JPS61273A - Production of insulator - Google Patents
Production of insulatorInfo
- Publication number
- JPS61273A JPS61273A JP6327985A JP6327985A JPS61273A JP S61273 A JPS61273 A JP S61273A JP 6327985 A JP6327985 A JP 6327985A JP 6327985 A JP6327985 A JP 6327985A JP S61273 A JPS61273 A JP S61273A
- Authority
- JP
- Japan
- Prior art keywords
- cement
- insulator
- water
- porcelain
- reducing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012212 insulator Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000004568 cement Substances 0.000 claims abstract description 35
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 9
- 239000011083 cement mortar Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 abstract description 6
- 229910052925 anhydrite Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- -1 anhydrous gypsum Chemical compound 0.000 abstract description 3
- 239000004576 sand Substances 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 2
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 13
- 230000001070 adhesive effect Effects 0.000 description 13
- 238000001723 curing Methods 0.000 description 7
- 239000011398 Portland cement Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000004570 mortar (masonry) Substances 0.000 description 5
- 239000010440 gypsum Substances 0.000 description 4
- 229910052602 gypsum Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000002411 adverse Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Inorganic Insulating Materials (AREA)
- Insulators (AREA)
- Insulating Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は碍子の金具と磁器とをポルトランドセメント系
接着剤で接着する方法に関し、より詳しくは他の特性に
悪影響を与えることなく、セメントの接着力を速やかに
発現させ、作業性を改良する方法に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for bonding insulator metal fittings and porcelain with a Portland cement adhesive, and more specifically, the present invention relates to a method for bonding insulator metal fittings and porcelain with a Portland cement adhesive. The present invention relates to a method for quickly developing adhesive strength and improving workability.
従来、碍子の磁器と金具とは、ポルトランドセメント等
の無機系接着剤又はエポキシ樹脂等の有機系の接着剤に
より接着して製造している。Conventionally, insulator porcelain and metal fittings have been manufactured by bonding them together using an inorganic adhesive such as Portland cement or an organic adhesive such as epoxy resin.
前者は、製品とするまでには１〜３日の蒸気養生が必要
であり、かつ引抜き強度が小さく、後者は高価格、有害
性、付着した接着剤の除去に問題がある。The former requires steam curing for 1 to 3 days before being made into a product and has a low pull-out strength, while the latter is expensive, harmful, and has problems in removing attached adhesive.
本発明は、ポルトランドセメントなどの通常のセメント
を改良し、短時間で充分な引抜き強度を発現させ、しか
も他の特性に悪影響を与えない碍子の製造法を提供する
ことを目的とする。An object of the present invention is to provide a method for producing an insulator that improves ordinary cement such as Portland cement, develops sufficient pull-out strength in a short period of time, and does not adversely affect other properties.
本発明は、セメントに対して硫酸カルシウムをＣａＳＯ
４成分として７〜２０重量％含有するセメントペースト
又はセメントモルタルを磁器と金具との間隙に充填し、
これを温度３０〜９０℃に保持する碍子の製造法におい
て、上記セメントペースト又はセメントモルタルに活性
シリカ微粉末とセメント減水剤とを添加することを特徴
とする。The present invention uses calcium sulfate for cement as CaSO
Cement paste or cement mortar containing 7 to 20% by weight of the four components is filled into the gap between the porcelain and the metal fittings,
A method for manufacturing an insulator in which the insulator is maintained at a temperature of 30 to 90 DEG C. is characterized by adding activated silica fine powder and a cement water reducing agent to the cement paste or cement mortar.
本発明において、硫酸カルシウムとは、無水塩、２水塩
、半水塩から選ばれた１種以上のものであって、好まし
くは不溶性の無水石膏である。その理由は、通常、セメ
ントには凝結調節剤としての２水石奮が添加されている
が、これにさらに不溶性の無水石膏以外の石膏を添加し
て、本発明の硫酸カルシウム量にすると、セメントの凝
結時間が著しく長くなって、生産性が低下するからであ
る。In the present invention, calcium sulfate is one or more selected from anhydrous salts, dihydrate salts, and hemihydrate salts, and is preferably insoluble anhydrite. The reason for this is that dihydrate is normally added to cement as a setting regulator, but when gypsum other than insoluble anhydrite is added to this to reach the amount of calcium sulfate of the present invention, cement This is because the coagulation time becomes significantly longer and productivity decreases.
半水布告は偽凝結しやすいので、使用にあたっては練り
殺しする必要かある。Half-water edict is prone to false condensation, so it may be necessary to knead it before use.
また、本発明でいうセメントとは、普通、早強、超早強
、中庸熱、白色のポルトランドセメント又はシリカ、フ
ライアッシュ等を配合した混合セメントである。Further, the cement as used in the present invention refers to normal, early strength, ultra early strength, moderate heat, white Portland cement, or mixed cement containing silica, fly ash, etc.
本発明においては、セメント中の硫酸カルシウム（７）
ＣａＳＯ４成分の含有量を、セメントに対して７〜２０
重量％にする。硫酸カルシウムのＣａ Ｓ Ｏ４成分が
７重量％以下であれば硫酸カルシウムを含有させること
による生産性向上等の効果が充分でなく、また２０重量
％−を越える量では、長期間にわたって膨み
張するので耐久性が悪（なる。好ましいＣａ５
Ｏｎ成分の含有量はセメントに対して１０〜１５重量％
である。In the present invention, calcium sulfate (7) in cement
The content of CaSO4 component is 7 to 20 relative to cement.
Convert to weight%. If the CaSO4 component of calcium sulfate is less than 7% by weight, the effect of improving productivity by including calcium sulfate will not be sufficient, and if it exceeds 20% by weight, it will swell over a long period of time.
The durability is poor (desirable) because of the tension.
The content of On component is 10 to 15% by weight based on cement.
It is.
本発明においては、活性シリカ微粉末及びセメント減水
剤を混合添加する。活性シリカは、例えばフェロシリコ
ン等の電炉より生じるシリカヒユームなとが好ましく、
１０μ以下の微粉状の５ｔ０２である。活性シリカはセ
メント永和物と反応し、カルシウムシリケート水和物を
生成し、高い接着強度を示す活性に富んだシリカである
。その添加量はセメン］・成分と石膏との和に対して０
．０５〜５重量％、好ましくは０．５〜３重量％である
。In the present invention, activated silica fine powder and cement water reducing agent are mixed and added. The activated silica is preferably a silica hume produced from an electric furnace such as ferrosilicon,
It is 5t02 in the form of a fine powder of 10μ or less. Activated silica is a highly active silica that reacts with cement permanents to form calcium silicate hydrates and exhibits high adhesive strength. The amount added is 0 for the sum of cement and gypsum.
．． 05-5% by weight, preferably 0.5-3% by weight.
セメント減水剤はナフタリンスルホン酸塩系、リグニン
スルボン酸塩系など通常の減水剤が使用され、その添加
量はセメント成分と石膏との和に対し０．１〜５重量％
、好ましくは０．２〜３重量％である。Common water reducing agents such as naphthalene sulfonate and lignin sulfonate are used as cement water reducing agents, and the amount added is 0.1 to 5% by weight based on the sum of cement components and gypsum.
, preferably 0.2 to 3% by weight.
なお、この場合、セメントに対して約０．５〜２重量倍
量の砂を加えてモルタルとすれは、碍子の耐久力が著し
く向上して好ましい。In this case, it is preferable to add sand in an amount of about 0.5 to 2 times the weight of cement and use it as a mortar, as this will significantly improve the durability of the insulator.
本発明に使用するセメントは水で混練し、磁器に設りた
金具を取（＝ｔ ｌるための間隙に、金具と共に前記混
練物を充填する。The cement used in the present invention is kneaded with water, and the kneaded mixture is filled together with the metal fittings into the gaps provided in the porcelain to remove the metal fittings.
加熱養生方法は温水、）ｂ気、電研波なとのよ・うに、
碍子の温度を高められる方法であればよい。The heating curing method is warm water, ) b ki, denkenha, etc.
Any method that can increase the temperature of the insulator may be used.
加熱温度は３０〜９０℃、好ましくは５０〜７０°Ｃで
ある。The heating temperature is 30-90°C, preferably 50-70°C.
３０℃以下では強度発現が悪＜、９０°Ｃ以上では強度
発現に悪影響を与える水和物が生成し、いずれの場合も
碍子の耐久性が低下する。加熱の開始時期は、接着剤が
凝結する前に行うと接着部分にひびわれを発生すること
があるので、セメントの凝結後に行うのがよい。加熱速
度は同様な理由により１０〜ｂ
保持時間は２〜８時間程度である。At temperatures below 30°C, strength development is poor; at temperatures above 90°C, hydrates are formed that adversely affect strength development, and in either case, the durability of the insulator is reduced. It is best to start heating after the cement has set, as cracks may occur in the bonded area if it is started before the adhesive has set. For the same reason, the heating rate is about 10-b and the holding time is about 2-8 hours.
以上説明した通り、本発明はＣａＳＯ４成分として７〜
２０重量％の硫酸カルシウムと活性シリカ微粉末と方メ
′ト減水剤“を含有す４１％７）−Ｓ−Ｘｉ−又はセメ
ントモルタルを用いて碍子を製造するものであり、下記
の効果を有する。As explained above, the present invention uses 7 to 7 as the CaSO4 component.
Insulators are manufactured using 41%7) -S-Xi- or cement mortar containing 20% by weight of calcium sulfate, activated silica fine powder, and cement mortar, and have the following effects: .
（１）従来のセメント系接着剤は１〜３日の養生を必要
としたが、本発明では２〜８時間で充分であり、生産性
が向上した。(1) Conventional cement-based adhesives require curing for 1 to 3 days, but in the present invention, curing for 2 to 8 hours is sufficient, improving productivity.
（２）接着強度がきわめζ高くなるので、その分、骨材
量を増加することができ、耐久性か一段と向上した。(2) Since the adhesive strength is extremely high, the amount of aggregate can be increased accordingly, and the durability is further improved.
（３）従来のセメント系接着剤では生産性を高めるため
に早強材を添加すると、高温度差性状（碍子を８０℃で
７日間乾燥後、１０℃の水中に７日間浸漬する操作を繰
返したときの性状）が著しく低下するが、本発明により
得られた碍子は、高温度差性状試験で良好な結果が得ら
れた。(3) With conventional cement adhesives, when early strengthening materials are added to increase productivity, high temperature difference properties (drying the insulator at 80°C for 7 days and then immersing it in water at 10°C for 7 days are repeated) However, the insulator obtained according to the present invention gave good results in the high temperature difference property test.
（４） アルミナセメントを接着剤とするものに比べ
て、長期耐久性が大であり、かつ、接着剤の取扱いが容
易である。(4) Compared to adhesives using alumina cement, long-term durability is greater and the adhesive is easier to handle.
市販の普通ポルトランドセメンｌ１−４５Ｑ、不溶性無
水石膏５０ｇ、５号珪砂５００ ｇ 、減水剤として「
マイティ １５０Ｊ （商品名：花玉石鹸０１製）５
ｇ（セメントと石膏との和に対し１重量％）、活性シリ
カとして「デンカフラワー」 （商品名：電気化学工業
（株製）を第１表に示す割合で混合し、水を加えてフロ
ーを２３０±１０とし、混練モルタルを得た。Commercially available ordinary Portland cement 1-45Q, 50 g of insoluble anhydrite, 500 g of No. 5 silica sand, water reducing agent:
Mighty 150J (Product name: Hanadama Soap 01) 5
g (1% by weight based on the sum of cement and gypsum) and "Denka Flower" (trade name: Denki Kagaku Kogyo Co., Ltd.) as activated silica were mixed in the proportions shown in Table 1, and water was added to control the flow. 230±10 to obtain a kneaded mortar.
この混練モルタルを、碍子の磁器に設けた間隙に金具と
共に充填し接着した。This kneaded mortar was filled into the gap provided in the porcelain insulator together with the metal fittings and bonded together.
この碍子を接着後、直ちに蒸気養生室に入れ、加熱速度
２０℃／時で最高温度７０℃まで上げ、６時間保持した
。この碍子の引抜き強度を測定した結果を第１表に示し
た。Immediately after bonding this insulator, it was placed in a steam curing chamber, and the temperature was raised to a maximum temperature of 70° C. at a heating rate of 20° C./hour, and maintained for 6 hours. Table 1 shows the results of measuring the pull-out strength of this insulator.
また、比較のため、上記成分中、無水石膏または減水剤
を加えない以外は上記方法と同様にして試験を行い、そ
の結果を第１表に併記した。For comparison, a test was conducted in the same manner as above except that anhydrite or water reducing agent was not added to the above ingredients, and the results are also listed in Table 1.
第 １ 表
（単位： Ｋｇ）
デンカフラワーと減水剤を併用したものは短時間で高強
度を発現し、養生時間かわすか２時間で、出荷可能な引
抜き強度３０’ＯＫｔ４に達した。Table 1 (Unit: Kg) The product using Denka Flower in combination with a water reducing agent developed high strength in a short period of time, and reached a shippingable pull-out strength of 30'OKt4 in just 2 hours of curing time.
別に、上記の方法で得た混練モルタルのデンカフラワー
１％、減水剤１％を添加したものを用いてＪＩＳ−Ｒ５
２１０に準じて４ Ｘ ４ Ｘ１６ｃｍのモルタル供試
体を成形し、直ちに蒸気養生室に入れ、加熱速度２０℃
／時で最高温度７０℃まで上げ、６時間保１３１した後
の圧縮強度を測定したところ、５３１Ｋｇ／ ｃ＋１！
であった。また、この供試体を水中養生したときの圧縮
強度は、２４時間後、３日後、７日後、２８日後、それ
ぞれ９８２Ｋｇ／ｃｎｌ、９９５ｈ ／ ｃｌ、１０３
８Ｋｇ／ ｃｎ＋、１１２１Ｋｇ／ｃｎ＋であった。Separately, using the kneaded mortar obtained by the above method to which 1% Denka flour and 1% water reducing agent were added,
210, a mortar specimen of 4 x 4 x 16 cm was molded, immediately placed in a steam curing chamber, and heated at a heating rate of 20°C.
When the compressive strength was measured after raising the temperature to a maximum temperature of 70℃/hour and holding it for 6 hours, it was 531Kg/c+1!
Met. In addition, the compressive strengths of this specimen when cured in water were 982 Kg/cnl, 995 h/cl, and 103 after 24 hours, 3 days, 7 days, and 28 days, respectively.
They were 8Kg/cn+ and 1121Kg/cn+.
また、これらの供試体を８０℃で７日間乾燥後〜１０℃
の水中に７日間浸漬する操作を３０サイクル繰返したと
ころ、いずれも変化がなかった。In addition, these specimens were dried at 80℃ for 7 days and then heated to 10℃.
After repeating 30 cycles of immersion in water for 7 days, there was no change in any of the cases.
また、早強ポルトランド′セメントを用いて、上記実施
例と同様の試験を行った表ころ、普通セメントを用いた
場合に比べて約１．３倍の強度が得られた。In addition, when the surface roller was subjected to the same test as in the above example using early-strength Portland' cement, the strength was approximately 1.3 times greater than that obtained when ordinary cement was used.
Claims (1)
して７〜２０重量％含有するセメントペースト又はセメ
ントモルタルを磁器と金具との間隙に充填し、これを温
度３０〜９０℃に保持する碍子の製造法において、上記
セメントペースト又はセメントモルタルに活性シリカ微
粉末とセメント減水剤とを添加することを特徴とする碍
子の製造法。In the insulator manufacturing method, the above method is performed by filling the gap between the porcelain and the metal fittings with cement paste or cement mortar containing 7 to 20% by weight of calcium sulfate as a CaSO_4 component to the cement, and maintaining this at a temperature of 30 to 90°C. A method for producing an insulator, which comprises adding activated silica fine powder and a cement water reducing agent to cement paste or cement mortar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6327985A JPS61273A (en) | 1985-03-29 | 1985-03-29 | Production of insulator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6327985A JPS61273A (en) | 1985-03-29 | 1985-03-29 | Production of insulator |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53150274A Division JPS5845762B2 (en) | 1978-12-05 | 1978-12-05 | Insulator manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61273A true JPS61273A (en) | 1986-01-06 |
| JPS622410B2 JPS622410B2 (en) | 1987-01-20 |
Family
ID=13224720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6327985A Granted JPS61273A (en) | 1985-03-29 | 1985-03-29 | Production of insulator |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61273A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102243914A (en) * | 2010-05-13 | 2011-11-16 | 苏州爱建电瓷有限公司 | Binding process of insulator |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS496016A (en) * | 1972-05-10 | 1974-01-19 | ||
| JPS5345322A (en) * | 1976-10-07 | 1978-04-24 | Ube Industries | Production of ultralighttweight concrete of high strength |
-
1985
- 1985-03-29 JP JP6327985A patent/JPS61273A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS496016A (en) * | 1972-05-10 | 1974-01-19 | ||
| JPS5345322A (en) * | 1976-10-07 | 1978-04-24 | Ube Industries | Production of ultralighttweight concrete of high strength |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102243914A (en) * | 2010-05-13 | 2011-11-16 | 苏州爱建电瓷有限公司 | Binding process of insulator |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS622410B2 (en) | 1987-01-20 |
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