JPS62196659A - Processing method for silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To decrease the volume of rinsing water by processing a silver halide color photographic sensitive material contg. a specific magenta coupler under specified conditions. CONSTITUTION:The silver halide color photographic sensitive material contains at least one kind of the magenta coupler expressed by formula I or formula II. The silver halide color photographic sensitive material for photographic subjected to imagewise exposing is immediately processed in a stabilizing bath contg. 2X10<-3>-10X10<-3>mol/l aldehyde compd. with substantially no rinsing stage after the processing in a bath provided with fixing capacity. The bath having fixing capacity contains 4X10<-2>-0.25mol/l sulfite ions. The amt. of the stabilizing bath to be replenished is 0.5-60 times the amt. to be carried over per unit surface area of the photosensitive material. The volume of the rinsing water is thereby decreased.

Description

Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a method for processing silver halide color photographic materials for photographing, and more specifically, to a method for processing a silver halide color photographic material for photographing, and more specifically, to
, and a treatment method in which the amount of washing water is significantly reduced.

(Prior Art) In recent years, many studies have been carried out with the aim of simplifying the processing by reducing the number of processing solutions used in the processing of silver halide color photographic materials. Ta.

In particular, in the processing of silver halide color photographic materials for photography, the process is completed by color development, bleaching, fixing or bleach-fixing, and further washing with water, but the uniformity of drying after processing and the dye image In order to ensure storage stability, it is often necessary to use a stabilizing bath as a final step after the water washing step.

Among the dye images of color photographic materials, magenta dyes (azomethine dyes) in particular are published in the Journal of the American Chemical Society (J.

Am, Chem, Soc, ) Volume 72, No. 1131.
Page ~ / As described on page 131 (luri!0) (,
It is known that dye images react with residual pyrazolone couplers and discolor, resulting in significant damage to the storage stability of dye images.

Of course, various improvement methods have been proposed in the past for such problems, such as U.S. Patent No. 314017.
No. 7 discloses a method for preventing fading of the magenta dye by treating it with an ammonium bath containing formaldehyde or acetaldehyde and an organic acid such as citric acid. Additionally, U.S. Patent No. 3671. /31. US Pat. No. 2,021,013 discloses a stabilizing bath containing an adduct of an aldehyde and bisulfite, and US Pat. The specification of No. 62 discloses a method of processing in a stabilizing bath containing formaldehyde, sodium chloride, and acetic acid, and proposes methods for improving storage stability and drying uniformity of magenta dye images, respectively. .

The aldehydes contained in these stabilizing baths are
Applied Photographic Engineering (J
,Appl,Photo,Engji,t(e)200
As described on pages 207 to 207, it is extremely effective in preventing fading of magenta dye images.

On the other hand, methods for reducing the amount of water used in the washing process by expanding the amount of water used in the washing process are described in Japanese Patent Application Publication No. 17-4Jμ3, No. 71-ta mO, No. 7-/7j Hiro-O, No. 24133, No. 24133, No. 7-J. ter itr
Ko 3 Ko 3, Ko 6O-23rrJx, and 60-2
It is described in No. 42/61 etc. However, in the processing of silver halide color photographic light-sensitive materials for photography, a stabilizing bath containing formalin as described above is present in the final bath, and this stabilizing bath is used as a pre-bath in the water washing process. When you let it flow, it's Tokukai Akira! As described in Tar λ6j No. 33, since precipitation occurs, the stabilizing bath and the replenishing solution for the washing process, which is a pre-bath, must be separated, and a new replenishing solution is required to perform water-saving treatment. It had the disadvantage of becoming

(Objective of the Invention) Therefore, an object of the present invention is to provide a method for saving water without increasing the number of processing solutions in the processing of silver halide color 7 photographic light-sensitive materials. Our goal is to provide a treatment method that integrates the washing process and stabilization process without impairing the properties of the product.

(Structure of the Invention) It has been found that the above object can be achieved by the following method.

(11) After processing the imagewise exposed silver halide color photographic light-sensitive material in a bath having fixing ability, the aldehyde compound is immediately removed from the 2
1. A method for processing a silver halide color photographic light-sensitive material, which comprises processing in a stabilizing bath containing from x10'' to 10 x 103 mol/l.

(2) The halogen compound color photograph according to configuration (1) of the invention, characterized in that the bath having fixing ability contains 4(X/0-2 to 0.21 m06/l) as sulfite ions. How to process photosensitive materials.

(3) The silver halide color photograph according to configuration (2) of the invention, characterized in that the replenishment 1 of the stabilizing bath is 0.5 to 60 times the amount brought in per photosensitive material area. How to process photosensitive materials.

(4) Structure of the invention characterized in that the silver halide color photographic light-sensitive material contains at least one magenta coupler represented by the following general formula (I) or (II), item (1) A method for processing a silver halide color photographic light-sensitive material as described in .

General formula [■] (In the general formula (IJ, %R1 represents a hydrogen atom or a substituent. Za%zb and Zc represent methine, substituted methine, = to or -NH-, and Za-Zb bond and Z
One of the bZc bonds is a double bond and the other is a single bond. The case where Zb-Zc is a carbon-carbon double bond includes the case where it is part of an aromatic ring. Furthermore, when Za, Zb or Zc is a substituted methine, the case where the substituted methine forms a multimer of λ-mer or more is also included. ) General formula (
IIJ (In the formula, R2 represents a carbonamide group or a ureido group, and R3 represents a phenyl group.) In the present invention, the amount of aldehyde used in the stabilizing bath is from l/-2 to l/-2, which is the conventionally used amount. It is surprising that image storage stability was not impaired even at such a low concentration of /μ by unifying the water washing step and the stabilization step.

In JP-A-17-4 juJ, color photographic paper is stabilized by containing a small amount of formalin, but in this case, yellow stain occurs over time after the treatment, and this is by no means the preferred method. Furthermore, there is no mention of the magenta coupler used in the present invention.

Furthermore, the stability of the stabilizing solution was greatly improved by reducing the aldehyde concentration and the concentration of sulfite ions in the pre-bath, which has the fixing ability, at night by containing Hiroshi XIO mole/1 or more. is no longer generated.

Next, general formula [1] will be explained in detail.
In H, R1 represents a hydrogen atom or a substituent. Za
, Zb and Zc represent methine, substituted methine, =H- or 1~H-, and one of the Za-Zb bond and the Zb-Zc bond is a double bond, and the other is a single bond. Zb
The case where -Zc is a carbon-carbon double bond includes the case where it is part of an aromatic ring. Also, Za, Zb, or Zc
When is a substituted methine, it also includes the case where the substituted methine forms a polymorphic form of λ-mer or more.

Furthermore, it also includes the case where R1 forms a multimer of 2 blue bodies or more.

In the general formula CI), a multimer means one having two or more groups represented by the general formula (N) in the molecule, and also includes bis forms and polymer couplers.Here, Polymer coupler h may be a homopolymer consisting only of a monomer (preferably one having a vinyl group, hereinafter referred to as vinyl monomer) having a moiety represented by the general formula CI, l, or an aromatic-class amine group (1). Copolymers may be made with non-chromogenic ethylene-like monomers that do not couple with the oxidation products.

The compound represented by the general formula (IJ) is a tri!-membered fM-r-membered ring fused nitrogen heterocyclic coupler, and its color-forming nucleus exhibits isoelectronic aromaticity with naphthalene, and its chemical structure is generally referred to as azapentalene. The general formula [IJ
Preferred compounds among the couplers represented by are lH-
imidazo[/, 2-bJ pyrazoles, lH-pyrazolo[/, j-bJ pyrazoles, lH-pyrazolo[! ,1
-c)(/.

λ, Hiro] triazoles, /) i-pyrazolo (/.

j-b) (/, 2.4J) lyazoles, lH-pyrazolo(/, t-dJ tetrazoles and lH-pyrazolo(
/, j-aJ benzimidazoles, each with the general formula [■No-2CI)-j(N-Hiro(1)-yo(IJ
-4 and (IJ-7). Among these, particularly preferred compounds are (IJ-2, (TJ-μ, CI)--
It is t.

(N-λ (IJ-3 R4R4 (1)-μ (IJ-j(I)-A
(IJ-7 general formula (1,1-2~CI)
The substituents R4, R5 and R6 up to -7 are hydrogen atoms, halogen atoms, alkyl groups, aryl groups, heterocyclic groups, cyano groups, alkokyne groups, aryloxy groups, heterocyclic ocy groups, acyloxy groups, carbamoyl Oxy group, 7lyloxy group, sulfonyloxy group, acylamino group, anilino group, ureido group, imido group, sulfamoylamino group, carbamoylamino group, argylthio group, arylthio group, heterocyclic thio group, alkoxycarminylamino group, aryl group, carponylamino group, sulfonamide group, carbamoyl group, anru group, sulfamoyl group,
Represents a sulfonyl group, sulfinyl group, alkoxycarbonyl group, or aryloxycarbonyl group.

R4, R5s R6 becomes a divalent group to form a bis body. In addition, the general formula (IJ-2~Cl3
When the moiety represented by -7 is in a vinyl monopole, R4s R5 or R6 represents a simple bond or linking group, through which the general formula (IJ-λ~(IJ-7
The moiety represented by is bonded to the vinyl group.

More specifically, R4, R5, and R6 are hydrogen atoms, halogen atoms (e.g., chlorine atom, bromine atom, etc.), alkyl groups (e.g., methyl group, propyl group, t-gutyl group, trifluoromethyl group, tridecyl group). , J-(J, 4
4-di-t-amylphenoquine imbrovir group, λ-dodenluoki7ethyl group, 3-phenoxypropyl group, λ-
hexylsulfonyl-ethyl group, cyclopentyl group, benzyl group, etc.), aryl group (e.g. phenyl group, μ
-1-butylphenyl group, 2. u-di-t-amylphenyl group, Hiro-tetradecanamidophenyl group, etc.), heterocyclic groups (e.g., λ-furyl group, λ-chenyl group, λ
-pyrimidinyl group, copenzothiazolyl group, etc.), 7
7 groups, alkokene groups (e.g., metoxy group, etkyne group, comethoxyethoxy group, λ-dodecyloxyethoxy group, comethanesulfonylethoxy group, %), aryloxy groups (e.g., phenoxy group, λ -methylphenol groups, <4-i-butylphenoxy groups, etc.), heterocyclic groups (e.g., cobenzimidazolyl groups, etc.), acyloxy groups (e.g., acetoxy groups,
7 hexadecanoyl groups, etc.), 7 carbamoyl groups
groups (e.g., hephenyl-rubamoyl-7 groups, he-ethyl-rubamoyl-7 groups, etc.), 7-ruruoki-7 groups (
For example, trimethylsilyloxy group, etc.), sulfonyloxy group (e.g., t, dodecylsulfonyloxy group, I
), afuramino group (e.g., acetamide group, benzamide group, tetradecanamide group, α-(2゜Hiro-di-
t-amylphenoxy)butyramide group, r-(J-t
-7'thyl-μmhydroquinphenoxy)butyramide group, α-(Hiro-(Hiro-hydroquinphenylsulfonyl)
(phenoxy)tecanamide L, etc.), anilino group (e.g. phenylamino group, λ-chloroani+)/group, 2-"Rolow J--y-tradecanamide anilino group, λ-chloro-1-dodefluoroxylponylanilino group, ～−
7-+ = tylanilino group, cochrolow j-(α-(3
-1-butyl-μm hydroxyphenoxy)dodecanamido)anilino group, etc.), ureido group (e.g., phenylureido group, methylureido group, etc.).

dibutyl ureido group, etc.), imide group (e.g., haeskunnimide group, 3-penzylhydantoynyl group,
μm (2-ethylhexanoylamino)phthalimide group, etc.), sulfamoylamino group (e.g., he,N-dipropylsulfamoylamino group, IN-methyl-he-defursulfamoylamino group, etc.), alkylthio groups (e.g., methylthio group, octylthio group, tetradecylthio group, coffee diethylthio group, 3-phenoxypropylthio group, J-(4C-i-butylphenoxy)propylthio group, etc.), Arylthio groups (e.g.
phenylthio group, 7-j-t-octylphenylthio group, 3-pentadecylferthio group, cocarpo-diphenylthio group, μm tetradecanamidophenylthio group, etc.), heterocyclic thio group (e.g., -1penzodiphenylthio group, etc.), thiazolylthio group, etc.), alkoxycarbonylamino group (e.g., methoxycarbonylamino group, tetradecyloxycarponylamino group, etc.), aryloxycarbonylamino group (e.g., t, phenoxycarbonylamino group, λ, < 4-di-tert-butylphenol dicarbonylamino group, l), sulfonamide group (e.g. methanesulfonamide group, hexadecanesulfonamide group, benzenesulfonamide group, p-toluenesulfonamide group, octadecanesulfonamide group, λ- methylbenzenesulfonamide group, etc.), carbamoyl group (e.g., heethylcarbamoyl group, N-methylcarbamoyl group, N
-(2-dodecyloxyethyl)carbamoyl group, N-
Methyl-N-dodecylcarbamoyl group, N-(J-(co, hiro-di-tert-amylphenol)propyl)carbamoyl group, etc.), anlu group (e.g., acetyl group, (co, lA-di-tert-amyl) (phenoxy)acetyl group, benzoyl group, etc.), sulfamoyl group (e.g., N-ethylsulfamoyl group, NlN-dipropylsulfamoyl M, N-(2-dodecyloxy7ethyl)
sulfamoyl group, h-ethylhedodecylsulfamoyl group, N,N-diethylsulfamoyl group, etc.),
Sulfonyl groups (e.g., eva, methanesulfonyl, octanesulfonyl, benzenesulfonyl, toluenesulfonyl, etc.), sulfinyl groups (e.g., octanesulfinyl, dotecylsulfinyl, phenylsulfinyl, etc.), alkoxycarbonyl groups ( For example, methoxycarbonyl group, butyloxycarbonyl group, dodecylcarbonyl group, ophtadefurcarbonyl Ll), aryloxycarbonyl group (for example, phenylox7carbonyl group, 3-interdecyloxine=car6yl group,
etc.).

When R4, R5=Re becomes a divalent group to form a bis body, this divalent group can be described in more detail as a substituted or unsubstituted alkylene group (for example, a methylene group, ethylene group, / , 10-decylene group, -CH2cH2-o-
ct-i 2ct-t2-1 etc.), 1t! t.

Substituted or unsubstituted phenylene group (e.g. /, Kufu unilene group, /, J-) unilene group, -Nl(CO-rt
2-coNt-i- group (R2 represents a substituted or unsubstituted alkylene group or phenylene group).

The linking group represented by R4, R5, or R6 when the one represented by the general formula [IJ-λ~(IJ-7 is present in the vinyl monomer) is an alkylene group (#substituted or unsubstituted alkylene group). groups, such as methine group, ethylene group%
/, 10-f silene group, -C)12 aH2ocH2c
Hz-1 etc.), phenylene group (tt-substituted or unsubstituted phenylene group, for example, 114 cm phenylene group, l,
3-phenyne-NHCO-1-CON)i-1-〇-1
It includes groups formed by combining -OCO- and aralkylene groups (for example, those selected from α, etc.).

The vinyl group in the vinyl monomer has the general formula (IJ-
[lambda]~(Includes cases where it has a substituent other than that represented by N-7. Preferred substituents are a hydrogen atom, a chlorine atom, or a lower alkyl group having /-4 carbon atoms.

Examples of non-chromogenic ethylene-like molecules that do not couple with the oxidation products of aromatic-grade amine compounds include acrylic acid,
α-chloroacrylic acid, α-alacrylic acid (such as methacrylic acid), and esters or amides derived from these acrylic acids (such as acrylamide, n-butylacrylamide, t-butylacrylamide, diacetone acrylamide, methacrylamide,
Methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, t-butyl acrylate, 1so-butyl acrylate, 2-ethylhedyl acrylate, n-octyl acrylate,
lauryl acrylate, methyl methacrylate, ethyl methacrylate, n-7' methyl methacrylate and β-hydroxy methacrylate), methylene dibis acrylamide, vinyl esters (e.g. vinyl acetate, vinyl propionate and vinyl laurate), acrylonitrile, methacrylonitrile, Aromatic i-vinyl compounds (e.g. styrene and its derivatives, vinyltoluene, divinylbenzene, vinylacetophenone and sulfostyrene), itaconic acid, citraconic acid, crotonic acid, vinylidene chloride, vinyl alkyl ethers (
Examples include vinyl ethyl ether), maleic acid, maleic acid ester, hevinyl-cohyrolidone, hevinylpyridine, and λ- and H-vinylpyridine. It also includes the case where two or more of the non-color-forming ethylene-like inorganic phase monoclonants used herein are used together.

Compound examples and synthesis methods of couplers represented by the general formulas (1)-λ to (IJ-7) are described in the documents listed below.

The compound of the general formula (IJ-2 is
etc., the compound of general formula (I)-j is disclosed in Japanese Patent Application Shorr-/5
In izzμ, etc., the compound of general formula (I)-μ is
7--27 Hiro // etc., the compound of general formula (I)-r is
Special request Shojt-Hiroshiko and Doyota 277μ! Etc., the compound of general formula (I)-403 is available from Tokuhan Sho! r-/1A
21rO/ etc., and the compound of the general formula (IJ-7 is
These are described in US Pat. No. 3,041, ≠32, etc., respectively.

Also, Japanese Patent Application Shojr-4c2o<tt, Patent Application Shojr-
rryuo, same jl-3'2?2J, same jl-j2 2
The highly color-forming ballast groups described in 1A and 11-42-27 are applicable to any of the compounds of the above general formulas (IJ-2 to (N-7).

Specific examples of the pyrazoloazole coupler used in the present invention are shown below, but the invention is not limited thereto.

(M-J/) x:y (Weight ratio, same below) (M-3λ) x:y=3:10 (M-JJ) x: y=! o: t.

(M-3≠) x:y=jj: μ! (M-3j) X:y=jO:jO Next, the general formula (IIJ) will be explained in detail: In the formula, R2 represents a carbonamide group, a sulfonamide group or a ureido group, and R3 represents a phenyl group.

R2 and R3 may be further substituted, examples of which include halogen atoms (e.g. fluorine atom, chlorine atom, bromine atom, etc.), alkyl groups (e.g. methyl group, t-octyl group, dodecyl group, trifluoromethyl group, etc.). ), alkenyl groups (e.g. allyl group, octadecenyl group, etc.), aryl groups (e.g. phenyl group, p-tolyl group, naphthyl group, etc.), alkoxy groups (e.g. methoxy7 group, penzyloquine group, methoxyethoxy7 group, etc.), arylthio groups (e.g., phenol group, co, ≠-di-tart-amylphenoxy group, 3-tert-methyl-μ-hydroquinphenoxy group, etc.), anlu group (e.g., acetyl group, benzoyl group, etc.), sulfonyl group ( Examples include methanesulfonyl group, toluenesulfonyl group, etc.), carbonyloxy group, sulfo group, cyano group, hydroxy group, amino group (e.g. amino group, dimethylamino group, etc.), carbonamide group (e.g. acedoamide group, trifluoro Acetamide group, tetradecanamide group, benzamide group, etc., sulfonamide group (e.g., methanesulfonamide group, heba-tecanesulfonamide group, p-toluenesulfonamide group, etc.), acyl group (e.g., acetoginyl, sulfonyl group, etc.), 7 groups (e.g., methanesulfonyl group, I, etc.), alkoxycarbonyl groups (e.g., dodefluorocarbonyl group, etc.), aryloxycarbonyl groups (e.g., phenoxycarzenyl group, etc.), carbamoyl groups (e.g., dimethylcarbamoyl group, tetracarbonyl group, etc.), decylcarbamoyl group, etc.), sulfamoyl group (e.g., methylsulfamoyl group, hexadecylsulfamoyl group), i is do group (e.g., succinimide group, phthalimide group, octadecenylsuccinimide group, etc.),
Heterocyclic groups (copyridyl group, cofuryl group, λ-chenyl group, etc.), alkyl ruthio groups (e.g. methylthio group, etc.),
Examples include arylthio groups (eg, phenylthio groups, etc.).

Either R2 or R3 may become a divalent or more polyvalent group to form a multimer such as a λ-mer (or a polymer by linking the polymer main chain and the coupler core). A coupler may also be formed.

It is also known in the art that the coupler represented by general formula (n) has the following keto-enol tautomerism.

Examples of the compound represented by the general formula (II), synthesis method, etc., are disclosed in, for example, JP-A Akihirota ///43/, JP-A-KOKAI JL-1?
! Hiro Q, same jj-42/A, eyes, same jt-/1rosa
, same jA-JI04A3, same j6-rouz, same j4
-/2tlJJ, same j7-≠0hiromu, same! 7-Jjtj
l, same j7-2 Hiro 752, same! rl-/71A4cO,
Same 1l-j OJ: 37, same j1-1rju! 2. 11
-//77 Hiro 4, same 11-/24130. Same 11-/1
41rigu, same! r-201/! l, Tokuko ShojlL-/
70, same j44-101L9/, same jlA-2/2! l
r, same jj-4t4Ajλ, same j3-g + Hiroyo 3, same j
7-j4j77, special application Sho zr-//l:) J-Taro, same jlr-/3213μ, same! λ672, U.S. Patent 32λ7 ju, U.S. Patent 3≠j2s21. Same lA3101.
/r, 43 site 7, etc.

Examples of preferable compounds among monovirazolone coequivalent magenta couplers represented by the general formula (IIJ) are shown below, but the invention is not limited thereto.

m -/ α -J C) i3 ha α -j -r H3 -IO SO2C) 13 m-/ / m-/2 0CH3 α m-/ Hirom -/ j H3 α m-2/ m-1μ CH3 m-+2j CH3 CH3 m-J (17 F3 -J4c CH3 m-37 m-32 m-μO to α) IcOc) l=c) 12 m-Hiro l H3 ■ m-≠2 α m-≠ ≠ x/ y=60/IAO(wt) X/y=j O/! 0 (W t ) m−j3 m−j Hiroshi X/Y=j O/! 0 (W t )X/'(=zo
7zO(wt) Two or more couplers of the present invention can be contained in the same layer. The same compound may be contained in two or more different layers.

The couplers of the invention generally contain from 0-3 moles to zio-' moles of coX per mole of silver in the emulsion layer, preferably from 10-2 moles of /X! X10-'' moles are added.

When used in combination with the above couplers, it is preferable that the total amount of the couplers that develop the same color is within the above range.

In order to introduce the above-mentioned couplers into the silver halide emulsion layer, known methods such as those described in US Pat. No. 2,322.027 can be used. For example, phthalic acid alkyl esters (dibutyl phthalate, dioctyl phthalate, etc.), phosphoric acid esters (diphenyl phosphate,
triphenyl phosphate, tricresyl phosphate, dioctyl dityl phosphate), citric acid esters (e.g. acetyl tributyl citrate), benzoic acid esters (e.g. octyl benzoate, alkylamides such as diethyl lauryl), fatty acid esters (e.g. dibutoxyethyl succinate, dioctyl azelate), or organic solvents with a boiling point of about 300C to /j00c, such as lower alkyl acetates such as ethyl acetate, butyl acetate, ethyl fropionate, secondary butyl alcohol, methyl isobutyl ketone. ,
After β-ethoxyethyl acetate, methyl celonorub acetate, etc. are dissolved in VC, they are dispersed in a hydrophilic colloid. A mixture of the above-mentioned high boiling point organic solvent and low boiling point organic solvent may also be used.

Also, Tokuko Akira l-32113, Tokuko Akira! /-j Tata Hiro J
The polymeric dispersion method described in VC can also be used.

When the coupler has an acid group such as carboxylic acid or sulfonic acid, it is introduced into the hydrophilic colloid as an alkaline aqueous solution.

Photographic emulsions made using the present invention may contain color image-forming couplers other than those of the present invention. The coupler is preferably a non-diffusive coupler having a hydrophobic group called a ballast group in its molecule. The coupler may be either di-equivalent or di-equivalent to silver ion.

It may also contain a color 7-docazole having a color correction effect or a coupler (so-called DIR coupler) that releases a phenomenon inhibitor during development.

The coupler may be such that the product of the coupling reaction is colorless.

As the yellow coloring coupler, a known open-chain ketomethylene coupler can be used. Among these, compounds of the zoylacetanilide and pivaloylacetanilide series are preferred.

As the cyan coloring coupler, phenolic compounds, naphthol compounds, etc. can be used. Especially Akira Tokgan! Ta 10 ko 3! As stated in the Hiro issue! Preferred are phenolic cyan couplers substituted with an acylamino group at the 2nd position and a ureido group at the 2nd position.

In addition, colored couplers, DIR couplers (especially DIR couplers that release highly diffusive phenomenon inhibitors)
etc. can also be used together.

In addition to the DIR coupler, the light-sensitive material may contain a compound that releases a phenomenon suppressor upon development (for example, U.S. Pat.
Those described in No. y, West German Patent Application (OLS) No. 2.4c/7,91A, JP-A-12-11271, and JP-A-13-1983-IT can be used.

The photosensitive material produced using the present invention includes hydrophilic colloid I.
T! It may contain an IIC UV absorber. For example, benzotriazole compounds substituted with aryl groups (such as those described in US Pat. No. 72ψ, !t3J), μm
Thiazolidone compounds (e.g. U.S. Patent J, !/I
A, 7P Hiro issue, same! , 31λ.

61r/), benzophenone compounds (for example, those described in JP-A-6-271≠), cinnamic acid ester compounds (for example, those described in U.S. Patent No. 3°701.1),
0! No. J, 707.371), butadiene compounds (for example, those described in U.S. Pat.
λ) or pendioquinzole compounds (e.g., U.S. Patent J, 700, 1A!).
) can be used. Furthermore, US Patent 3. ≠Tata, No. 74, Tokukai Shoj'fi-44133
Those described in No. 1 can also be used. An ultraviolet absorbing coupler (for example, an α-naphthol cyan dye-forming coupler) or an ultraviolet absorbing polymer may be used. These UV absorbers may be mordanted into certain layers.

The photographic emulsion used in the present invention is P, Glafki
Chimie at Physique Ph
Otographique (published by Paul Monte 1, 1967), G, F.

Photographic Emuls by Duffin
ion Chemistry (The Focal P
ress, 1996), V, L, Zeli
Making and Co by kman et al.
ating Photographic Emulsio
n(The Focal Press, lli6
It can be adjusted using the method described in , etc.

In the present invention, silver halide emulsions with regular crystal shapes and nearly uniform grain sizes can also be used.

One or more silver monohalide emulsions formed separately may be used in combination.

In the coupler of the present invention, tabular grains, particularly grains with a grain size/thickness ratio of 5 or more, particularly r or more, account for jO% of the total projected area.
It may be used in combination with the emulsions mentioned above.

In the process of silver halide grain formation or physical ripening,
A cadvaram salt, a zinc salt, a lead salt, a thallium salt, an iridium salt or a complex salt thereof, a rhodium salt or a complex salt thereof, an iron salt or an iron complex salt, etc. may be present.

Gelatin is advantageously used as a binder or protective colloid in photographic emulsions, but other hydrophilic colloids can also be used.

The photographic emulsion used in the present invention can contain various compounds for the purpose of preventing capri or stabilizing photographic performance during the manufacturing process, storage, or photographic processing of the light-sensitive material. That is, azoles such as benzothiazolium salts, nitroindazoles, nitrobenzimidazoles, chlorobenzimidazoles, bromobenzimidazoles, mercaptothiazoles, mercaptobenzothiazoles, mercaptobenzimidazoles, mercaptothiadiazoles, aminotriazoles. , benzotriazoles, nitrobenzotriazoles, mercaptothiazoles (especially /-phenyl-
! mercaptopyrimidines; mercaptotriazines; thioketo compounds such as oquinacyrinthion; azaindenes, such as triazaindenes, tetraazaindenes (particularly hiro-hydro-substituted (/, j, 7) Tetrazaindenes], pentaazaindenes, etc.: Adding many compounds known as antifoggants or stabilizers such as henzenethiosulfonic acid, benzenesulfinic acid, benzenesulfonic acid amide, etc. For example, U.S. Patent No. 3,912.
It is possible to use those described in Japanese Patent Publication No. 4c7 and Japanese Patent Publication No. 2-2f, No. 660.

In the photographic emulsion layer of the photographic light-sensitive material of the present invention, for the purpose of increasing sensitivity, increasing contrast, or accelerating development, for example, polyalkylene oxide, derivatives thereof such as ethers, esters, and amines, thiol compounds, thiomorpholines, quaternary ammonium salt compounds, urethane derivatives, urea derivatives, imidazole derivatives, 3-pyrazolidones, and the like.

The photographic emulsions used in this invention may be spectrally sensitized with methine dyes and others. The dyes used include cyanine dyes, merocyanine dyes, complex cyanine dyes, complex merocyanine dyes, holopolar-cyanine dyes, hemicyanine dyes, styryl dyes, and hemioquinol dyes. Specially useful dyes are cyanine dyes, merocyanine dyes, and dyes belonging to complex merocyanine dyes. For these dyes, any of the nuclei normally used for cyanine dyes can be applied as the basic heterocyclic nucleus. Namely, pyrroline nucleus, oxazoline nucleus, thiazoline nucleus, pyrrole nucleus, oxazole nucleus, thiazole nucleus, cenazole nucleus, ibadazole nucleus, tetrazole nucleus, pyridine nucleus, etc.; these nuclei have an alicyclic hydrocarbon ring. and a nucleus in which an aromatic hydrocarbon ring is fused to these nuclei, i.e., an indolenine nucleus, a benzindolenine nucleus,
Indole nucleus, benzothiazole nucleus, naphthoxazole nucleus, benzothiazole nucleus, naphthothiazole nucleus, benzoselenazole nucleus, tanzimidazole nucleus, quinoline nucleus, etc. are applicable. These nuclei may be substituted on carbon atoms.

Merocyanine dyes or complex merocyanine dyes contain e-lazoline! as a core with a ketomethinone structure. -On nucleus, thiohydantoin nucleus, Cochioo beef silydin-2
J-4-membered heterocyclic nuclei such as a 2 μm dione nucleus, a thiazolidine-21 μm dione nucleus, a rotor-bin nucleus, and a thiobarbital acid group can be applied.

These sensitizing dyes may be used alone or in combination (combinations of sensitizing dyes are often used especially for the purpose of supersensitization).

Along with the sensitizing dye, it is a dye that itself does not have a spectral sensitizing effect or a substance that does not substantially absorb visible light,
A substance exhibiting supersensitization may also be included in the emulsion.

The photosensitive material produced using the present invention may contain a water-soluble dye in the hydrophilic colloid layer as a filter dye or for various purposes such as preventing irradiation. Such dyes include oxonol dyes, hemioxonol dyes, styryl dyes, merocyanine dyes, anine dyes and azo dyes. Among them, oxonol dyes; oxonol dyes and merocyanine dyes are useful.

In the photosensitive material produced using the present invention, the photographic emulsion layer and other hydrophilic colloids may contain brighteners such as stilbene-based, triazine-based, oxazole-based, or coumarin-based brighteners. Even if it’s a sexual thing (,
A water-insoluble brightener may also be used in the form of a dispersion.

In carrying out the present invention, the following known antifading agents may be used in combination, and the color image stabilizers used in the present invention may be used alone or in combination of two or more.

Known anti-fading agents include --idomerin derivatives, gallic acid derivatives, p-alco diphenols, p-ogyu 7 phenol derivatives, bisphenols, and the like.

The light-sensitive material produced using the present invention may contain hydroquinone derivatives, aminophenol derivatives, gallic acid derivatives, ascorbic acid derivatives, etc. as color anticaprilants.

The invention is also applicable to multilayer, multicolor photographic materials having two different spectral sensitivities on the support.

Multilayer natural color photographic materials usually have a red-sensitive emulsion layer on a support,
It has at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer. The order of these layers can be arbitrarily selected as necessary. Usually, the red-sensitive emulsion layer contains a cyan-forming coupler, the green-sensitive emulsion layer contains a magenta-forming coupler, and the blue-sensitive emulsion layer contains a yellow-forming coupler, but different combinations may be used depending on the case.

Next, details of the stabilizing bath used in the present invention will be explained.

The stabilizing bath of the present invention substantially does not require a water washing step.
It is used after a bath with fixing ability.

Here, ``substantially without undergoing a water washing step'' refers to a case where the entire washing step is preferably not included, and does not exclude short-time washing or rinsing, which may be performed as necessary. In the present invention, the "bath with fixing ability" means:
It mainly refers to conventional bleach-fixing baths and fixing baths, and these baths preferably contain thiosulfate as described below.

The stabilizing bath of the present invention contains JX/(7 to ioxio-3 mol
/l of aldehyde compounds. Preferably 3XI
Contains O-3 to rxlQ-3 mol/l. Examples of aldehyde compounds include the following compounds, but the present invention is not limited to these compounds.

Formaldehyde Acetaldehyde Propionaldehyde In Butyraldehyde n-Butyraldehyde Aldol Propiolaldehyde Acrolein Crotonaldehyde Stylaldehyde Glyoxalic acid Mucochloric acid Mucobromic acid Furfural Diglycol Aldehyde Glyoxal Sacnonaldehyde Glutaraldehyde α-Methylglutaraldehyde Cyclo-methylglutaraldehyde Xialdehyde Among the above compounds,
Formaldehyde is especially bad.

These aldehyde compounds may partially form adducts with sulfite ions and bisulfite ions brought in from the previous bath in the stabilizing bath.

In addition to the above-mentioned compounds, the stabilizing bath of the present invention can contain various surfactants in order to prevent uneven water droplets when drying the photosensitive material after processing. These surfactants include polyethylene glycol type nonionic surfactants, polyhydric alcohol type nonionic surfactants, aluminum layer benzene sulfonate type anionic surfactants, and higher alcohol sulfate ester salt type anionic surfactants. surfactant,
There are alkylnaphthalene sulfonate type anionic surfactants, μ-class ammonium salt type cationic surfactants, amine salt type cationic surfactants, amino acid type amphoteric surfactants, and betaine type amphoteric surfactants. It is preferable to use a nonionic surfactant, especially nonionic surfactants, as they may mix with the treatment and combine with various ions to form insoluble substances. The alkylphenol is preferably octyl, nonyl, doorful or dinonylphenol, and the number of moles of ethylene oxide added is preferably lr-/μmol.

The stabilizing bath of the present invention can also contain various antibacterial and antifungal agents in order to prevent water stains and mold from forming on the photographic material after processing. Examples of these antibacterial agents and antifungal agents include JP-A-17-17/J-7.
Thiazolylbenzimidazole compounds such as those shown in No. 21Aμ and JT-10!1lAj, or JP-A-Sho! Isothiazolone compounds as shown in No. 7-IjlAJ, lolophenol compounds as typified by trichlorophenol, bromophenol compounds, organotin and organozinc compounds, or thiocyanic acid and isothionanic acid compounds. compounds, or acid abad compounds, diazine and triazine compounds, or thiourea compounds, benzo), azole alkylguanidine compounds, or μ-class ammonium salts such as benzalkonium chloride. , or antibiotics such as penicillin, etc., Journal of Antibacteria and Antifungal Agents (J, Antibact, Antifung).

Agents) Voll, Aj%p-207~223(
1g or more of the general-purpose anti-spill agent described in 15'1r3) may be used in combination.

Furthermore, various fungicides described in JP-A-4CT-R3R2O can also be used.

In addition, various compounds may be added to the stabilizing bath of the present invention. For example, metal salts such as magnesium salts, aluminum salts, zinc salts, nickel salts and bismuth salts, hardening agents for reducing drying load, etc. can be added as necessary.

Also, L, E, West "Water Quality Criteria" (@Water Quality
Criteria “) Photographic Science
and Engineering (Photo, Sci, and
Compounds described in Eng, ), Volta, 46 (/ri6!), etc. may be added.

Furthermore, various ammonium salts such as ammonium chloride, ammonium nitrate, ammonium sulfate, ammonium phosphate, ammonium sulfite, ammonium thiosulfate, etc. can be added as a membrane pi adjusting agent after treatment.

The stable solution of the present invention is used after adjusting p)iJ to fvc94, and for pH adjustment, alkali metal hydroxides such as sodium hydroxide and potassium hydroxide, ammonia, and mineral acids such as sulfuric acid and hydrochloric acid are used. Organic acids such as , acetic acid, tartaric acid, citric acid can be used.

In particular, it is preferable to add a chelating agent to the stabilizer of the present invention from the viewpoint of liquid stability. Examples of the chelating agent include inorganic phosphoric acid, aminopolycarboxylic acid, organic phosphoric acid, aminopolyphosphonic acid, and phosphonocarboxylic acid. Typical examples of typical chelate types are shown below.
It is not limited to these.

F-/ Na4P4012 F -J Na 6 P 4013F-≠ to ■ C) 12COO) I F-taF-// 1:"-/2 F-/3 F-lhiro)'-/j F-/ 6 F/7 F-/r F-tyF-20 F-2/F-22 H2 C)12COOI-1 F-co JF-21A CH3cH2Coo)i I CH(P 03 H2) 2 CH2P O
3H2C)12Coo)l F-core 1;'-24 CEi2COO)l C)13CH3
Uti2uUU1-1 1;”-27p-,2r l CH2CH2 F-Kota F-30 C)12 ■ CH2C00H F-J/F-32 C)12COO)1 C(PO3Hz)z C)12Coo)i Of these chelating agents It may form a salt with a carboxylic acid or phosphonic acid group, machinenium, calcium, bismuth, lithium, sodium, potassium, ammonium, and metal ions such as iron and zinc.

The chelating agent used in the present invention is 1xl per 11 stabilizers.
It can be contained in the range of Q-7 to 1XIO-1 mole,
Preferably, it can be contained at a concentration of 0-2 mol.

The above-mentioned chelating agent may be added to the stabilizing bath, or may be supplied by being brought in from the pre-bath by being included in the developer, bleach, fixer, or bleach-fix solution in the pre-bath.

The stabilizing bath of the present invention is preferably a multi-stage countercurrent water washing of λ or more, and particularly preferably a co-tank to a ri-tank.

The amount of replenishment of the stabilizing solution is per unit area of the photosensitive material to be processed.
Amount of o, z brought in from the pre-bath (fixing bath, bleach-fixing bath)
-to times, preferably 3 to 4 times.

Here, the above relationship between the amount of replenishment and the amount brought in from the pre-bath only needs to hold true at least in the tank closest to the pre-bath, but all six multi-stage tanks have this ratio relationship. It is preferable.

The temperature of the stabilizing bath may be arbitrary, but j'c-uj'c.

Preferably lo'c-uo'c.

The processing method of the present invention can be applied to any processing of color light-sensitive materials for silver halide photography, such as color negative films for general use or motion pictures, and color reversal films. It can also be applied to processing color X-ray films.

Typical processing steps in the present invention are shown below, but it goes without saying that the process is not limited thereto.

A, Color development - Bleach - Constant washing - Stable - Drying B. Color development - Bleach - Constant fixing - Stable - Drying C. Color development - Bleach - Bleach fixing - Stable - Drying D. Color development - Bleach fixing - Stable - Drying Drying E, Color development - Bleach - Bleach-fixing - Constant - Stable - Drying F, Color development - Washing - Bleach-fixing - Stable - Drying G, 1st development (black and white development) - Washing - Reversal - Color development - Adjustment - Constant bleaching - Stabilization - Drying H1 - Phenomenon - Washing - Reversal - Color development - Adjustment - Bleach - Bleach-fixing - Stabilization - Drying 1, Development - Washing - Reversal - Color development II - Adjustment - Bleach-fixing - Stability-drying J, 1st phenomenon-Water-washing-Reversal-Color development-Bleach Constant fixing-Stability-Drying, 1st-Development-Water-washing-Reversal-1 Color development-Bleach-Bleach-fixing-Stability-Drying, No. 1 - Washing with water - Reversing - Color development - Bleach fixing - Stable - Drying Bleach-fixing - Stability - Drying 0, Stage - Present - Washing - Color appearance 1 - Bleach-fixing - Stability - Drying Next, the color developing solution used in the present invention will be explained.

The primary aromatic amino color developer (walling agent) used in the color developer in the present invention includes known ones that are widely used in many color photographic processes. These include aminophenol-based and p-phenylenediamine-based derivatives.A preferred example is a p-phenylenediamine derivative, and representative examples are shown below, but the invention is not limited thereto.

D-tN, N-diethyl-p-) nisenediamine D-22-amino-! -diethylaminotoluene D-j λ-Abanoyo-(N-ethyl-helaurylamino)toluene D-4c μm [h-ethyl-N-(β-hydroquinethyl)aminonoaniline])-12-methyl-μm [8-Ethyl-he-(β-hydroquinethyl)aminonoaniline D-4N-ethyl-he-(β-methanesulfonamidoethyl)-3-methyl-Hiro-aminoaniline D-7N-(λ-amino !-diethylaminophenylethyl) methanesulfonado D-t N,N-dimethyl-p-phunilene diazine D-2μm amino-3-methyl-he-ethylhemethoxy7ethylaniline 1) -10≠-amino 3-methyl-N-ethyl-N-
β-ethoxyethylaniline D-// ≠-amino-3-methyl-N-ethyl-N-
β-Butoxyethylaniline These polyphenylenediamine derivatives may also be salts such as sulfate, hydrochloride, sulfite, and p-toluenesulfonate. The above compound is described in US Patent No. 2. /RiJ
,0/! No., same λ, ! j2.

2μ/issue, same λ, jA Otsu, 27/issue, same λ, j 2.3
&u No. 3,616,910, 3゜6rir, yo2
It is described in No. 5, etc. The amount of the aromatic-grade amine developing agent used is about 0.00% per liter of developer solution. /9 to about -20g,
More preferably, the concentration is from about Q, I to about iog.

As is well known, the color phenomenon liquid used in the present invention may contain hydroxylamines.

Drogylamines can be used in the form of free amines in color rendering solutions;
It is more common to use it in the form of acid salts.

Common examples of such salts are sulfates, oxalates, chlorides, phosphates, carbonates, acetates, and the like. Hydrofluavanes may be substituted or unsubstituted (,
The nitrogen atom of the hydroxylamines may be substituted with an alkyl group.

The amount of hydroxylamine added is preferably 0/l-/017 per liter of color rendering solution, more preferably 0/l-/017, more preferably or
It is g. If the stability of the color developer is maintained,
It is preferable that the amount added be small.

Also, as a preservative, sodium sulfite, potassium sulfite,
It is preferable to contain sulfites such as sodium bisulfite, potassium bisulfite, sodium metasulfite, potassium metasulfite, and carbonyl sulfite adducts. The amount of these added is preferably og to 2 og/l, and more preferably og/l.
G~! I/l, and if the stability of the color developer is maintained, the smaller the number, the better.

Other preservatives include Japanese Patent Application Laid-Open No. Jλ-μ2112r,
Same 74 1A7031, same j4-32/4AQ, same! Aromatic polyhydro 7 compounds described in Terno≦01 μλ and U.S. Pat. No. 374c4j Hiromu, U.S. Pat. No. 3,6i
J, Roi No. and British Patent I.

Hydroxyacetones described in J O-1, / 74; JP-A-52-/≠3020 and z3-ry Ko 25
α-Aminocarbonyl compound described in JP-A No. 3'7-
Various metals described in uu/4CI No. 7-437≠ri, etc.; JP-A-Sho! Various saccharides described in λ-102727; hydromuic acids described in λ-Core 63; same!
D/1.0/≠/ α, α′-dicarbonyl compound described in issue; same! ? -/Salicylic acids described in No. 10111;
Same as μm 3. Alkanol abans described in No. 32; Same as j
4-1 Poly(aluminum imine) described in Ko 3 Hiro issue;
Examples include gluconic acid derivatives described in No. 36-7j+4c7. Use these preservatives as needed.
More than one species may be used together.

The color developing solution used in the present invention preferably has a pH of ~12, preferably a pH of ~//, 0, and the color developing solution may contain other known compounds as components of the developing solution. can be included.

In order to maintain the above p)l, it is preferable to use various buffering agents.

Buffers include carbonate, phosphate, borate, tetraborate, hydrobenzoate, Grin's salt, N,N dimethylglycine salt, leucine salt, norloin salt, guanine salt, J, 4 - Diphenylalanine salt, alanine salt, aminobutyrate, co-amino-2-methyl-l in dihydro,
3-prononone diol salt, valine salt, proline salt, trishydroquinamine methane salt, lysine salt, etc. can be used. In particular, carbonates, phosphates, tetraborates, and hydroxybenzoates have excellent solubility and buffering ability in the high pH range of p) 1 and 0 or higher, and can be added to color developing solutions. It is particularly preferable to use these buffering agents because they have the advantage that they have no negative effects on photographic performance (fogging, etc.).

Specific examples of these buffers include sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, trisodium phosphate, tripotassium phosphate, disodium phosphate, dipotassium phosphate, sodium borate, and boric acid. Potassium, sodium tetraborate (borax), potassium tetraborate, sodium O-hydroxy 7benzoate (sodium salicylate), 0- and potassium 7benzoate,! -Sulfohydroxbenzoic acid, sodium (j-sodium sulfosalicylate),! -Sulfo λ-potassium hydrobovinebenzoate (j-potassium sulfosalicylate)
etc. can be mentioned. However, the present invention is not limited to these compounds.

The amount of the buffer added to the color developing solution is 0.7 mol/
It is preferably 1 or more, especially 0.1 mol/l-0
．． Particular preference is given to μmol/l.

In addition, one chelating agent can be used in the color developer as an agent for preventing precipitation of calcium or magnesium, or to improve the stability of the color developer.

As the rate agent, organic acid compounds are preferable, for example,
Tokuko Showa Al-0304 Rino issue and Dokoro 44-302
Aminopolycarboxylic acids described in No. 3λ, JP-A-6-2
73≠7, Special Publication No. 6-3 3J, and West German Patent λ
, organic phosphonic acids described in λ27,1,3, JP-A-2-102721S, JP-A No. 53-≠2730, JP-A No. 53-≠2730, Ibid.
Hiroshi-/2//Core issue, same j! -/ulJ Hiro 1 and ulJ
! -469jG, etc., the phosphonocarboxylic acids described in
Other Unexamined Japanese Patent Publication No. 31/1973 5rvj, same jr-co 0bI
Compounds described in No. 0 and Japanese Patent Publication No. 3-Hiro Q 00 can be mentioned. Adult examples are shown below, but are not limited to these.

・Nitrilotriacetic acid・Diethylenetriaminepentaacetic acid・Triethylenetetraminehexaacetic acid・N,N,N-trimethylenephosphonic acid・ethylenediamine-to, N,N',N'-tetramethylenephosphonic acid・/,! -Diamino-λ-propanol-hydroacetic acid, transcyclohexanediaminetetraacetic acid, nitrilotripropionic acid, /, J-diaminopropanetetraacetic acid, hydroxyethyliminodiacetic acid, glycol ether diamine tetraacetic acid, hydroxyethylenediaminetriacetic acid, ethylenediamine orthohydroxyphenyl Acetic acid/2-phosphonobutane-1,≠-tricallic acid/l-hydroxyethane-7,/-diphosphonic acid/N,N/-vinu(λ- and doro-cybenzyl ethylenediamine-N,N '-Diacetic acid These chelating agents may be used together in Jfli or more if necessary.The amount of these chelating agents added may be sufficient as long as it is sufficient to sequester metal ions in the color developer.

For example, 0.0 per liter. /g to iog.

If necessary, an arbitrary image accelerator can be added to the color developer. However, it does not substantially contain benzyl alcohol, and the amount added is 0.00% per liter of color developer. ! ill/l
or less, preferably total (not contained). Other phenomenon promoters include Japanese Patent Publication Publication No. 37-7torr, No. 37-j
No. 917, No. 3r-7126, No. ua-ixJro, IAt-t.

/F and U.S. Patent No. 3113λμ7, etc.; p-] dinisundiamine compounds described in JP-A Shoj, 2-Hori R, 2, and to-its-z Hiro. , Tokusho 3-0-/37726, Tokuko Akihiro≠-JOO7 Hiro, Tokukai Sho! 6-/16126 and the same! 2-IA31A2Y, etc.; p-amine phenols described in U.S. Pat. No. 410.122 and U.S. Patent No. 1A42;

No. 203, J, /CoI, /12, Dohiro, λ30.7
Riwo No., same J, 233, Rili No., special public Sho Ii &
/-//lA3/, U.S. Patent 2, 4lr2,
J4T, same, Jri 6,921. No. and 3. j♂ko.

Amine compounds described in No. 3μ6, etc.; Special Publication No. 37-7t
orr, No. 42 J j 20/, U.S. Patent No. 3. /21. /r, No. 3, Special Publication Showa 44/-//'A3
/ No. ≠ 2-21frJ and U.S. Patent 3. ! 32,
polyalkylene oxide described in jO1 etc., others, l-phenyl-3-pyrazolidones, hydrazines,
Menion type compounds, thione compounds, imidazoles, etc. can be added as necessary. Particularly preferred are thioether compounds and phenyl-3-pyrazolidones.

In the present invention, an arbitrary antifoggant can be added to the color developer, if necessary. As antifoggants, alkali metal halides such as potassium bromide, sodium bromide, potassium iodide, and organic antifoggants can be used.

Examples of organic antifoggants include (zotriazole, t-nitrobenzimidazole, j-nitroiso(7),
ter7''-k,j-7i thylbenzotriazole,!-
Nitropenzotriazole! -Nitrogen-containing heterocyclic compounds such as chlorobenzotriazole, 2-thiazolyl-benzimidazole, λ-thiazolylmethyl-benzimidazole, hydroxyazaindolizine, and l-phenyl-! Mercapto-substituted heterocyclic compounds such as -mercaptotetrazole, 2-mercaptobenzimidazole, comercaptobenzothiazole, adenine and also mercapto-substituted aromatic compounds such as thiosalicylic acid can be used. Particularly preferred are nitrogen-containing heterocyclic compounds. These antifogging agents may be eluted from the color light-sensitive material during processing and may accumulate in the color developer.

The color developer of the present invention preferably contains a fluorescent brightener such as μ, t1. /-diamino-2+2'-disulfostilbene type compounds are preferred. Additive bond is 0-j g/l preferably 0.7 g to 29
/l.

Furthermore, various surfactants such as alkylphosphonic acids, arylphosphonic acids, aliphatic carboxylic acids, and aromatic carmenic acids may be added as necessary.

The processing temperature of the color developer of the present invention is preferably λ0-100C, more preferably 30-≠00C. The processing time is 20 seconds to 10 minutes, preferably 30 seconds! It's a minute. Supplementary charging is 10 rnl ~ 2000 per m2 of photosensitive material
rnl preferably 100!11~/! 00rfL1.

The bleaching agent used in the bleaching solution or bleach-fixing solution used in the present invention is a ferric ion complex that is a combination of ferric ion and a chelating agent such as aminopolycarboxylic acid, aminopolyphosphonic acid, or a salt thereof. It is a complex. Aminopolycarboxylic acid salts or aminopolyphosphonic acid salts are salts of aminopolycarboxylic acids or aminopolyphosphonic acids with alkali metals, ammonium, or water-soluble amines. Examples of alkali metals include sodium, potassium, and lithium, and examples of water-soluble amines include methylamines, diethylamine, triethylamine, and alkylamines such as butylamine, ring-type amines such as cyclohexylamine, aniline, and m-1 luidine. arylamines such as pyridine, morpholine, pyridine, and heterocyclic amines such as lysine.

Typical examples of chelating agents such as these aminopolycarboxylic acids and aminopolyphosphonic acids or their salts include: ethylenediaminetetraacetic acid ethylenediaminetetraacetic acid disodium salt ethylenediaminetetraacetic acid diammonium salt ethylenediaminetetraacetic acid tetra(trimethylammonium) salt ethylenediamine Tetrapotassium tetraacetate Ethylenediamine Tetrasodium tetraacetate Ethylenediamine Trisodium tetraacetate Diethylenetriamine diethylenetriamine is Intasodium triacetate
・ Ethylenediamine-to-(β-ox7ethyl)-to, N
', N'-ethylenediamine triacetate-to-(β-oxyethyl)-to, N
',N'-Triacetic acid trisodium salt ethylenediamine-to-(β-oxyethyl)-N,N
',N'-triammonium triacetate propylene diamine tetraacetic acid propylene diamine tetraacetic acid disodium salt nitrilotriacetic acid nitrilotriacetic acid sodium salt cyclohexanediamine tetraacetic acid cyclohexane diamine tetraacetic acid disodium salt iminodiacetic acid dihydroxyethylglycine ethyl ether diamine tetra Acetic acid glycol ether diamine tetraacetic acid ethylene cyanide tetrazolopionic acid phenylene diamine tetraacetic acid 1,! -diaminopropanol N, ~, N'.

N'-tetramethylenephosphonic acid ethylenediamine-N, N, N', N/-tetramethylenephosphonic acid/, J-f propylene diamine-he, ~lN'1'
-tetramethylenephosphonic acid and the like, but are not limited to these exemplified compounds.

The ferric ion complex salt may be used in the form of a complex salt, or as a ferric ion complex salt.
Salts of iron salts, such as ferric sulfate, ferric chloride, ferric nitrate, ferric ammonium sulfate, ferric phosphate, etc., and aminopolycarboxylic acids, aminopolyphosphonic acids, phosphonocarboxylic acids, etc. A ferric ion complex salt may be formed in a solution using an agent. When used in the form of a complex salt, one type of complex salt may be used, or more than one type of complex salt may be used. - If a complex salt is formed in a solution using a ferrous salt and a chelating agent, seven or more kinds of ferric salts may be used. Furthermore, seven types or two or more types of intermediate rate agents may be used. Furthermore, in either case, the irradiating agent may be used in excess of the amount required to form the ferric ion complex. Among the iron complexes, aminopolycarboxylic acid iron complexes are preferred, and the amount added is 0.0/-/, 0m06/l.
Preferably o, o j-o, somol/l
It is.

Further, a bleach accelerator may be used in the bleaching solution or bleach-fixing solution, if necessary. Examples of useful bleach accelerators include U.S. Pat. λPO, No. 112, λ, OS RI, 91111
No., Japanese Patent Publication No. 13-371J/
No., J74t/I, same! J-1, 1732, same j
3-7. l623, same 3-tayo 30, same j3-
Ta j1.3/No., Ta j3-10 Hiroshi No. 232, Ta J3-/
, 2hiro≠λhiro, same! J-/4C/AJj-j3-1 same j j-2r IA 21. Compounds having a mercapto group or a disulfide group, such as those described in Research Disclosure No. 4/7/2'Z (published in July 2007); JP-A-Sho! Thiazolidine derivatives such as those described in No. O-/140/λ; Japanese Patent Publication No. 4 Lj-ryo 06, Japanese Patent Publication No. 4 Lj-r-06, No. 06 of Japanese Patent Publication No. 4/140/λ; Thiourea derivatives as described in tJ-32731, US Pat. No. 3.70≦, sti;
West German Patent No. 1, /27.7/! No. JP-A-Sho J-1! −
/423! West German Patent No. 244.4c
io issue, same 2, 74CIr, l! Polyethylene opoids described in No.-30; polyamine compounds described in Japanese Patent Publication No. Sho≠yo-r136; and other JP-A No. 9-442
1tJu issue, 4CP-rytti-a issue, same! 3-ta 1tY27, same! Hiro-31727, same jyoichi 26!
Issue 06 and the same! Examples include the compounds described in No. r-/132 Hirotheta, iodine, bromine ions, and the like. Among these, compounds having a mercapto group or a disulfide group are preferred from the viewpoint of a large promoting effect, and are particularly preferred as described in US Pat. r
3rd try, West German patent No. 1. Jri 0, 11/2 issue,
Compounds described in JP-A No. 3-21430 are preferred.

In addition, the bleaching solution or bleach-fixing solution of the present invention contains bromide (
For example, a rehalogenating agent of potassium bromide, sodium bromide, ammonium bromide) or chloride (eg potassium chloride, sodium chloride, ammonium chloride) or iodide (eg ammonium iodide) can be included. Boric acid, borax, metaboric acid as required) One type with pH buffering ability such as IJum, acetic acid, sodium acetate, sodium carbonate, potassium carbonate, phosphorous acid, phosphoric acid, sodium phosphate, citric acid, sodium citrate, tartaric acid, etc. The above-mentioned inorganic acids, organic acids, alkali metal or ammonium salts thereof, or humic inhibitors such as ammonium nitrate and guanidine can be added.

The fixing agent used in the bleach-fixing solution or fixing solution of the present invention is:
Known fixing agents, i.e. thiosulfates) Thiosulfates such as IJium and ammonium thiosulfate; Thiocyanates such as sodium thiocyanate and ammonium thiocyanate;
Ethylene bisthioglycolic acid, j,4-dithia-i,
water-soluble silver halide solubilizers such as thioether compounds such as r-octanediol and thioureas;
These can be used alone or in combination of two or more. It is also possible to use a special bleach-fix solution made of a combination of a fixing agent and a polyhalide such as potassium iodide as described in Japanese Patent Application Laid-Open No. 6J-/J, No. JjlA. In the present invention, the use of thiosulfates, particularly ammonium thiosulfates, is preferred. The adhesion of the fixing agent per liter is preferably from 0.3 to .lambda. mol, more preferably from o, r to i, o mol.

The p)L region of the bleach-fix solution or fix solution in the present invention is 3
~10 is preferred, and j~ri is particularly preferred. pH
If this value is low, desilvering performance is improved, but deterioration of the solution and leucoization of the cyan dye are promoted. On the other hand, if the pH is higher than this, desilvering is delayed and staining is likely to occur.

In order to adjust the pH, hydrochloric acid, sulfuric acid, nitric acid, acetic acid, bicarbonate, ammonia, caustic potash, caustic soda, sodium carbonate, potassium carbonate, etc. can be added as necessary.

The bleach-fix solution VC can also contain various other fluorescent brighteners, antifoaming agents, surfactants, and organic solvents such as polyvinylpyrrolidone and methanol.

The bleach-fix solution and fixer solution of the present invention contain sulfite (for example, sodium sulfite, potassium sulfite, 'Mfi) as a preservative.
ammonium ltrate, etc.), bisulfites (e.g. ammonium bisulfite, sodium bisulfite, potassium bisulfite, etc.), metasulfates (e.g. potassium metabisulfite, sodium metabisulfite, ammonium metabisulfite, etc.) ) containing sulfite ion-releasing compounds. These compounds are approximately 0-02 in terms of sulfate ion.
The content is preferably 0.30 mol/l, more preferably o, o4cmo, 25 mol/l.

If the sulfite ion concentration is higher than the concentration of the present invention, desilvering failure, fixation failure, or cyan dye leuco bodies are likely to occur (
If the temperature is low, precipitation will easily occur in the stabilizing bath, as mentioned above.

As a preservative, sulfite is generally added, but ascorbic acid, carbonyl bisulfite adducts, carbonyl compounds, etc. may also be added. Furthermore, buffering agents, fluorescent brighteners, chelating agents, antifungal agents, etc. may be added as necessary.

(Example) Examples of the present invention will be specifically shown below, but the present invention is not limited thereto.

EXAMPLE A multilayer color light-sensitive material having each layer having the composition shown below was prepared on a triacetyl cellulose film support provided with an undercoat mt.

1st layer; antihalation layer; gelatin layer containing black colloidal silver; λ layer; intermediate layer; gelatin layer containing an emulsified dispersion of j-di-t-octylhydroquinone; 3rd layer; low-sensitivity red-sensitive emulsion layer; iodobromide layer; Silver emulsion (silver iodide; 3 mol%)...Silver coating amount
/, Af/m2 Sensitizing dye I...tXio ``mole per mol of silver Sensitizing dye ■...t, z x 7'o, 5 mol coupler EX-/・ per mol of silver Q, O≠ moles per mole of silver Coupler EX-z・0.003 moles per mole of silver Coupler EX-1・O, ooot moles per mole of silver Silver bromide emulsion (silver iodide, 10 mol%)...Silver coating t 1. Hirot/@2 Sensitizing dye...JXlo' mol sensitizing dye for 1 mol of silver... ...1, λX10 mole coupler EX-2 for 1 mole of silver, 0.0.2 mole coupler EX-j for 1 mole of silver, o, ooi mole for 1 mole of silver, jth layer; intermediate layer 6th layer same as 2nd layer; low-sensitivity green-sensitive emulsion layer Monodispersed silver iodobromide emulsion (silver iodide; ≠ mol %)...Amount of coated silver /, 2f/z2 Sensitizing dye...・3×10-5 mol per 1 mol of silver Sensitizing dye ■・・・i×10-5 mol per 1 mol of silver Coupler listed in the table/・0.02 mol coupler per 1 mol of silver EX-If・o, oor mole per mol of silver Coupler EX-4・0.00/! mol per mol of silver 7th layer; High-sensitivity green-sensitive emulsion layer Silver iodobromide emulsion (silver iodide; lO morti)...Amount of coated silver /, Jt/rIL2 Sensitizing dye■...For 1 mole of silver, λ,!x/0-5 mole Sensitizing dye■...For 1 mole of silver 0, r x 70' mole Couplers listed in Table 1 - 0.0/7 mole for 1 mole of silver Coupler EX-1r - 0.003 mole for 1 mole of silver Coupler EX-7o - 1 mole of silver yellow filter layer; gelatin layer containing yellow colloidal silver and an emulsified dispersion of 2.!-di-t-octylhydroquinone in an aqueous gelatin solution; low device blue-sensitive emulsion layer; Silver emulsion (silver iodide; 6 mol%)...Amount of coated silver
o, yf/m2 Coupler EX-4 0.2 J'' mol per 1 mol of silver Coupler EX-4 0.2 J'' mol per 1 mol of silver 10th layer; High-sensitivity blue-sensitive emulsion layer Silver iodobromide ( Silver iodide; 6 mol%)...Coated silver amount 0
, A f / 1rL2 coupler EX-ta - 0.01 mol per mol of silver 1st/layer; 1st protective layer silver iodobromide (1 mol of silver iodide, average grain size 0.07μ )・・
... Coated silver amount o, rt Gelatin layer 1st λ layer containing an emulsified dispersion of ultraviolet absorber UV-/; 2nd protective layer trimethylmethanoacrylate particles (@ diameter about 7°!μ)
Apply a gelatin layer containing.

In addition to the above composition, a gelatin hardening agent H-/ and a surfactant were added to each layer.

Compound sensitizing dye I used to prepare the specimen; anhydro-!・! ′-Dichloro 3.3
′-di(γ-sulfopropyl)-terethyl-thiacarbocyanine hydroxide pyridinium salt sensitizing dye■;Anthroterethyl-3・3′-di(γ-sulfopropyl)-μ・!・≠′−! ′-ji(/
Dithiacarbocyanine hydroxide/triethylamine salt sensitizing dye ■;Anthrotherethyl-! -! ′--)
/Colo-3・i/-di(γ-sulfopropyl)oxacarbocyanine/sodium salt sensitizing dye■:Anhydroj-4・j'・6'-tetrachloro-/-/'-
Diethyl-3,3'-cy(β-[β-(γ-sulfopropyl)ethoxy]ethylimidazolocarbocyanine hydroxide sodium salt coupler EX-/X-2 EX-7 a EX-t.

EX-t EX-2 H2C=Q(So 2 Q(2C0NH(Q(212N
HCOD (2So 2CH= Q(2UV-/) This photographic element was cut into kJJm/m, then imagewise exposed, and continuous processing was carried out by the following processing process person and B. The processing amount was determined by the amount of color developer. Continue until the amount of refill is three times the tank capacity.

The process person is countercurrent water washing from ■→■, and process B is a three-stage countercurrent water washing from stable ■→■→■.

The formulations of each treatment liquid used are shown below.

<Color developer> Please be sure to use the following recipe for both treatment steps A and B.

Tank fluid Replenisher diethylene triamine J, Of J, O
Sodium pentaacetic acid sulfite Hiroshi, Of 4A, ≠ Potassium carbonate 30.0? J co, Of
Potassium bromide /, Hirof 0.7
f Potassium iodide i, 3 mg −
Hydroxylamine 2.44f λ, tf
Sulfate Hiro-(N-ethyl-N-β-hydroxyethylamine)-λ-methylaniline sulfate ≠, jt j,
Add ol water /, ol /
, 0LDH10,0010,0 <Bleach solution> Both processing steps A and B are common, and the following formulation is used.

Tank liquid Replenishment amount Ethylenediaminetetraacetic acid ferric ammonium salt 100. Of Ilo, Of
Ethylenediaminetetraacetic acid disodium trilam salt r,ot io,or ammonium bromide /! o, of i7z, of
Ammonium nitrate 1. Of 10.0?
Ammonia water 7.0rnl lA,
0ml (2?%) l Add water /, Ol /, 01p
a≦, OpH! , 7 <Fixer> The following formulation was used in both processing steps A and B.

Tank fluid replenishment amount Ethylenediaminetetraacetic acid di-sodium ram λ, Of Hiro, ≠1 Sodium sulfite / A., Or 7,
0 f Thiosulfuric acid ammonium aqueous solution (777%) 200.0ml -≠0 sodium bisulfite Hiroshi, Of 12.2f
Add ammonia water io, o water i, ot i, otpH7
,j7. ! Stabilizing liquid〉 Processing process 8A and B are common, and the following formulation is used.

Tank fluid Replenisher formalin (37% by weight) Listed in Table 1 Listed in Table 1 Fujido 2
iwel j, 0ral l, otnl
Add ethylenediaminetetraacetic acid disodium water and add 1,000 g. The formalin concentration in the stabilizing bath was changed as shown in Table 1.
At the end of continuous processing, the color temperature of the photosensitive material is set to t&:ar using a filter using a tungsten light source.

After adjusting to OoK and giving an exposure of λjcMs, the image is processed.

Each sample after treatment was divided into two equal parts, one at 72 m at ro 0c.
The other one was left for μ weeks under the conditions of 4co 0c/riO%RH, and the change in photographic properties (Δ
DBmin, ΔDG) are shown in Table 1.

Here, ΔDGmin indicates the change in the minimum density of yellow immediately after processing, and ΔDa/,j indicates the change in density of magenta at the point D=/,j immediately after processing, and the minus sign indicates the change over time. The concentration will be lower than immediately after treatment.
A plus sign indicates this opposite change. These numbers are
The closer to O, that is, the smaller the difference in density between immediately after processing and after time, the better the image storage stability is.

At the same time, visually check the presence or absence of precipitation in the stabilizing bath. The results are shown in Table 1.

In step A, if the formalin concentration is lowered, the fading of the magenta dye worsens, but in step B, the fading does not worsen (AJ), and in step B,
If the formalin concentration is high, precipitation will occur in the stabilizing solution (S3
). Furthermore, if the formalin concentration is lower than the range of the present invention, the fading of the magenta dye will be significant (Y7). Furthermore, when comparative coupler (2) is used, yellow stain is generated more than in the present invention (Cliff!1.r, P), which is not preferable.

(7) Example 2 On a subbed cellulose triacetate film support,
A sample of a multilayer color photosensitive material consisting of each layer with the composition shown below was prepared.

(Composition of photosensitive layer) First layer (antihalation layer) Black colloidal silver ・・・・・・・・・・・・
・0.3 gelatin ・・・・・・・
・・・・・・/, 0 UV absorber UV-/ ・・
・・・・・・・・・・・・0. / Same as above UV-2...
・・・・・・・・・0. /Same as above UV-j
・・・・・・・・・・・・0. / Same as above UV-Hiroshi
・・・・・・・・・・・・0. /Dispersion oil 0i
l-/ ・・・・・・・・・・・・0.2 Same as above
0i1-a ・Old...Old...0. /Second layer (middle layer) Gelatin ・・・・・・・・・・・・
・7.0 colored coupler C-/・・・・・・
...0.02 dispersion oil 0il-/ ...
...0.07 Third layer (first red-sensitive emulsion layer) Monodispersed silver bromide emulsion (silver iodide j morch, average grain size 0, jμ
) ゛ ・1 old・・・o, r gelatin
・・・・・・・・・・・・O0! Sensitizing dye processing ・・・・・・・・・3×10
'Sensitizing dye■ ・・・・・・・・・×
10' Coupler C-/・・・・・・
...0.3 coupler C-λ ・
・・・・・・・・・O0O Coupler C-3・・・・・・
...0.0! Coupler C-≠・Old・
group・0.0/dispersed oil Oi l −j ・・
...0.03 dispersion oil 0il-Hiroshi
・・・・・・・・・0.03rd μ layer (intermediate layer) Gelatin ・・・・・・・・・・
・・１． θ compound person...
...Q, l 5th layer (first green-sensitive emulsion layer) Monodispersed silver iodobromide emulsion (average grain size after 2 moles of silver iodide o, rμ
)...O.

Gelatin ・・・・・・・・・・・・
O1l sensitizing dye■ ・・・・・・・・・J
Xlo' Same as above ■ ・・・・・・・・・
・/X/ 0-' Same as above V...
...JXlo-4 coupler C-r
・・・・・・・・・・・・0.7 coupler C-+
・・・・・・・・・・・・O0/Cub, y-
C-7・・・・・・・・・・・・0. /Coupler C-
r...0.0! Coupler C-ta ・・・・・・・・・0. OJ dispersion oil Qil-J ・・・・・・・・・・・・
0. /Layer (intermediate layer) Fine grain silver bromide (average particle size 0.07μ)...o, i Gelatin.../
, 0 7th layer (1f sensitive emulsion) Monodisperse silver iodobromide emulsion (silver iodide t morch, average grain size 0.7
μ)...0 gelatin...
...1.0 sensitizing dye■ ...
・・・・・・−X10' Same as above ■ ・・
・・・・・・λ×lθ-4 coupler C-10...
・・・・・・・・・／、Kota coupler C-／／
・・・・・・・・・・・・0.2 dispersion oil
0il-/ ・・・・・・・・・・・・0. /th layer (middle/i) Gelatin ・・・・・・・・・0.
Oj Kaimono B ・・・・・・・・・
...o, i distribution 0i1-1 ...
...O, or f-th layer (first green-sensitive emulsion layer) Silver iodobromide emulsion (silver iodide lcomorti, average grain size/, tμ)
・・・・・・・・・・・・／、! Gelatin ・・・・・・・・・・・・／、
2 Sensitizing dye processing ・・・・・・・・・3×1
0 ' Same as above ■ ・・・・・・・・・3
×io 'Coupler C-/Co...
......0. /Coupler C-l ・
・・・・・・・・・・・・0.3 coupler C-s
・・・・・・・・・0.02.4A Dispersion oil 0il-Q ・・・・・・・・・・・・0
．． 2 10th layer (middle layer) Gelatin ・・・・・・・・・・・・
・/, 0 coupler C-7・・・・・・・・・・・・0
．． 2 Compound A ・・・・・・・・・
・・・O0/Dispersion oil Oi 1-J ・・・
...0. OJ″ 1st/layer (second green-sensitive layer) Tabular silver iodobromide emulsion (silver iodide 10 molti, average aspect ratio 10, average grain size μ) ・・・・・・・・・・・・/, jt Gelatin ・・・・・・・・・・・・
・1.0 coupler C-/J ・・・・・・
...O1λ coupler C-r ・
・・・・・・・・・Q, 02 dispersion oil 0il-/
・・・・・・・・・・・・O, 4c 1st layer (yellow filter skin) Gelatin ・・・・・・・・・・・・
・／、2 Yellow colloidal silver ・・・・・・・
...0.2 Compound B ...
...... θ, λ dispersion oil 0il-/
・・・・・・・・・・・・0. -2 73rd layer (2nd
Blue-sensitive emulsion I-) Tabular silver iodobromide emulsion (silver iodide 3 molt, average aspect ratio l!, average grain size λ, jμ) ・・・・・・・・・・・・O, r Fine grain iodine Silver bromide emulsion (average grain size O0θriμ)...
・・・・・・・・・O, cogelatin ,,,,,,,,,/
, , 2 sensitizing dye ■ ・・・・・・・・・・
・3×10 4 Same as above ■ ・・・・・・・・・
.../X10' Coupler C-10...
...0.3 coupler C-// ...
......0.3 dispersion oil 0il-/
-0, -6, -0, OA first child layer (first protective layer) Fine grain silver bromide emulsion (average grain size 0.07μ)...
・・・・・・0.2 Ultraviolet absorber UV-/ ・・・・・・・・・0
．． 0! Same as above UV-λ ・・・・・・・・・0
．． Oj Same as above UV-3・・・・・・・・・0.02
Same as above UV-≠ ・・・・・・・・・o, or
Same as above UV-3・・・・・・・・・0.02 Gelatin ・・・・・・・・・・・・O4
Dispersing oil 0il-a ・・・・・・・・・
...0. /1st layer (second protective layer) Gelatin ・・・・・・・・・・・・
・O0j polymethyl methacrylate particles (diameter/,!
μ・・・・・・・・・0.2 In addition to the above ingredients, a surfactant W-/i is added as a coating aid to each layer. Additionally, formalin scavenger was added.

The following compounds used in the examples C-/ 0-Hiro-J- -j C-7c' -r H H C-// C-72 C-/3 Sensitizing dye I ((-'H2) a 5U3Na Same as above ■ Same as above ■ Same as above ■ Same as above V Same as above ■ Same as above ■ UV-/ UV-coUV-J UV-HiroshiUV~I C2H5 1l-1 Oil -2 1l-3 Oil -μ and 2H5 11-j Compound AW-/ Compound B The color photographic light-sensitive material for photographing was subjected to further processing in the following processing steps C and D in the same manner as in the examples.

Process C is a countercurrent flow from washing ■→■, and the process is stable ■→
Multi-stage countercurrent flow from ■→■.

The formulation of each treatment solution used is shown below.

<Color developer> The same formulation as in Example was used in processing steps C and D.

<Bleach solution> The following formulation was used in both treatment steps C and D.

Tank liquid><Supplementary light amount> Ethylenediamine /20f /20
9 Tetraacetic acid ferric ammonium salt ethylenediamine 709 109
Conatrilum tetraacetate salt ammonia water /7ml /
7 Ammonium Gonitrate / Of
/ Of ammonium bromide 1oor
<ooy bleach accelerator jXlo mol j x 10' mol Add water
it 1tpH+, r it <Bleach-fix solution> Common to processing steps C and D, use the following formulation to <Tank liquid><Replenisher> Ethylenediamine rot -ferric ammonium tetraacetate salt ethylenediamine rf IOf conatrirum tetraacetate salt Sodium sulfite ixy λoy ammonium thiosulfate 2 hiro0rrtl ≠00ml
Ammonium aqueous solution (70%) Ammonia water 10 resistance -Ammonium bromide ≠Of -Add water
/1 /1 pH 7, 27, z <Stabilizing solution> The following formulation was used in common with treatment steps C and D.

<Tank fluid> Refill amount> Ethylenediamine 0.2! t O, 2! f
Di-sodium trilamsulfanil tetraacetate o,iot o,io
t Dobenzotriazo-〇,! Of O, IOofruj-rioo-J-3orrq 3oIn9methyl-≠-isothiazoline- 3-one Formalin Listed in Table 2 Listed in Table 1 (
37 weight section) Fuji Drywell 3-, o~j, 0
rnl hexahydro-/, 0.2ft
O, 21? J,! -) Lis(--Hydroxyethyl)-s-triazine water was added and treated for 1000 g. After continuous treatment for 1000 g., ro 0c elapsed, Hiroo 'C
Table 2 shows the results of Q%RH over time and the presence or absence of precipitation.

According to the present invention, (A/Hiroshi, /j116) there was little discoloration of GL and no precipitation occurred during continuous treatment, whereas the amount of formalin was reduced and conventional treatment (
&/2), the discoloration was large, and the same result was obtained in the treatment not containing formalin (Y/7).

Patent Applicant: Fuji Photo Film Co., Ltd. Procedural Amendment (Voluntary) No. 311, June 1939

Claims (4)

[Claims] (1) After processing the imagewise exposed silver halide color photographic light-sensitive material in a bath having fixing ability, the aldehyde compound is immediately treated with 2
A method for processing a silver halide color photographic light-sensitive material, which comprises processing in a stabilizing bath containing x10^-^3 to 10 x 10^-^3 mol/l. (2) The silver halide color according to claim 1, wherein the bath having fixing ability contains 4×10^-^2 to 0.25 mol/l of sulfite ions. Method of processing photographic materials. (3) A silver halide color photograph according to claim (2), characterized in that the amount of replenishment of the stabilizing bath is 0.5 to 60 times the amount brought in per unit area of the light-sensitive material. How to process photosensitive materials. (4) Claim (1) characterized in that the silver halide color photographic light-sensitive material contains at least one magenta coupler represented by the following general formula (I) or (II). A method for processing the silver halide color photographic light-sensitive material described above. General formula [I] ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the general formula [I], R_1 represents a hydrogen atom or a substituent. Za, Zb and Zc are methine, substituted methine, =N- or -NH - represents a Za-Zb bond and a Zb-Zc bond, one of which is a double bond and the other is a single bond.If Zb-Zc is a carbon-carbon double bond, it is part of an aromatic ring. Including cases where Za,
When Zb or Zc is a substituted methine, it also includes the case where the substituted methine forms a dimer or more multimer. ) General formula [II] ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (In the formula, R_2 represents a carbonamide group, sulfonamide or ureido group, and R_3 represents a phenyl group.