JPS61225139A - 超臨界ガスあるいは高圧液化ガスを媒体とした包接分離法 - Google Patents
超臨界ガスあるいは高圧液化ガスを媒体とした包接分離法Info
- Publication number
- JPS61225139A JPS61225139A JP60064586A JP6458685A JPS61225139A JP S61225139 A JPS61225139 A JP S61225139A JP 60064586 A JP60064586 A JP 60064586A JP 6458685 A JP6458685 A JP 6458685A JP S61225139 A JPS61225139 A JP S61225139A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- clathrate
- pressure
- supercritical
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000926 separation method Methods 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 150000001875 compounds Chemical class 0.000 claims abstract description 48
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 33
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004202 carbamide Substances 0.000 claims abstract description 26
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 25
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 24
- 238000000605 extraction Methods 0.000 claims abstract description 21
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 12
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 12
- 239000001272 nitrous oxide Substances 0.000 claims abstract description 8
- KXGVEGMKQFWNSR-LLQZFEROSA-N deoxycholic acid Chemical compound C([C@H]1CC2)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 KXGVEGMKQFWNSR-LLQZFEROSA-N 0.000 claims abstract description 5
- 229960003964 deoxycholic acid Drugs 0.000 claims abstract description 5
- KXGVEGMKQFWNSR-UHFFFAOYSA-N deoxycholic acid Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(O)=O)C)C1(C)C(O)C2 KXGVEGMKQFWNSR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 19
- 229930195729 fatty acid Natural products 0.000 claims description 19
- 239000000194 fatty acid Substances 0.000 claims description 19
- -1 fatty acid ester Chemical class 0.000 claims description 8
- 230000003213 activating effect Effects 0.000 claims 2
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 230000001419 dependent effect Effects 0.000 abstract description 2
- 230000004936 stimulating effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 52
- 238000000354 decomposition reaction Methods 0.000 description 21
- 238000000034 method Methods 0.000 description 18
- 239000002994 raw material Substances 0.000 description 17
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 15
- 150000004665 fatty acids Chemical class 0.000 description 12
- 238000011084 recovery Methods 0.000 description 7
- 150000004671 saturated fatty acids Chemical class 0.000 description 7
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 235000021323 fish oil Nutrition 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 235000003441 saturated fatty acids Nutrition 0.000 description 5
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 5
- MBMBGCFOFBJSGT-KUBAVDMBSA-N all-cis-docosa-4,7,10,13,16,19-hexaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCC(O)=O MBMBGCFOFBJSGT-KUBAVDMBSA-N 0.000 description 4
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 235000020669 docosahexaenoic acid Nutrition 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
- 241000219925 Oenothera Species 0.000 description 2
- 235000004496 Oenothera biennis Nutrition 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 235000020778 linoleic acid Nutrition 0.000 description 2
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004165 Methyl ester of fatty acids Substances 0.000 description 1
- 101100365741 Mus musculus Shisa2 gene Proteins 0.000 description 1
- 101100365738 Xenopus laevis shisa1 gene Proteins 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- DPFFXSPEODLYOH-UHFFFAOYSA-N bis($l^{1}-oxidanyl)methanone Chemical compound [O]C([O])=O DPFFXSPEODLYOH-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229940090949 docosahexaenoic acid Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 1
- JAZBEHYOTPTENJ-UHFFFAOYSA-N eicosapentaenoic acid Natural products CCC=CCC=CCC=CCC=CCC=CCCCC(O)=O JAZBEHYOTPTENJ-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- VZCCETWTMQHEPK-UHFFFAOYSA-N gamma-Linolensaeure Natural products CCCCCC=CCC=CCC=CCCCCC(O)=O VZCCETWTMQHEPK-UHFFFAOYSA-N 0.000 description 1
- VZCCETWTMQHEPK-QNEBEIHSSA-N gamma-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCC(O)=O VZCCETWTMQHEPK-QNEBEIHSSA-N 0.000 description 1
- 235000020664 gamma-linolenic acid Nutrition 0.000 description 1
- 229960002733 gamolenic acid Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000004808 supercritical fluid chromatography Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Fats And Perfumes (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60064586A JPS61225139A (ja) | 1985-03-28 | 1985-03-28 | 超臨界ガスあるいは高圧液化ガスを媒体とした包接分離法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60064586A JPS61225139A (ja) | 1985-03-28 | 1985-03-28 | 超臨界ガスあるいは高圧液化ガスを媒体とした包接分離法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61225139A true JPS61225139A (ja) | 1986-10-06 |
| JPH0329441B2 JPH0329441B2 (fr) | 1991-04-24 |
Family
ID=13262496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60064586A Granted JPS61225139A (ja) | 1985-03-28 | 1985-03-28 | 超臨界ガスあるいは高圧液化ガスを媒体とした包接分離法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61225139A (fr) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01249742A (ja) * | 1988-03-31 | 1989-10-05 | Miyagi Pref Gov | 高度不飽和脂肪酸またはそのエステルなどの混合物の成分濃縮分別装置とその成分濃縮分別法 |
| US5013443A (en) * | 1989-01-23 | 1991-05-07 | Nihon Bunko Kogyo Kabushiki Kaisha | Extraction and separation method and apparatus using supercritical fluid |
| WO1995033541A1 (fr) * | 1994-06-09 | 1995-12-14 | Idaho Research Foundation, Inc. | Extraction de metaux et metalloides de fluides |
| US5606724A (en) * | 1995-11-03 | 1997-02-25 | Idaho Research Foundation, Inc. | Extracting metals directly from metal oxides |
| US5730874A (en) * | 1991-06-12 | 1998-03-24 | Idaho Research Foundation, Inc. | Extraction of metals using supercritical fluid and chelate forming legand |
| US5770085A (en) * | 1991-06-12 | 1998-06-23 | Idaho Research Foundation, Inc. | Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts |
| US5792357A (en) * | 1996-07-26 | 1998-08-11 | Idaho Research Foundation, Inc. | Method and apparatus for back-extracting metal chelates |
| US7128840B2 (en) | 2002-03-26 | 2006-10-31 | Idaho Research Foundation, Inc. | Ultrasound enhanced process for extracting metal species in supercritical fluids |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5231855A (en) * | 1975-09-02 | 1977-03-10 | Giichi Masuda | Processing and treating method of corn germ |
-
1985
- 1985-03-28 JP JP60064586A patent/JPS61225139A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5231855A (en) * | 1975-09-02 | 1977-03-10 | Giichi Masuda | Processing and treating method of corn germ |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01249742A (ja) * | 1988-03-31 | 1989-10-05 | Miyagi Pref Gov | 高度不飽和脂肪酸またはそのエステルなどの混合物の成分濃縮分別装置とその成分濃縮分別法 |
| US5013443A (en) * | 1989-01-23 | 1991-05-07 | Nihon Bunko Kogyo Kabushiki Kaisha | Extraction and separation method and apparatus using supercritical fluid |
| US5730874A (en) * | 1991-06-12 | 1998-03-24 | Idaho Research Foundation, Inc. | Extraction of metals using supercritical fluid and chelate forming legand |
| US5770085A (en) * | 1991-06-12 | 1998-06-23 | Idaho Research Foundation, Inc. | Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts |
| WO1995033541A1 (fr) * | 1994-06-09 | 1995-12-14 | Idaho Research Foundation, Inc. | Extraction de metaux et metalloides de fluides |
| US5606724A (en) * | 1995-11-03 | 1997-02-25 | Idaho Research Foundation, Inc. | Extracting metals directly from metal oxides |
| US5792357A (en) * | 1996-07-26 | 1998-08-11 | Idaho Research Foundation, Inc. | Method and apparatus for back-extracting metal chelates |
| US7128840B2 (en) | 2002-03-26 | 2006-10-31 | Idaho Research Foundation, Inc. | Ultrasound enhanced process for extracting metal species in supercritical fluids |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0329441B2 (fr) | 1991-04-24 |
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