JPS6119440B2 - - Google Patents
Info
- Publication number
- JPS6119440B2 JPS6119440B2 JP56048168A JP4816881A JPS6119440B2 JP S6119440 B2 JPS6119440 B2 JP S6119440B2 JP 56048168 A JP56048168 A JP 56048168A JP 4816881 A JP4816881 A JP 4816881A JP S6119440 B2 JPS6119440 B2 JP S6119440B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- paint
- layer
- transfer paper
- bone china
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
Landscapes
- Decoration By Transfer Pictures (AREA)
Description
【発明の詳細な説明】
本発明は、ボーンチヤイナ製品にるり色の彩飾
を施すために使用する転写紙に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a transfer paper used to decorate bone china products with magenta.
従来、陶磁器製品中、最高級品と称されている
ホーンチヤイナ製品にるり色を彩飾する方法とし
ては、一般的にボーンチヤイナの締焼素地または
釉焼素地面に、るり色に発色するコバルト顔料を
含む絵具に適量のパインダーおよび溶剤を加えて
液状にした絵具を噴霧して塗布したり（スプレー
法）あるいは刷毛や筆で塗布したり（刷毛塗り
法）、さらには前記ボーンチヤイナ素地を、前記
液状の絵具中に浸して塗布する（デイビング法）
方法が行なわれていた。 Conventionally, the method of decorating bone china products, which are considered to be the highest quality among ceramic products, with a magenta color generally involves adding a cobalt pigment that develops a magenta color to the fired or glazed base of the bone china. The liquid paint can be applied by adding an appropriate amount of binder and solvent to the paint (spray method), or can be applied with a brush or brush (brush coating method), or the bone china substrate can be coated with the liquid paint. Dip it in and apply it (diving method)
method was being used.
しかし、以上のような方法で均質なるり色の装
飾を施すためには、ボーンチヤイナの締焼素地や
釉焼素地の面に液状にしたるり絵具を一定の厚み
で均一に塗布する必要があるが、それに対して
は、熟練された高度の技能が必要であり、熟練技
能者が不可欠である。また、スプレー法やデイビ
ング法で液状にしたるり絵具を部分的に塗布する
には、塗布の不必要部分を、シリコンゴムや鉛板
で型取つたマスクで被覆しなければならず、その
ため、マスクの準備、装着、除去という面倒な作
業が必要である。さらにバインダーと溶剤を加え
て液状にした絵具は、絵付焼成前において、ボー
ンチヤイナの締焼素地または釉焼素地の面への付
着力が極めて弱く、僅かな接触によつても塗布し
た絵具が剥がれるなど種々の欠点があつた。 However, in order to apply a homogeneous lurid decoration using the method described above, it is necessary to uniformly apply liquid lubrication paint to a certain thickness on the surface of the glazed and fired base of bone china. For this purpose, highly skilled and highly skilled workers are required, and skilled technicians are indispensable. In addition, in order to partially apply liquid lubrication paint using the spraying or dabbing method, it is necessary to cover the unnecessary areas with a mask molded from silicone rubber or lead plate. The troublesome work of preparing, attaching, and removing is required. Furthermore, paint made into a liquid by adding a binder and a solvent has extremely weak adhesion to the surface of the bone china sintered base or glazed base before painting and firing, and even the slightest contact can cause the applied paint to peel off. There were various shortcomings.
本発明は、このような欠点に鑑みてなされたも
のであつて、その目的とするところは、均質な色
合いをもつるり色彩飾の施されたボーンチヤイナ
製品を簡易かつ大量に製造することを可能にする
ボーンチヤイナ製品のるり色彩飾用転写紙を提供
することにある。 The present invention has been made in view of these drawbacks, and its purpose is to make it possible to easily and mass-produce bone china products with uniform coloring and smooth colored decoration. The purpose of the present invention is to provide a decorative transfer paper made of bone china products.
以下図面を参照しつつ本発明を詳細に説明して
ゆく。 The present invention will be described in detail below with reference to the drawings.
第１図は、本発明の一実施例に係るボーンチヤ
イナ製品のるり色彩飾用転写紙の部分拡大断面図
である。本実施例の転写紙１は、転写加工紙２上
に、デキストリンなどの糊料層３を介して、焼成
によりるり色に発色するけい酸コバルト
（Co2Sio4）顔料18〜64重量％に対し、酸化鉛
（Pbo）35〜55重量％、二酸化けい素（Sio2）30〜
40重量％、酸化ほう素（B2o3）２〜６重量％、酸
化アルミニウム（Al2o3）５〜10重量％、酸化亜
鉛（Zno）５〜10重量％を主成分とするほうけい
酸鉛系の低融点フラツクス36〜82重量％を配合添
加して得られたるり色絵具100重量部に対して、
エトセル系樹脂、アルキツド樹脂、エチレングリ
コールモノエチルエーテルなどから成る速乾性メ
ジウムオイルを30〜75重量部配合して得られたる
り色絵具ペーストを、少なくとも厚みが40〜50μ
になるように印刷して形成されたるり色絵具層４
および該るり色絵具層４を保護するように被覆し
たアクリル樹脂の被覆層５から成るものである。 FIG. 1 is a partially enlarged sectional view of a decorative transfer paper made of bone china products according to an embodiment of the present invention. The transfer paper 1 of this embodiment is coated with 18 to 64% by weight of cobalt silicate (Co 2 Sio 4 ) pigment, which develops a deep blue color upon firing, on a transfer paper 2 via a glue layer 3 such as dextrin. On the other hand, lead oxide (Pbo) 35~55% by weight, silicon dioxide ( Sio2 ) 30~
40% by weight, boron oxide (B 2 o 3 ) 2-6% by weight, aluminum oxide (Al 2 o 3 ) 5-10% by weight, zinc oxide (Zno) 5-10% by weight. For 100 parts by weight of blue color paint obtained by blending and adding 36 to 82% by weight of acid lead-based low melting point flux,
A russet paint paste obtained by blending 30 to 75 parts by weight of quick-drying medium oil consisting of ethocel resin, alkyd resin, ethylene glycol monoethyl ether, etc., is applied to a thickness of at least 40 to 50 μm.
Ruri color paint layer 4 formed by printing so that
and a coating layer 5 of acrylic resin which is coated to protect the maroon paint layer 4.
この場合において、けい酸コバルト顔料にほう
けい酸鉛系の低融点フラツクスを配合添加して前
記るり色絵具を作る理由は、けい酸コバルト顔料
のみでは絵具焼成後におけるボーンチヤイナの締
焼素地への付着力が無く剥れ易いので、その付着
力を増しかつ前記るり色絵具ペーストの印刷適正
をもたせると同時にけい酸コバルト顔料の発色濃
度をボーンチヤイナの釉焼温度範囲内（1040〜
1140℃）に適合させるためである。 In this case, the reason why the azure color paint is made by blending and adding lead borosilicate-based low melting point flux to the cobalt silicate pigment is that if the cobalt silicate pigment alone is not used, it will not adhere to the compacted base of the bone china after the paint is fired. Since it has no adhesive strength and easily peels off, it is necessary to increase its adhesive strength and improve the printing suitability of the maroon paint paste, while at the same time adjusting the coloring density of the cobalt silicate pigment within the glazing temperature range of bone china (1040 ~
1140℃).
また、このようにして得られたるり色絵具をペ
ースト化するにあたり、エトセル系樹脂、アルキ
ツド系樹脂、エチレングリコールモノエチルエー
テルなどから成る速乾性メジウムオイルを使用す
るのは、スクリーン印刷により、少なくとも厚み
が40〜50μになるようにるり色絵具層４を成形し
てゆくには、通常少なくとも２〜３回るり色絵具
ペーストを刷り重ねていく必要があるが、遅乾性
メジウムオイルでは印刷したるり色絵具ペースト
を１回毎長時間乾燥しなければ刷り重ねができな
いという時間的な無駄を省くためである。また、
るり色絵具100重量部に対して速乾性メジウムオ
イルが30重量部未満では、るり色絵具ペーストの
粘土が高くて印刷適正という点において劣り、75
重量部を超えると、るり色絵具ペーストを印刷積
層して形成されたるり色絵具層４の厚みの割に
は、充分に濃い色合をもつるり色の発明が得られ
ず、またいわゆる「絵チヂレ」という不良の発生
原因となる。 In addition, when making a paste from the russet paint obtained in this way, a quick-drying medium oil made of ethocel resin, alkyd resin, ethylene glycol monoethyl ether, etc. is used. In order to form the magenta paint layer 4 so that the color is 40 to 50μ, it is usually necessary to print the magenta paint paste at least 2 to 3 times, but with slow-drying medium oil, the magenta color that is printed This is to avoid wasting time in that the paint paste must be dried for a long time each time before it is possible to print over and over again. Also,
If the amount of quick-drying medium oil is less than 30 parts by weight per 100 parts by weight of the Rurikiro paint, the clay of the Rurikiro paint paste will be high and printing properties will be poor.
If the weight exceeds 1 part by weight, it will not be possible to obtain a sufficiently deep color for the thickness of the russet paint layer 4 formed by printing and laminating the russet paint paste, and the so-called ” may cause defects.
次に、上記のような構成を有するボーンチヤイ
ナ製品のるり色彩飾用転写紙の製造方法の一実施
例を説明する。 Next, an embodiment of a method for manufacturing a decorative transfer paper of a blue bone china product having the above-mentioned structure will be described.
まず、第２図に示すように、けい酸コバルト顔
料60〜80重量％に対し、酸化鉛35〜55重量％、二
酸化けい素30〜40重量％、酸化ほう素２〜６重量
％、酸化アルミニウム５〜10重量％、酸化亜鉛５
〜10重量％を主成分とするほうけい酸鉛系の低融
点フラツクスを20〜40重量％を添加した後、フリ
ツト化してるり色原絵具を作る。次に前記るり色
原絵具30〜80重量％に前記ほうけい酸鉛系の低融
点フラツクスと同一成分および同一組成を有しか
つフリツト化された低融点フラツクスを20〜70重
量％配合してるり色絵具を作る。次に該るり色絵
具100重量部に対してエトセル系樹脂14.5重量
％、アルキツド樹脂23重量％、エチレングリコー
ルモノエチルエーテル62.5重量％から成る速乾性
メジウムオイルを30〜75重量部配合して、るり色
絵具ペーストを作る。次に前記るり色絵具ペース
トを、転写加工紙２上のデキストリンなどの糊料
層３を介して、第１層４ａを印刷し、乾燥した後
第２層４ｂを刷り重ね、乾燥した後、さらに第３
層４ｃを刷り重ねて、るり色絵具層４を、厚みが
少なくとも40〜50μとなるように形成する。るり
色絵具ペーストを印刷するにあたり250メツシユ
の印刷用スクリーンを用いた場合に１回の印刷で
印刷されるるり色絵具ペーストの厚みは10〜20μ
程度である。したがつて他のメツシユの印刷用ス
クリーンを使用する場合には、適宜刷り重ねの回
数を調整すればよい。次に第３層４ｅを乾燥した
後に、るり色絵具層４を被覆するようにアクリル
樹脂を印刷して被覆層５を形成すれば、本発明の
転写紙を完成することができる。 First, as shown in Figure 2, for 60-80% by weight of cobalt silicate pigment, 35-55% by weight of lead oxide, 30-40% by weight of silicon dioxide, 2-6% by weight of boron oxide, and 60-80% by weight of cobalt silicate pigment. 5-10% by weight, zinc oxide 5
After adding 20 to 40% by weight of a lead borosilicate-based low melting point flux containing ~10% by weight as the main component, it is fritted to produce a color pigment. Next, 20-70% by weight of a fritted low-melting flux having the same components and composition as the lead borosilicate-based low-melting flux is blended with 30-80% by weight of the original maroon color. Make colored paints. Next, 30 to 75 parts by weight of a quick-drying medium oil consisting of 14.5% by weight of ethocel resin, 23% by weight of alkyd resin, and 62.5% by weight of ethylene glycol monoethyl ether are added to 100 parts by weight of the russet paint. Make colored paint paste. Next, the first layer 4a is printed with the violet color paint paste through a glue layer 3 such as dextrin on the transfer paper 2, and after drying, the second layer 4b is overprinted, and after drying, Third
Layer 4c is overprinted to form magenta paint layer 4 having a thickness of at least 40 to 50 microns. When printing russet paint paste using a 250 mesh printing screen, the thickness of the russet paint paste printed in one print is 10 to 20 μm.
That's about it. Therefore, when using a printing screen with a different mesh, the number of times of overprinting can be adjusted as appropriate. Next, after drying the third layer 4e, an acrylic resin is printed to cover the magenta paint layer 4 to form a covering layer 5, thereby completing the transfer paper of the present invention.
なお、前記転写紙を使用してるり色彩装飾をボ
ーンチヤイナ製品に施す場合は、ボーンチヤイナ
の締焼素地面に転写を行なつた後、800℃〜1050
℃での予備焼成を経て釉がけ、釉焼成を行なうこ
とにより彩飾する方法（アンダーグレーズ法）
や、ボーンチヤイナの釉焼素地面に転写を行なつ
た後1040℃〜1140℃で焼成を行ない、釉薬中に顔
料を浸み込ませることによつて彩飾する方法（イ
ングレーズ法）のいずれにも適応できるのであ
る。 In addition, when applying color decoration to bone china products using the transfer paper, after performing the transfer on the compacted surface of the bone china, heat at 800℃ to 1050℃.
A method of decorating by pre-firing at ℃, then glazing and firing the glaze (underglaze method)
Or, after transferring to the glazed clay surface of bone china, firing at 1040℃ to 1140℃ and decorating by impregnating the pigment into the glaze (Inglaze method). It can be adapted.
以上のように本発明は、るり色彩飾の施された
ボーンチヤイナ製品を製造する上において、熟練
技能者を必要とせず、またスプレー法やデイピン
グ法による場合に必要とされたマスクが不要とな
るため製造工程の短縮、製造コストの低減を計る
ことが可能となりさらに彩飾されたるり色の色合
いを均質にすることを可能にして品質の向上を計
ることができ、また、たとえば、コーヒー碗など
のカツプの内面などの凹状の曲面にも簡単な転写
紙の貼り作業によつてるり色の彩飾を施すことが
できるなど均質な色合いをもつるり色彩飾の施さ
れたボーンチヤイナ製品の大量かつ簡易な製造を
可能とするものである。 As described above, the present invention does not require skilled technicians to manufacture bone china products decorated with bright colors, and also eliminates the need for masks that are required when using the spraying method or dipping method. It is possible to shorten the manufacturing process and reduce manufacturing costs, and it is also possible to improve quality by making the hue of the decorated lapisole uniform. Easy and large-scale production of bone china products with uniform coloring, such as the ability to decorate concave curved surfaces such as the inner surface of a car with a glossy color by simply pasting transfer paper. This makes it possible to
第１図は本発明の一実施例に係るボーンチヤイ
ナ製品のるり色彩飾用転写紙の部分拡大断面図。
第２図はるり色絵具ペーストの製造工程を示す略
図である。
図中の記号の説明、１…転写紙、２…転写加工
紙、３…糊料層、４…るり色絵具層、５…被覆
層。
FIG. 1 is a partially enlarged cross-sectional view of a decorative transfer paper made of a bone china product in an embodiment of the present invention.
FIG. 2 is a schematic diagram showing the manufacturing process of a bright colored paint paste. Explanation of symbols in the figures: 1... Transfer paper, 2... Transfer processed paper, 3... Glue layer, 4... Bright color paint layer, 5... Covering layer.
Claims (1)
バルト顔料18〜64重量％、ほうけい酸鉛系の低融
点フラツクス36〜82重量％から成る絵具100重量
部に対して、速乾性メジウムオイル30〜75重量部
を配合した絵具ペーストを、少なくとも厚みが40
〜50μになるように印刷した絵具層と、該絵具層
を保護する被覆層を形成することを特徴とするボ
ーンチヤイナ製品のるり色彩飾用転写紙。1 Apply a quick-drying medium to 100 parts by weight of a paint consisting of 18-64% by weight of cobalt silicate pigment and 36-82% by weight of lead borosilicate-based low-melting flux on transfer paper via a glue layer. Add paint paste containing 30 to 75 parts by weight of oil to a thickness of at least 40
A decorative transfer paper made from Born China, characterized by forming a paint layer printed to a thickness of ~50μ and a coating layer for protecting the paint layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4816881A JPS57160689A (en) | 1981-03-30 | 1981-03-30 | Transfer sheet for lapis lazuri decoration firing on bone china product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4816881A JPS57160689A (en) | 1981-03-30 | 1981-03-30 | Transfer sheet for lapis lazuri decoration firing on bone china product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57160689A JPS57160689A (en) | 1982-10-04 |
| JPS6119440B2 true JPS6119440B2 (en) | 1986-05-17 |
Family
ID=12795857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4816881A Granted JPS57160689A (en) | 1981-03-30 | 1981-03-30 | Transfer sheet for lapis lazuri decoration firing on bone china product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57160689A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19709011C2 (en) * | 1997-03-05 | 2002-08-01 | Michael Zimmer | Processes and color compositions for the production of decorated ceramic and glass products |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5752468Y2 (en) * | 1977-07-21 | 1982-11-15 |
-
1981
- 1981-03-30 JP JP4816881A patent/JPS57160689A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57160689A (en) | 1982-10-04 |
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