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS61149226A (ja) *	1984-12-25	1986-07-07	Agency Of Ind Science & Technol	ガス選択透過性複合膜およびその製造方法
US5176724A (en) *	1987-11-10	1993-01-05	Matsushita Electric Industrial Co., Ltd.	Permselective composite membrane having improved gas permeability and selectivity
US5342432A (en) *	1989-12-23	1994-08-30	Hoechst Aktiengesellschaft	Composite membrane, process for its production and its use
WO2014141868A1 (fr) *	2013-03-14	2014-09-18	富士フイルム株式会社	Membrane composite de séparation de gaz, module de séparation de gaz, dispositif de séparation de gaz, et procédé de séparation de gaz
JP2016513160A (ja) *	2013-02-26	2016-05-12	ワッカーケミーアクチエンゲゼルシャフトＷａｃｋｅｒＣｈｅｍｉｅＡＧ	架橋熱可塑性シリコーンエラストマーで作製された多孔性膜
WO2019044196A1 (fr) *	2017-08-30	2019-03-07	富士フイルム株式会社	Membrane de séparation, module de membrane de séparation, dispositif de séparation, composition de la formation de la membrane de séparation, procédé de production de la membrane composite pour séparation, et composé cellulosique
JP2020507459A (ja) *	2017-02-09	2020-03-12	サウジアラビアンオイルカンパニーＳａｕｄｉＡｒａｂｉａｎＯｉｌＣｏｍｐａｎｙ	重質炭化水素回収のための変性シロキサン複合膜

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5730528A (en) *	1980-07-30	1982-02-18	Toyota Central Res & Dev Lab Inc	Vapor-separating member
JPS5959210A (ja) *	1982-09-27	1984-04-05	Matsushita Electric Ind Co Ltd	選択性気体透過複合膜
JPS5959214A (ja) *	1982-09-28	1984-04-05	Asahi Glass Co Ltd	ガス分離用複合膜

1984
- 1984-11-28 JP JP25229084A patent/JPS61129008A/ja active Granted

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5730528A (en) *	1980-07-30	1982-02-18	Toyota Central Res & Dev Lab Inc	Vapor-separating member
JPS5959210A (ja) *	1982-09-27	1984-04-05	Matsushita Electric Ind Co Ltd	選択性気体透過複合膜
JPS5959214A (ja) *	1982-09-28	1984-04-05	Asahi Glass Co Ltd	ガス分離用複合膜

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS61149226A (ja) *	1984-12-25	1986-07-07	Agency Of Ind Science & Technol	ガス選択透過性複合膜およびその製造方法
US5176724A (en) *	1987-11-10	1993-01-05	Matsushita Electric Industrial Co., Ltd.	Permselective composite membrane having improved gas permeability and selectivity
US5342432A (en) *	1989-12-23	1994-08-30	Hoechst Aktiengesellschaft	Composite membrane, process for its production and its use
JP2016513160A (ja) *	2013-02-26	2016-05-12	ワッカーケミーアクチエンゲゼルシャフトＷａｃｋｅｒＣｈｅｍｉｅＡＧ	架橋熱可塑性シリコーンエラストマーで作製された多孔性膜
WO2014141868A1 (fr) *	2013-03-14	2014-09-18	富士フイルム株式会社	Membrane composite de séparation de gaz, module de séparation de gaz, dispositif de séparation de gaz, et procédé de séparation de gaz
JP2020507459A (ja) *	2017-02-09	2020-03-12	サウジアラビアンオイルカンパニーＳａｕｄｉＡｒａｂｉａｎＯｉｌＣｏｍｐａｎｙ	重質炭化水素回収のための変性シロキサン複合膜
WO2019044196A1 (fr) *	2017-08-30	2019-03-07	富士フイルム株式会社	Membrane de séparation, module de membrane de séparation, dispositif de séparation, composition de la formation de la membrane de séparation, procédé de production de la membrane composite pour séparation, et composé cellulosique

Also Published As

Publication number	Publication date
JPH0451218B2 (fr)	1992-08-18

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Date	Code	Title	Description
2004-08-18	LAPS	Cancellation because of no payment of annual fees

Publication	Publication Date	Title
US4689267A (en)	1987-08-25	Composite hollow fiber
US4778868A (en)	1988-10-18	Polymer and a membrane having an improved gas-permeability and selectivity
EP0226141A2 (fr)	1987-06-24	Membranes polymères fluorées pour des procédés de séparation gazeuse
US4759776A (en)	1988-07-26	Polytrialkylgermylpropyne polymers and membranes
JPS61129008A (ja)	1986-06-17	気体分離用複合膜および製造法
JPS6253211B2 (fr)	1987-11-09
US5176724A (en)	1993-01-05	Permselective composite membrane having improved gas permeability and selectivity
JPS61192322A (ja)	1986-08-26	分離用複合膜
JPS63214319A (ja)	1988-09-07	分離用複合膜
JPS61107922A (ja)	1986-05-26	気体分離用複合膜
JPH0747221A (ja)	1995-02-21	気体分離用複合膜とその製造方法
CN117917262A (zh)	2024-04-23	气体分离膜
JPS58223407A (ja)	1983-12-26	気体分離膜
JPH0446172B2 (fr)	1992-07-29
JPS6336286B2 (fr)	1988-07-19
JPS6334772B2 (fr)	1988-07-12
JPS59127602A (ja)	1984-07-23	ガス選択透過性膜およびその製造方法
JPH0698284B2 (ja)	1994-12-07	多孔性中空糸複合膜及びその製造方法
JPH0440223A (ja)	1992-02-10	気体分離複合膜
JP4883683B2 (ja)	2012-02-22	気体分離膜用オルガノポリシロキサン
JPS618108A (ja)	1986-01-14	分離膜の製造方法
JPS6118421A (ja)	1986-01-27	気体分離膜
JP3299298B2 (ja)	2002-07-08	ガス選択透過性複合膜
JPS5895538A (ja)	1983-06-07	気体分離膜
JPS58223405A (ja)	1983-12-26	気体分離膜

JPS61129008A - 気体分離用複合膜および製造法 - Google Patents

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Cited By (7)

Citations (3)

Patent Citations (3)

Cited By (7)

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