JPS6226201A - Mothproof agent - Google Patents
Mothproof agentInfo
- Publication number
- JPS6226201A JPS6226201A JP16405185A JP16405185A JPS6226201A JP S6226201 A JPS6226201 A JP S6226201A JP 16405185 A JP16405185 A JP 16405185A JP 16405185 A JP16405185 A JP 16405185A JP S6226201 A JPS6226201 A JP S6226201A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- clothing
- effect
- container
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000003349 gelling agent Substances 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims abstract description 3
- 230000008961 swelling Effects 0.000 claims abstract description 3
- 235000019441 ethanol Nutrition 0.000 claims description 29
- 239000000077 insect repellent Substances 0.000 claims description 17
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 9
- 239000004033 plastic Substances 0.000 abstract description 6
- 229920003023 plastic Polymers 0.000 abstract description 6
- 235000013601 eggs Nutrition 0.000 abstract description 4
- 238000001704 evaporation Methods 0.000 abstract description 4
- 230000008020 evaporation Effects 0.000 abstract description 4
- 241000238631 Hexapoda Species 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 230000002542 deteriorative effect Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 230000002070 germicidal effect Effects 0.000 abstract 1
- 230000000266 injurious effect Effects 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229940123973 Oxygen scavenger Drugs 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- -1 pulcohol Chemical compound 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000250966 Tanacetum cinerariifolium Species 0.000 description 1
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940015367 pyrethrum Drugs 0.000 description 1
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はC3以下のアルコールを有効成分とし、
。[Detailed description of the invention] [Industrial field of application] The present invention uses alcohol of C3 or less as an active ingredient,
.
衣類等を収納する容器内で揮散させることによって効果
を発揮する防虫剤に関する。This invention relates to an insect repellent that is effective by being volatilized in a container for storing clothing, etc.
従来防虫剤、とくに衣類等の防虫剤として(1)
’パラシクロールベンゼン、 (2)ナフタリン、(
3)樟脳、(4)ピレスロイド、(5)脱酸素剤等が使
用されている。このうち(1)〜(3)は強い臭いがあ
るため ゛保管場所から出してすぐ着用するのに抵
抗があり、(4)は非常に高価で一般的ではない。また
(5)は酸素不透過性の高い容器との組合せで有効であ
るため、実用には制約がある。Conventional insect repellent, especially as an insect repellent for clothing, etc. (1)
'Paracyclobenzene, (2) Naphthalene, (
3) Camphor, (4) pyrethroids, (5) oxygen scavengers, etc. are used. Among these, items (1) to (3) have a strong odor, making it difficult to wear them immediately after taking them out of storage, and item (4) is very expensive and not common. Furthermore, since (5) is effective in combination with a container having high oxygen impermeability, there are limitations in practical use.
最近は衣類の収納形態が多様化しており、押 □入
れ、ファンンーケース等のような密封度の低 □い
場所に保管することが多くなっているため、 ゛
(1)〜(4)の防虫剤単独では効かない場合が多い。Recently, the storage formats for clothes have become more diverse, and they are often stored in poorly sealed places such as closets and fan cases. In many cases, insect repellents alone are not effective.
゛本発明者らは上記の事情に鑑み、保管形態に
合わせた防虫剤として各種薬剤を鋭意検討した結果、ア
ルコール類が強い防虫性を有することを見出し、次に述
べる発明に到達した。In view of the above-mentioned circumstances, the inventors of the present invention have intensively investigated various insect repellents suitable for storage formats, and as a result, have discovered that alcohols have strong insect repellent properties, and have arrived at the invention described below.
すなわち本発明はC3以下のアルコールを密閉容器内で
揮散させてなる防虫剤である。That is, the present invention is an insect repellent made by volatilizing alcohol of C3 or less in a closed container.
C6以下のアルコールとしてはメチルアルコール、エチ
ルアルコール、フロビルアルコール、プf ル、 フル
コール、アミルアルコールであり、この中メチルアルコ
ールは毒性があって沸点が低く、逆にブチルアルコール
、アミルアルコールは高沸点であるため、エチルアルコ
ール、n−プロピルアルコール、i−7”ロピルアルコ
ールが好ましい。Alcohols with C6 or lower include methyl alcohol, ethyl alcohol, flobyl alcohol, pulcohol, fluorol, and amyl alcohol. Among these, methyl alcohol is toxic and has a low boiling point, while butyl alcohol and amyl alcohol have high boiling points. Therefore, ethyl alcohol, n-propyl alcohol, and i-7'' propyl alcohol are preferred.
本発明に使用される密閉容器としては袋状フィルムが好
ましい。アルコール類は極性が大であるからプラスチッ
ク製フィルムからアルコール蒸気は透過しにくく、最も
透過性大とされるポリエチレンフィルムでも透過量は小
さい。A bag-like film is preferable as the airtight container used in the present invention. Since alcohols are highly polar, alcohol vapor is difficult to permeate through plastic films, and even polyethylene film, which is considered to have the highest permeability, has a small amount of permeation.
なお各種アルコール蒸気のプラスチック製袋・\の影響
は第1表のとおりである。The effects of various types of alcohol vapor on plastic bags are shown in Table 1.
第1表(容器内非接触30℃、1ケ月)密閉容器として
の袋状フィルムは一方に開口部を設け、チャック状に開
閉自在にすればアルコール収納容器、衣類の出入れが簡
便で好ましい。(図参照)
この袋状フィルム中に衣類を収納し開口部を密閉して保
管すれば、袋状フィルム内のアルコールが揮散し、アル
コール蒸気が短時間で充満し、衣類に付着した害虫の卵
、幼虫、成虫を死滅させる。03以下のアルコールでは
特て気化が速いため防虫効果は速効性であり、かつ衣類
を取出した後のアルコール臭もすぐ気散し残存しない。Table 1 (Container non-contact at 30° C. for 1 month) It is preferable that the bag-like film used as a sealed container has an opening on one side and can be opened and closed like a zipper, making it easy to put in and take out the alcohol storage container and clothes. (See figure) If you store clothes in this bag-like film and keep the opening sealed, the alcohol inside the bag-like film will evaporate and the alcohol vapor will fill up in a short time, causing eggs of pests attached to the clothes. , kills larvae and adults. Alcohol of 0.03 or lower evaporates particularly quickly, so the insect repellent effect is fast-acting, and the alcohol smell dissipates quickly and does not remain after clothes are removed.
なお、アルコールを液態のまま容器に収納し袋状フィル
ムに入れてもよいが、容器の転倒でアルコールがこぼれ
ないように予めP紙等にアルコールを滲み込ませたもの
や、ゲル化剤、膨潤剤等でゲル状、固形状にして収納す
るのが好ましい。It is also possible to store alcohol in liquid form in a container and place it in a bag-like film, but in order to prevent the alcohol from spilling if the container falls over, you can use P paper soaked with alcohol in advance, a gelling agent, or a swelling film. It is preferable to store it in a gel or solid form with an agent or the like.
実施例1
スリ合セプタの付いた2tのガラス容器中にイガ幼虫1
0頭、羊毛先約50m9および各種防虫剤42を入れ、
20℃恒温槽中に1週間静置した。(但し蒸散性ピレス
ロイド系薬剤は大日本除虫菊■製を201分使用した。Example 1 One burr larva was placed in a 2t glass container with a slit septa.
0 head, about 50m9 of wool tip and 42 kinds of insect repellents,
It was left standing in a constant temperature bath at 20°C for one week. (However, the transpiration pyrethroid drug manufactured by Dainippon Pyrethrum was used for 201 minutes.
また脱酸素酸は空気3tC酸素600171/り分用で
ある。)第 2 表
実施例2
340m+++X 240wX 40 μmの低密度ポ
リエチレン袋に約1tの空気とイガ卵10頭、幼虫10
頭および各種防虫剤42を入れた(ピレスロイド系、脱
酸素剤は実施例1と同条件)。The deoxidizing acid is for air 3tC oxygen 600171/min. ) Table 2 Example 2 340m+++X 240wX Approximately 1 ton of air, 10 burr eggs, and 10 larvae in a 40 μm low-density polyethylene bag
and various insect repellents 42 (pyrethroid type and oxygen scavenger under the same conditions as in Example 1).
20℃恒温槽に袋を入れ1週間静置した結果を第3表に
示す。Table 3 shows the results of placing the bag in a thermostat at 20° C. and leaving it for one week.
第 3 表
〔発明の効果〕
本発明によれば有効成分がアルコールのため蒸発速度が
速くかつ効力が強いため衣類の害虫の卵、幼虫、成虫を
死滅させるが、その効果は長期間継続し、密閉度の十分
でない容器でも効果は低下しない。アルコールであるか
ら人体に対する安全性は高く、衣類やその付属品(金属
、プラスチック等)に害を及ぼさず、容器のプラスチッ
クも侵さない。また蒸発速度が速いため速効性であると
共に衣類にアルコール臭が残留しない。そのほかアルコ
ールには殺カビ、殺菌効果もあるので、衣類をプラスチ
ック製に収納保管する場合シて最も適した防虫剤であり
、その利用範囲は広い。Table 3 [Effects of the Invention] According to the present invention, since the active ingredient is alcohol, the evaporation rate is fast and the efficacy is strong, so it kills eggs, larvae, and adults of pests on clothing, and the effect lasts for a long time. Even if the container is not tightly sealed, the effectiveness will not be reduced. Since it is alcohol, it is highly safe for the human body, does not harm clothing or its accessories (metal, plastic, etc.), and does not attack the plastic containers. In addition, since the evaporation rate is fast, it is fast-acting and does not leave an alcohol odor on clothing. In addition, alcohol has fungicidal and bactericidal effects, so it is the most suitable insect repellent for storing clothing in plastic, and its range of uses is wide.
図は本発明のアルコールを入れた袋状フィルム容器に衣
類を収納した状態を示す図である。 :1・・・
・・・袋状フィルム容器
2・・・・・・アルコール
3・・・・・・衣類
4・・・・・・袋の開口部The figure shows a state in which clothing is stored in a bag-like film container containing alcohol according to the present invention. :1...
... Bag-shaped film container 2 ... Alcohol 3 ... Clothes 4 ... Opening of bag
Claims (6)
てなる防虫剤(1) Insect repellent made by volatilizing alcohol of C_5 or less in a sealed container
−プロピルアルコール、i−プロピルアルコールである
特許請求の範囲第(1)項記載の防虫剤(2) Alcohol with C_5 or less is ethyl alcohol, n
- The insect repellent according to claim (1), which is propyl alcohol or i-propyl alcohol.
(1)項記載の防虫剤(3) The insect repellent according to claim (1), wherein the airtight container is a bag-like film.
する袋状フィルムである特許請求の範囲第(1)項また
は第(3)項記載の防虫剤(4) The insect repellent according to claim (1) or (3), wherein the airtight container is a bag-like film having a zipper-like opening that can be opened and closed.
形態である特許請求の範囲第(1)項または第(2)項
記載の防虫剤。(5) The insect repellent according to claim (1) or (2), which is in the form of a filter paper or the like impregnated with C_5 or less alcohol.
り、ゲル状、固形状の形態である特許請求の範囲第(1
)項または第(2)項記載の防虫剤(6) The alcohol of C_5 or less is in a gel or solid form by using a gelling agent or a swelling agent.
Insect repellent described in paragraph ) or paragraph (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16405185A JPS6226201A (en) | 1985-07-26 | 1985-07-26 | Mothproof agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16405185A JPS6226201A (en) | 1985-07-26 | 1985-07-26 | Mothproof agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6226201A true JPS6226201A (en) | 1987-02-04 |
| JPH0580441B2 JPH0580441B2 (en) | 1993-11-09 |
Family
ID=15785859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16405185A Granted JPS6226201A (en) | 1985-07-26 | 1985-07-26 | Mothproof agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6226201A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03141310A (en) * | 1989-10-27 | 1991-06-17 | Canon Inc | Zoom lens with focus adjustment means |
| JPH0494980U (en) * | 1991-01-10 | 1992-08-18 | ||
| JPH10287507A (en) * | 1997-04-14 | 1998-10-27 | S T Chem Co Ltd | Hatching inhibitor of fiber pest egg and insect control |
| JP2004026777A (en) * | 2002-06-28 | 2004-01-29 | Earth Chem Corp Ltd | Egg killer and method |
| JP2004175745A (en) * | 2002-11-28 | 2004-06-24 | S T Chem Co Ltd | Insect-proofing agent for grain/dried food product and method for controlling insect pest for grain/dried food product |
| JP2011246364A (en) * | 2010-05-25 | 2011-12-08 | Dainippon Jochugiku Co Ltd | Clothes pest egg hatching inhibitor and pest controlling method using the same |
| JP2013010788A (en) * | 2002-07-10 | 2013-01-17 | Earth Chemical Co Ltd | Ovicide to egg of noxious insect in clothing and ovicidal method to egg of noxious insect in clothing |
-
1985
- 1985-07-26 JP JP16405185A patent/JPS6226201A/en active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03141310A (en) * | 1989-10-27 | 1991-06-17 | Canon Inc | Zoom lens with focus adjustment means |
| JPH0494980U (en) * | 1991-01-10 | 1992-08-18 | ||
| JPH10287507A (en) * | 1997-04-14 | 1998-10-27 | S T Chem Co Ltd | Hatching inhibitor of fiber pest egg and insect control |
| JP2004026777A (en) * | 2002-06-28 | 2004-01-29 | Earth Chem Corp Ltd | Egg killer and method |
| JP2013010788A (en) * | 2002-07-10 | 2013-01-17 | Earth Chemical Co Ltd | Ovicide to egg of noxious insect in clothing and ovicidal method to egg of noxious insect in clothing |
| JP2004175745A (en) * | 2002-11-28 | 2004-06-24 | S T Chem Co Ltd | Insect-proofing agent for grain/dried food product and method for controlling insect pest for grain/dried food product |
| JP2011246364A (en) * | 2010-05-25 | 2011-12-08 | Dainippon Jochugiku Co Ltd | Clothes pest egg hatching inhibitor and pest controlling method using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0580441B2 (en) | 1993-11-09 |
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