JPS62192560A - Amorphous alloy foil for magnetic core excellent in space factor and its production - Google Patents

Amorphous alloy foil for magnetic core excellent in space factor and its production

Info

Publication number
JPS62192560A
JPS62192560A JP61032854A JP3285486A JPS62192560A JP S62192560 A JPS62192560 A JP S62192560A JP 61032854 A JP61032854 A JP 61032854A JP 3285486 A JP3285486 A JP 3285486A JP S62192560 A JPS62192560 A JP S62192560A
Authority
JP
Japan
Prior art keywords
amorphous alloy
space factor
magnetic core
ribbon
foil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61032854A
Other languages
Japanese (ja)
Other versions
JPH0742559B2 (en
Inventor
Hiroshi Shishido
宍戸 浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP61032854A priority Critical patent/JPH0742559B2/en
Publication of JPS62192560A publication Critical patent/JPS62192560A/en
Publication of JPH0742559B2 publication Critical patent/JPH0742559B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/147Alloys characterised by their composition
    • H01F1/153Amorphous metallic alloys, e.g. glassy metals
    • H01F1/15308Amorphous metallic alloys, e.g. glassy metals based on Fe/Ni

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

PURPOSE:To manufacture an amorphous alloy foil for magnetic core excellent in space factor, by subjecting a molten alloy having a specific composition in which trace amounts of Cr, Mo, etc., are added to an Fe-Si-B alloy to solidifi cation by rapid cooling and by applying proper surface smoothing treatment to the surface of the above foil. CONSTITUTION:An amorphous alloy foil is manufactured from the molten alloy having a composition represented by a chemical formula Fe100-x-y-zBxSiyMz (where M means one or two elements among Cr, Mo, Ta, Mn, Ni, Co, V, Nb, and W, (x) is 5-20at%, (y) is 5-20at%, and (z) is 0.05-5at%) by means of a method of solidification by rapid cooling. Then surface smoothing treatment such as light rolling treatment, polishing treatment, etc., is applied to the above foil to finish the surface of above-mentioned thin film into <=0.4mum surface roughness Ra. In this way, space factor is improved into at least about 85% or above, so that amorphous alloy foil can be obtained.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、磁心すなわちトランスの鉄心等の用途に用
いて好適な磁心用非晶質合金薄帯およびその製造方法に
関し、とくに占積率の有利な向上を図ったものである。
[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to an amorphous alloy ribbon for a magnetic core, which is suitable for use as a magnetic core, i.e., the iron core of a transformer, and a method for manufacturing the same. This is an advantageous improvement.

(従来の技術) 非晶質合金とりわけ磁気特性に優れたPa系非晶質合金
は、トランス等の磁心材料として有望視されていて、最
近では配電トランス用としてフィールド・テストが行わ
れるなど実用化の直前段階にある。   ゛ かかる非晶質合金としては、特開昭54−148122
号や同55−94460号各公報に開示されているよう
なFe−3i−B系合金があり、周知のように、高速で
回転する冷却ロールなどの冷却体を用いて溶融状態の合
金を直接冷却して薄帯とするいわゆる急冷凝固法によっ
て製造される。
(Prior art) Amorphous alloys, especially Pa-based amorphous alloys with excellent magnetic properties, are seen as promising magnetic core materials for transformers, etc., and have recently been put into practical use, with field tests being conducted for use in power distribution transformers. It is at the stage immediately before. ``Such an amorphous alloy is disclosed in Japanese Patent Application Laid-Open No. 54-148122.
There are Fe-3i-B alloys, such as those disclosed in Japanese Patent No. 55-94460. It is manufactured by a so-called rapid solidification method in which it is cooled into a thin ribbon.

(発明が解決しようとする問題点) ところでかような方法で製造された板を用いてトランス
磁心を作製したときの欠点の1つとして、積層した場合
における占積率の低下が挙げられる。
(Problems to be Solved by the Invention) One of the drawbacks of producing a transformer core using plates manufactured by such a method is a decrease in space factor when laminated.

今まで試作されたトランスの占積率は78〜85%であ
り、従来のけい素鋼板を用いた場合のそれが98%前後
であるのと比べると大幅に劣る。
The space factor of the transformers prototyped so far is 78 to 85%, which is significantly inferior to the 98% or so obtained when conventional silicon steel plates are used.

かかる占積率の低下は、磁心において同一の磁気回路的
効果を得ようとする場合に、磁心の体積を増加せざるを
得ないという弊害を招いていた。
Such a decrease in the space factor has caused the disadvantage that the volume of the magnetic core must be increased if the same magnetic circuit effect is to be obtained in the magnetic core.

また占積率の低下は、表面あらさが大きいことがその一
因であるが、表面あらさが大きいと板同志の接触が不均
一となって接触部の接触電気抵抗が増大するため、そこ
に熱が集中し、磁心を破損するおそれもあった。
In addition, one of the reasons for the decrease in the space factor is the large surface roughness, but when the surface roughness is large, the contact between the plates becomes uneven and the electrical contact resistance of the contact area increases, so heat is generated there. There was also a risk that the particles would concentrate and damage the magnetic core.

この発明は、上記の問題を有利に解決するもので、表面
粗度調整によって占積率を少なくとも85%以上にさせ
た非晶質合金薄帯を、その有利な製造方法と共に提案す
ることを目的とする。
The purpose of this invention is to advantageously solve the above-mentioned problems, and to propose an amorphous alloy ribbon with a space factor of at least 85% or more by adjusting the surface roughness, together with an advantageous manufacturing method thereof. shall be.

(問題点を解決するための手段) さてこの発明では、非晶質合金薄帯の占積率を向上させ
るために、薄帯の表面粗度調整を行うわけであるが、一
般に非晶質合金は硬いこともあって表面加工は難しい。
(Means for solving the problem) In the present invention, the surface roughness of the amorphous alloy ribbon is adjusted in order to improve the space factor of the amorphous alloy ribbon. It is difficult to process the surface because it is hard.

そこでこの発明では、Fe−5t−83元系合金に加工
性を向上させる元素を微量添加し、加工性を改善した上
で、表面平滑化処理を施すことによって、少なくとも8
5%の占積率を実現したのである。
Therefore, in this invention, a trace amount of an element that improves the workability is added to the Fe-5t-83 element alloy to improve the workability, and then surface smoothing treatment is performed to improve the workability of the Fe-5t-83 element alloy.
They achieved a occupancy rate of 5%.

すなわちこの発明は、 化学式:Fe1oo−に−y−2B)ISiJzここで
M:Cr、Mo、Ta、Mn、Ni。
That is, this invention has the following chemical formula: Fe1oo-y-2B)ISiJz where M: Cr, Mo, Ta, Mn, Ni.

Co、V、NbおよびWのうちから 選んだ一種または二種 x:5〜20a t% y : 5〜20a t% z  : 0.05〜5 at% で示される組成になる非晶質合金薄帯であって、該薄帯
の表面あらさが平均あらさRaで0. 4μm以下であ
る、占積率の優れた磁心用非晶質合金薄帯である。
One or two selected from Co, V, Nb and W x: 5 to 20 at% Y: 5 to 20 at% Z: 0.05 to 5 at% Amorphous alloy thin The ribbon has an average roughness Ra of 0. This is an amorphous alloy ribbon for magnetic cores with an excellent space factor of 4 μm or less.

またこの発明は、 化学式: Fe100−x−v−zBxSiyMzここ
でM:Cr、Mo、Ta、Mn、Ni。
Moreover, this invention has the following chemical formula: Fe100-x-v-zBxSiyMz where M: Cr, Mo, Ta, Mn, Ni.

Co、V、NbおよびWのうちから 選んだ一種または二種 X : 5〜20at% y:5〜20at% Z : 0.05〜5 at% で示される組成になる合金溶湯から、急冷凝固法によっ
て非晶質合金薄帯を作製したのち、表面平滑化処理を施
して該薄帯の表面を平均あらさRaで0.4μm以下に
仕上げることを特徴とする占積率の優れた磁心用非晶質
合金薄帯の製造方法である。
One or two selected from Co, V, Nb and W An amorphous alloy ribbon for a magnetic core having an excellent space factor, characterized in that an amorphous alloy ribbon is prepared by the above method, and then subjected to a surface smoothing treatment to finish the surface of the ribbon to an average roughness Ra of 0.4 μm or less. This is a method for producing quality alloy ribbon.

以下この発明を具体的に説明する。This invention will be specifically explained below.

まずこの発明において成分組成を上記の範囲に限定した
理由について説明する。
First, the reason why the component composition is limited to the above range in this invention will be explained.

B:5〜20% B含有量が5%に満たなかったり20%を超えたりする
と、室温では非晶質合金化が著しく困難となるので、5
〜20%の範囲に限定した。
B: 5-20% If the B content is less than 5% or exceeds 20%, it will be extremely difficult to form an amorphous alloy at room temperature.
It was limited to a range of ~20%.

Si:5〜20% Si含有量が5%より少ないと非晶質合金化したときに
優れた磁気特性が得られず、一方20%より多くなると
非晶質合金化が困難になり、しかもかりに非晶質合金化
したとしても飽和磁束密度が低下するので、Si含有量
は5〜20%の範囲に限定した。
Si: 5-20% If the Si content is less than 5%, excellent magnetic properties cannot be obtained when forming an amorphous alloy, while if it exceeds 20%, it becomes difficult to form an amorphous alloy, and Since the saturation magnetic flux density decreases even if an amorphous alloy is formed, the Si content is limited to a range of 5 to 20%.

記号Mで示したCr、Mo、Ta、Mn、Ni。Cr, Mo, Ta, Mn, and Ni indicated by the symbol M.

Co、V、NbおよびWはいずれも加工性を向上させる
元素として均等である。しかしながら上記の各元素を単
独で使用する場合および併用いずれの場合においても、
添加量が0.05%より少ないと圧延に対する顕著な効
果は得られず、一方5%より多くても加工性はともかく
飽和磁束密度を低下させ、磁心材料として不適当になる
ので添加量は0.05〜5%の範囲に限定した。
Co, V, Nb, and W are all elements that improve workability. However, when each of the above elements is used alone or in combination,
If the amount added is less than 0.05%, no significant effect on rolling will be obtained, while if it is more than 5%, it will reduce the saturation magnetic flux density, apart from the workability, making it unsuitable as a magnetic core material, so the amount added is 0. It was limited to a range of .05 to 5%.

上記のような好適成分組成に調製した合金溶湯から、急
冷凝固法によって非晶質合金薄帯を作製するのであるが
、急冷凝固ままの薄帯の表面は荒れているため、そのま
までは十分満足のいく鉄損特性は得られない。
An amorphous alloy ribbon is produced by a rapid solidification method from a molten alloy prepared to have a suitable composition as described above, but since the surface of the ribbon as rapidly solidified is rough, it is not completely satisfactory as it is. It is not possible to obtain good iron loss characteristics.

そこでこの発明では、急冷凝固後に表面平滑化処理を施
して、薄帯の表面あらさを平均あらさRaで0.4 μ
m以下に仕上げるのである。
Therefore, in this invention, a surface smoothing treatment is performed after rapid solidification to reduce the surface roughness of the ribbon to an average roughness Ra of 0.4 μm.
It is finished to be less than m.

第1図に、単ロール法で作製したFeytSi+5Bq
V+組成の非晶質合金薄帯を種々の表面あらさに粗度調
整したものについて、エプスタインサイズに切出し、そ
れぞれ400枚重ねたものについての占積率と表面平均
あらさRaとの関係について調べた結果を示す。なお通
常の単ロール法で得られた非晶質合金薄帯の表面あらさ
ば、ロール面側で0.8μm程度、自由面で1.2μl
程度である。
Figure 1 shows FeytSi+5Bq produced by the single roll method.
The results of investigating the relationship between the space factor and the average surface roughness Ra for V+ composition amorphous alloy ribbons with various surface roughnesses cut to Epstein size and stacked with 400 sheets. shows. The surface roughness of the amorphous alloy ribbon obtained by the normal single roll method is approximately 0.8 μm on the roll side and 1.2 μl on the free side.
That's about it.

同図より明らかなように、表面平均あらさRaが0.4
μm以下であれば、85%以上の高い占積率が得られた
As is clear from the figure, the average surface roughness Ra is 0.4.
When the thickness was less than μm, a high space factor of 85% or more was obtained.

(作 用) 表面平滑化処理としては、冷間や温間における軽圧延処
理、ならびに化学研磨、電解研磨およびパフ研磨などの
研磨処理が有利に適合する。
(Function) As the surface smoothing treatment, cold or warm light rolling treatment, and polishing treatment such as chemical polishing, electrolytic polishing, and puff polishing are advantageously suitable.

なお温間圧延で表面あらさの粗度調整を行う場合、処理
温度が300℃を超えると合金成分によっては結晶化を
生じて本来の優れた磁気特性が得られない場合があるの
で、300℃以下の温度域で処理する必要がある。
When adjusting the surface roughness by warm rolling, if the processing temperature exceeds 300°C, some alloy components may crystallize and the original excellent magnetic properties may not be obtained, so the treatment temperature should not exceed 300°C. It is necessary to process in a temperature range of

(実施例) 実施例 1 表1に示す成分組成に調製した溶融合金を単ロール法に
て急冷凝固させて非晶質合金薄帯とした。
(Examples) Example 1 A molten alloy prepared to have the composition shown in Table 1 was rapidly solidified by a single roll method to obtain an amorphous alloy ribbon.

急冷凝固後の薄帯の板厚は25〜29μ清、また表面平
均あらさRaは0.8〜1.1 μmであった。
The thickness of the ribbon after rapid solidification was 25 to 29 μm, and the average surface roughness Ra was 0.8 to 1.1 μm.

これらの薄帯に対して、圧下率15%付近の冷間圧延を
施して表1に示す各表面平均あらさRaに仕上げた。
These ribbons were cold rolled at a rolling reduction of around 15% to give each surface an average roughness Ra shown in Table 1.

かくして得られた製品薄帯の圧延前、後における占積率
について調べた結果を表1に併記する。
Table 1 also shows the results of investigating the space factor of the thus obtained product ribbon before and after rolling.

表  1 同表より明らかなように、この発明に従い、急冷凝固後
に冷間圧延による表面平滑化処理を施して表面平均あら
さRaを0.4μm以下に調整した場合には、占積率の
大幅な向上が達成されている。
Table 1 As is clear from the same table, when the surface smoothing treatment by cold rolling is performed after rapid solidification according to the present invention to adjust the surface average roughness Ra to 0.4 μm or less, the space factor significantly increases. Improvements have been achieved.

またこのとき冷延性も良好であった。Moreover, cold rollability was also good at this time.

実施例 2 表2に示す成分組成に調製した溶融合金を単ロール法に
て急速に凝固させて非晶質合金薄帯を作成した。このと
きの板厚は25〜29μm、また表面平均あらさRaは
0.8〜1.1 μmであった。これらの薄帯に200
℃での温間圧延を平均圧下率10〜40%の範囲で施し
て、表2に示す平均あらさRaに仕上げた。
Example 2 A molten alloy prepared to have the composition shown in Table 2 was rapidly solidified by a single roll method to produce an amorphous alloy ribbon. The plate thickness at this time was 25 to 29 μm, and the average surface roughness Ra was 0.8 to 1.1 μm. 200 on these thin strips
Warm rolling at °C was performed at an average rolling reduction of 10 to 40% to give the average roughness Ra shown in Table 2.

かくして得られた製品薄帯の圧延前、後における占積率
についての測定結果を表2に併記する。
Table 2 also shows the measurement results for the space factor before and after rolling of the product ribbon thus obtained.

実施例 3 表3に示す組成を示す溶湯合金を急冷凝固させて非晶質
合金とした。このときの板厚は25〜28μmの範囲に
あった。これらの材料に対して、過酸化水素とりん酸を
主体とする液で化学研磨を施して、表3に示す板厚とし
たのち380℃で1時間“の焼鈍を行ないその後冷却し
た。
Example 3 A molten alloy having the composition shown in Table 3 was rapidly solidified to obtain an amorphous alloy. The plate thickness at this time was in the range of 25 to 28 μm. These materials were chemically polished with a solution mainly containing hydrogen peroxide and phosphoric acid to obtain the plate thicknesses shown in Table 3, and then annealed at 380° C. for 1 hour and then cooled.

かくして得られた非晶質合金薄帯についての特性を表3
に併記した。
Table 3 shows the properties of the amorphous alloy ribbon thus obtained.
Also listed.

(発明の効果) かくしてこの発明によれば、急冷凝固法により得られた
非晶質合金薄帯の占積率を大幅に向上させることができ
、磁気特性の向上が図れるのみならず、電磁機器の小型
化にも大きく貢献する。
(Effects of the Invention) Thus, according to the present invention, it is possible to significantly improve the space factor of the amorphous alloy ribbon obtained by the rapid solidification method, which not only improves the magnetic properties but also improves electromagnetic equipment. It also greatly contributes to the miniaturization of

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、Fet、5itJqV+非晶質合金薄帯の表
面平均あらさRaと占積率との関係を示したグラフであ
る。
FIG. 1 is a graph showing the relationship between the surface average roughness Ra and the space factor of Fet, 5itJqV+amorphous alloy ribbon.

Claims (1)

【特許請求の範囲】 1、化学式:Fe_1_0_0_−_x_−_y_−_
zB_zSi_yM_zここでM:Cr、Mo、Ta、
Mn、Ni、Co、V、NbおよびWのうち から選んだ一種または二種 x:5〜20at% y:5〜20at% z:0.05〜5at% で示される組成になる非晶質合金薄帯であって、該薄帯
の表面あらさが平均あらさRaで0.4μm以下である
、占積率の優れた磁心用非晶質合金薄帯。 2、化学式:Fe_1_0_0_−_x_−_y_−_
zB_xSi_yM_zここでM:Cr、Mo、Ta、
Mn、Ni、Co、V、NbおよびWのうち から選んだ一種または二種 x:5〜20at% y:5〜20at% z:0.05〜5at% で示される組成になる合金溶湯から、急冷凝固法によっ
て非晶質合金薄帯を作製したのち、表面平滑化処理を施
して該薄帯の表面を平均あらさRaで0.4μm以下に
仕上げることを特徴とする占積率の優れた磁心用非晶質
合金薄帯の製造方法。
[Claims] 1. Chemical formula: Fe_1_0_0_-_x_-_y_-_
zB_zSi_yM_z where M: Cr, Mo, Ta,
One or two selected from Mn, Ni, Co, V, Nb and W x: 5 to 20 at% y: 5 to 20 at% z: 0.05 to 5 at% Amorphous alloy An amorphous alloy ribbon for a magnetic core, which is a ribbon and has an average surface roughness Ra of 0.4 μm or less, and has an excellent space factor. 2. Chemical formula: Fe_1_0_0_-_x_-_y_-_
zB_xSi_yM_z where M: Cr, Mo, Ta,
One or two selected from Mn, Ni, Co, V, Nb and W. x: 5 to 20 at% y: 5 to 20 at% z: 0.05 to 5 at%. A magnetic core with an excellent space factor, characterized in that an amorphous alloy ribbon is produced by a rapid solidification method, and then subjected to surface smoothing treatment to finish the surface of the ribbon to an average roughness Ra of 0.4 μm or less. A method for producing amorphous alloy ribbon for use.
JP61032854A 1986-02-19 1986-02-19 Amorphous alloy ribbon for magnetic core with excellent space factor and method for producing the same Expired - Fee Related JPH0742559B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61032854A JPH0742559B2 (en) 1986-02-19 1986-02-19 Amorphous alloy ribbon for magnetic core with excellent space factor and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61032854A JPH0742559B2 (en) 1986-02-19 1986-02-19 Amorphous alloy ribbon for magnetic core with excellent space factor and method for producing the same

Publications (2)

Publication Number Publication Date
JPS62192560A true JPS62192560A (en) 1987-08-24
JPH0742559B2 JPH0742559B2 (en) 1995-05-10

Family

ID=12370423

Family Applications (1)

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Country Status (1)

Country Link
JP (1) JPH0742559B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62226602A (en) * 1986-03-28 1987-10-05 Hitachi Metals Ltd High space factor low loss amorphous magnetic core
JPH02194503A (en) * 1989-01-23 1990-08-01 Tdk Corp Core for noise filter
EP0787814A1 (en) 1996-01-31 1997-08-06 Kawasaki Steel Corporation Low boron amorphous alloy and process for producing same
KR100358592B1 (en) * 1994-11-23 2003-01-29 가와사끼 세이데쓰 가부시키가이샤 Iron amorphous alloy with excellent magnetic properties and excellent fracture resistance and its manufacturing method
KR100360762B1 (en) * 1995-05-18 2003-02-11 가와사끼 세이데쓰 가부시키가이샤 Iron Amorphous Alloy Strip for Winding Trans
CN114360883A (en) * 2021-12-31 2022-04-15 华南理工大学 High-magnetic-induction magnetic powder core based on amorphous crystallization dual-functional elements and preparation method and application thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62226602A (en) * 1986-03-28 1987-10-05 Hitachi Metals Ltd High space factor low loss amorphous magnetic core
JPH02194503A (en) * 1989-01-23 1990-08-01 Tdk Corp Core for noise filter
KR100358592B1 (en) * 1994-11-23 2003-01-29 가와사끼 세이데쓰 가부시키가이샤 Iron amorphous alloy with excellent magnetic properties and excellent fracture resistance and its manufacturing method
KR100360762B1 (en) * 1995-05-18 2003-02-11 가와사끼 세이데쓰 가부시키가이샤 Iron Amorphous Alloy Strip for Winding Trans
EP0787814A1 (en) 1996-01-31 1997-08-06 Kawasaki Steel Corporation Low boron amorphous alloy and process for producing same
US6273967B1 (en) 1996-01-31 2001-08-14 Kawasaki Steel Corporation Low boron amorphous alloy and process for producing same
CN114360883A (en) * 2021-12-31 2022-04-15 华南理工大学 High-magnetic-induction magnetic powder core based on amorphous crystallization dual-functional elements and preparation method and application thereof
CN114360883B (en) * 2021-12-31 2022-11-01 华南理工大学 High-magnetic-induction magnetic powder core based on amorphous crystallization dual-functional elements and preparation method and application thereof

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