JPS6145223B2 - - Google Patents
Info
- Publication number
- JPS6145223B2 JPS6145223B2 JP55056424A JP5642480A JPS6145223B2 JP S6145223 B2 JPS6145223 B2 JP S6145223B2 JP 55056424 A JP55056424 A JP 55056424A JP 5642480 A JP5642480 A JP 5642480A JP S6145223 B2 JPS6145223 B2 JP S6145223B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon black
- layer
- image
- dye
- gelatin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006229 carbon black Substances 0.000 claims description 85
- 230000003647 oxidation Effects 0.000 claims description 30
- 238000007254 oxidation reaction Methods 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 24
- 239000010410 layer Substances 0.000 description 110
- 235000019241 carbon black Nutrition 0.000 description 84
- 239000000975 dye Substances 0.000 description 51
- -1 silver halide Chemical class 0.000 description 37
- 150000001875 compounds Chemical class 0.000 description 36
- 238000000034 method Methods 0.000 description 35
- 239000000839 emulsion Substances 0.000 description 33
- 108010010803 Gelatin Proteins 0.000 description 32
- 229920000159 gelatin Polymers 0.000 description 32
- 239000008273 gelatin Substances 0.000 description 32
- 235000019322 gelatine Nutrition 0.000 description 32
- 235000011852 gelatine desserts Nutrition 0.000 description 32
- 229910052709 silver Inorganic materials 0.000 description 27
- 239000004332 silver Substances 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 238000012545 processing Methods 0.000 description 19
- 238000012546 transfer Methods 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 12
- 238000009792 diffusion process Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000007800 oxidant agent Substances 0.000 description 10
- 239000005708 Sodium hypochlorite Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 8
- 229910001385 heavy metal Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 235000010265 sodium sulphite Nutrition 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- 239000002667 nucleating agent Substances 0.000 description 5
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- IELLVVGAXDLVSW-UHFFFAOYSA-N tricyclohexyl phosphate Chemical compound C1CCCCC1OP(OC1CCCCC1)(=O)OC1CCCCC1 IELLVVGAXDLVSW-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- 101150006989 NDEL1 gene Proteins 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000007793 ph indicator Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000001235 sensitizing effect Effects 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 239000001043 yellow dye Substances 0.000 description 3
- SZABDZQEJIVBIB-UHFFFAOYSA-N 2-pentadecylbenzene-1,4-diol;sodium Chemical compound [Na].CCCCCCCCCCCCCCCC1=CC(O)=CC=C1O SZABDZQEJIVBIB-UHFFFAOYSA-N 0.000 description 2
- SJSJAWHHGDPBOC-UHFFFAOYSA-N 4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(C)CN1C1=CC=CC=C1 SJSJAWHHGDPBOC-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 2
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229940081735 acetylcellulose Drugs 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 2
- 150000004986 phenylenediamines Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- 239000003232 water-soluble binding agent Substances 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZKEGGSPWBGCPNF-UHFFFAOYSA-N 2,5-dihydroxy-5-methyl-3-(piperidin-1-ylamino)cyclopent-2-en-1-one Chemical compound O=C1C(C)(O)CC(NN2CCCCC2)=C1O ZKEGGSPWBGCPNF-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- JUVJNJSHVZFMHX-UHFFFAOYSA-N 4-hydroxy-2,4-dimethyl-1-(4-methylphenyl)pyrazolidin-3-one Chemical compound C1C(C)(O)C(=O)N(C)N1C1=CC=C(C)C=C1 JUVJNJSHVZFMHX-UHFFFAOYSA-N 0.000 description 1
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 235000009697 arginine Nutrition 0.000 description 1
- 229940072107 ascorbate Drugs 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical class OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- JOXWSDNHLSQKCC-UHFFFAOYSA-N ethenesulfonamide Chemical class NS(=O)(=O)C=C JOXWSDNHLSQKCC-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000012948 isocyanate Chemical class 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- ORQYPOUSZINNCB-UHFFFAOYSA-N potassium;hypobromite Chemical compound [K+].Br[O-] ORQYPOUSZINNCB-UHFFFAOYSA-N 0.000 description 1
- UJQKSBYNVKHMFX-UHFFFAOYSA-N potassium;hypoiodite Chemical compound [K+].I[O-] UJQKSBYNVKHMFX-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- XOQRNNDIPPJGLV-UHFFFAOYSA-M sodium;2,5-dihydroxy-4-pentadecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC1=CC(O)=C(S([O-])(=O)=O)C=C1O XOQRNNDIPPJGLV-UHFFFAOYSA-M 0.000 description 1
- CRWJEUDFKNYSBX-UHFFFAOYSA-N sodium;hypobromite Chemical compound [Na+].Br[O-] CRWJEUDFKNYSBX-UHFFFAOYSA-N 0.000 description 1
- SAFWHKYSCUAGHQ-UHFFFAOYSA-N sodium;hypoiodite Chemical compound [Na+].I[O-] SAFWHKYSCUAGHQ-UHFFFAOYSA-N 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- SFENPMLASUEABX-UHFFFAOYSA-N trihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OCCCCCC SFENPMLASUEABX-UHFFFAOYSA-N 0.000 description 1
- XOKPOPWYLRKXEA-UHFFFAOYSA-N trihexylazanium;chloride Chemical compound Cl.CCCCCCN(CCCCCC)CCCCCC XOKPOPWYLRKXEA-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/52—Bases or auxiliary layers; Substances therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/95—Photosensitive materials characterised by the base or auxiliary layers rendered opaque or writable, e.g. with inert particulate additives
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/44—Integral units, i.e. the image-forming section not being separated from the image-receiving section
- G03C8/48—Integral units, i.e. the image-forming section not being separated from the image-receiving section characterised by substances used for masking the image-forming section
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
æ¬çºæã¯åçæå
ææã«é¢ããç¹ã«ã«ãŒãã³ã
ã©ãã¯ãå«ãããã²ã³åéåçæå ææã«é¢ã
ãã ã«ã©ãŒæ¡æ£è»¢åæ³çšåçæå ææã¯æ®åœ±åŸçŽã¡
ã«ã«ã©ãŒåçã楜ãããâã€ã³ã¹ã¿ã³ãâåççš
ãšããŠå®çšãããŠããããããŠæ®åœ±è ãé£ç¶çã«
ã«ã¡ã©ã®ã·ã€ãã¿ãŒãæŒããããã«ããã®ææã¯
æ®åœ±åŸçŽã¡ã«ã«ã¡ã©ïŒæç®±ïŒããæŒãåºãããŠæ
æäžã§çŸåãçµäºãããã工倫ãããŠãããå³
ã¡ããã®çš®ã®ææã§ã¯æ®åœ±åŸã«ã¯æå å±€ãäºã€ã®
é®å å±€ïŒéåžžãã«ãŒãã³ãã©ãã¯ãå«æããå±€ïŒ
ã§ãµã³ãã€ããç¶ã«å ãŸãããã®åŸã®æ害ãªé²å
ããä¿è·ããããã工倫ãããŠããããã®ãããª
ææèšèšã¯å€ãããææ¡ãããŠãããäŸãã°ç±³åœ
ç¹èš±3053659å·çã«èšèŒãããã ããããªãããåŸæ¥æªåŠçã®ã«ãŒãã³ãã©ãã¯
ã䜿çšããŠé®å å±€ã圢æãããšãææ補é æåã³
ææã®ä¿åäžã«è©²é®å å±€ãããã®è¿åã®ããã²ã³
åéä¹³å€å±€ã«æªåœ±é¿ãåãŒããŠãåŸããã転åç»
åã®æå°æ¿åºŠïŒDminïŒãäžããããæ倧æ¿åºŠ
ïŒDmaxïŒãäžããæ¬ ç¹ããã€ãããã®äºã¯ãã
ã²ã³åéä¹³å€ãšããŠãäºãã«ãããããŠããªãå
ã®çŽæ¥ããžä¹³å€ãã䜿çšããå Žåã«ç¹ã«é¡èã§ã
ãããŸããæªåŠçã®ã«ãŒãã³ãã©ãã¯ã§é®å å±€ã
圢æããããšè»¢åè²çŽ ããã®å±€äžãæ¡æ£ããéã«
ã«ãŒãã³ãã©ãã¯ã«æç²ïŒåžçïŒããã転åè²çŽ
ç»åã®æ倧æ¿åºŠãäœäžããããç»ååºçŸæéãé
ãããšããæ¬ ç¹ããã€ãã ã«ãŒãã³ãã©ãã¯ã®äœ¿çšã«ããã«ããªçºçã®é²
æ¢ã®ããã«ã«ãããŠã ãéçã®ééå±ã®æ°Žæº¶æ§å¡©
ãã«ãŒãã³ãã©ãã¯å«æå±€ã«æ·»å ããäºããç±³åœ
ç¹èš±3900323å·ã«ææ¡ãããŠããããããããã®
ãããªééå±å¡©ã®äœ¿çšã¯ãå ¬å®³ãåŒãèµ·ãåå ã«
ãªãã°ããã§ãªããã«ãŒãã³ãã©ãã¯ã®ãããã«
ããäžçŽç©ïŒã€ãªãŠååç©ïŒã®éã®å€åã«èŠåã
ééå±å¡©ã®æ·»å éããã®éœåºŠèª¿ç¯ããã®ãé£ãã
ãšããæè¡çãªåé¡ãããããŸããééå±å¡©ã®äœ¿
çšéãå€ããããšãããã€ãŠééå±å¡©èªèº«ãåç
æ§ã«æªåœ±é¿ãåãŒããåçæ床ãäœäžãããïŒã«
ãŒãã³ãã©ãã¯ã®äœ¿çšãããã«ããåçã®å質ã«
ãã©ãããçããïŒæ¬ ç¹ãããã æ¬çºæã®ç®çã¯ãåçæ§ã«æªã圱é¿ãåãŒããª
ãã«ãŒãã³ãã©ãã¯ãå«æããåçæå ææãæ
äŸããäºã«ããã äžèšç®çã¯ã匷å¶é žååŠçãããã«ãŒãã³ãã©
ãã¯ãå«æããåçæå ææã«ãã€ãŠå¹æçã«é
æã§ããã æ¬çºæã®å®æœã«åœã€ãŠäœ¿çšããã«ãŒãã³ãã©ã
ã¯ã®åæãšããŠã¯ããã€ã³ãã«ãã©ãã¯
ïŒChannel BlackïŒããµãŒãã«ãã©ãã¯ïŒThermal
BlackïŒåã³ãã¢ãŒãã¹ãã©ãã¯ïŒFurnace
BlackïŒãªã©ä»»æã®è£œæ³ã®ãã®ã䜿çšã§ãããã«
ãŒãã³ãã©ãã¯ã®ç²åãµã€ãºã¯ç¹ã«éå®ãããªã
ãã0.03ÎŒã0.12ÎŒã®ãã®ã奜ãŸããã ãŸã匷å¶é žååŠçã®æ¹æ³ãšããŠã¯æªåŠçã®ã«ãŒ
ãã³ãã©ãã¯ã«é žåå€ãæ°çžã§äœçšãããæ¹æ³ãš
液çžã§äœçšãããæ¹æ³ãšãããã åè ã®å Žåã«ã¯ç©ºæ°ããªãŸã³ã䜿çšããäºãã§
ããååŸè ã®å Žåã«ã¯éé ¢é žãéç¡«é žã«ãªãŠã ã
éç¡«é žãããªãŠã ãéç¡«é žã¢ã³ã¢ããŠã ãéé žå
æ°ŽçŽ ãªã©ã®éé žåç©ïŒç¡é žãªã©ã®é žååã®ãã
é žïŒæ¬¡äºããã²ã³é žå¡©ãªã©ééå±å¡©ã§ãªããã®ã
䜿çšã§ããããããã®é žåå€ã䜿çšãããéã«ã¯
å ç±ããã®ããããç¹ã«çŽ40âã100âã«å ç±ã
ãã®ã奜ãŸãããåå¿æã®PHã¯äœ¿çšããé žåå€ã«
ããé žæ§åã³ã¢ã«ã«ãªæ§ã®ä»»æã®PHããéžæãã
ããšãã§ããã ã«ãŒãã³ãã©ãã¯ã匷å¶é žåããçšåºŠã¯é žåå€
ã®çš®é¡ã«å¿ããŠé©å®æ±ºå®ã§ããããåŸã®å®éšäŸã«
èšèŒãããã«ãŒãã³ãã©ãã¯ãžã®è²çŽ ããã®åž
çéã®æž¬å®ãã®æ¡ä»¶äžã«æž¬å®ãããè²çŽ ããã®
åžçéããã€ãŠäžã€ã®ç®å®ãšããããšãã§ããã
å³ã¡ããã®æž¬å®æ¡ä»¶ã«æŒãŠæªåŠçã®ã«ãŒãã³ãã©
ãã¯ã®å Žåã«æ¯ã¹ãŠäžèšã®è²çŽ ããã85ïŒ ä»¥äž
ã®åžçéã瀺ããããªçšåºŠã«ãæ¯èŒãããæªåŠç
ã®ãããšåäžã®ã«ãŒãã³ãã©ãã¯ã匷å¶é žåãã
ã®ã奜ãŸããã é žåå€ãæ°çžã§äœçšãããããã液çžã§äœçšã
ããæ¹ã奜ãŸããããªãã§ã次äºããã²ã³é žå¡©
ïŒäœããééå±å¡©ã¯é€ãïŒã䜿çšããã®ã奜ãŸã
ãã 奜ãŸãã次äºããã²ã³é žå¡©ãšããŠã¯ã次äºãã
ã²ã³é žã®ã¢ã«ã«ãªéå±å¡©ãã¢ã«ã«ãªåé¡éå±å¡©ãª
ã©ããããæŽã«å ·äœçã«ã¯æ¬¡äºå¡©çŽ é žãœãŒãã次
äºèçŽ é žãœãŒãã次äºæ²çŽ é žãœãŒãã次äºå¡©çŽ é ž
ã«ãªã次äºèçŽ é žã«ãªã次äºæ²çŽ é žã«ãªã次äºå¡©
çŽ é žã«ã«ã·ãŠã ãªã©ãæããããšãã§ãããç¹ã«
次äºå¡©çŽ é žãœãŒãã䜿çšããã®ã奜ãŸããã 液çžã§åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯
ã¯ãæªåŠçã®ã«ãŒãã³ãã©ãã¯ãåæ£ããæ°Žåæ£
液ã«å ã«è¿°ã¹ãé žåå€ãæ·»å ããå ç±çã«ããã«
ãŒãã³ãã©ãã¯ã匷å¶é žåããŠã€ããããšãã§ã
ãããã®å Žåã«ã¯æ®åé žåå€ã®æªåœ±é¿ãé€ããã
ã«ãåçæ§ã«åœ±é¿ã®å°ãªãéå å€ãäŸãã°äºç¡«é ž
ãããªãŠã ãã¢ã¹ã³ã«ãã³é žãã°ã«ã³ãŒã¹ãã·ãš
ç³çã®éå å€ã§åŸåŠçããããšã奜ãŸããããã
ãããã®ããã«ããŠåŸãããã«ãŒãã³ãã©ãã¯æ°Ž
åæ£ç©ããã¯ãåçæ§ã«å®³ãåãŒãé žåå€åå¿ç©
ãéå å€åå¿ç©ãé€å»ããå¿ èŠãããããã®ãã
ã«ã¯éâæ°ŽæŽâéã®æäœãç¹°ãè¿ãæ¹æ³ãã
ãããã«ãŒãã³ãã©ãã¯ã匷å¶é žååŠçãããã®
ã¯ãæ°Žãšã®èŠªåæ§ãå¢ããéããã®ã«é·æéã
èŠãããšããé£ç¹ãããããŸãåéèãå©çšãã
æ¹æ³ãããããåå¿ç©ãå®å šã«é€å»ããã®ã«é·æ
éãããããšãæ°Žã®äœ¿çšéãå€ãããšçã®é£ç¹ã
ããããããã®é£ç¹ã¯åŒ·å¶é žååŠçãããã«ãŒã
ã³ãã©ãã¯æ°Žåæ£ç©ã«ãŒã©ãã³ãå ããŒã©ãã³å
æ£ç©ãšããããŒãã«æ°ŽæŽæ³ãæ²éæ³çã«ããåèš
ã®åå¿çæç©ãæ°ŽæŽé€å»ããã°å¹æçã«è§£æ±ºã§ã
ããããŒãã«æ°ŽæŽæ³ãæ²éæ³ã¯ããŒã©ãã³ããã²
ã³åéä¹³å€è£œé æã®å¯æº¶æ§å¡©é¡ã®é€å»æ¹æ³ãšããŠ
ããç¥ãããŠãããã¡ãªã¿ã«ããŒãã«æ°ŽæŽæ³ãšã¯
ãŒã©ãã³æ°Žæº¶æ¶²ãã²ã«åãããããããµã€ã³ãç¶
åã¯ãã©ãç¶ã«çŽ°æããŠæ°ŽæŽããæ¹æ³ã§ãããå
æ²éæ³ãšã¯å€äŸ¡ã¢ããªã³ããæãç¡æ©å¡©é¡ïŒããš
ãã°ç¡«é žãããªãŠã ïŒãã¢ããªã³æ§çé¢æŽ»æ§å€ã
ã¢ããªã³æ§ããªããŒïŒããšãã°ããªã¹ãã¬ã³ã¹ã«
ãã³é žïŒããŒã©ãã³èªå°äœïŒããšãã°èèªæã¢ã·
ã«åãŒã©ãã³ãè³éŠæã¢ã·ã«åãŒã©ãã³ãè³éŠæ
ã«ã«ãã¢ã€ã«åãŒã©ãã³ãªã©ïŒçãçšããŠãŒã©ã
ã³ãæ²éãããŠæ°ŽæŽããæ¹æ³ã§ãããæ°çžã§ã«ãŒ
ãã³ãã©ãã¯ã匷å¶é žåããã«ã¯ã容åšäžã«ã«ãŒ
ãã³ãã©ãã¯ãæµ®éãããŠãããããã«ãªãŸã³ç
ã®æ°äœé žåå€ãå¹ã蟌ãã§è¡ããã åèšã®æ¹æ³ã«æŒãŠæªåŠçã®åã¯åŒ·å¶é žååŠçã
ããã«ãŒãã³ãã©ãã¯ãæ°Žã«åæ£ãããã«ã¯ãã«
ãŒãã³ãã©ãã¯ãæ°Žãšåã«æ··åããŠãããããé¡
æã®åæ£æè¡åéã«ãããŠããç¥ãããŠããåæ£
å€ãçšããŠåæ£ãããããšãåäžãªåŸ®ç²ååæ£ç©
ãåŸãããçã®ç¹ã§å¥œãŸããã奜ãŸããåæ£å€ãš
ããŠã¯ãã¢ããªã³åã³ãããªã³æ§ç©è³ªã§ãããäŸ
ãã°ã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³
é žå¡©ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãããã¿
ã¬ã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ã
ãªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¹ã«ãã¢ã«
ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«ãšãŒã
ã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãšãŒãã«é¡ã
ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«ãšãŒãã«
é¡ããã«ã ã¢ã«ããããšããã¿ã¬ã³ã¹ã«ããªã³é ž
å¡©ã®éåç©ãããªã¹ãã¬ã³ã¹ã«ããªã³é žå¡©ãããª
ããã«ã¢ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«ããŒ
ã¹ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ãã¢ã«ã®ãã³ç
çš®ã ãªçé¢æŽ»æ§å€åã³ããªããŒã䜿çšããããšã
ã§ããã åèšã®æ¹æ³ã§åŒ·å¶é žååŠçãããã«ãŒãã³ãã©
ãã¯ã¯ãå¿ èŠã«å¿ããŠåæ£å€ã®ååšäžã§åæ£ãã
ãåŸãå¡åžå©å€ã氎溶æ§ãã€ã³ããŒã硬èå€çã
å ããŠé®å å±€ãšããŠå¡åžããã 氎溶æ§ãã€ã³ããŒãšããŠã¯ããŒã©ãã³ãçšãã
ã®ãæå©ã§ãããããã以å€ã®èŠªæ°Žæ§ã³ãã€ãã
çšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœïŒã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯ãããã®ã¢ãããŒæåããèªå°ããã
å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«ååç©è³ªãçš
ããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãBull.Soc.Sci.Phot.JapanïŒNo.16ïŒ30
é ïŒ1966ïŒã«èšèŒããããããªé µçŽ åŠçãŒã©ãã³
ãçšããŠããããåãŒã©ãã³ã®å æ°Žå解ç©ãé µçŽ
å解ç©ãçšããããšãã§ããããŒã©ãã³èªå°äœãš
ããŠã¯ããŒã©ãã³ã«ããšãã°é žãã©ã€ããé žç¡æ°Ž
ç©ãã€ãœã·ã¢ããŒãé¡ãããã¢é ¢é žãã¢ã«ã«ã³ãµ
ã«ãã³é¡ãããã«ã¹ã«ãã³ã¢ããé¡ããã¬ã€ã³ã€
ããååç©é¡ãããªã¢ã«ãã¬ã³ãªãã·ãé¡ããšã
ãã·ååç©é¡çãçš®ã ã®ååç©ãåå¿ãããŠåŸã
ãããã®ãçšããããã åèšã®é®å å±€ã«ã¯ãçš®ã ã®åæã©ããã¯ã¹ããª
ããŒãæ·»å ããããšãã§ãããããšãã°ã¢ã«ãã«
ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒããã¢ã¯ãªã«
é žãåã³ã¹ã«ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿
ã¯ãªã¬ãŒããã¢ãããŒæåãšããã©ããã¯ã¹ããª
ããŒçãçšããããšãã§ããããã®å ·äœäŸã¯ç±³åœ
ç¹èš±3142568å·ãå3193386å·ãå3062672å·ãå
3220844å·ãªã©ã«èšèŒãããŠããã æ¬çºæã®åŒ·å¶é žåãããã«ãŒãã³ãã©ãã¯ã¯ã
åŠç液ã«å«ãŸããã«ãŒãã³ãã©ãã¯ã«äœ¿çšããã
ãšãã§ããããã®å Žåã¯ããŒã©ãã³ãå«ãŸãªãã«
ãŒãã³ãã©ãã¯æ°Žåæ£ç©ãçšããããšã奜ãŸã
ããã«ãŒãã³ãã©ãã¯ã®äœ¿çšéã¯åŠç液ïŒïœåœã
0.08ïœã0.3ïœãé©ããŠããã æ¬çºæã®åçæå ææã¯ãäŸãã°ã«ã©ãŒæ¡æ£è»¢
åæ³çšåçãã€ã«ã ãŠããããšããŠæçšã§ããã
ç¹ã«äžèšã®æ§æã®ãã®ãæå¹ã§ãããå³ã¡ãéæ
æ¯æäœãååå±€ãè²çŽ åäŸäžååç©ãšçµåããã
ãããã²ã³åéä¹³å€å±€ãåã³åŠç液ãå èµããã
å§åã§ç Žå£å¯èœãªå®¹åšããå°ããšãæãã«ã©ãŒæ¡
æ£è»¢åæ³çšåçãã€ã«ã ãŠãããã«æŒãŠã匷å¶é ž
ååŠçãããã«ãŒãã³ãã©ãã¯ã第ïŒã®æ¯æäœã
ããã¯è©²ååå±€ãšããã²ã³åéä¹³å€å±€ã®éã®å±€äž
ããåã¯è©²åŠç液äžã«å«æãããŠããäºãç¹åŸŽãš
ããã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«ã ãŠãããã æ¬çºæã®ã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«ã ãŠã
ããã®å žåçãªæ æ§ãšããŠãäžèšã®ã¿ã€ãã®ãã®
ãæããããšãã§ããã éææ¯æäœäžã«ååå±€ãçœè²åå°å±€ïŒé žåã
ã¿ã³ãªã©ãå«ãïŒã匷å¶é žååŠçãããã«ãŒã
ã³ãã©ãã¯ãå«ãé®å å±€ãã·ã¢ã³è²çŽ åäŸäžå
åç©ãå«ãå±€ãèµ€ææ§ããã²ã³åéä¹³å€å±€ãäž
éå±€ãããŒã³ã¿è²çŽ åäŸäžååç©ãå«ãå±€ãç·
ææ§ããã²ã³åéä¹³å€å±€ãäžéå±€ãã€ãšããŒè²
çŽ åäŸäžååç©ãå«ãå±€ãéææ§ããã²ã³åé
ä¹³å€å±€ãä¿è·å±€ãé 次ç©å±€ããããã®ïŒæå ã·
ãŒãïŒãšç¬¬ïŒã®éææ¯æäœäžã«äžåå±€ãã¿ã€ã
ã³ã°å±€ãç©å±€ããããã®ïŒã«ããŒã·ãŒãïŒãšã
é¢å¯Ÿé¢ã®é¢ä¿ã§éããããŠãããããããã®é
ã«ã«ãŒãã³ãã©ãã¯ãå«ãåŠç液ã延å±ããã
ãããªäœçœ®ã«è©²åŠç液ãå èµãããå§åã§ç Žå£
å¯èœãªå®¹åšãé 眮ãããŠããŠããããäžè ãäž
äœçã«åºå®ããããã®ã 匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã䜿çš
ãã以å€ã¯ããã®ãããªãã€ã«ã ãŠãããã®æ§
æã¯åŸæ¥ããç¥ãããŠãããäŸãã°
Photographic Science and EngineeringïŒã
ãªãã°ã©ãã€ãã¯ã»ãµã€ãšã³ã¹ã»ãšã³ãã»ãšã³
ãžãã¢ãªã³ã°ïŒãrol.20ïŒNo.ïŒïŒpp.155ã164
JulyïŒAugust 1976幎ã«è©³ãã説æãããããŸ
ãããã«ãã€ãŠè»¢åç»åãåŸãããåå¿æ©æ§ã«
ã€ããŠã詳ãã説æãããŠããã éææ¯æäœäžã«äžåå±€ãã¿ã€ãã³ã°å±€ãåå
å±€ãç©å±€ããããã®ïŒååã·ãŒãïŒãšéæãã
ãã¯äžéæã®ç¬¬ïŒã®æ¯æäœäžã«åŒ·å¶é žååŠçã
ããã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€ãã·ã¢ã³è²
çŽ åäŸäžååç©ãå«ãå±€ãèµ€ææ§ããã²ã³åé
ä¹³å€å±€ãäžéå±€ãããŒã³ã¿è²çŽ åäŸäžååç©ã
å«ãå±€ãç·ææ§ããã²ã³åéä¹³å€å±€ãäžéå±€ã
ã€ãšããŒè²çŽ åäŸäžååç©ãå«ãå±€ãéææ§ã
ãã²ã³åéä¹³å€å±€ãä¿è·å±€ãé 次ç©å±€ãããæ
å ã·ãŒããšãé¢å¯Ÿé¢ã®é¢ä¿ã§åãåã€ãŠéãã
ããŠãããããããã®éã«è€æ°ã®PHã€ã³ãžã±ãŒ
ã¿ãŒææãšé žåãã¿ã³ãå«ãåŠç液ã延å±ãã
ããããªäœçœ®ã«è©²åŠç液ãå èµãããå§åã§ç Ž
å£å¯èœãªå®¹åšãé 眮ãããŠããŠããããäžè ã
äžäœçã«åºå®ããããã®ã 匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯å±€ã䜿
çšãã以å€ã¯ããã®ãããªãã€ã«ã ãŠãããã®
æ§æã¯åŸæ¥ããç¥ãããŠãããäŸãã°
Neblettes Handbook of Photography and
Reprography MaterialsïŒProcesses and
SystemsïŒããã¬ãºã»ãã³ãããã¯ã»ãªãã»ã
ãªãã°ã©ãã€ãŒã»ãšã³ãã»ãªããã°ã©ãã€ãŒã»
ãããªã¢ã«ãºã»ããã»ã¹ã€ãºã»ãšã³ãã»ã·ã¹ã
ã ãºïŒãSeventh Ed.ïŒ1977幎ïŒã®ç¬¬12ç« ã«è©³
ãã説æãããããŸãããã«ãã€ãŠè»¢åç»åã
åŸãããåå¿æ©æ§ã«ã€ããŠã詳ãã説æãããŠ
ãããåèšã®PHã€ã³ãžã±ãŒã¿ãŒææãäŸãã°ç±³
åœç¹èš±3647437å·ãå3833615å·ã«å ·äœçãªèª¬æ
ãããã 該æ æ§ãšã®å±€æ§æã¯é©å®å€æŽã§ãããäŸã
ã°è²çŽ åäŸäžååç©ãšããã²ã³åéãšã¯åäžã®å±€
äžã«ãã€ãŠãããã äžæ¹ãã¿ã€ãã³ã°å±€ã¯è€æ°å±€åããŠããããå
æ æ§ã«æŒãŠåŠç液äžã®ã«ãŒãã³ãã©ãã¯ã¯åæ§
ã«åŒ·å¶é žååŠçããããã®ã§ãããã æ æ§ã®å¥œãŸããå±€æ§æã¯ãæ æ§ã«æŒãŠåŒ·å¶
é žååŠçãããã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€å
ã³åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ãšã·ã¢ã³
è²çŽ åäŸäžååç©ãå«ãå±€ãããªããã®ã§ããã
å³ã¡ãã·ã¢ã³è²çŽ åäŸäžååç©ãå«ãå±€ã¯åŒ·å¶é ž
ååŠçãããã«ãŒãã³ãã©ãã¯ã®å°ããšãäžéšã
å«ãã®ã奜ãŸããã æ¬çºæã«ãã€ãŠæ¬¡ã®ãããªè«žå¹æãåŸãããã ååå±€ãžæ¡æ£è»¢åããè²çŽ ãã«ãŒãã³ãã©ã
ã¯ãå«ãå±€ã«æç²ãããäºãå°ããè²çŽ ã®è»¢å
ãä¿é²ããããçµå±ãç»åã®åºçŸæéãçããª
ãããããDmaxã®é«ã転åç»åãåŸãããã ã«ãŒãã³ãã©ãã¯ã«ããåçæ§èœã®æªåããª
ãïŒåŸããã転åç»åã®DminãäœããDmax
ã¯é«ãïŒã ã«ãŒãã³ãã©ãã¯ãè²çŽ åäŸäžååç©ã®å«æ
å±€ã«æ·»å ã§ããã®ã§ãã«ãŒãã³ãã©ãã¯ãšè²çŽ
åäŸäžååç©ãå¥ã ã®å±€ã«å«æãããå Žåã«æ¯
ã¹ãŠèå±€åã§ããè²çŽ ã®è»¢åãä¿é²ããããçµ
å±ã転åç»åã®åºçŸæéãçããªããããã¯
âã€ã³ã¹ã¿ã³ãåçâã®ç®çã«ããåèŽããã ã«ãŒãã³ãã©ãã¯ç²åã®åéäœãæžå°ããã
ã®ããé®å èœãåäžãããçµå±ãåŸæ¥ããå°é
ã®ã«ãŒãã³ãã©ãã¯ã®äœ¿çšã§æžã¿ãçµæžçã§ã
ãã°ããã§ãªããèå±€åãã§ããããã®ãã転
åç»åã®åºçŸæéãçãã§ããã æç±å¢è²ïŒçŸååŠçããåŸãååå±€ã«åœ¢æã
ããè²åã®æ¿åºŠãçµæãšãšãã«å¢å€§ããäºïŒã
ç¹ã«ã·ã¢ã³ã®æç±å¢è²ãé²æ¢ã§ããã æ 滲ã¿ïŒããªã³ãã®çœå°æ ã«è²çŽ ã滲ãã§åº
ãŠããäºïŒãç¹ã«ã·ã¢ã³è²çŽ ã®æ 滲ã¿ãé²æ¢ã§
ããã ãŸãæ¬çºæã®åçæå ææã¯ãŠãªãã·ãŠãªãã¬
ãªãŒãç»åã圢æããæå ææïŒãã®ææãç»å
ã圢æããæ©æ§ã«ã€ããŠã¯ç±³åœç¹èš±3440049å·ã
å4076531å·çã«èšèŒãããïŒãšããŠæçšã§ã
ãããã®å Žåã匷å¶é žååŠçãããã«ãŒãã³ãã©
ãã¯ã¯ãã¬ãŒã·ãšã³é²æ¢å±€ã«å«æããã®ãæå¹ã§
ããããŸããæ¬çºæã®åçæå ææã¯ãã³ãããª
ãã¯ã¹ã»ãã€ã«ã ãšããŠãæçšã§ããããã®å Ž
åã匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã¯ãã
ã²ã³åéä¹³å€å±€ã«å«æããã®ãæå¹ã§ããããã³
ãããªãã¯ã¹ã»ãã€ã«ã ã«ã€ããŠã¯ãäŸãã°P.
GlafkidesèPhotographic ChemistryïŒããªãã°
ã©ãã€ãã¯ã»ã±ãã¹ããªãŒïŒç¬¬ïŒå·»Fountain
PressïŒ1960幎ïŒã®689ã701é ãKodak Color
Data BookïŒã³ããã¯ã»ã«ã©ãŒã»ããŒã¿ãŒã»ãã
ã¯ïŒïŒ1951幎ïŒå¯é¡Kodak Dye Transfer
ProcessïŒã³ããã¯ã»ãã€ã»ãã©ã³ã¹ãã¢ãŒã»ã
ãã»ã¹ïŒã«èšèŒãããã æ¬çºæã®åçæå ææã«äœ¿çšãããããã²ã³å
éä¹³å€ã¯ãå¡©åéãèåéãå¡©èåéãæ²èå
éãå¡©æ²èåéãããã¯ãããã®æ··åç©ã®èŠªæ°Žæ§
ã³ãã€ãç¶åæ£ç©ã§ãã€ãŠãããã²ã³çµæã¯æå
ææã®äœ¿çšç®çãšåŠçæ¡ä»¶ã«å¿ããŠéžæããã
ããæ²åç©å«éã10moleïŒ ä»¥äžãå¡©åç©å«éã
30moleïŒ ä»¥äžã®èåéãæ²èåéåã¯å¡©æ²èå
éãç¹ã«å¥œãŸããã æ¬çºæã§ã¯ç²åè¡šé¢ã«äž»ã«æœåã圢æããâè¡š
é¢æœåâåããã²ã³åéä¹³å€ã䜿çšã§ããããå
ç²åå éšã«äž»ã«æœåã圢æããâå éšæœåâåã
ãã²ã³åéä¹³å€ã䜿çšã§ããããåŸè ãç¹ã«å¥œãŸ
ãããæå©ã«äœ¿çšãããå éšæœååããã²ã³åé
ä¹³å€ãšããŠã¯ãç±³åœç¹èš±2592250å·ãå3206313
å·ãå3447927å·ãå3761276å·ãåã³å3935014
å·çã«èšèŒãããã³ã³ããŒãžãšã³åä¹³å€ãã³ã¢ïŒ
ã·ãšã«åä¹³å€ãç°çš®éå±ãå èµãããä¹³å€çãæ
ããããšãã§ããã ãã®åã®ä¹³å€ã¯é²å åŸãé æ žå€ã®ååšäžã«çŸå
åŠçããŠçŽæ¥ããžåãåŸãã®ã«å¥œé©ã§ãããé æ ž
å€ãšããŠã¯ãç±³åœç¹èš±2588982å·ãå2563785å·ã«
èšèŒãããããã©ãžã³é¡ïŒå3227552å·ã«èšèŒã
ããããã©ãžãé¡ãšããã©ãŸã³é¡ïŒè±åœç¹èš±
1283835å·ãç¹å ¬æ49â38164å·ãç±³åœç¹èš±
3734738å·ãå3719494å·ãå3615615å·ã«èšèŒã
ããåçŽå¡©ååç©ïŒç±³åœç¹èš±3718470å·ã«èšèŒã
ããããã¶ããäœçšã®ããïŒnucleatingïŒçœ®æåº
ãè²çŽ ååäžã«æããå¢æè²çŽ ïŒç±³åœç¹èš±
4030925å·ãå4031127å·ã«èšèŒãããã¢ã·ã«ãã
ã©ãžãããšãã«ããªå°¿çŽ ç³»ååç©ã代衚çãªãã®
ã§ããã æ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã¯ãææ
ã«å¿ããŠåå å¢æè²çŽ ã«ãã€ãŠæ¡å€§ãããæè²æ§
ããã¡åŸããåå å¢æè²çŽ ãšããŠã¯ãã·ã¢ãã³è²
çŽ ãã¡ãã·ã¢ãã³è²çŽ çãé©å®äœ¿çšã§ããã æ¬çºæã«äœ¿çšãããè²çŽ åäŸäžååç©ãšããŠå
çš®ã®ååç©ãå©çšããããšãåºæ¥ãããè²çŽ æŸåº
ã¬ããã¯ã¹ååç©ãè²çŽ çŸåè¬ãç¹ã«æçšã§ã
ãã è²çŽ æŸåºã¬ããã¯ã¹ååç©ã®ãã¡ãé žåãåã
ãååç©ãã¢ã«ã«ãªå æ°Žå解ããŠè²çŽ ãæŸåºãã
ãã®ãšããŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæãã
ããšãã§ããã ç±³åœç¹èš±4053312å·ãå4055428å·ãå4076529
å·ãå4152153å·ãå4135929å·ãç¹éæ53â
149328å·ãå51â104343å·ãå53â46730å·ãå
54â130122å·ãå53â3819å·ãç¹é¡æ54â89128
å·ãå54â90806å·ãå54â91187å·ãç ãã®ãã¡ãã€ãšããŒè²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±4013633å·ãç¹éæ53â149328å·ãå
51â114930å·ãç¹é¡æ54â148237å·ããªãµãŒãã»
ãã€ã¹ã¯ããŒãžã€ãŒïŒResearch DisclosureïŒ
17630ïŒâ78ïŒãå16475ïŒâ77ïŒç ããŒã³ã¿è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3954476å·ãå3931144å·ãå3932308
å·ãç¹éæ53â23628å·ãå52â106727å·ãå54
â65034å·ãç¹é¡æ53â69488å·ãå53â76162
å·ãå53â96445å·ãå54â149777å·ãå54â
146655å·ãå54â42848å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2847371å·ãç ã·ã¢ã³è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3942987å·ãå3929760å·ãå4013635
å·ãç¹éæ51â109928å·ãå53â149328å·ãå52
â8827å·ãå53â143323å·ãå53â47823å·ãç¹
é¡æ54â146654å·ãç ãŸããé žåãåããªãã€ãæ¹ã®ååç©ãéç°ã
ããªã©ããŠè²çŽ ãæŸåºããã¬ããã¯ã¹ååç©ãšã
ãŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæããããšãã§
ããã ç±³åœç¹èš±4139379å·ãå3980479å·ã西ç¬ç¹èš±åº
é¡ïŒOLSïŒ2402900å·ãå2448811å·ãçã è²çŽ çŸåè¬ãšããŠã¯ãç±³åœç¹èš±2983606å·ç
çš®ã ã®ç¹èš±ã«èšèŒã®ãã®ããS.M.BloomïŒM.
GreenïŒM.Idelson ïŒ M.S.SimonèThe
Cnemistry of Synthetic DyesïŒã¶ã»ã±ãã¹ããª
ãŒã»ãªãã»ã¹ã€ã³ã»ããã¯ãã€ãºïŒãvol.8ïŒK.
Venkataramanç·šAcademic Press New York
1978幎pp.331ã387ã«èšèŒã®ãã®çã䜿çšã§ã
ãã æ¬çºæã®åçãã€ã«ã ãŠãããã«ãããŠãè²çŽ
åäŸäžååç©ãã¯ãã¹é žåã§ãããã®ã§ããé
ããã©ã®ãããªããã²ã³åéçŸåè¬ã§ã䜿çšãã
ããšãã§ããããã®ãããªçŸåè¬ã¯ãã¢ã«ã«ãªæ§
åŠç液ã®äžã«å«ãŸããŠãããããåçèŠçŽ ã®é©åœ
ãªå±€ã«å«ãŸããŠããããæ¬çºæã«ãããŠäœ¿çšãã
ãçŸåè¬ã®äŸãããããšæ¬¡ã®éãã§ããã ç¹é¡æ54â91187å·ã«èšèŒã®ãã€ããããã³
é¡ãã¢ããããšããŒã«é¡ãããšãã¬ã³ãžã¢ãã³
é¡ããã©ãŸãªãžãã³é¡ãäŸãã°ããšããã³ãïŒâ
ããšãã«âïŒâãã©ãŸãªãžãã³ããžã¡ãŸã³ïŒïŒâ
ããšãã«âïŒïŒïŒâãžã¡ãã«âïŒâãã©ãŸãªãžã
ã³ïŒãïŒâïœâããªã«âïŒâã¡ãã«âïŒâãªãã·
ã¡ãã«âïŒâãã©ãŸãªãžãã³ãïŒâïŒ4â²âã¡ãã
ã·ããšãã«ïŒâïŒâã¡ãã«âïŒâãªãã·ã¡ãã«â
ïŒâãã©ãŸãªãžãã³ãïŒâããšãã«âïŒâã¡ãã«
âïŒâãªãã·ã¡ãã«âïŒâãã©ãŸãªãžãã³ããª
ã©ã ããã«ããããã®ã®ãªãã§ãããšãã¬ã³ãžã¢ã
ã³é¡ãªã©ã®ã«ã©ãŒçŸåè¬ãããäžè¬ã«ååå±€ã®ã¹
ãã€ã³åœ¢æã軜æžããæ§è³ªãå ·ããŠããçœé»çŸå
å€ïŒãªãã§ããã©ãŸãªãžãã³é¡ïŒããç¹ã«å¥œãŸã
ãã æ¬çºæã®æå ææããŠãªãã·ãŠãªãã¬ãªãŒãå
ã圢æããæææãã¯ãã³ãããªãã¯ã¹ã»ãã€ã«
ã ã§ããå Žåã«ã¯ãã¿ã³ãã³ã°çŸåè¬ã䜿çšãã
ããã¿ã³ãã³ã°çŸåè¬ãšããŠã¯äŸãã°ãåŸæ¥å ¬ç¥
ã®ãã®ã䜿çšã§ããã åŠç液ã¯ãæ°Žé žåãããªãŠã ãæ°Žé žåã«ãªãŠ
ã ãçé žãããªãŠã ããªã³é žãããªãŠã ã®ãããª
å¡©åºãå«ã¿PHïŒä»¥äžã奜ãŸããã¯11.5以äžã®ã¢ã«
ã«ãªåŒ·åºŠãæã€ãåŠç液ã¯äºç¡«é žãããªãŠã ãã¢
ã¹ã³ã«ãã³é žå¡©ããããªãžããããœãŒãºã¬ãã¯ã
ã³ã®åŠãé žåé²æ¢å€ãå«æããèåã«ãªãŠã ã®ã
ããªéã€ãªã³æ¿åºŠèª¿ç¯å€ãå«æãåŸããåããã
ãã·ãšãã«ã»ã«ããŒã¹ããããªãŠã ã«ã«ããã·ã¡
ãã«ã»ã«ããŒã¹ã®åŠãç²åºŠå¢å ååç©ãå«æãã
ãŠãããã åæ¬ã¢ã«ã«ãªæ§åŠç液äžã«ã¯çŸåä¿é²ãããã¯
è²çŽ ã®æ¡æ£ãä¿é²ããåŠãååç©ãå«ãŸããŠãã
ãïŒããšãã°ãã³ãžã«ã¢ã«ã³ãŒã«ã®åŠãåå
ç©ïŒã äžéå±€ãšè²çŽ åäŸäžäœãå«æããå±€ã®éã«ç¹é¡
æ53â125600å·ã«èšèŒãããããã«éé¢å±€ãèšã
ãŠããããåäžéå±€äžã«ç¹é¡æ54â144155å·ã«èš
èŒãããããã«ããã²ã³åéä¹³å€ãå ããŠãã
ãã æ¬çºæã®ã«ã©ãŒæ¡æ£è»¢åæ³çšã®æå ææã«äœ¿çš
ãããåªæå±€ãäžåå±€ãäžåé床調ç¯å±€ïŒã¿ã€ã
ã³ã°å±€ïŒãåŠççµæç©çã«ã€ããŠã¯ãäŸãã°ç¹é
æ52â64533å·ã«èšèŒã®ãã®ãé©çšã§ããã å®éšäŸ (A) 匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã®èª¿è£œ ãªãŸã³åŠçã«ããæ¹æ³ ã«ãŒãã³ãã©ãã¯ïŒäžè±åæ(æ ª)補10BïŒ50
ïœãæ¹ææ©ã€ãïŒã¬ã©ã¹å®¹åšã«å ¥ãã18â
22âã«ä¿ã¡ãªãããæ¿ããæ¹æããã«ãŒãã³
ãã©ãã¯ã空æ°äžã«æµ®éããç¶æ ã«ä¿ã€ãã
ãã®äžã«æ¯æ1775ïœã®ãªãŸã³ãïŒæéæµéã
é žååŠçãããæµéåŸããã«ïŒæéæ¹æãã
åŸãäžå€é眮ãå ç©ããã«ãŒãã³ãã©ãã¯ã
æéããã éé žåæ°ŽçŽ åŠçã«ããæ¹æ³ ã«ãŒãã³ãã©ãã¯ïŒäžè±åæ(æ ª)補10BïŒ
100ïœããã³æ°Ž400mlãããªãåæ£ç©ã70âã«
å æž©ããæ¹æããªãã35ïŒ éé žåæ°ŽçŽ æ°Ž400
mlãïŒæéãããŠæ»Žäžããã滎äžåŸã70âã«
ä¿ã¡ãªããïŒæéåå¿ããããéãæ°ŽæŽåŸ
ïŒïŒ äºç¡«é žãããªãŠã ïŒãšå ±ã«ïŒæéæ¹æ
ããåŸæ°ŽæŽåŸä¹Ÿç¥ããã 次äºå¡©çŽ é žãœãŒãåŠçã«ããæ¹æ³âïŒ ã«ãŒãã³ãã©ãã¯ïŒäžè±åæ(æ ª)補10BïŒ
150ïœããã³æ°Ž600mlãããªãåæ£ç©ã70âã«
å æž©ããæ¹æããªãã12ïŒ æ¬¡äºå¡©çŽ é žãããª
ãŠã 300mlã20åãããŠæ»Žäžããã滎äžåŸã
70âã«ä¿ã¡ãªããïŒæéåå¿ããããåå¿æ··
åç©ãéãæ°ŽæŽåŸãïŒïŒ äºç¡«é žãããªãŠã
ïŒãšå ±ã«ïŒæéæ¹æããåŸãéãæ°ŽæŽåŸ
也ç¥ããã 次äºå¡©çŽ é žãœãŒãåŠçã«ããæ¹æ³âïŒ ã«ãŒãã³ãã©ãã¯ïŒã³ãã³ãã¢ã³ã«ãŒãã³
瀟補â450ïŒã36ïŒ ããã³ã¿ã¢ãŒã«SNïŒã
ã«ã ã¢ã«ããããšããã¿ã¬ã³ã¹ã«ãã³é žãœãŒ
ãã®éåç©ãïŒïŒ å«ãã§ããæ°Žåæ£ç©375ïœ
ã70âã«å æž©ããåŸãæ¹æããªãã12ïŒ æ¬¡äº
å¡©çŽ é žãœãŒã260mlã40åãããŠåŸã ã«å ã
ãã滎äžçµäºåŸ70âã«ä¿ã¡ãªãããïŒæéæ¹
æãããåå¿æ··åç©ã宀枩ãŸã§å·ãããåŸã
æ®åãã次äºå¡©çŽ é žãœãŒããç¡å¹åããã
ããäºç¡«é žãœãŒã21ïœããã³æ°Ž40mlãããªã
溶液ãå ããŠãïŒæéæ¹æããã次ã«æž©åºŠ40
âã§10ïŒ ãŒã©ãã³æ°Žæº¶æ¶²675mlãå ããåŸã
å·åŽåºåããããµã€ã³ãç¶ã«çŽ°æããæµæ°Žäž
ã«ïŒæéæŸçœ®ããŠæ®ååå¿ç©ãé€å»ããã (B) ã«ãŒãã³ãã©ãã¯ãžã®è²çŽ ããã®åžçéã®
æž¬å® äžèšã®ãã®ããã«åŒ·å¶é žååŠçãããã«
ãŒãã³ãã©ãã¯ïœïŒïœïŒïœåã³ç©ºæ°äžã«é·æé
ããããããåŠçãããŠããªãã«ãŒãã³ãã©ã
ã¯ïŒäžè±åæ(æ ª)補10BïŒãå¯Ÿç §çšã«ãŒãã³ãã©
ãã¯ïœ ãã®å0.2ïœããè²çŽ ãã0.01ïŒ ãå«
ã1NKOH氎溶液40mlã«å ãã25âã§30åéæ¹
æãããç¶ããŠé å¿åé¢æ©ã䜿çšããŠãäžæŸæ¶²
ãšã«ãŒãã³ãã©ãã¯ãåé¢ããããã®äžæŸæ¶²ã®
654mÎŒã«ãããåžåæ¿åºŠãå ã®è²çŽ ããã®
氎溶液ã®åžåæ¿åºŠãšæ¯èŒããããšã«ãããäžæŸ
液äžã®è²çŽ ããã®éãæ±ãããã®å€ããäžè¡š
ã®åžçéãåŸãã
ã©ãã¯ãå«ãããã²ã³åéåçæå ææã«é¢ã
ãã ã«ã©ãŒæ¡æ£è»¢åæ³çšåçæå ææã¯æ®åœ±åŸçŽã¡
ã«ã«ã©ãŒåçã楜ãããâã€ã³ã¹ã¿ã³ãâåççš
ãšããŠå®çšãããŠããããããŠæ®åœ±è ãé£ç¶çã«
ã«ã¡ã©ã®ã·ã€ãã¿ãŒãæŒããããã«ããã®ææã¯
æ®åœ±åŸçŽã¡ã«ã«ã¡ã©ïŒæç®±ïŒããæŒãåºãããŠæ
æäžã§çŸåãçµäºãããã工倫ãããŠãããå³
ã¡ããã®çš®ã®ææã§ã¯æ®åœ±åŸã«ã¯æå å±€ãäºã€ã®
é®å å±€ïŒéåžžãã«ãŒãã³ãã©ãã¯ãå«æããå±€ïŒ
ã§ãµã³ãã€ããç¶ã«å ãŸãããã®åŸã®æ害ãªé²å
ããä¿è·ããããã工倫ãããŠããããã®ãããª
ææèšèšã¯å€ãããææ¡ãããŠãããäŸãã°ç±³åœ
ç¹èš±3053659å·çã«èšèŒãããã ããããªãããåŸæ¥æªåŠçã®ã«ãŒãã³ãã©ãã¯
ã䜿çšããŠé®å å±€ã圢æãããšãææ補é æåã³
ææã®ä¿åäžã«è©²é®å å±€ãããã®è¿åã®ããã²ã³
åéä¹³å€å±€ã«æªåœ±é¿ãåãŒããŠãåŸããã転åç»
åã®æå°æ¿åºŠïŒDminïŒãäžããããæ倧æ¿åºŠ
ïŒDmaxïŒãäžããæ¬ ç¹ããã€ãããã®äºã¯ãã
ã²ã³åéä¹³å€ãšããŠãäºãã«ãããããŠããªãå
ã®çŽæ¥ããžä¹³å€ãã䜿çšããå Žåã«ç¹ã«é¡èã§ã
ãããŸããæªåŠçã®ã«ãŒãã³ãã©ãã¯ã§é®å å±€ã
圢æããããšè»¢åè²çŽ ããã®å±€äžãæ¡æ£ããéã«
ã«ãŒãã³ãã©ãã¯ã«æç²ïŒåžçïŒããã転åè²çŽ
ç»åã®æ倧æ¿åºŠãäœäžããããç»ååºçŸæéãé
ãããšããæ¬ ç¹ããã€ãã ã«ãŒãã³ãã©ãã¯ã®äœ¿çšã«ããã«ããªçºçã®é²
æ¢ã®ããã«ã«ãããŠã ãéçã®ééå±ã®æ°Žæº¶æ§å¡©
ãã«ãŒãã³ãã©ãã¯å«æå±€ã«æ·»å ããäºããç±³åœ
ç¹èš±3900323å·ã«ææ¡ãããŠããããããããã®
ãããªééå±å¡©ã®äœ¿çšã¯ãå ¬å®³ãåŒãèµ·ãåå ã«
ãªãã°ããã§ãªããã«ãŒãã³ãã©ãã¯ã®ãããã«
ããäžçŽç©ïŒã€ãªãŠååç©ïŒã®éã®å€åã«èŠåã
ééå±å¡©ã®æ·»å éããã®éœåºŠèª¿ç¯ããã®ãé£ãã
ãšããæè¡çãªåé¡ãããããŸããééå±å¡©ã®äœ¿
çšéãå€ããããšãããã€ãŠééå±å¡©èªèº«ãåç
æ§ã«æªåœ±é¿ãåãŒããåçæ床ãäœäžãããïŒã«
ãŒãã³ãã©ãã¯ã®äœ¿çšãããã«ããåçã®å質ã«
ãã©ãããçããïŒæ¬ ç¹ãããã æ¬çºæã®ç®çã¯ãåçæ§ã«æªã圱é¿ãåãŒããª
ãã«ãŒãã³ãã©ãã¯ãå«æããåçæå ææãæ
äŸããäºã«ããã äžèšç®çã¯ã匷å¶é žååŠçãããã«ãŒãã³ãã©
ãã¯ãå«æããåçæå ææã«ãã€ãŠå¹æçã«é
æã§ããã æ¬çºæã®å®æœã«åœã€ãŠäœ¿çšããã«ãŒãã³ãã©ã
ã¯ã®åæãšããŠã¯ããã€ã³ãã«ãã©ãã¯
ïŒChannel BlackïŒããµãŒãã«ãã©ãã¯ïŒThermal
BlackïŒåã³ãã¢ãŒãã¹ãã©ãã¯ïŒFurnace
BlackïŒãªã©ä»»æã®è£œæ³ã®ãã®ã䜿çšã§ãããã«
ãŒãã³ãã©ãã¯ã®ç²åãµã€ãºã¯ç¹ã«éå®ãããªã
ãã0.03ÎŒã0.12ÎŒã®ãã®ã奜ãŸããã ãŸã匷å¶é žååŠçã®æ¹æ³ãšããŠã¯æªåŠçã®ã«ãŒ
ãã³ãã©ãã¯ã«é žåå€ãæ°çžã§äœçšãããæ¹æ³ãš
液çžã§äœçšãããæ¹æ³ãšãããã åè ã®å Žåã«ã¯ç©ºæ°ããªãŸã³ã䜿çšããäºãã§
ããååŸè ã®å Žåã«ã¯éé ¢é žãéç¡«é žã«ãªãŠã ã
éç¡«é žãããªãŠã ãéç¡«é žã¢ã³ã¢ããŠã ãéé žå
æ°ŽçŽ ãªã©ã®éé žåç©ïŒç¡é žãªã©ã®é žååã®ãã
é žïŒæ¬¡äºããã²ã³é žå¡©ãªã©ééå±å¡©ã§ãªããã®ã
䜿çšã§ããããããã®é žåå€ã䜿çšãããéã«ã¯
å ç±ããã®ããããç¹ã«çŽ40âã100âã«å ç±ã
ãã®ã奜ãŸãããåå¿æã®PHã¯äœ¿çšããé žåå€ã«
ããé žæ§åã³ã¢ã«ã«ãªæ§ã®ä»»æã®PHããéžæãã
ããšãã§ããã ã«ãŒãã³ãã©ãã¯ã匷å¶é žåããçšåºŠã¯é žåå€
ã®çš®é¡ã«å¿ããŠé©å®æ±ºå®ã§ããããåŸã®å®éšäŸã«
èšèŒãããã«ãŒãã³ãã©ãã¯ãžã®è²çŽ ããã®åž
çéã®æž¬å®ãã®æ¡ä»¶äžã«æž¬å®ãããè²çŽ ããã®
åžçéããã€ãŠäžã€ã®ç®å®ãšããããšãã§ããã
å³ã¡ããã®æž¬å®æ¡ä»¶ã«æŒãŠæªåŠçã®ã«ãŒãã³ãã©
ãã¯ã®å Žåã«æ¯ã¹ãŠäžèšã®è²çŽ ããã85ïŒ ä»¥äž
ã®åžçéã瀺ããããªçšåºŠã«ãæ¯èŒãããæªåŠç
ã®ãããšåäžã®ã«ãŒãã³ãã©ãã¯ã匷å¶é žåãã
ã®ã奜ãŸããã é žåå€ãæ°çžã§äœçšãããããã液çžã§äœçšã
ããæ¹ã奜ãŸããããªãã§ã次äºããã²ã³é žå¡©
ïŒäœããééå±å¡©ã¯é€ãïŒã䜿çšããã®ã奜ãŸã
ãã 奜ãŸãã次äºããã²ã³é žå¡©ãšããŠã¯ã次äºãã
ã²ã³é žã®ã¢ã«ã«ãªéå±å¡©ãã¢ã«ã«ãªåé¡éå±å¡©ãª
ã©ããããæŽã«å ·äœçã«ã¯æ¬¡äºå¡©çŽ é žãœãŒãã次
äºèçŽ é žãœãŒãã次äºæ²çŽ é žãœãŒãã次äºå¡©çŽ é ž
ã«ãªã次äºèçŽ é žã«ãªã次äºæ²çŽ é žã«ãªã次äºå¡©
çŽ é žã«ã«ã·ãŠã ãªã©ãæããããšãã§ãããç¹ã«
次äºå¡©çŽ é žãœãŒãã䜿çšããã®ã奜ãŸããã 液çžã§åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯
ã¯ãæªåŠçã®ã«ãŒãã³ãã©ãã¯ãåæ£ããæ°Žåæ£
液ã«å ã«è¿°ã¹ãé žåå€ãæ·»å ããå ç±çã«ããã«
ãŒãã³ãã©ãã¯ã匷å¶é žåããŠã€ããããšãã§ã
ãããã®å Žåã«ã¯æ®åé žåå€ã®æªåœ±é¿ãé€ããã
ã«ãåçæ§ã«åœ±é¿ã®å°ãªãéå å€ãäŸãã°äºç¡«é ž
ãããªãŠã ãã¢ã¹ã³ã«ãã³é žãã°ã«ã³ãŒã¹ãã·ãš
ç³çã®éå å€ã§åŸåŠçããããšã奜ãŸããããã
ãããã®ããã«ããŠåŸãããã«ãŒãã³ãã©ãã¯æ°Ž
åæ£ç©ããã¯ãåçæ§ã«å®³ãåãŒãé žåå€åå¿ç©
ãéå å€åå¿ç©ãé€å»ããå¿ èŠãããããã®ãã
ã«ã¯éâæ°ŽæŽâéã®æäœãç¹°ãè¿ãæ¹æ³ãã
ãããã«ãŒãã³ãã©ãã¯ã匷å¶é žååŠçãããã®
ã¯ãæ°Žãšã®èŠªåæ§ãå¢ããéããã®ã«é·æéã
èŠãããšããé£ç¹ãããããŸãåéèãå©çšãã
æ¹æ³ãããããåå¿ç©ãå®å šã«é€å»ããã®ã«é·æ
éãããããšãæ°Žã®äœ¿çšéãå€ãããšçã®é£ç¹ã
ããããããã®é£ç¹ã¯åŒ·å¶é žååŠçãããã«ãŒã
ã³ãã©ãã¯æ°Žåæ£ç©ã«ãŒã©ãã³ãå ããŒã©ãã³å
æ£ç©ãšããããŒãã«æ°ŽæŽæ³ãæ²éæ³çã«ããåèš
ã®åå¿çæç©ãæ°ŽæŽé€å»ããã°å¹æçã«è§£æ±ºã§ã
ããããŒãã«æ°ŽæŽæ³ãæ²éæ³ã¯ããŒã©ãã³ããã²
ã³åéä¹³å€è£œé æã®å¯æº¶æ§å¡©é¡ã®é€å»æ¹æ³ãšããŠ
ããç¥ãããŠãããã¡ãªã¿ã«ããŒãã«æ°ŽæŽæ³ãšã¯
ãŒã©ãã³æ°Žæº¶æ¶²ãã²ã«åãããããããµã€ã³ãç¶
åã¯ãã©ãç¶ã«çŽ°æããŠæ°ŽæŽããæ¹æ³ã§ãããå
æ²éæ³ãšã¯å€äŸ¡ã¢ããªã³ããæãç¡æ©å¡©é¡ïŒããš
ãã°ç¡«é žãããªãŠã ïŒãã¢ããªã³æ§çé¢æŽ»æ§å€ã
ã¢ããªã³æ§ããªããŒïŒããšãã°ããªã¹ãã¬ã³ã¹ã«
ãã³é žïŒããŒã©ãã³èªå°äœïŒããšãã°èèªæã¢ã·
ã«åãŒã©ãã³ãè³éŠæã¢ã·ã«åãŒã©ãã³ãè³éŠæ
ã«ã«ãã¢ã€ã«åãŒã©ãã³ãªã©ïŒçãçšããŠãŒã©ã
ã³ãæ²éãããŠæ°ŽæŽããæ¹æ³ã§ãããæ°çžã§ã«ãŒ
ãã³ãã©ãã¯ã匷å¶é žåããã«ã¯ã容åšäžã«ã«ãŒ
ãã³ãã©ãã¯ãæµ®éãããŠãããããã«ãªãŸã³ç
ã®æ°äœé žåå€ãå¹ã蟌ãã§è¡ããã åèšã®æ¹æ³ã«æŒãŠæªåŠçã®åã¯åŒ·å¶é žååŠçã
ããã«ãŒãã³ãã©ãã¯ãæ°Žã«åæ£ãããã«ã¯ãã«
ãŒãã³ãã©ãã¯ãæ°Žãšåã«æ··åããŠãããããé¡
æã®åæ£æè¡åéã«ãããŠããç¥ãããŠããåæ£
å€ãçšããŠåæ£ãããããšãåäžãªåŸ®ç²ååæ£ç©
ãåŸãããçã®ç¹ã§å¥œãŸããã奜ãŸããåæ£å€ãš
ããŠã¯ãã¢ããªã³åã³ãããªã³æ§ç©è³ªã§ãããäŸ
ãã°ã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã¹ã«ããªã³
é žå¡©ãã¢ã«ãã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãããã¿
ã¬ã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³ã¹ã«ã
ãªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¹ã«ãã¢ã«
ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«ãšãŒã
ã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãšãŒãã«é¡ã
ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«ãšãŒãã«
é¡ããã«ã ã¢ã«ããããšããã¿ã¬ã³ã¹ã«ããªã³é ž
å¡©ã®éåç©ãããªã¹ãã¬ã³ã¹ã«ããªã³é žå¡©ãããª
ããã«ã¢ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«ããŒ
ã¹ãã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ãã¢ã«ã®ãã³ç
çš®ã ãªçé¢æŽ»æ§å€åã³ããªããŒã䜿çšããããšã
ã§ããã åèšã®æ¹æ³ã§åŒ·å¶é žååŠçãããã«ãŒãã³ãã©
ãã¯ã¯ãå¿ èŠã«å¿ããŠåæ£å€ã®ååšäžã§åæ£ãã
ãåŸãå¡åžå©å€ã氎溶æ§ãã€ã³ããŒã硬èå€çã
å ããŠé®å å±€ãšããŠå¡åžããã 氎溶æ§ãã€ã³ããŒãšããŠã¯ããŒã©ãã³ãçšãã
ã®ãæå©ã§ãããããã以å€ã®èŠªæ°Žæ§ã³ãã€ãã
çšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœïŒã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯ãããã®ã¢ãããŒæåããèªå°ããã
å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«ååç©è³ªãçš
ããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ãé žåŠ
çãŒã©ãã³ãBull.Soc.Sci.Phot.JapanïŒNo.16ïŒ30
é ïŒ1966ïŒã«èšèŒããããããªé µçŽ åŠçãŒã©ãã³
ãçšããŠããããåãŒã©ãã³ã®å æ°Žå解ç©ãé µçŽ
å解ç©ãçšããããšãã§ããããŒã©ãã³èªå°äœãš
ããŠã¯ããŒã©ãã³ã«ããšãã°é žãã©ã€ããé žç¡æ°Ž
ç©ãã€ãœã·ã¢ããŒãé¡ãããã¢é ¢é žãã¢ã«ã«ã³ãµ
ã«ãã³é¡ãããã«ã¹ã«ãã³ã¢ããé¡ããã¬ã€ã³ã€
ããååç©é¡ãããªã¢ã«ãã¬ã³ãªãã·ãé¡ããšã
ãã·ååç©é¡çãçš®ã ã®ååç©ãåå¿ãããŠåŸã
ãããã®ãçšããããã åèšã®é®å å±€ã«ã¯ãçš®ã ã®åæã©ããã¯ã¹ããª
ããŒãæ·»å ããããšãã§ãããããšãã°ã¢ã«ãã«
ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿ã¯ãªã¬ãŒããã¢ã¯ãªã«
é žãåã³ã¹ã«ãã¢ã«ãã«ã¢ã¯ãªã¬ãŒããŸãã¯ã¡ã¿
ã¯ãªã¬ãŒããã¢ãããŒæåãšããã©ããã¯ã¹ããª
ããŒçãçšããããšãã§ããããã®å ·äœäŸã¯ç±³åœ
ç¹èš±3142568å·ãå3193386å·ãå3062672å·ãå
3220844å·ãªã©ã«èšèŒãããŠããã æ¬çºæã®åŒ·å¶é žåãããã«ãŒãã³ãã©ãã¯ã¯ã
åŠç液ã«å«ãŸããã«ãŒãã³ãã©ãã¯ã«äœ¿çšããã
ãšãã§ããããã®å Žåã¯ããŒã©ãã³ãå«ãŸãªãã«
ãŒãã³ãã©ãã¯æ°Žåæ£ç©ãçšããããšã奜ãŸã
ããã«ãŒãã³ãã©ãã¯ã®äœ¿çšéã¯åŠç液ïŒïœåœã
0.08ïœã0.3ïœãé©ããŠããã æ¬çºæã®åçæå ææã¯ãäŸãã°ã«ã©ãŒæ¡æ£è»¢
åæ³çšåçãã€ã«ã ãŠããããšããŠæçšã§ããã
ç¹ã«äžèšã®æ§æã®ãã®ãæå¹ã§ãããå³ã¡ãéæ
æ¯æäœãååå±€ãè²çŽ åäŸäžååç©ãšçµåããã
ãããã²ã³åéä¹³å€å±€ãåã³åŠç液ãå èµããã
å§åã§ç Žå£å¯èœãªå®¹åšããå°ããšãæãã«ã©ãŒæ¡
æ£è»¢åæ³çšåçãã€ã«ã ãŠãããã«æŒãŠã匷å¶é ž
ååŠçãããã«ãŒãã³ãã©ãã¯ã第ïŒã®æ¯æäœã
ããã¯è©²ååå±€ãšããã²ã³åéä¹³å€å±€ã®éã®å±€äž
ããåã¯è©²åŠç液äžã«å«æãããŠããäºãç¹åŸŽãš
ããã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«ã ãŠãããã æ¬çºæã®ã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«ã ãŠã
ããã®å žåçãªæ æ§ãšããŠãäžèšã®ã¿ã€ãã®ãã®
ãæããããšãã§ããã éææ¯æäœäžã«ååå±€ãçœè²åå°å±€ïŒé žåã
ã¿ã³ãªã©ãå«ãïŒã匷å¶é žååŠçãããã«ãŒã
ã³ãã©ãã¯ãå«ãé®å å±€ãã·ã¢ã³è²çŽ åäŸäžå
åç©ãå«ãå±€ãèµ€ææ§ããã²ã³åéä¹³å€å±€ãäž
éå±€ãããŒã³ã¿è²çŽ åäŸäžååç©ãå«ãå±€ãç·
ææ§ããã²ã³åéä¹³å€å±€ãäžéå±€ãã€ãšããŒè²
çŽ åäŸäžååç©ãå«ãå±€ãéææ§ããã²ã³åé
ä¹³å€å±€ãä¿è·å±€ãé 次ç©å±€ããããã®ïŒæå ã·
ãŒãïŒãšç¬¬ïŒã®éææ¯æäœäžã«äžåå±€ãã¿ã€ã
ã³ã°å±€ãç©å±€ããããã®ïŒã«ããŒã·ãŒãïŒãšã
é¢å¯Ÿé¢ã®é¢ä¿ã§éããããŠãããããããã®é
ã«ã«ãŒãã³ãã©ãã¯ãå«ãåŠç液ã延å±ããã
ãããªäœçœ®ã«è©²åŠç液ãå èµãããå§åã§ç Žå£
å¯èœãªå®¹åšãé 眮ãããŠããŠããããäžè ãäž
äœçã«åºå®ããããã®ã 匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã䜿çš
ãã以å€ã¯ããã®ãããªãã€ã«ã ãŠãããã®æ§
æã¯åŸæ¥ããç¥ãããŠãããäŸãã°
Photographic Science and EngineeringïŒã
ãªãã°ã©ãã€ãã¯ã»ãµã€ãšã³ã¹ã»ãšã³ãã»ãšã³
ãžãã¢ãªã³ã°ïŒãrol.20ïŒNo.ïŒïŒpp.155ã164
JulyïŒAugust 1976幎ã«è©³ãã説æãããããŸ
ãããã«ãã€ãŠè»¢åç»åãåŸãããåå¿æ©æ§ã«
ã€ããŠã詳ãã説æãããŠããã éææ¯æäœäžã«äžåå±€ãã¿ã€ãã³ã°å±€ãåå
å±€ãç©å±€ããããã®ïŒååã·ãŒãïŒãšéæãã
ãã¯äžéæã®ç¬¬ïŒã®æ¯æäœäžã«åŒ·å¶é žååŠçã
ããã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€ãã·ã¢ã³è²
çŽ åäŸäžååç©ãå«ãå±€ãèµ€ææ§ããã²ã³åé
ä¹³å€å±€ãäžéå±€ãããŒã³ã¿è²çŽ åäŸäžååç©ã
å«ãå±€ãç·ææ§ããã²ã³åéä¹³å€å±€ãäžéå±€ã
ã€ãšããŒè²çŽ åäŸäžååç©ãå«ãå±€ãéææ§ã
ãã²ã³åéä¹³å€å±€ãä¿è·å±€ãé 次ç©å±€ãããæ
å ã·ãŒããšãé¢å¯Ÿé¢ã®é¢ä¿ã§åãåã€ãŠéãã
ããŠãããããããã®éã«è€æ°ã®PHã€ã³ãžã±ãŒ
ã¿ãŒææãšé žåãã¿ã³ãå«ãåŠç液ã延å±ãã
ããããªäœçœ®ã«è©²åŠç液ãå èµãããå§åã§ç Ž
å£å¯èœãªå®¹åšãé 眮ãããŠããŠããããäžè ã
äžäœçã«åºå®ããããã®ã 匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯å±€ã䜿
çšãã以å€ã¯ããã®ãããªãã€ã«ã ãŠãããã®
æ§æã¯åŸæ¥ããç¥ãããŠãããäŸãã°
Neblettes Handbook of Photography and
Reprography MaterialsïŒProcesses and
SystemsïŒããã¬ãºã»ãã³ãããã¯ã»ãªãã»ã
ãªãã°ã©ãã€ãŒã»ãšã³ãã»ãªããã°ã©ãã€ãŒã»
ãããªã¢ã«ãºã»ããã»ã¹ã€ãºã»ãšã³ãã»ã·ã¹ã
ã ãºïŒãSeventh Ed.ïŒ1977幎ïŒã®ç¬¬12ç« ã«è©³
ãã説æãããããŸãããã«ãã€ãŠè»¢åç»åã
åŸãããåå¿æ©æ§ã«ã€ããŠã詳ãã説æãããŠ
ãããåèšã®PHã€ã³ãžã±ãŒã¿ãŒææãäŸãã°ç±³
åœç¹èš±3647437å·ãå3833615å·ã«å ·äœçãªèª¬æ
ãããã 該æ æ§ãšã®å±€æ§æã¯é©å®å€æŽã§ãããäŸã
ã°è²çŽ åäŸäžååç©ãšããã²ã³åéãšã¯åäžã®å±€
äžã«ãã€ãŠãããã äžæ¹ãã¿ã€ãã³ã°å±€ã¯è€æ°å±€åããŠããããå
æ æ§ã«æŒãŠåŠç液äžã®ã«ãŒãã³ãã©ãã¯ã¯åæ§
ã«åŒ·å¶é žååŠçããããã®ã§ãããã æ æ§ã®å¥œãŸããå±€æ§æã¯ãæ æ§ã«æŒãŠåŒ·å¶
é žååŠçãããã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€å
ã³åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ãšã·ã¢ã³
è²çŽ åäŸäžååç©ãå«ãå±€ãããªããã®ã§ããã
å³ã¡ãã·ã¢ã³è²çŽ åäŸäžååç©ãå«ãå±€ã¯åŒ·å¶é ž
ååŠçãããã«ãŒãã³ãã©ãã¯ã®å°ããšãäžéšã
å«ãã®ã奜ãŸããã æ¬çºæã«ãã€ãŠæ¬¡ã®ãããªè«žå¹æãåŸãããã ååå±€ãžæ¡æ£è»¢åããè²çŽ ãã«ãŒãã³ãã©ã
ã¯ãå«ãå±€ã«æç²ãããäºãå°ããè²çŽ ã®è»¢å
ãä¿é²ããããçµå±ãç»åã®åºçŸæéãçããª
ãããããDmaxã®é«ã転åç»åãåŸãããã ã«ãŒãã³ãã©ãã¯ã«ããåçæ§èœã®æªåããª
ãïŒåŸããã転åç»åã®DminãäœããDmax
ã¯é«ãïŒã ã«ãŒãã³ãã©ãã¯ãè²çŽ åäŸäžååç©ã®å«æ
å±€ã«æ·»å ã§ããã®ã§ãã«ãŒãã³ãã©ãã¯ãšè²çŽ
åäŸäžååç©ãå¥ã ã®å±€ã«å«æãããå Žåã«æ¯
ã¹ãŠèå±€åã§ããè²çŽ ã®è»¢åãä¿é²ããããçµ
å±ã転åç»åã®åºçŸæéãçããªããããã¯
âã€ã³ã¹ã¿ã³ãåçâã®ç®çã«ããåèŽããã ã«ãŒãã³ãã©ãã¯ç²åã®åéäœãæžå°ããã
ã®ããé®å èœãåäžãããçµå±ãåŸæ¥ããå°é
ã®ã«ãŒãã³ãã©ãã¯ã®äœ¿çšã§æžã¿ãçµæžçã§ã
ãã°ããã§ãªããèå±€åãã§ããããã®ãã転
åç»åã®åºçŸæéãçãã§ããã æç±å¢è²ïŒçŸååŠçããåŸãååå±€ã«åœ¢æã
ããè²åã®æ¿åºŠãçµæãšãšãã«å¢å€§ããäºïŒã
ç¹ã«ã·ã¢ã³ã®æç±å¢è²ãé²æ¢ã§ããã æ 滲ã¿ïŒããªã³ãã®çœå°æ ã«è²çŽ ã滲ãã§åº
ãŠããäºïŒãç¹ã«ã·ã¢ã³è²çŽ ã®æ 滲ã¿ãé²æ¢ã§
ããã ãŸãæ¬çºæã®åçæå ææã¯ãŠãªãã·ãŠãªãã¬
ãªãŒãç»åã圢æããæå ææïŒãã®ææãç»å
ã圢æããæ©æ§ã«ã€ããŠã¯ç±³åœç¹èš±3440049å·ã
å4076531å·çã«èšèŒãããïŒãšããŠæçšã§ã
ãããã®å Žåã匷å¶é žååŠçãããã«ãŒãã³ãã©
ãã¯ã¯ãã¬ãŒã·ãšã³é²æ¢å±€ã«å«æããã®ãæå¹ã§
ããããŸããæ¬çºæã®åçæå ææã¯ãã³ãããª
ãã¯ã¹ã»ãã€ã«ã ãšããŠãæçšã§ããããã®å Ž
åã匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã¯ãã
ã²ã³åéä¹³å€å±€ã«å«æããã®ãæå¹ã§ããããã³
ãããªãã¯ã¹ã»ãã€ã«ã ã«ã€ããŠã¯ãäŸãã°P.
GlafkidesèPhotographic ChemistryïŒããªãã°
ã©ãã€ãã¯ã»ã±ãã¹ããªãŒïŒç¬¬ïŒå·»Fountain
PressïŒ1960幎ïŒã®689ã701é ãKodak Color
Data BookïŒã³ããã¯ã»ã«ã©ãŒã»ããŒã¿ãŒã»ãã
ã¯ïŒïŒ1951幎ïŒå¯é¡Kodak Dye Transfer
ProcessïŒã³ããã¯ã»ãã€ã»ãã©ã³ã¹ãã¢ãŒã»ã
ãã»ã¹ïŒã«èšèŒãããã æ¬çºæã®åçæå ææã«äœ¿çšãããããã²ã³å
éä¹³å€ã¯ãå¡©åéãèåéãå¡©èåéãæ²èå
éãå¡©æ²èåéãããã¯ãããã®æ··åç©ã®èŠªæ°Žæ§
ã³ãã€ãç¶åæ£ç©ã§ãã€ãŠãããã²ã³çµæã¯æå
ææã®äœ¿çšç®çãšåŠçæ¡ä»¶ã«å¿ããŠéžæããã
ããæ²åç©å«éã10moleïŒ ä»¥äžãå¡©åç©å«éã
30moleïŒ ä»¥äžã®èåéãæ²èåéåã¯å¡©æ²èå
éãç¹ã«å¥œãŸããã æ¬çºæã§ã¯ç²åè¡šé¢ã«äž»ã«æœåã圢æããâè¡š
é¢æœåâåããã²ã³åéä¹³å€ã䜿çšã§ããããå
ç²åå éšã«äž»ã«æœåã圢æããâå éšæœåâåã
ãã²ã³åéä¹³å€ã䜿çšã§ããããåŸè ãç¹ã«å¥œãŸ
ãããæå©ã«äœ¿çšãããå éšæœååããã²ã³åé
ä¹³å€ãšããŠã¯ãç±³åœç¹èš±2592250å·ãå3206313
å·ãå3447927å·ãå3761276å·ãåã³å3935014
å·çã«èšèŒãããã³ã³ããŒãžãšã³åä¹³å€ãã³ã¢ïŒ
ã·ãšã«åä¹³å€ãç°çš®éå±ãå èµãããä¹³å€çãæ
ããããšãã§ããã ãã®åã®ä¹³å€ã¯é²å åŸãé æ žå€ã®ååšäžã«çŸå
åŠçããŠçŽæ¥ããžåãåŸãã®ã«å¥œé©ã§ãããé æ ž
å€ãšããŠã¯ãç±³åœç¹èš±2588982å·ãå2563785å·ã«
èšèŒãããããã©ãžã³é¡ïŒå3227552å·ã«èšèŒã
ããããã©ãžãé¡ãšããã©ãŸã³é¡ïŒè±åœç¹èš±
1283835å·ãç¹å ¬æ49â38164å·ãç±³åœç¹èš±
3734738å·ãå3719494å·ãå3615615å·ã«èšèŒã
ããåçŽå¡©ååç©ïŒç±³åœç¹èš±3718470å·ã«èšèŒã
ããããã¶ããäœçšã®ããïŒnucleatingïŒçœ®æåº
ãè²çŽ ååäžã«æããå¢æè²çŽ ïŒç±³åœç¹èš±
4030925å·ãå4031127å·ã«èšèŒãããã¢ã·ã«ãã
ã©ãžãããšãã«ããªå°¿çŽ ç³»ååç©ã代衚çãªãã®
ã§ããã æ¬çºæã«äœ¿çšãããããã²ã³åéä¹³å€ã¯ãææ
ã«å¿ããŠåå å¢æè²çŽ ã«ãã€ãŠæ¡å€§ãããæè²æ§
ããã¡åŸããåå å¢æè²çŽ ãšããŠã¯ãã·ã¢ãã³è²
çŽ ãã¡ãã·ã¢ãã³è²çŽ çãé©å®äœ¿çšã§ããã æ¬çºæã«äœ¿çšãããè²çŽ åäŸäžååç©ãšããŠå
çš®ã®ååç©ãå©çšããããšãåºæ¥ãããè²çŽ æŸåº
ã¬ããã¯ã¹ååç©ãè²çŽ çŸåè¬ãç¹ã«æçšã§ã
ãã è²çŽ æŸåºã¬ããã¯ã¹ååç©ã®ãã¡ãé žåãåã
ãååç©ãã¢ã«ã«ãªå æ°Žå解ããŠè²çŽ ãæŸåºãã
ãã®ãšããŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæãã
ããšãã§ããã ç±³åœç¹èš±4053312å·ãå4055428å·ãå4076529
å·ãå4152153å·ãå4135929å·ãç¹éæ53â
149328å·ãå51â104343å·ãå53â46730å·ãå
54â130122å·ãå53â3819å·ãç¹é¡æ54â89128
å·ãå54â90806å·ãå54â91187å·ãç ãã®ãã¡ãã€ãšããŒè²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±4013633å·ãç¹éæ53â149328å·ãå
51â114930å·ãç¹é¡æ54â148237å·ããªãµãŒãã»
ãã€ã¹ã¯ããŒãžã€ãŒïŒResearch DisclosureïŒ
17630ïŒâ78ïŒãå16475ïŒâ77ïŒç ããŒã³ã¿è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3954476å·ãå3931144å·ãå3932308
å·ãç¹éæ53â23628å·ãå52â106727å·ãå54
â65034å·ãç¹é¡æ53â69488å·ãå53â76162
å·ãå53â96445å·ãå54â149777å·ãå54â
146655å·ãå54â42848å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2847371å·ãç ã·ã¢ã³è²çŽ ãæŸåºãããã®ïŒ ç±³åœç¹èš±3942987å·ãå3929760å·ãå4013635
å·ãç¹éæ51â109928å·ãå53â149328å·ãå52
â8827å·ãå53â143323å·ãå53â47823å·ãç¹
é¡æ54â146654å·ãç ãŸããé žåãåããªãã€ãæ¹ã®ååç©ãéç°ã
ããªã©ããŠè²çŽ ãæŸåºããã¬ããã¯ã¹ååç©ãšã
ãŠã¯ãäžèšã®æç®ã«èšèŒã®ãã®ãæããããšãã§
ããã ç±³åœç¹èš±4139379å·ãå3980479å·ã西ç¬ç¹èš±åº
é¡ïŒOLSïŒ2402900å·ãå2448811å·ãçã è²çŽ çŸåè¬ãšããŠã¯ãç±³åœç¹èš±2983606å·ç
çš®ã ã®ç¹èš±ã«èšèŒã®ãã®ããS.M.BloomïŒM.
GreenïŒM.Idelson ïŒ M.S.SimonèThe
Cnemistry of Synthetic DyesïŒã¶ã»ã±ãã¹ããª
ãŒã»ãªãã»ã¹ã€ã³ã»ããã¯ãã€ãºïŒãvol.8ïŒK.
Venkataramanç·šAcademic Press New York
1978幎pp.331ã387ã«èšèŒã®ãã®çã䜿çšã§ã
ãã æ¬çºæã®åçãã€ã«ã ãŠãããã«ãããŠãè²çŽ
åäŸäžååç©ãã¯ãã¹é žåã§ãããã®ã§ããé
ããã©ã®ãããªããã²ã³åéçŸåè¬ã§ã䜿çšãã
ããšãã§ããããã®ãããªçŸåè¬ã¯ãã¢ã«ã«ãªæ§
åŠç液ã®äžã«å«ãŸããŠãããããåçèŠçŽ ã®é©åœ
ãªå±€ã«å«ãŸããŠããããæ¬çºæã«ãããŠäœ¿çšãã
ãçŸåè¬ã®äŸãããããšæ¬¡ã®éãã§ããã ç¹é¡æ54â91187å·ã«èšèŒã®ãã€ããããã³
é¡ãã¢ããããšããŒã«é¡ãããšãã¬ã³ãžã¢ãã³
é¡ããã©ãŸãªãžãã³é¡ãäŸãã°ããšããã³ãïŒâ
ããšãã«âïŒâãã©ãŸãªãžãã³ããžã¡ãŸã³ïŒïŒâ
ããšãã«âïŒïŒïŒâãžã¡ãã«âïŒâãã©ãŸãªãžã
ã³ïŒãïŒâïœâããªã«âïŒâã¡ãã«âïŒâãªãã·
ã¡ãã«âïŒâãã©ãŸãªãžãã³ãïŒâïŒ4â²âã¡ãã
ã·ããšãã«ïŒâïŒâã¡ãã«âïŒâãªãã·ã¡ãã«â
ïŒâãã©ãŸãªãžãã³ãïŒâããšãã«âïŒâã¡ãã«
âïŒâãªãã·ã¡ãã«âïŒâãã©ãŸãªãžãã³ããª
ã©ã ããã«ããããã®ã®ãªãã§ãããšãã¬ã³ãžã¢ã
ã³é¡ãªã©ã®ã«ã©ãŒçŸåè¬ãããäžè¬ã«ååå±€ã®ã¹
ãã€ã³åœ¢æã軜æžããæ§è³ªãå ·ããŠããçœé»çŸå
å€ïŒãªãã§ããã©ãŸãªãžãã³é¡ïŒããç¹ã«å¥œãŸã
ãã æ¬çºæã®æå ææããŠãªãã·ãŠãªãã¬ãªãŒãå
ã圢æããæææãã¯ãã³ãããªãã¯ã¹ã»ãã€ã«
ã ã§ããå Žåã«ã¯ãã¿ã³ãã³ã°çŸåè¬ã䜿çšãã
ããã¿ã³ãã³ã°çŸåè¬ãšããŠã¯äŸãã°ãåŸæ¥å ¬ç¥
ã®ãã®ã䜿çšã§ããã åŠç液ã¯ãæ°Žé žåãããªãŠã ãæ°Žé žåã«ãªãŠ
ã ãçé žãããªãŠã ããªã³é žãããªãŠã ã®ãããª
å¡©åºãå«ã¿PHïŒä»¥äžã奜ãŸããã¯11.5以äžã®ã¢ã«
ã«ãªåŒ·åºŠãæã€ãåŠç液ã¯äºç¡«é žãããªãŠã ãã¢
ã¹ã³ã«ãã³é žå¡©ããããªãžããããœãŒãºã¬ãã¯ã
ã³ã®åŠãé žåé²æ¢å€ãå«æããèåã«ãªãŠã ã®ã
ããªéã€ãªã³æ¿åºŠèª¿ç¯å€ãå«æãåŸããåããã
ãã·ãšãã«ã»ã«ããŒã¹ããããªãŠã ã«ã«ããã·ã¡
ãã«ã»ã«ããŒã¹ã®åŠãç²åºŠå¢å ååç©ãå«æãã
ãŠãããã åæ¬ã¢ã«ã«ãªæ§åŠç液äžã«ã¯çŸåä¿é²ãããã¯
è²çŽ ã®æ¡æ£ãä¿é²ããåŠãååç©ãå«ãŸããŠãã
ãïŒããšãã°ãã³ãžã«ã¢ã«ã³ãŒã«ã®åŠãåå
ç©ïŒã äžéå±€ãšè²çŽ åäŸäžäœãå«æããå±€ã®éã«ç¹é¡
æ53â125600å·ã«èšèŒãããããã«éé¢å±€ãèšã
ãŠããããåäžéå±€äžã«ç¹é¡æ54â144155å·ã«èš
èŒãããããã«ããã²ã³åéä¹³å€ãå ããŠãã
ãã æ¬çºæã®ã«ã©ãŒæ¡æ£è»¢åæ³çšã®æå ææã«äœ¿çš
ãããåªæå±€ãäžåå±€ãäžåé床調ç¯å±€ïŒã¿ã€ã
ã³ã°å±€ïŒãåŠççµæç©çã«ã€ããŠã¯ãäŸãã°ç¹é
æ52â64533å·ã«èšèŒã®ãã®ãé©çšã§ããã å®éšäŸ (A) 匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã®èª¿è£œ ãªãŸã³åŠçã«ããæ¹æ³ ã«ãŒãã³ãã©ãã¯ïŒäžè±åæ(æ ª)補10BïŒ50
ïœãæ¹ææ©ã€ãïŒã¬ã©ã¹å®¹åšã«å ¥ãã18â
22âã«ä¿ã¡ãªãããæ¿ããæ¹æããã«ãŒãã³
ãã©ãã¯ã空æ°äžã«æµ®éããç¶æ ã«ä¿ã€ãã
ãã®äžã«æ¯æ1775ïœã®ãªãŸã³ãïŒæéæµéã
é žååŠçãããæµéåŸããã«ïŒæéæ¹æãã
åŸãäžå€é眮ãå ç©ããã«ãŒãã³ãã©ãã¯ã
æéããã éé žåæ°ŽçŽ åŠçã«ããæ¹æ³ ã«ãŒãã³ãã©ãã¯ïŒäžè±åæ(æ ª)補10BïŒ
100ïœããã³æ°Ž400mlãããªãåæ£ç©ã70âã«
å æž©ããæ¹æããªãã35ïŒ éé žåæ°ŽçŽ æ°Ž400
mlãïŒæéãããŠæ»Žäžããã滎äžåŸã70âã«
ä¿ã¡ãªããïŒæéåå¿ããããéãæ°ŽæŽåŸ
ïŒïŒ äºç¡«é žãããªãŠã ïŒãšå ±ã«ïŒæéæ¹æ
ããåŸæ°ŽæŽåŸä¹Ÿç¥ããã 次äºå¡©çŽ é žãœãŒãåŠçã«ããæ¹æ³âïŒ ã«ãŒãã³ãã©ãã¯ïŒäžè±åæ(æ ª)補10BïŒ
150ïœããã³æ°Ž600mlãããªãåæ£ç©ã70âã«
å æž©ããæ¹æããªãã12ïŒ æ¬¡äºå¡©çŽ é žãããª
ãŠã 300mlã20åãããŠæ»Žäžããã滎äžåŸã
70âã«ä¿ã¡ãªããïŒæéåå¿ããããåå¿æ··
åç©ãéãæ°ŽæŽåŸãïŒïŒ äºç¡«é žãããªãŠã
ïŒãšå ±ã«ïŒæéæ¹æããåŸãéãæ°ŽæŽåŸ
也ç¥ããã 次äºå¡©çŽ é žãœãŒãåŠçã«ããæ¹æ³âïŒ ã«ãŒãã³ãã©ãã¯ïŒã³ãã³ãã¢ã³ã«ãŒãã³
瀟補â450ïŒã36ïŒ ããã³ã¿ã¢ãŒã«SNïŒã
ã«ã ã¢ã«ããããšããã¿ã¬ã³ã¹ã«ãã³é žãœãŒ
ãã®éåç©ãïŒïŒ å«ãã§ããæ°Žåæ£ç©375ïœ
ã70âã«å æž©ããåŸãæ¹æããªãã12ïŒ æ¬¡äº
å¡©çŽ é žãœãŒã260mlã40åãããŠåŸã ã«å ã
ãã滎äžçµäºåŸ70âã«ä¿ã¡ãªãããïŒæéæ¹
æãããåå¿æ··åç©ã宀枩ãŸã§å·ãããåŸã
æ®åãã次äºå¡©çŽ é žãœãŒããç¡å¹åããã
ããäºç¡«é žãœãŒã21ïœããã³æ°Ž40mlãããªã
溶液ãå ããŠãïŒæéæ¹æããã次ã«æž©åºŠ40
âã§10ïŒ ãŒã©ãã³æ°Žæº¶æ¶²675mlãå ããåŸã
å·åŽåºåããããµã€ã³ãç¶ã«çŽ°æããæµæ°Žäž
ã«ïŒæéæŸçœ®ããŠæ®ååå¿ç©ãé€å»ããã (B) ã«ãŒãã³ãã©ãã¯ãžã®è²çŽ ããã®åžçéã®
æž¬å® äžèšã®ãã®ããã«åŒ·å¶é žååŠçãããã«
ãŒãã³ãã©ãã¯ïœïŒïœïŒïœåã³ç©ºæ°äžã«é·æé
ããããããåŠçãããŠããªãã«ãŒãã³ãã©ã
ã¯ïŒäžè±åæ(æ ª)補10BïŒãå¯Ÿç §çšã«ãŒãã³ãã©
ãã¯ïœ ãã®å0.2ïœããè²çŽ ãã0.01ïŒ ãå«
ã1NKOH氎溶液40mlã«å ãã25âã§30åéæ¹
æãããç¶ããŠé å¿åé¢æ©ã䜿çšããŠãäžæŸæ¶²
ãšã«ãŒãã³ãã©ãã¯ãåé¢ããããã®äžæŸæ¶²ã®
654mÎŒã«ãããåžåæ¿åºŠãå ã®è²çŽ ããã®
氎溶液ã®åžåæ¿åºŠãšæ¯èŒããããšã«ãããäžæŸ
液äžã®è²çŽ ããã®éãæ±ãããã®å€ããäžè¡š
ã®åžçéãåŸãã
ãè¡šã
å®æœäŸ ïŒ
ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãéææ¯æäœäžã«ã
次ã®åŠãåå±€ãå¡åžããŠæå ã·ãŒããäœã€ãã (1) ã³ããªãã¹ãã¬ã³ââããã«ãã³ãžã«â
ïŒïŒ®ïŒïŒ®âããªããã·ã«ã¢ã³ã¢ããŠã ã¯ããª
ãã3.0ïœïŒm2ããŒã©ãã³3.0ïœïŒm2ãå«æãã
åªæå±€ã (2) äºé žåãã¿ã³20ïœïŒm2ããŒã©ãã³2.0ïœïŒm2
ãå«æããå åå°å±€ã (3) ã«ãŒãã³ãã©ãã¯2.0ïœïŒm2ãšãŒã©ãã³1.5
ïœïŒm2ãå«æããé®å å±€ã (4) äžèšã®ã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©0.44
ïœïŒm2ãããªã·ã¯ãããã·ã«ãã¹ããšãŒã0.09
ïœïŒm2ãïŒïŒïŒâãžâïœâãã³ã¿ãã·ã«ãã€ã
ãããã³0.008ïœïŒm2ãããã³ãŒã©ãã³0.8ïœïŒ
m2ãå«æããå±€ã (5) èµ€ææ§å æœåçŽæ¥ããžèåéä¹³å€ïŒéã®éã§
1.03ïœïŒm2ïŒããŒã©ãã³1.2ïœïŒm2ãäžèšã®é æ ž
å€0.04mgïŒm2ããã³ïŒâã¹ã«ãâïŒâïœâãã³
ã¿ãã·ã«ãã€ããããã³ã»ãããªãŠã å¡©0.13
ïœïŒm2ãå«æããèµ€ææ§ä¹³å€å±€ã (6) ïŒïŒïŒâãžâïœâãã³ã¿ãã·ã«ãã€ãããã
ã³0.43ïœïŒm2ãããªããã·ã«ãã¹ããšãŒã0.1
ïœïŒm2ããã³ãŒã©ãã³0.4ïœïŒm2ãå«æãã
å±€ã (7) äžèšæ§é ã®ããŒã³ã¿è²çŽ æŸåºã¬ããã¯ã¹å
åç©ïŒ0.21ïœïŒm2ïŒãæ§é ã®ããŒã³ã¿è²çŽ æŸ
åºã¬ããã¯ã¹ååç©ïŒ0.11ïœïŒm2ïŒãããªã·ã¯
ãããã·ã«ãã¹ããšãŒãïŒ0.08ïœïŒm2ïŒãïŒïŒ
ïŒâãžâïœâãã³ã¿ãã·ã«ãã€ããããã³
ïŒ0.009ïœïŒm2ïŒåã³ãŒã©ãã³ïŒ0.9ïœïŒm2ïŒã
å«æããå±€ã (8) ç·ææ§å æœåçŽæ¥ããžèåéä¹³å€ïŒéã®éã§
0.82ïœïŒm2ïŒããŒã©ãã³ïŒ0.9ïœïŒm2ïŒãå±€(5)ãš
åãé æ žå€ïŒ0.03mgïŒm2ïŒããã³ïŒâã¹ã«ãâ
ïŒâïœâãã³ã¿ãã·ã«ãã€ããããã³ã»ãããª
ãŠã å¡©ïŒ0.08ïœïŒm2ïŒãå«æããç·ææ§ä¹³å€
å±€ã (9) (6)ãšåäžã®å±€ã (10) äžèšæ§é ã®ã€ãšããŒè²çŽ æŸåºã¬ããã¯ã¹åå
ç©ïŒ0.53ïœïŒm2ïŒãããªã·ã¯ãããã·ã«ãã¹ã
ãšãŒãïŒ0.13ïœïŒm2ïŒãïŒïŒïŒâãžâïœâãã³
ã¿ãã·ã«ãã€ããããã³ïŒ0.014ïœïŒm2ïŒãã
ã³ãŒã©ãã³ïŒ0.7ïœïŒm2ïŒãå«æããå±€ã (11) éææ§å æœåçŽæ¥ããžèåéä¹³å€ïŒéã®éã§
1.09ïœïŒm2ïŒããŒã©ãã³ïŒ1.1ïœïŒm2ïŒãå±€(5)ãš
åãé æ žå€ïŒ0.04mgïŒm2ïŒããã³ïŒâã¹ã«ãâ
ïŒâïœâãã³ã¿ãã·ã«ãã€ããããã³ã»ãããª
ãŠã å¡©ïŒ0.07ïœïŒm2ïŒãå«æããéææ§ä¹³å€
å±€ã (12) ãŒã©ãã³ïŒ1.0ïœïŒm2ïŒãå«æããå±€ãäžèš
æå ã·ãŒãã®(3)å±€ã«æŒãŠãã«ãŒãã³ãã©ãã¯ãš
ããŠãå®éšäŸã«èšèŒã®ã«ãŒãã³ãã©ãã¯ïœïŒ
ïœïŒïœåã³æªåŠçã®ã«ãŒãã³ãã©ãã¯ïœ ã䜿çš
ãããã®ãããããæå ã·ãŒãïŒïŒïŒïŒïŒïŒïŒ
ãšåä»ããã ãããã®æå ã·ãŒãïŒãïŒãšäžèšã®ã«ããŒã·
ãŒããšãããããé¢å¯Ÿé¢ã®é¢ä¿ã§éãåããã
æŽã«äžèšã®çµæã®åŠç液ãå§åã§ç Žè£å¯èœãªè¢
ã«ã€ãããã®ãšãåã äžäœçã«åºå®ããŠåçã
ã€ã«ã ãŠããããäœæããã ã«ããŒã·ãŒãã®æ§æ éæãªããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«
é 次ã以äžã®å±€ïŒ1â²ïŒãïŒ3â²ïŒãå¡åžããŠã«ããŒ
ã·ãŒããäœè£œããã ïŒ1â²ïŒ ã¢ã¯ãªã«é žãšã¢ã¯ãªã«é žããã«ã®80察20
ïŒééæ¯ïŒã®å ±éåäœïŒ22ïœïŒm2ïŒããã³ïŒïŒ
ïŒâãã¹ïŒïŒïŒïŒâãšããã·ããããã·ïŒâã
ã¿ã³ïŒ0.44ïœïŒm2ïŒãå«æããå±€ã ïŒ2â²ïŒ ã¢ã»ãã«ã»ã«ããŒã¹ïŒ100ïœã®ã¢ã»ãã«ã»
ã«ããŒã¹ãå æ°Žå解ããŠã39.4ïœã®ã¢ã»ãã«åº
ãçæãããã®ïŒïŒ3.8ïœïŒm2ïŒããã³ã¹ãã¬ã³
ãšç¡æ°Žãã¬ã€ã³é žã®60察40ïŒééæ¯ïŒã®å ±éå
äœïŒååéçŽïŒäžïŒïŒ0.2ïœïŒm2ïŒããã³ïŒâ
ïŒÎ²âã·ã¢ããšãã«ããªïŒâïŒâããšãã«ããã©
ãŸãŒã«ïŒ0.115ïœïŒm2ïŒãå«æããå±€ã ïŒ3â²ïŒ å¡©åãããªãã³ãšã¡ãã«ã¢ã¯ãªã¬ãŒããš
ã¢ã¯ãªã«é žã®85察12察ïŒïŒééæ¯ïŒã®å ±éåäœ
ã©ããã¯ã¹ïŒ2.5ïœïŒm2ïŒããã³ããªã¡ãã«ã¡
ã¿ã¢ã¯ãªã¬ãŒãã©ããã¯ã¹ïŒç²åŸïŒãïŒÎŒïœïŒ
ïŒ0.05ïœïŒm2ïŒãå«æããå±€ã åŠç液ã®çµæ ïŒâïœâããªã«âïŒâããããã· ã¡ãã«âïŒâã¡ãã«âïŒâãã© ãŸãªãã³ 6.9ïœ ã¡ãã«ãã€ããããã³ 0.3ïœ ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã« 3.5ïœ äºç¡«é žãããªãŠã ïŒç¡æ°ŽïŒ 0.2ïœ ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ã» Naå¡© 58ïœ æ°Žé žåã«ãªãŠã ïŒ28ïŒ æ°Žæº¶æ¶²ïŒ 200c.c. ãã³ãžã«ã¢ã«ã³ãŒã« 1.5c.c. ã«ãŒãã³ãã©ã㯠150ïœ æ°Ž 685c.c. äžèšåçãã€ã«ã ãŠãããããã®ã«ããŒã·ãŒã
åŽããåã ç°è²ãŠãšããžã§é²å ããåŸã25âã§æŒ
å§éšæã«ããåŠç液ã80ãã¯ãã³ã®åã¿ã«å±éã
ãŠè»¢åè²ç»åãåŸãããã®ãšãã®ç»ååºçŸæéå
ã³ïŒæéåŸã®è»¢åè²åã®æ¿åºŠãèµ€ïŒïŒ²ïŒãç·
ïŒïŒ§ïŒåã³éïŒïŒ¢ïŒãã€ã«ã¿ãŒãéããŠæž¬å®ãã
äžè¡šã®å€ãåŸãã
次ã®åŠãåå±€ãå¡åžããŠæå ã·ãŒããäœã€ãã (1) ã³ããªãã¹ãã¬ã³ââããã«ãã³ãžã«â
ïŒïŒ®ïŒïŒ®âããªããã·ã«ã¢ã³ã¢ããŠã ã¯ããª
ãã3.0ïœïŒm2ããŒã©ãã³3.0ïœïŒm2ãå«æãã
åªæå±€ã (2) äºé žåãã¿ã³20ïœïŒm2ããŒã©ãã³2.0ïœïŒm2
ãå«æããå åå°å±€ã (3) ã«ãŒãã³ãã©ãã¯2.0ïœïŒm2ãšãŒã©ãã³1.5
ïœïŒm2ãå«æããé®å å±€ã (4) äžèšã®ã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©0.44
ïœïŒm2ãããªã·ã¯ãããã·ã«ãã¹ããšãŒã0.09
ïœïŒm2ãïŒïŒïŒâãžâïœâãã³ã¿ãã·ã«ãã€ã
ãããã³0.008ïœïŒm2ãããã³ãŒã©ãã³0.8ïœïŒ
m2ãå«æããå±€ã (5) èµ€ææ§å æœåçŽæ¥ããžèåéä¹³å€ïŒéã®éã§
1.03ïœïŒm2ïŒããŒã©ãã³1.2ïœïŒm2ãäžèšã®é æ ž
å€0.04mgïŒm2ããã³ïŒâã¹ã«ãâïŒâïœâãã³
ã¿ãã·ã«ãã€ããããã³ã»ãããªãŠã å¡©0.13
ïœïŒm2ãå«æããèµ€ææ§ä¹³å€å±€ã (6) ïŒïŒïŒâãžâïœâãã³ã¿ãã·ã«ãã€ãããã
ã³0.43ïœïŒm2ãããªããã·ã«ãã¹ããšãŒã0.1
ïœïŒm2ããã³ãŒã©ãã³0.4ïœïŒm2ãå«æãã
å±€ã (7) äžèšæ§é ã®ããŒã³ã¿è²çŽ æŸåºã¬ããã¯ã¹å
åç©ïŒ0.21ïœïŒm2ïŒãæ§é ã®ããŒã³ã¿è²çŽ æŸ
åºã¬ããã¯ã¹ååç©ïŒ0.11ïœïŒm2ïŒãããªã·ã¯
ãããã·ã«ãã¹ããšãŒãïŒ0.08ïœïŒm2ïŒãïŒïŒ
ïŒâãžâïœâãã³ã¿ãã·ã«ãã€ããããã³
ïŒ0.009ïœïŒm2ïŒåã³ãŒã©ãã³ïŒ0.9ïœïŒm2ïŒã
å«æããå±€ã (8) ç·ææ§å æœåçŽæ¥ããžèåéä¹³å€ïŒéã®éã§
0.82ïœïŒm2ïŒããŒã©ãã³ïŒ0.9ïœïŒm2ïŒãå±€(5)ãš
åãé æ žå€ïŒ0.03mgïŒm2ïŒããã³ïŒâã¹ã«ãâ
ïŒâïœâãã³ã¿ãã·ã«ãã€ããããã³ã»ãããª
ãŠã å¡©ïŒ0.08ïœïŒm2ïŒãå«æããç·ææ§ä¹³å€
å±€ã (9) (6)ãšåäžã®å±€ã (10) äžèšæ§é ã®ã€ãšããŒè²çŽ æŸåºã¬ããã¯ã¹åå
ç©ïŒ0.53ïœïŒm2ïŒãããªã·ã¯ãããã·ã«ãã¹ã
ãšãŒãïŒ0.13ïœïŒm2ïŒãïŒïŒïŒâãžâïœâãã³
ã¿ãã·ã«ãã€ããããã³ïŒ0.014ïœïŒm2ïŒãã
ã³ãŒã©ãã³ïŒ0.7ïœïŒm2ïŒãå«æããå±€ã (11) éææ§å æœåçŽæ¥ããžèåéä¹³å€ïŒéã®éã§
1.09ïœïŒm2ïŒããŒã©ãã³ïŒ1.1ïœïŒm2ïŒãå±€(5)ãš
åãé æ žå€ïŒ0.04mgïŒm2ïŒããã³ïŒâã¹ã«ãâ
ïŒâïœâãã³ã¿ãã·ã«ãã€ããããã³ã»ãããª
ãŠã å¡©ïŒ0.07ïœïŒm2ïŒãå«æããéææ§ä¹³å€
å±€ã (12) ãŒã©ãã³ïŒ1.0ïœïŒm2ïŒãå«æããå±€ãäžèš
æå ã·ãŒãã®(3)å±€ã«æŒãŠãã«ãŒãã³ãã©ãã¯ãš
ããŠãå®éšäŸã«èšèŒã®ã«ãŒãã³ãã©ãã¯ïœïŒ
ïœïŒïœåã³æªåŠçã®ã«ãŒãã³ãã©ãã¯ïœ ã䜿çš
ãããã®ãããããæå ã·ãŒãïŒïŒïŒïŒïŒïŒïŒ
ãšåä»ããã ãããã®æå ã·ãŒãïŒãïŒãšäžèšã®ã«ããŒã·
ãŒããšãããããé¢å¯Ÿé¢ã®é¢ä¿ã§éãåããã
æŽã«äžèšã®çµæã®åŠç液ãå§åã§ç Žè£å¯èœãªè¢
ã«ã€ãããã®ãšãåã äžäœçã«åºå®ããŠåçã
ã€ã«ã ãŠããããäœæããã ã«ããŒã·ãŒãã®æ§æ éæãªããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æäœäžã«
é 次ã以äžã®å±€ïŒ1â²ïŒãïŒ3â²ïŒãå¡åžããŠã«ããŒ
ã·ãŒããäœè£œããã ïŒ1â²ïŒ ã¢ã¯ãªã«é žãšã¢ã¯ãªã«é žããã«ã®80察20
ïŒééæ¯ïŒã®å ±éåäœïŒ22ïœïŒm2ïŒããã³ïŒïŒ
ïŒâãã¹ïŒïŒïŒïŒâãšããã·ããããã·ïŒâã
ã¿ã³ïŒ0.44ïœïŒm2ïŒãå«æããå±€ã ïŒ2â²ïŒ ã¢ã»ãã«ã»ã«ããŒã¹ïŒ100ïœã®ã¢ã»ãã«ã»
ã«ããŒã¹ãå æ°Žå解ããŠã39.4ïœã®ã¢ã»ãã«åº
ãçæãããã®ïŒïŒ3.8ïœïŒm2ïŒããã³ã¹ãã¬ã³
ãšç¡æ°Žãã¬ã€ã³é žã®60察40ïŒééæ¯ïŒã®å ±éå
äœïŒååéçŽïŒäžïŒïŒ0.2ïœïŒm2ïŒããã³ïŒâ
ïŒÎ²âã·ã¢ããšãã«ããªïŒâïŒâããšãã«ããã©
ãŸãŒã«ïŒ0.115ïœïŒm2ïŒãå«æããå±€ã ïŒ3â²ïŒ å¡©åãããªãã³ãšã¡ãã«ã¢ã¯ãªã¬ãŒããš
ã¢ã¯ãªã«é žã®85察12察ïŒïŒééæ¯ïŒã®å ±éåäœ
ã©ããã¯ã¹ïŒ2.5ïœïŒm2ïŒããã³ããªã¡ãã«ã¡
ã¿ã¢ã¯ãªã¬ãŒãã©ããã¯ã¹ïŒç²åŸïŒãïŒÎŒïœïŒ
ïŒ0.05ïœïŒm2ïŒãå«æããå±€ã åŠç液ã®çµæ ïŒâïœâããªã«âïŒâããããã· ã¡ãã«âïŒâã¡ãã«âïŒâãã© ãŸãªãã³ 6.9ïœ ã¡ãã«ãã€ããããã³ 0.3ïœ ïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã« 3.5ïœ äºç¡«é žãããªãŠã ïŒç¡æ°ŽïŒ 0.2ïœ ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹ã» Naå¡© 58ïœ æ°Žé žåã«ãªãŠã ïŒ28ïŒ æ°Žæº¶æ¶²ïŒ 200c.c. ãã³ãžã«ã¢ã«ã³ãŒã« 1.5c.c. ã«ãŒãã³ãã©ã㯠150ïœ æ°Ž 685c.c. äžèšåçãã€ã«ã ãŠãããããã®ã«ããŒã·ãŒã
åŽããåã ç°è²ãŠãšããžã§é²å ããåŸã25âã§æŒ
å§éšæã«ããåŠç液ã80ãã¯ãã³ã®åã¿ã«å±éã
ãŠè»¢åè²ç»åãåŸãããã®ãšãã®ç»ååºçŸæéå
ã³ïŒæéåŸã®è»¢åè²åã®æ¿åºŠãèµ€ïŒïŒ²ïŒãç·
ïŒïŒ§ïŒåã³éïŒïŒ¢ïŒãã€ã«ã¿ãŒãéããŠæž¬å®ãã
äžè¡šã®å€ãåŸãã
ãè¡šã
ãã®è¡šããã匷å¶é
žååŠçãããã«ãŒãã³ãã©
ãã¯ãé®å å±€ã«çšããããšã«ãããç»ååºçŸæé
ãççž®ããç¹ã«ïŒ²ã®DmaxãäžæããŠããããšã
ããããç¹ã«æ¬¡äºå¡©çŽ é žãœãŒãã§åŠçããã«ãŒã
ã³ãã©ãã¯ã¯ãã®çšåºŠãé¡èã§ãããäžã€Dmin
ãé¡èã«æžå°ããŠããããè¯å¥œãªè»¢åç»è³ªãäžã
ãããšããããã å®æœäŸ ïŒ å®æœäŸâïŒã®ã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€(3)
ãšã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©ãå«ãå±€(4)ã
äžäœåããŠäžèšã®åŠãæå ã·ãŒãïŒãïŒãäœã€
ãããã®ä»ã®å±€æ§æã¯å®æœäŸâïŒãšåãã§ããã äžäœåããå±€ã®çµæ å®æœäŸâïŒã®ã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©
0.44ïœïŒm2ãããªã·ã¯ãããã·ã«ãã¹ããšãŒã
0.09ïœïŒm2ãïŒïŒïŒâãžâïœâãã³ã¿ãã·ã«ãã€
ããããã³0.008ïœïŒm2ããŒã©ãã³2.0ïœïŒm2ãã
ãã³åèšã®ã«ãŒãã³ãã©ãã¯ïœãïœ ãå2.0ïœïŒ
m2ãå«æããå±€ã
ãã¯ãé®å å±€ã«çšããããšã«ãããç»ååºçŸæé
ãççž®ããç¹ã«ïŒ²ã®DmaxãäžæããŠããããšã
ããããç¹ã«æ¬¡äºå¡©çŽ é žãœãŒãã§åŠçããã«ãŒã
ã³ãã©ãã¯ã¯ãã®çšåºŠãé¡èã§ãããäžã€Dmin
ãé¡èã«æžå°ããŠããããè¯å¥œãªè»¢åç»è³ªãäžã
ãããšããããã å®æœäŸ ïŒ å®æœäŸâïŒã®ã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€(3)
ãšã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©ãå«ãå±€(4)ã
äžäœåããŠäžèšã®åŠãæå ã·ãŒãïŒãïŒãäœã€
ãããã®ä»ã®å±€æ§æã¯å®æœäŸâïŒãšåãã§ããã äžäœåããå±€ã®çµæ å®æœäŸâïŒã®ã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©
0.44ïœïŒm2ãããªã·ã¯ãããã·ã«ãã¹ããšãŒã
0.09ïœïŒm2ãïŒïŒïŒâãžâïœâãã³ã¿ãã·ã«ãã€
ããããã³0.008ïœïŒm2ããŒã©ãã³2.0ïœïŒm2ãã
ãã³åèšã®ã«ãŒãã³ãã©ãã¯ïœãïœ ãå2.0ïœïŒ
m2ãå«æããå±€ã
ãè¡šã
å®æœäŸâïŒãšåãåŠçãè¡ãªããïŒæéåŸã®è»¢
åè²åã®ïŒ²ïŒïŒ§ïŒïŒ¢æ¿åºŠãæ±ããäžè¡šã®å€ãåŸ
ãã
åè²åã®ïŒ²ïŒïŒ§ïŒïŒ¢æ¿åºŠãæ±ããäžè¡šã®å€ãåŸ
ãã
ãè¡šã
ãã®è¡šãããåŠçãããŠããªãã«ãŒãã³ãã©ã
ã¯ïœ ã«èŒã¹ãé žååŠçãããã«ãŒãã³ãã©ãã¯
ã¯ãé«ãDmaxãšäœãDminãäžããããšããã
ããåŠçãããŠããªãã«ãŒãã³ãã©ãã¯ãçšãã
æå ã·ãŒãïŒã¯ãç¹ã«ïŒ²ã®Dminãé«ããããã
ã¯æ¬å®æœäŸã«ãããŠèµ€ææ§ä¹³å€å±€ãšã«ãŒãã³ãã©
ãã¯å±€ãæ¥ããŠããããã«çãããã®ã§ãããã
ãã«æ¯èŒããŠæ¬çºæã®ã«ãŒãã³ãã©ãã¯ã®æ¹è¯å¹
æã¯æããã§ããã å®æœäŸ ïŒ å®æœäŸâïŒã®ã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€(3)
ãšã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©ãå«ãå±€(4)ã
äžèšã®åŠãå€ããæå ã·ãŒãïŒåã³10ãäœã€ãã
ãã®ä»ã®å±€æ§æã¯å®æœäŸâïŒãšåãã§ããã
ã¯ïœ ã«èŒã¹ãé žååŠçãããã«ãŒãã³ãã©ãã¯
ã¯ãé«ãDmaxãšäœãDminãäžããããšããã
ããåŠçãããŠããªãã«ãŒãã³ãã©ãã¯ãçšãã
æå ã·ãŒãïŒã¯ãç¹ã«ïŒ²ã®Dminãé«ããããã
ã¯æ¬å®æœäŸã«ãããŠèµ€ææ§ä¹³å€å±€ãšã«ãŒãã³ãã©
ãã¯å±€ãæ¥ããŠããããã«çãããã®ã§ãããã
ãã«æ¯èŒããŠæ¬çºæã®ã«ãŒãã³ãã©ãã¯ã®æ¹è¯å¹
æã¯æããã§ããã å®æœäŸ ïŒ å®æœäŸâïŒã®ã«ãŒãã³ãã©ãã¯ãå«ãé®å å±€(3)
ãšã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©ãå«ãå±€(4)ã
äžèšã®åŠãå€ããæå ã·ãŒãïŒåã³10ãäœã€ãã
ãã®ä»ã®å±€æ§æã¯å®æœäŸâïŒãšåãã§ããã
ãè¡šã
å®æœäŸâïŒãšåãåŠçãè¡ãªããç»ååºçŸæé
åã³ïŒæéåŸã®è»¢åè²åã®ïŒ²ïŒïŒ§ïŒïŒ¢æ¿åºŠãæ±ã
ãã
åã³ïŒæéåŸã®è»¢åè²åã®ïŒ²ïŒïŒ§ïŒïŒ¢æ¿åºŠãæ±ã
ãã
ãè¡šã
æ¬å®æœäŸã®åŠããã«ãŒãã³ãã©ãã¯ãé®å
å±€ãš
ã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©å«æå±€ã«åå²ã
ãŠæ·»å ããå Žåãã匷å¶é žååŠçãããã«ãŒãã³
ãã©ãã¯ã¯ç»ååºçŸæéãDmaxïŒDminïŒç¹ã«
ïŒã«å¯ŸããŠæ¹è¯å¹æãèããããšããããã 以äžã«æ¬çºæã®å¥œãŸããå®æœæ æ§ãåèšããã
ãããã®ã¿ã«éå®ããããã®ã§ã¯ãªãã ïŒ éææ¯æäœãååå±€ãè²çŽ åäŸäžååç©ãšçµ
åããããããã²ã³åéä¹³å€å±€åã³åŠç液ãå
èµãããå§åã§ç Žå£å¯èœãªå®¹åšããå°ããšãæ
ãã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«ã ãŠãããã«
æŒãŠã匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã
第ïŒã®æ¯æäœãããã¯è©²ååå±€ãšããã²ã³åé
ä¹³å€å±€ã®éã®å±€äžããåã¯è©²åŠç液äžã«å«æã
ããŠããäºãç¹åŸŽãšããã«ã©ãŒæ¡æ£è»¢åæ³çšå
çãã€ã«ã ãŠãããã ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ãå«æ
ããå±€ãã匷å¶é žååŠçãããã«ãŒãã³ãã©ã
ã¯ã®ãŒã©ãã³âæ°Žåæ£ç©ãæ°ŽæŽããåŸã«å¡åžã
ãŠåœ¢æããããã®ã§ããäºãç¹åŸŽãšããå®æœæ
æ§ç¬¬ïŒé èšèŒã®ã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«
ã ãŠãããã ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ããã¬
ãŒã·ãšã³é²æ¢å±€ã«å«æãããŠãªãã·ãŠãªãã¬ãª
ãŒãç»åã圢æããæå ææã ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ããã
ã²ã³åéä¹³å€å±€ã«å«æãããã³ãããªãã¯ã¹ã»
ãã€ã«ã ã
ã·ã¢ã³è²çŽ æŸåºã¬ããã¯ã¹ååç©å«æå±€ã«åå²ã
ãŠæ·»å ããå Žåãã匷å¶é žååŠçãããã«ãŒãã³
ãã©ãã¯ã¯ç»ååºçŸæéãDmaxïŒDminïŒç¹ã«
ïŒã«å¯ŸããŠæ¹è¯å¹æãèããããšããããã 以äžã«æ¬çºæã®å¥œãŸããå®æœæ æ§ãåèšããã
ãããã®ã¿ã«éå®ããããã®ã§ã¯ãªãã ïŒ éææ¯æäœãååå±€ãè²çŽ åäŸäžååç©ãšçµ
åããããããã²ã³åéä¹³å€å±€åã³åŠç液ãå
èµãããå§åã§ç Žå£å¯èœãªå®¹åšããå°ããšãæ
ãã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«ã ãŠãããã«
æŒãŠã匷å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ã
第ïŒã®æ¯æäœãããã¯è©²ååå±€ãšããã²ã³åé
ä¹³å€å±€ã®éã®å±€äžããåã¯è©²åŠç液äžã«å«æã
ããŠããäºãç¹åŸŽãšããã«ã©ãŒæ¡æ£è»¢åæ³çšå
çãã€ã«ã ãŠãããã ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ãå«æ
ããå±€ãã匷å¶é žååŠçãããã«ãŒãã³ãã©ã
ã¯ã®ãŒã©ãã³âæ°Žåæ£ç©ãæ°ŽæŽããåŸã«å¡åžã
ãŠåœ¢æããããã®ã§ããäºãç¹åŸŽãšããå®æœæ
æ§ç¬¬ïŒé èšèŒã®ã«ã©ãŒæ¡æ£è»¢åæ³çšåçãã€ã«
ã ãŠãããã ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ããã¬
ãŒã·ãšã³é²æ¢å±€ã«å«æãããŠãªãã·ãŠãªãã¬ãª
ãŒãç»åã圢æããæå ææã ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ããã
ã²ã³åéä¹³å€å±€ã«å«æãããã³ãããªãã¯ã¹ã»
ãã€ã«ã ã
Claims (1)
- ïŒ åŒ·å¶é žååŠçãããã«ãŒãã³ãã©ãã¯ãå«æ
ããåçæå ææã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5642480A JPS56151935A (en) | 1980-04-28 | 1980-04-28 | Photographic sensitive material |
| GB8112958A GB2076170B (en) | 1980-04-28 | 1981-04-27 | Photographic light-sensitive material |
| DE19813116809 DE3116809A1 (de) | 1980-04-28 | 1981-04-28 | Lichtempfindliches photographisches material |
| US06/471,918 US4444866A (en) | 1980-04-28 | 1983-03-03 | Photographic light-sensitive material with forced oxidized carbon black |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5642480A JPS56151935A (en) | 1980-04-28 | 1980-04-28 | Photographic sensitive material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56151935A JPS56151935A (en) | 1981-11-25 |
| JPS6145223B2 true JPS6145223B2 (ja) | 1986-10-07 |
Family
ID=13026709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5642480A Granted JPS56151935A (en) | 1980-04-28 | 1980-04-28 | Photographic sensitive material |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4444866A (ja) |
| JP (1) | JPS56151935A (ja) |
| DE (1) | DE3116809A1 (ja) |
| GB (1) | GB2076170B (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5997142A (ja) * | 1982-11-26 | 1984-06-04 | Fuji Photo Film Co Ltd | æ¡æ£è»¢åçšåçèŠçŽ |
| US4450222A (en) * | 1982-12-20 | 1984-05-22 | Eastman Kodak Company | Use of carbon adsorption deactivating compounds in image transfer elements |
| US4471047A (en) * | 1982-12-20 | 1984-09-11 | Eastman Kodak Company | Use of carbon adsorption deactivating compounds in image transfer elements |
| US4489152A (en) * | 1984-02-29 | 1984-12-18 | Polaroid Corporation | Photographic product for silver transfer images with polyvinylpyrrolidone in carbon black layer |
| JPH0635688B2 (ja) * | 1986-09-30 | 1994-05-11 | æ±æŽã€ã³ã補é æ ªåŒäŒç€Ÿ | ããªãšã¹ãã«ç¹ç¶åççšé»è²æ¶²ç¶çè²å€ |
| US5408447A (en) * | 1992-07-15 | 1995-04-18 | Polaroid Corporation | Method and apparatus for scanning of image in integral film structure |
| JP3693726B2 (ja) * | 1995-12-04 | 2005-09-07 | ãªãªã±ã³ãååŠå·¥æ¥æ ªåŒäŒç€Ÿ | çèšæ¿çšæ°Žç³»é»è²ã€ã³ãçµæç© |
| JP6012927B2 (ja) * | 2007-04-24 | 2016-10-25 | ãã£ããã ã³ãŒãã¬ã€ã·ã§ã³ïŒ£ïœïœïœïœ ïœïœïœïœïœïœïœïœïœïœ | äœæ§é ã«ãŒãã³ãã©ãã¯ããã³ãã®äœè£œæ¹æ³ |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1447892A1 (de) * | 1962-05-14 | 1969-03-06 | Eastman Kodak Co | Photographisches Material sowie Verfahren zur Herstellung von Druckmatrizen aus diesem Material |
| US3900323A (en) * | 1973-10-23 | 1975-08-19 | Polaroid Corp | Photographic element comprising an opaque backcoat |
| US4076531A (en) * | 1975-07-30 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Image anchorage in photographic films |
| US4272594A (en) * | 1978-12-04 | 1981-06-09 | Polaroid Corporation | Photographic product including a light-reflecting layer with carbon coated with reflecting material |
-
1980
- 1980-04-28 JP JP5642480A patent/JPS56151935A/ja active Granted
-
1981
- 1981-04-27 GB GB8112958A patent/GB2076170B/en not_active Expired
- 1981-04-28 DE DE19813116809 patent/DE3116809A1/de not_active Withdrawn
-
1983
- 1983-03-03 US US06/471,918 patent/US4444866A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE3116809A1 (de) | 1982-03-11 |
| GB2076170B (en) | 1983-06-29 |
| US4444866A (en) | 1984-04-24 |
| JPS56151935A (en) | 1981-11-25 |
| GB2076170A (en) | 1981-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6145223B2 (ja) | ||
| JPH0612427B2 (ja) | åçéé¯å¡©æ¡æ£è»¢ååè»¢æ³ | |
| JPS6230619B2 (ja) | ||
| US4626494A (en) | Hardened color diffusion transfer photographic materials | |
| JPS6161099B2 (ja) | ||
| JPS5854381B2 (ja) | ã«ã©âã«ã¯ãµã³ãã³ã·ã€ãšãŠã·ã€ã·ã³ã¶ã€ãªãšãŠ | |
| JPS6147414B2 (ja) | ||
| US4511643A (en) | Color diffusion transfer photographic element | |
| JPS63286846A (ja) | åçææã®åŠçæ¹æ³ | |
| JPS6147413B2 (ja) | ||
| JPS6319849B2 (ja) | ||
| JPH0612426B2 (ja) | éé¯å¡©æ¡æ£è»¢åæ³ã«ããé£ç¶è²èª¿éåã®è£œé æ³ããã³ææ | |
| JPS5845697B2 (ja) | ã«ã©âã·ã€ã·ã³ã«ã³ã³ãŠã¶ã€ãªãšãŠ | |
| JP3122140B2 (ja) | åçåŠçæ¹æ³åã³åçåŠçææ | |
| JPS5931700B2 (ja) | åçéæäœ | |
| CA1119871A (en) | Alkaline processing compositon containing a saturated, aliphatic w-amino acid or a mixture of a saturated carboxylic acid and a primary amine | |
| JP3136224B2 (ja) | éå¡©æ¡æ£è»¢åæ³ | |
| GB1564065A (en) | Photographic silver halide colour diffusion transfer film units | |
| JPS6245542B2 (ja) | ||
| JP3351896B2 (ja) | ã«ã©ãŒæ¡æ£è»¢åæ³çšç»å圢ææ¹æ³ | |
| JPH01106051A (ja) | ã«ã©ãŒæ¡æ£è»¢åæ³çšåçèŠçŽ | |
| JP2816622B2 (ja) | éå¡©æ¡æ£è»¢ååŠçæ³ | |
| JPS60220335A (ja) | ç»å圢ææ³ | |
| JP2002107890A (ja) | é žåãã¿ã³å«ææ°Žåæ£ç©ããã³ã«ã©ãŒæ¡æ£è»¢ååçãã€ã«ã ãŠããã | |
| GB2070795A (en) | Photographic process |