JPS62286041A - Photographic film magazine - Google Patents
Photographic film magazineInfo
- Publication number
- JPS62286041A JPS62286041A JP12988186A JP12988186A JPS62286041A JP S62286041 A JPS62286041 A JP S62286041A JP 12988186 A JP12988186 A JP 12988186A JP 12988186 A JP12988186 A JP 12988186A JP S62286041 A JPS62286041 A JP S62286041A
- Authority
- JP
- Japan
- Prior art keywords
- film
- shielding member
- antistatic agent
- light
- phosphoric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002216 antistatic agent Substances 0.000 claims abstract description 44
- 239000000314 lubricant Substances 0.000 claims abstract description 33
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 24
- -1 phosphoric acid compound Chemical class 0.000 claims description 68
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 9
- 150000002148 esters Chemical class 0.000 abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 7
- 230000001476 alcoholic effect Effects 0.000 abstract description 6
- 150000005846 sugar alcohols Polymers 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 208000014617 hemorrhoid Diseases 0.000 abstract description 4
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 239000007795 chemical reaction product Substances 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 2
- 230000035945 sensitivity Effects 0.000 abstract description 2
- 125000001424 substituent group Chemical group 0.000 abstract description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 35
- 239000000839 emulsion Substances 0.000 description 34
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 30
- 108010010803 Gelatin Proteins 0.000 description 29
- 239000008273 gelatin Substances 0.000 description 29
- 229920000159 gelatin Polymers 0.000 description 29
- 235000019322 gelatine Nutrition 0.000 description 29
- 235000011852 gelatine desserts Nutrition 0.000 description 29
- 229910052709 silver Inorganic materials 0.000 description 29
- 239000004332 silver Substances 0.000 description 29
- 239000000243 solution Substances 0.000 description 21
- 230000003068 static effect Effects 0.000 description 20
- 238000000034 method Methods 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 12
- 239000000835 fiber Substances 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 7
- 229910021612 Silver iodide Inorganic materials 0.000 description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 7
- 229910052737 gold Inorganic materials 0.000 description 7
- 239000010931 gold Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- 229940045105 silver iodide Drugs 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 6
- NHQVTOYJPBRYNG-UHFFFAOYSA-M sodium;2,4,7-tri(propan-2-yl)naphthalene-1-sulfonate Chemical compound [Na+].CC(C)C1=CC(C(C)C)=C(S([O-])(=O)=O)C2=CC(C(C)C)=CC=C21 NHQVTOYJPBRYNG-UHFFFAOYSA-M 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 2
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical compound SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000257465 Echinoidea Species 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 150000004668 long chain fatty acids Chemical class 0.000 description 2
- 239000006224 matting agent Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 229930182490 saponin Natural products 0.000 description 2
- 150000007949 saponins Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 description 1
- SRBSSROHORQGBO-UHFFFAOYSA-N 11-methyldodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C SRBSSROHORQGBO-UHFFFAOYSA-N 0.000 description 1
- RDMIJQCFPQDYQN-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=CC=C1O RDMIJQCFPQDYQN-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 101100207372 Curvularia clavata TR09 gene Proteins 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
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- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- HVWGGPRWKSHASF-UHFFFAOYSA-N Sulfuric acid, monooctadecyl ester Chemical compound CCCCCCCCCCCCCCCCCCOS(O)(=O)=O HVWGGPRWKSHASF-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- 229960001413 acetanilide Drugs 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 125000002947 alkylene group Chemical group 0.000 description 1
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- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 150000001555 benzenes Chemical group 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
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- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
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- ZUIVNYGZFPOXFW-UHFFFAOYSA-N chembl1717603 Chemical compound N1=C(C)C=C(O)N2N=CN=C21 ZUIVNYGZFPOXFW-UHFFFAOYSA-N 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
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- 238000011109 contamination Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
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- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 235000021331 green beans Nutrition 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DHEJKONKJWLHGP-UHFFFAOYSA-N n-[4-[2,4-bis(2-methylbutan-2-yl)phenoxy]butyl]-1-hydroxynaphthalene-2-carboxamide Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC=C1OCCCCNC(=O)C1=CC=C(C=CC=C2)C2=C1O DHEJKONKJWLHGP-UHFFFAOYSA-N 0.000 description 1
- RMHJJUOPOWPRBP-UHFFFAOYSA-N naphthalene-1-carboxamide Chemical compound C1=CC=C2C(C(=O)N)=CC=CC2=C1 RMHJJUOPOWPRBP-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000001148 pentyloxycarbonyl group Chemical group 0.000 description 1
- YEHCICAEULNIGD-MZMPZRCHSA-N pergolide Chemical compound C1=CC([C@H]2C[C@@H](CSC)CN([C@@H]2C2)CCC)=C3C2=CNC3=C1 YEHCICAEULNIGD-MZMPZRCHSA-N 0.000 description 1
- 229940088507 permax Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C3/00—Packages of films for inserting into cameras, e.g. roll-films, film-packs; Wrapping materials for light-sensitive plates, films or papers, e.g. materials characterised by the use of special dyes, printing inks, adhesives
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
Description
【発明の詳細な説明】
３、発明の詳細な説明
［産業上の利用分野］
本発明は写真フィルムマガジンに関し、詳しくは写真フ
ィルムマガジンのフィルム出入口部に貼着されるパイル
を有する遮光部材を改良した写真フィルムマガジンに関
する。Detailed Description of the Invention 3. Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a photographic film magazine, and more specifically, an improvement to a light-shielding member having a pile attached to the film entrance/exit portion of a photographic film magazine. Regarding the photographic film magazine.
［発明の背明１
写真フィルムマガジンは、通常、フィルム出入口部から
光がマガジン本体内部に進入しないようにフィルム出入
口部分に遮光部材が貼着されている。この遮光部材は、
フィルムの感光防止のほか、フィルム引出し時及び巻ぎ
戻し時のフィルムの損傷防止並びにフィルム引出し及び
巻き戻し操作の円滑化をはかることができるものでなｔ
プればならないために、パイル織物等の柔軟な月利が使
用されている。[Background of the Invention 1 In a photographic film magazine, a light shielding member is usually attached to the film entrance/exit portion to prevent light from entering the inside of the magazine body from the film entrance/exit portion. This light shielding member is
In addition to preventing the film from being exposed to light, it can also be used to prevent damage to the film when drawing out and rewinding the film, and to make the operation of drawing out and rewinding the film smoother.
Because of this, flexible monthly rates such as pile fabrics are used.
又、最近のカメラの動向どしては、高速自動巻き上げ巻
ぎ戻しのカメラが中心となっているのが現状である。こ
れらのカメラの普及に伴い、カメラの操作時に写真フィ
ルムマガジンの出入口に貼着された遮光部材とフィルム
の接触により静電気が発生し、これが放電することによ
り、放電部分のみ感光し、現像処理により樹枝状、雲状
、綿状等と様々な汚染部が坦われることがある。以下、
これらの汚染部をスタチックマークと言う。Furthermore, the current trend in cameras is that cameras with high-speed automatic winding and rewinding have become the main focus. With the spread of these cameras, when the camera is operated, static electricity is generated due to contact between the film and the light-shielding material affixed to the entrance/exit of the photographic film magazine, and as this discharges, only the discharged area becomes exposed to light, and during the development process, the branches of the tree are exposed. Various types of contamination may occur, such as cloud-like, cloud-like, and cotton-like shapes. below,
These contaminated areas are called static marks.
これらスタチックマークの発生を防ぐ手段として特開昭
５５−１２９１７号に記載されている如く、パイルに有
機導電性ＩＩ紺を使用したり、実開昭４６−２８２１８
号に記載されている如く、パイル表面に銀、金、銅、黄
銅、ニッケル等の導電性微粉末を合成樹脂等に分散し、
これをパイル表面に接着被覆した連光部材を使用する技
術が開示されている。As a means to prevent the generation of these static marks, organic conductive II navy blue is used for the pile as described in Japanese Patent Application Laid-Open No. 55-12917, and
As described in the issue, conductive fine powder of silver, gold, copper, brass, nickel, etc. is dispersed in synthetic resin etc. on the pile surface,
A technique has been disclosed in which a light-linking member is adhesively coated on the pile surface.
しかしながらこれらの帯電防止法は、帯電防止の効果と
してはあるが、繊維の柔軟性が失われ、フィルムにキズ
がつきやすくなったり、）１電竹を増すだめの導電性物
質の添加比率を増加することはさらにキズに対する危険
が増加するし、ロス１〜高にもなり好ましい方法ではな
い。However, although these antistatic methods have an antistatic effect, they also cause the fibers to lose their flexibility, making the film more susceptible to scratches, and increase the ratio of conductive substances added to increase the strength of the electric bamboo. Doing so will further increase the risk of scratches and result in loss of 1 to 10%, which is not a preferable method.
他方、フィルムを引出す時の摩擦を少しでｂ減少するた
めに、フィルム出入口部の高さを写真フィルムマガジン
の機能を損なわない程度に拡げて対応を取ることも知ら
れている。しかしながらこの方法は確かにある程度の摩
擦が減少するため静電気の発生は減少させる事は可能で
あるが、最大の欠点としては写真フィルムマガジンの生
産のバラツキによりその適正高さを製造上管理すること
が困難であり、フィルム出入口部の高さが高くなったり
低くなったりすることがあり、高（なった場合は出入口
からの漏光の問題、又低くなった場合は摩擦が強くなり
静電気の発生が多くなる、といった様に安定な生産を維
持する事が非常に困難な手段である。On the other hand, it is also known to increase the height of the film inlet/outlet portion to an extent that does not impair the functionality of the photographic film magazine in order to reduce the friction even slightly when pulling out the film. However, although this method does reduce friction to a certain extent and can reduce the generation of static electricity, the biggest drawback is that it is difficult to control the appropriate height during manufacturing due to variations in the production of photographic film magazines. This is difficult, and the height of the film entrance/exit part may be high or low. It is extremely difficult to maintain stable production.
一方、使用するフィルムもフィルム出入口部の遮光部材
との接触に伴う静電気の帯電を少しでも減らずためにフ
ィルムに帯電防止処理を施したり、フィルムの裏面に帯
電防止層を設けたり、又、スベり性を改良してはいる。On the other hand, in order to prevent even the slightest reduction in the electrostatic charge caused by contact with the light-shielding member at the film entrance/exit, the film used is treated with antistatic treatment, an antistatic layer is provided on the back side of the film, and a smooth surface is used. The durability has been improved.
しかしながら最近のフィルムはＡ Ｓ Ａ １０００、
Ａｓへ１６００のように感度が極めて高いもの、さらに
高品位のものが指向されており、さらに機械的強度及び
寸法安定性の向上を目的どして静電気が発生し易いポリ
エステルフィルムベースが使用されるようになり、上記
フィルムに帯電防止を施す従来の手段だ（Ｊでは、自動
巻上げ、巻房し機構の付いたカメラを使用した高速写真
撮影時には、前記スタチックマークの発生は防ぎきれな
くなっているのが現状である。However, recent films are ASA 1000,
Products with extremely high sensitivity such as As 1600 and even higher quality products are being sought after, and polyester film bases, which tend to generate static electricity, are used to improve mechanical strength and dimensional stability. This is a conventional means of applying anti-static properties to the above film. is the current situation.
［発明の目的］
従って、本発明の目的は高感度、高品位の写真フィルム
を内蔵しても、写真フィルムマガジンの機能を損なうこ
となしに安価にかつ安定に帯電防止機能を向上した遮光
部材を有する写真フィルムマガジンを提供することであ
る。[Object of the Invention] Therefore, the object of the present invention is to provide a light-shielding member that stably improves the antistatic function at low cost and without impairing the function of the photographic film magazine even when high-sensitivity, high-quality photographic film is incorporated. To provide a photographic film magazine with
［発明の構成］
本発明の上記［１的は、パイルを有する遮光部材が写真
フィルム出入口部に貼着されＩＣ写真フィルムマガジン
において、前記遮光部材がリン酸化合物系帯電防止剤お
よび潤滑剤で処理されている写真フィルムマガジンによ
り達成される。[Structure of the Invention] [1] The above-mentioned aspect of the present invention is an IC photographic film magazine in which a light-shielding member having a pile is attached to an entrance/exit portion of a photographic film, and the light-shielding member is treated with a phosphoric acid compound-based antistatic agent and a lubricant. Achieved by photographic film magazines.
［発明の具体的構成］
本発明の写真フィルムマガジンは、パイルを有づ−る遮
光部材がリン酸化合物系帯電防止剤および１ｌｖＩ滑剤
で処理されているものである。[Specific Structure of the Invention] In the photographic film magazine of the present invention, the light-shielding member having piles is treated with a phosphoric acid compound-based antistatic agent and a lvI lubricant.
本発明に用いられるリン酸化合物系帯電防止剤としては
、米国特許第２．１４２．９９８号、同２，２５５，１
１２号、同２，２８６，７９４号、同２，２７９，５０
０号、同２，２７９、５０１号、同２，３１８．２９６
号、同２，３３６，２３０号、同２、３４５．７３４号
、同 ２，３６４，３４８号、同 ２，３７６．１３０
号、同２，３８６，２５０号、同２．４１３．４２８号
、同２．４３０．５６９号、同２，４９８，４０８号、
同２．５７７、６３５号、同２．６７６゜１２２号、同
２．６７６、９２４号、同２，７２７，８５０号、同２
、７３０．４９８号、同 ２，７４２，３７９号、同
２，６９１，５５６号、同２，６７６．９７５月等に記
載の化合物が挙げられる。As the phosphoric acid compound-based antistatic agent used in the present invention, US Pat.
No. 12, No. 2,286,794, No. 2,279,50
No. 0, No. 2,279, No. 501, No. 2,318.296
No. 2,336,230, No. 2,345.734, No. 2,364,348, No. 2,376.130
No. 2,386,250, No. 2.413.428, No. 2.430.569, No. 2,498,408,
2.577, 635, 2.676°122, 2.676, 924, 2,727,850, 2
, No. 730.498, No. 2,742,379, No. 730.498, No. 2,742,379, No.
Examples include compounds described in No. 2,691,556, No. 2,676.975, and the like.
具体的には亜リン酸、亜リン酸塩、リン酸、リン酸塩の
群ど秒々のアルコール性またはフェノール性水酸基を右
する化合物どのエステル反応生成物が挙げられる。Specific examples include ester reaction products of phosphorous acid, phosphites, phosphoric acid, phosphate groups, and compounds having alcoholic or phenolic hydroxyl groups.
上記アルコール性水酸基を有する化合物どしては、好ま
しくは炭素原子数５〜１８の一価アルコール、多価アル
コールが挙げられ、また、主鎖にエーテル結合を有する
、例えばポリアルキレンオキシ基を有するアルコール性
水酸基誘導体も包含される。さらにフェノール性水１１
ｆ’ｌを有する化合物は、好ましくはベンゼン核に炭素
原子数５〜１６のアルキル基等の置換基が置換したフェ
ノール等が挙げられる。The above-mentioned compounds having an alcoholic hydroxyl group preferably include monohydric alcohols and polyhydric alcohols having 5 to 18 carbon atoms, and alcohols having an ether bond in the main chain, for example, a polyalkyleneoxy group. hydroxyl group derivatives are also included. Furthermore, phenolic water 11
Preferably, the compound having f'l is a phenol having a benzene nucleus substituted with a substituent such as an alkyl group having 5 to 16 carbon atoms.
以下に本発明に用いられるリン酸化合物系帯電防止剤の
具体例を商品名で示す。Specific examples of the phosphoric acid compound-based antistatic agents used in the present invention are shown below by trade names.
ニレタラ！−ＪＡＡ−４２８（一方社油脂Ｔ業判製）、
エレナイ１〜ＡＢ−１００，−ＡＢ−１５０（高松油脂
社製）、アルコール性 Ｓ−１３６１Ｅ 。Nile cod! -JAA-428 (manufactured by Ichisha Yushi T-gyoban),
Elenai 1 to AB-100, -AB-150 (manufactured by Takamatsu Yushi Co., Ltd.), alcoholic S-1361E.
−ＴＳ−２３０Ｆ、−Ｃ８−１４１Ｅ、−ＰＳ−８１０
Ｅ、 −ＰＳ−４４０Ｅ、 −ＰＳ−５０９Ｅ （加電
化社製）、エレク！−〇ストリッパーに、−Ｆ、エスタ
ミットＴＲ０９（花王社製）、デートロンＮ。-TS-230F, -C8-141E, -PS-810
E, -PS-440E, -PS-509E (manufactured by Kadenkasha), Elec! -〇 Stripper, -F, Estamit TR09 (manufactured by Kao Corporation), Daytron N.
−Ｎ−２０，−Ｎ−３０（日華化学工業社製）、Ａ Ｉ
ｍａｒ （アルマ−）１」〈目星化成社製）、Ｆ ｒｒ
ｃｏｌ （エフコール）３０１（松本油脂社製）、Ｆ
ｍａｌｏｘ （工ｖロツクス）ＤＥＰ−１，１−ＥＰ
−１、ｐｅｒｍａｘ （バーマックス） ｐ Ｍ −
３００１゜−ｐＭ−５０３，−ＰＭ−３００８（吉村油
化学社製）、Ｆ ｌ １ｍ１ｎａ （エリミナ）Ｓ−２
，−８Ｒ（丸菱油化社製） 、Ｅ １ｅｔｏｌ （ニ
レトール）ＯＰ（朝日油脂社製） 、Ｅ １ｅｎｏｎ
（ニレノン）Ｎｏ １９Ｍ、Ｎ。-N-20, -N-30 (manufactured by Nicca Chemical Industry Co., Ltd.), A I
mar (Almar) 1" (manufactured by Meboshi Kasei Co., Ltd.), F rr
col (Fcol) 301 (manufactured by Matsumoto Yushi Co., Ltd.), F
malox DEP-1,1-EP
-1, permax (vermax) p M -
3001°-pM-503, -PM-3008 (manufactured by Yoshimura Yukagaku Co., Ltd.), Fl 1mlna (Elimina) S-2
, -8R (manufactured by Marubishi Yuka Co., Ltd.), E 1etol OP (manufactured by Asahi Yuka Co., Ltd.), E 1enon
(Nirenon) No. 19M, N.
−１００３（第１工業製薬社製） 、３ ａｎｓｔａｔ
（ザンスタッ１〜）２３０−Ｄ（三洋化成工業社製）
、Ｓ ｕｎｔｅｘ （サンテックス）ＨＥ（平松油化
社製）、３ ｅｐａｒｏｎ （セパロン＞Ａ、−ＡＰ（
入京化学社製） 、ｚｅ＋ｅｘ（ゼレツクス）ＯＫ（ミ
ヨシ油脂社製） 、［］ｅｓｔａｔ （デスタット）
ＡＰ−１，−ＡＮ（共栄社油脂化学工業社製） 、Ｈｙ
ｐｌｏｎ （ハイブロン）ＡＰ（日新化学社製） 、
ｌ” ｕｋｓｔａｔ （７クスタツト）Ａ−５０（上幅
化学工業社製）、ｌ−ｅｏｍｉｎ （レオミン）ＰＥ
、 −ＰＮ ［１−（ｏｅ（ヒユー）社製］等。-1003 (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.), 3 anstat
(Zansta 1~) 230-D (manufactured by Sanyo Chemical Industries, Ltd.)
, Suntex HE (manufactured by Hiramatsu Yuka Co., Ltd.), 3 eparon (Separon > A, -AP (
(manufactured by Ikyo Kagaku Co., Ltd.), ze+ex OK (manufactured by Miyoshi Yushi Co., Ltd.), []estat (Destat)
AP-1, -AN (manufactured by Kyoeisha Yushi Kagaku Kogyo Co., Ltd.), Hy
plon (Hybron) AP (manufactured by Nissin Chemical Co., Ltd.),
l”ukstat (7kstat) A-50 (manufactured by Uehaba Kagaku Kogyo Co., Ltd.), l-eomin (Leomin) PE
, -PN [1-(manufactured by OE), etc.
上記本発明に用いられるリン酸化合物系帯電防止剤は１
種を単独で用いても２種以上併用してもよく、ざらにノ
ニオン性弄面活性剤と併用１−ることもできる。The phosphoric acid compound antistatic agent used in the present invention is 1
The species may be used alone or in combination of two or more species, and may also be used in combination with a nonionic surfactant.
Ｖｆ用できるノニオーン性界面活性剤どしては、例えば
ザボニン〈ステロイド系）、アルキレンオキザイド誘導
体（例えば、ポリエチレングリコール／ポリプロピレン
グリコール縮合物、ポリエチレングリコールアルキルエ
ーテル類またはポリエチレングリコールアルキルアリー
ルエーテル類、ポリエチレングリコールエステル類、ポ
リエチレングリコールソルビタンエステル類、ポリアル
キレングリコールアルキルアミンまたはアミド類、シリ
コーンのポリエヂレンオキザイド付加物類）、グリシド
ール誘導体（例えばアルケニルコハク酸ポリグリセリド
、アルキルフェノールポリグリセリド）、多価アルコー
ルの脂肪酸エステル類、糖のアルキルエステル類等が挙
げられる。Nonionic surfactants that can be used for Vf include, for example, Zabonin (steroid type), alkylene oxide derivatives (for example, polyethylene glycol/polypropylene glycol condensates, polyethylene glycol alkyl ethers or polyethylene glycol alkyl aryl ethers, polyethylene glycol esters, polyethylene glycol sorbitan esters, polyalkylene glycol alkylamines or amides, polyethylene oxide adducts of silicones), glycidol derivatives (e.g. alkenylsuccinic acid polyglycerides, alkylphenol polyglycerides), fatty acids of polyhydric alcohols. Examples include esters and sugar alkyl esters.
」１記において、グリセリン、ポリエチレングリコール
、ソルビトール等の多価アルコール類は帯電防止の効果
を有するが吸湿性が強く、写真フィルムに対し保存時に
おける悪影響を与えることからその使用は好ましくない
。また、上記の帯電防止剤に併用される塩化リチウム、
塩化マグネシウム、醋酸カリ等の吸湿性が強い塩類の使
用も好ましくない。1, polyhydric alcohols such as glycerin, polyethylene glycol, and sorbitol have an antistatic effect, but are highly hygroscopic and have an adverse effect on photographic film during storage, so their use is not preferred. In addition, lithium chloride, which is used in combination with the above antistatic agent,
It is also not preferable to use highly hygroscopic salts such as magnesium chloride and potassium acetate.
上記リン酸化合物系帯電防止剤でパイルを有する遮光部
材を処理するには、パイルを有する遮光部材に帯電防止
機能が付与されれば、パイルを有する遮光部材の製造工
程のどの段階、例えばパイル系等の製造過程で処理して
もよいが、最大の効果を得るには遮光部月製造の最終工
程で処理することが好ましい。In order to treat a pile-containing light-shielding member with the above-mentioned phosphoric acid compound-based antistatic agent, if the pile-containing light-shielding member is imparted with an antistatic function, at which stage of the manufacturing process of the pile-containing light-shielding member, for example, pile type However, in order to obtain the maximum effect, it is preferable to perform the treatment in the final step of manufacturing the light shielding part.
具体的な処理方法としては、リン酸化合物系帯電防止剤
の添加液に遮光部材を浸漬するか、リン酸化合物系帯電
防止剤添加液を遮光部材の表面、特にパイル面側に均一
にスプレー等の手段により散布する等が挙げられる。Specific treatment methods include immersing the light-shielding member in an additive solution of a phosphoric acid compound-based antistatic agent, or spraying a phosphoric acid compound-based antistatic agent additive solution uniformly on the surface of the light-shielding member, especially on the pile side. Examples include dispersing by means of.
パイルを有する遮光部材をリン酸化合物系帯電防止剤添
加液に浸漬処理する場合、一般的に下記式で表わされる
絞り率
（％）
で絞った後、遮光部材を加熱乾燥させる。この場合、乾
燥は比較的低温で長時間で乾燥しても前乾燥し、次いで
高温乾熱処理を行なってもよい。この前乾燥の温度は、
用いるパイル繊維、基布繊維等の種類、帯電防止剤の種
類等により賃なるが、概ね６０〜１２０℃で３０〜２４
０秒の範囲が好ましく用いられ、高温乾熱処理温度も同
様に１５０〜１９０℃で２０〜６０秒の範囲が好ましく
用いられる。When a light-shielding member having a pile is immersed in a solution containing a phosphoric acid compound-based antistatic agent, the light-shielding member is heated and dried after being squeezed at a reduction ratio (%) generally expressed by the following formula. In this case, the drying may be performed at a relatively low temperature for a long time, or may be pre-dried, followed by high-temperature dry heat treatment. The pre-drying temperature is
Although it depends on the type of pile fiber, base fabric fiber, etc. used, the type of antistatic agent, etc., it is generally 30~24℃ at 60~120℃.
A range of 0 seconds is preferably used, and a high temperature dry heat treatment temperature of 150 to 190°C and a range of 20 to 60 seconds is also preferably used.
上記リン酸化合物系帯電防止剤で処理した乾燥条件は、
前記スプレー等による遮光部材の帯電防止剤処理の際に
も適用できるものである。The drying conditions for treatment with the above phosphoric acid compound antistatic agent are as follows:
It can also be applied when treating a light shielding member with an antistatic agent using the spray or the like.
上記リン酸化合物系帯電防止剤は水溶媒に溶解して添加
液として用いられる場合、リン酸化合物系帯電防止剤の
種類、遮光部材に用いるｖａｎの種類等により異なるが
、その添加液濃度は、浸漬処理用の場合、０，５〜３重
量％程度で使用され、スプレー等による散布処理用の場
合２〜１０重量％程度の範囲で用いられるのが好ましい
。When the above-mentioned phosphoric acid compound-based antistatic agent is dissolved in an aqueous solvent and used as an additive liquid, the concentration of the additive liquid varies depending on the type of phosphoric acid compound-based antistatic agent, the type of van used for the light-shielding member, etc. In the case of dipping treatment, it is preferably used in an amount of about 0.5 to 3% by weight, and in the case of dispersion treatment by spraying, it is preferably used in a range of about 2 to 10% by weight.
上記リン酸化合物系帯電防止剤のパイルを有する遮光部
材への付き量は、帯電防止剤の種類、遮光部材繊維の種
類等により異なるが、概ね、乾燥後の重量として０．０
５〜１０（］／ｕ’が好ましく、より好ましくは０．５
〜７ｇ／］Ｉ２の範囲である。The amount of the above-mentioned phosphoric acid compound-based antistatic agent applied to the light-shielding member having piles varies depending on the type of antistatic agent, the type of light-shielding member fiber, etc., but is approximately 0.0 as the weight after drying.
5 to 10(]/u' is preferable, more preferably 0.5
~7g/]I2.
本発明においては、上記リン酸化合物系帯電防止剤で処
理すると同時にまたは独立して潤滑剤で、パイルを有す
る遮光部材を処理する。In the present invention, the light-shielding member having piles is treated with a lubricant simultaneously or independently with the treatment with the phosphoric acid compound-based antistatic agent.
本発明に用いられる潤滑剤は、一般に潤滑剤と呼ばれる
ものが全て包含され、具体的には以下のものが挙げられ
る。The lubricant used in the present invention includes all those generally called lubricants, and specifically includes the following.
長鎖アルキル硫酸エステル塩類（例えば、ドデシル硫酸
ナトリウム、オクタデシル硫酸す１ヘリウム等）、長鎖
脂肪酸アミド類（例えば、Ｎ、 Ｉｌ−ジエチルステア
リン酸アミド、ベヘン酸アミド等）、脂肪酸エステル類
（例えば、ラウリン酸メチル、ステアリン酸イソトリデ
シル、Ａレイン酸イソブヂル等）、多塩基酸のエステル
類（例えば、フタル酸ジデシル、ピロメリト酸テ］へラ
オクヂル、１〜リメリｌ−Ｍ ｔ−リイソデシル等）、
多価アルコールの脂肪酸エステル類（例えば、ソルビタ
ンモノラウレ−１・、ソルビタンモノステアレート、ポ
リオキシエヂレンソルビタンモノステアレ−１・、ボリ
エヂ１ノングリコールジステアレート等）、グリセリン
の脂肪酸エステル類（例えば、ステアリン酸モノグリセ
ライド、ステアリン酸ジグリセライド、カプリン酸ｉ〜
リグリセライド等）、ワックス類、パラフィン油類、長
鎖α−カルボン酸ベタイン類（例えば、Ｎ−ステアリル
−Ｎ、Ｎ−ジメチル−α−カルボン酸ベタイン＠）、シ
リコーン類［例えば、信越化学工業株式会社製のシリコ
ーン類（例えば、商品名Ｐ ｏｌｏｎ−Ｍ Ｒ、−Ｍ
Ｇ 。Long-chain alkyl sulfate ester salts (e.g., sodium dodecyl sulfate, octadecyl sulfate, etc.), long-chain fatty acid amides (e.g., N, Il-diethylstearamide, behenic acid amide, etc.), fatty acid esters (e.g., methyl laurate, isotridecyl stearate, isobutyl Aleate, etc.), esters of polybasic acids (for example, didecyl phthalate, te]heraocdyl pyromellitate, 1-limelli l-M t-liisodecyl, etc.),
Fatty acid esters of polyhydric alcohols (e.g., sorbitan monolaure-1, sorbitan monostearate, polyoxyethylene sorbitan monostearate-1, polyethylene 1 non-glycol distearate, etc.), fatty acid esters of glycerin (For example, stearic acid monoglyceride, stearic acid diglyceride, capric acid i~
liglycerides, etc.), waxes, paraffin oils, long-chain α-carboxylic acid betaines (e.g., N-stearyl-N, N-dimethyl-α-carboxylic acid betaine @), silicones [e.g., Shin-Etsu Chemical Co., Ltd. Company-manufactured silicones (for example, product name Polon-MR, -M
G.
−ＭＮ、−ＭＦ−２Ａ、 −ＭＦ−６，−ＭＷＳ。-MN, -MF-2A, -MF-6, -MWS.
−ＭＹ、−ＭＫ−２０６、Ｋ１−９６等）、共栄社油脂
化学工業株式会社製のシリコーン類（例えば、商品名ラ
イトシリ」−ンＭ−５０５，−Ｊ−７０２。-MY, -MK-206, K1-96, etc.), silicones manufactured by Kyoeisha Yushi Kagaku Kogyo Co., Ltd. (for example, trade name Light Silicone M-505, -J-702).
−Ｎｏ−７５等）等１、コ［１イダルシリ方類［例えば
、日産化学工業株式会ネ］製のコロイダルシリカ類（例
えば、商品名スノーラテックス２０゜−３０，−／１０
．−Ｃ，−Ｎ、−０，−８゜−２０１，−０１−雪）等
］、アルミナ水和物（ベーマイト系）の＝１０イド液［
例えば、Ｆ１産化学工業株式会社製のアルミナゾル等］
等、さらに、」−記以外にも特公昭４６−２７４２８月
、同５３−２９２号、米［ｌ特許第３，０４２，５２２
号等に記載の潤滑剤も用いることができる。-No.75, etc.) etc. 1, colloidal silica manufactured by [e.g. Nissan Chemical Industries, Ltd.] (e.g., trade name Snow Latex 20°-30, -/10)
．． -C, -N, -0, -8° -201, -01-yuki), etc.], =10 id solution of alumina hydrate (boehmite type) [
For example, alumina sol manufactured by F1 San Kagaku Kogyo Co., Ltd.]
In addition to the above, there are also Japanese Patent Publications No. 53-292, August 1973, and U.S. Patent No. 3,042,522.
The lubricants described in No. 1, etc. can also be used.
上記潤滑剤はで−べて本発明に有効であるが、本発明に
好ましく用いられるものとしては、脂肪酸エステル類、
長鎖脂肪酸アミド類、シリコーン類、コロイダルシリカ
類、アルミナ水和物のコロイド液、ワックス類等であり
、特に好ましく用いられるしのは脂肪酸エステル類、シ
リコーン類、］コロイダルシリカ類アルミナ水和物の］
［１イド液である。All of the above lubricants are effective in the present invention, but those preferably used in the present invention include fatty acid esters,
These include long-chain fatty acid amides, silicones, colloidal silicas, colloidal liquids of alumina hydrates, waxes, etc. Particularly preferably used are fatty acid esters, silicones, colloidal silicas, alumina hydrates, etc. ]
[1 id liquid.
本発明に４３いて、上記潤滑剤を用いてパイルを有する
遮光部材を処理する方法どしては、前記帯電防止剤と同
時にまたは独立して潤滑剤を水、アルコール類（メタノ
ール、エタノール等）、ケトン類（アセ１〜ン等）、エ
ステル類（酢酸エチル等）等の溶媒に適宜の濃度に溶解
または分散して潤滑剤の溶液または分散液とし、該液を
スプレー等の手段にＪ：り遮光部材のパイル面側に散布
して行うことができる。また、この場合、遮光部材のパ
イル面側のみを前記潤滑剤の液に浸漬したり、液を塗布
してもよい。According to the present invention, a method for treating a light shielding member having a pile using the above lubricant includes adding a lubricant to water, alcohols (methanol, ethanol, etc.) simultaneously or independently with the antistatic agent. A lubricant solution or dispersion is obtained by dissolving or dispersing ketones (acetate, etc.), esters (ethyl acetate, etc.) in a solvent such as esters (ethyl acetate, etc.) at an appropriate concentration, and the liquid is sprayed or otherwise sprayed. This can be done by scattering it on the pile surface side of the light shielding member. Further, in this case, only the pile surface side of the light shielding member may be immersed in the lubricant liquid or may be coated with the lubricant liquid.
また、潤滑剤の処理はパイルを有づる遮光部材をフィル
ムマガジン本体に貼着する前でも貼着後でもよい。Further, the lubricant treatment may be performed before or after the light shielding member having the pile is attached to the film magazine body.
上記潤滑剤は１梗を単独で用いても２梗以上を併用して
もよく、潤滑剤のパイルを右づる遮光部材のパイル面側
への処理爪どしては、遮光部材、特にパイルの月貿、潤
滑剤の種類等にＪ：り大きく異なるが、概ね、乾燥後の
パイル面側の付き吊として０．０３〜２ （１／ ｖ’
であることが好ましく、より好ましくは０．０５〜２（
１／ｗ’であり、特に好ましくは０．１〜１．５ｇ／ｉ
’の範囲である。The above-mentioned lubricant may be used alone or in combination with two or more. When the lubricant is applied to the pile surface side of the light-shielding member that moves the pile of lubricant to the right, the light-shielding member, especially the pile. Although it varies greatly depending on the month, type of lubricant, etc., it is generally 0.03 to 2 (1/v') for the hanging on the pile surface side after drying.
It is preferable that it is, more preferably 0.05 to 2 (
1/w', particularly preferably 0.1 to 1.5 g/i
' range.
上記リン酸化合物系帯電防止剤および潤滑剤の処理と同
時または独立して、各種樹脂類、はっ水剤、柔軟剤等の
各種仕上加工剤で本発明の遮光部材を処理することは当
然本発明に包含される。It goes without saying that the light-shielding member of the present invention may be treated with various finishing agents such as various resins, water repellents, and softeners simultaneously or independently of the treatment with the phosphoric acid compound-based antistatic agent and lubricant. covered by the invention.
本発明の上記リン酸化合物系帯電防止剤および潤滑剤で
処理がされるパイルを有する遮光部材としては、パイル
および基布用繊維の材質、その縄絹織または８１１１Ｊ
ｔ等任意のものが使用することができ、パイル用繊維お
よび基布用繊維は同じでも異なってもよく、例えばナイ
ロン６．６等のポリアミド系、ポリエチレンテレフタレ
ート等のポリエステル系、ポリエチレン等のポリオレフ
ィン系、ポリビニルアルコール系、ポリ塩化ビニリタン
系、ポリ塩化ビニル系、ポリアクリロニＩ・リル系、ポ
リシアン化ビニリデン系、ポリフルオロエチレン系、ポ
リウレタン系等の合成繊維、絹、綿、羊毛、セルロース
系、セルロースエステル系等の天然繊維、再生域Ｉｌｆ
′（レーヨン）の中から選ばれる１種もしくは２種以上
を組合せた繊維が挙げられる。The light-shielding member having a pile treated with the above-mentioned phosphoric acid compound-based antistatic agent and lubricant of the present invention includes the material of the pile and the fiber for the base fabric, its rope silk weave or 8111J
Any fiber such as t can be used, and the pile fiber and the base fabric fiber may be the same or different, such as polyamide-based materials such as nylon 6.6, polyester-based materials such as polyethylene terephthalate, and polyolefin-based materials such as polyethylene. Synthetic fibers such as polyvinyl alcohol, polyvinylithane, polyvinyl chloride, polyacryloni-I-Lyl, polycyanide vinylidene, polyfluoroethylene, polyurethane, silk, cotton, wool, cellulose, cellulose ester Natural fibers such as, recycled area Ilf
' (rayon), or a combination of two or more of them.
本発明に用いられるパイルを有する遮光部材の具体的に
は、実開昭５９−１０４１４３号、同５７−３２９４８
号、同５１−１２７７３７号、同４５−８６９４４号、
特開昭６０−２０８７５１号、同５４−３６９２３号、
同５３−１０５２２２号、特願昭６０−２５１７４１号
、同 ６０−１６７０８３号、同 ６０−２３８９３３
号、同６０−２６７５００号、同６０−２０５１２８号
等に記載されているものを挙げることができる。Specifically, the light shielding member having a pile used in the present invention is disclosed in Japanese Utility Model Publication Nos. 59-104143 and 57-32948.
No. 51-127737, No. 45-86944,
JP-A-60-208751, JP-A No. 54-36923,
Japanese Patent Application No. 53-105222, Japanese Patent Application No. 60-251741, Japanese Patent Application No. 60-167083, Japanese Patent Application No. 60-238933
No. 60-267500, No. 60-205128, and the like.
本発明に用いられる遮光部材をマガジン本体に貼着する
方法としては、特開１１ｒ（４９−９６０４９号、同５
３−１０５２１９号、同５３−１０５２２０号、同５３
−１０５２２１号、同５４−４９３２号、特願昭６０−
７５２０７号等に記載されている方法が適用できる。ざ
らに、実開昭５８−９２２６号に記載の方法を併用て使
用することもできる。The method for attaching the light shielding member used in the present invention to the magazine body is as follows:
No. 3-105219, No. 53-105220, No. 53
-No. 105221, No. 54-4932, Patent Application 1986-
The method described in No. 75207 etc. can be applied. In addition, the method described in Japanese Utility Model Application Publication No. 58-9226 can also be used in combination.
本発明の写真フィルムマガジンにおいて、マガジン本体
を形成する金属としては、例えば、鉄鋼類、亜鉛類、ア
ルミニウム類、銅類およびそれらの合金類が用いられる
。また、これらの金属の表面は、リン酸塩皮膜化成法、
酸化鉄皮膜化成法、クロメート皮膜化成法、クロム酸系
酸化皮膜化成法、クロム酸ニリン酸系皮膜化成法等によ
り金属表面処理を行なわれていても良い。さらに、金属
の表面は、特開昭６０−２６０６４号、同６０−２６０
６２号、同６０−２６０６３号、特願昭６０−７５２０
７号等に記載の塗料、インク等で被覆されていてもよい
。具体的な塗料、インク等としては、アルキド樹脂系、
アミノ−アルキド樹脂系、ビニル樹脂系、アクリル樹脂
系、エポキシ樹脂系、ポリウレタン樹脂系、ポリエステ
ル樹脂系、各種サビ化めペイント、水系ペイント、セル
ロース誘導体等の塗料、インク等が挙げられる。また、
特開昭６０−２６０６１号、同６０−２６０６２号、同
６０−２６０６３号等に記載の如く、併用で用いること
もできる。In the photographic film magazine of the present invention, metals forming the magazine body include, for example, steel, zinc, aluminum, copper, and alloys thereof. In addition, the surface of these metals can be coated with phosphate coating method,
The metal surface treatment may be carried out by an iron oxide film chemical formation method, a chromate film formation method, a chromic acid-based oxide film formation method, a chromate diphosphate film formation method, or the like. Furthermore, the metal surface is
No. 62, No. 60-26063, Patent Application No. 60-7520
It may be coated with the paint, ink, etc. described in No. 7 and the like. Specific paints, inks, etc. include alkyd resins,
Examples include paints and inks such as amino-alkyd resins, vinyl resins, acrylic resins, epoxy resins, polyurethane resins, polyester resins, various rust paints, water-based paints, and cellulose derivatives. Also,
They can also be used in combination as described in JP-A-60-26061, JP-A-60-26062, JP-A-60-26063, and the like.
本発明に用いられる遮光部材において、パイルが基布か
ら抜は落ちないようかつ接着剤がパイル部に浸透してこ
ないよう目止め剤を用いることができる。本発明に用い
られる目止め剤としては、例えばポリビニル系、ポリオ
レフィン系、ポリウレタン系、ポリアミド系、ポリエス
テル系、合成ゴム系、エポキシ系、フェノール系、これ
らに含まれないアクリル系等の合成樹脂エマルジョンか
ら選ばれる１種または２種以上のブレンド物あるいはこ
れらを組み合わせた共重合体エマルジョンが挙げられる
。In the light shielding member used in the present invention, a filler can be used to prevent the pile from falling off the base fabric and to prevent the adhesive from penetrating into the pile portion. The sealants used in the present invention include synthetic resin emulsions such as polyvinyl, polyolefin, polyurethane, polyamide, polyester, synthetic rubber, epoxy, phenol, and acrylic not included in these. Examples include a copolymer emulsion of one or more selected blends or a combination thereof.
本発明において、上記パイルを有する遮光部材とマガジ
ン本体とを貼着するために用いられる接着剤としては、
ポリエチレン等のポリオレフィン系、エチレン−酢酸ビ
ニル共重合体等の酢酸ビニル共重合体系、■ヂレンーエ
チルアクリレー１〜、エチレン−イソブチルアクリレ−
１〜等のアクリル酸エステル共重合体系、ナイロン６、
ナイロン６゜６、ナイロン１０、ナイロン１２、Ｎ−メ
トキシメチル化ナイロン等のポリアミド系、テレフタル
酸系等のポリエステル系、ポリビニルブチラール系、ポ
リ酢酸ビニル系、アセテ−１〜、メチルセルロース、ア
セテ−１へブヂレー１−等のセルロース誘導体系、ポリ
メチルメタクリレート等のポリメタクリル酸エステル系
、ポリビニルメチルエーテル等のポリビニルエーテル系
、ボリウレタ系、ポリカーボネート系、スチレン−エチ
レン−ブチレン−スチレン等のスチレン系ブロック共重
合体系、スチレンブタジェン、イソプレン、ブチルゴム
等の合成ゴム系またはこれらに含まれない特殊ゴム系、
また以上に含まれないアクリル系共重合体等から選ばれ
る１種または２種以上の混合物が挙げられる。In the present invention, the adhesive used for pasting the light shielding member having the pile and the magazine body includes:
Polyolefins such as polyethylene, vinyl acetate copolymers such as ethylene-vinyl acetate copolymers, ■Dylene-ethyl acrylate 1~, ethylene-isobutyl acrylate
Acrylic acid ester copolymer system such as 1 to 1, nylon 6,
Polyamides such as nylon 6゜6, nylon 10, nylon 12, N-methoxymethylated nylon, polyesters such as terephthalic acid, polyvinyl butyral, polyvinyl acetate, acetate-1~, methylcellulose, acetate-1 Cellulose derivatives such as Budzire 1-, polymethacrylic acid esters such as polymethyl methacrylate, polyvinyl ethers such as polyvinyl methyl ether, polyurethanes, polycarbonates, and styrene block copolymers such as styrene-ethylene-butylene-styrene. , synthetic rubbers such as styrene butadiene, isoprene, butyl rubber, or special rubbers not included in these,
Further, one type or a mixture of two or more types selected from acrylic copolymers etc. not included in the above may be mentioned.
［発明の具体的効果］
以上説明した如く、本発明の写真フィルムマガジンにお
いては、そのフィルム出入口部に貼着する遮光部材にリ
ン酸化合物系帯電防止剤および潤滑剤で処理することに
より帯電防止特性のすぐれた写真フィルムマガジンを提
供する事が可能になった。[Specific Effects of the Invention] As explained above, in the photographic film magazine of the present invention, antistatic properties are achieved by treating the light shielding member attached to the film entrance and exit portion with a phosphoric acid compound-based antistatic agent and a lubricant. We are now able to provide an excellent photographic film magazine.
［発明の具体的実施例］
以下、本発明を実施例により具体的に説明するが、本発
明の実施の態様はこれらに限定されるものではない。[Specific Examples of the Invention] Hereinafter, the present invention will be specifically explained using Examples, but the embodiments of the present invention are not limited thereto.
実施例−１ 以下の条件にて遮光部材を帯電防止処理を施した。Example-1 The light shielding member was subjected to antistatic treatment under the following conditions.
（Ａ−１）遮光部材
基布用ｍ舵：レーヨン
パイル用繊Ｈ：ナイロン６．６
（，１２）帯電防止剤および潤滑剤処理条件帯電防止剤
どして下記表−１の種類のものを浸漬法により処理温度
条件および乾燥時の付き吊が下記表−２の如くなるよう
に処理し、次いで潤滑剤の種類および乾燥時のイ］き量
が下記表−１の如くなるＪ：うにスプレーで散布処理し
た。(A-1) Rudder for light-shielding member base fabric: Fiber for rayon pile H: Nylon 6.6 (,12) Antistatic agent and lubricant treatment conditions Use antistatic agents of the types listed in Table 1 below. J: Sea urchin spray using the immersion method so that the treatment temperature conditions and hanging during drying are as shown in Table 2 below, and then the type of lubricant and amount of water during drying are as shown in Table 1 below. It was sprayed with.
以下余白
なお、表−１で用いた帯電防止剤およびその処理条件を
表−２に示す。Table 2 shows the antistatic agents used in Table 1 and their treatment conditions.
以下余白
表−２
前記の遮光部材試料１〜３０を用いて、通常の写真フィ
ルムマガジンのフィルム出入口部と同様の条件となるに
うにバイル面が互いに向き合うように上下に遮光部拐（
各遮光部材のパイル高さは１ 、３ｍｍ ）を貼着した
フィルム通過口を設定した。Margin Table 2: Using the above-mentioned light-shielding member samples 1 to 30, cut the light-shielding parts vertically so that the film surfaces face each other so that the conditions are similar to those of the film entrance and exit section of a normal photographic film magazine.
The pile height of each light-shielding member was 1.3 mm), and a film passage hole was set.
フィルム通過口高さ： １．８０ｍｍ（但し、この条
件で２０，０００ルクスの光源下１１１１では遮光部材
間からの漏光はないことを確認した。）
上記フィルム通過口に下記で作成したフィルムＡおＪ：
びＢを周囲環境５℃、湿度２０％の条件下で通過速度４
０ＣＭ秒で通過させた。Film passage port height: 1.80 mm (However, under this condition, under a light source of 20,000 lux, it was confirmed that there was no leakage of light from between the light shielding members.) Film A or the film A prepared below was placed in the above film passage port. J:
and B in an ambient environment of 5°C and 20% humidity at a passing rate of 4.
It passed in 0CM seconds.
なお、フィルムＡは帯電防止剤処理なし、フィルムＢは
保護層に帯電防止剤処理をしたものである。Note that Film A was not treated with an antistatic agent, and Film B was treated with an antistatic agent on the protective layer.
［フィルムＡの作製］
透明なセルロース・トリアセテートフィルムからなる支
持体上に下記の各層を支持体側から順次設層し、多層カ
ラーネガ感光材料を作成した。[Preparation of Film A] The following layers were sequentially formed on a support made of a transparent cellulose triacetate film from the support side to prepare a multilayer color negative light-sensitive material.
（支持体を含むフィルム厚さ１４５μｌ１ｌ）第１層：
ハレーション防止層
黒色コロイド銀を含むゼラチン水溶液を銀０．３（１／
ＴＩ’の割合で乾燥膜厚３．０μｍになるように塗布し
た。(Film thickness 145 μl 1 l including support) 1st layer:
Antihalation layer A gelatin aqueous solution containing black colloidal silver was added to the silver 0.3 (1/
It was applied at a ratio of TI' to a dry film thickness of 3.0 μm.
第２層：中間層
ゼラチン水溶液を乾燥膜厚１．０μｍになるように塗布
した。Second layer: Intermediate layer An aqueous gelatin solution was applied to give a dry film thickness of 1.0 μm.
第３層：赤感性低感度ハロゲン化銀乳剤層沃臭化銀乳剤
（平均粒子サイズ０，４５μｍ、沃化銀４モル％を含む
沃臭化銀乳剤）を金および硫黄増感剤で化学増感し、更
に赤感性増感色素として、無水９−エチル−３，３′−
ジー（３−スルホプロピルｉ４．５．４’ 、５’ −
ジベンゾヂア力ルポシアニンヒドロキシド；無水５．５
’ −ジクロロ−９−エチル−３，３′−ジー（３−ス
ルホブデル）チアカルボシアニンヒドロキシド：および
無水５．５′−ジクロロ−３′、９−ジエチル−３−（
４−スルホブチル）オキシチアカルボシアニンヒドロキ
シドを加えたのちに４−ヒドロキシ−６−メチル−１，
３，３ａ、７−テトラザインデン１．０（１、１−）Ｊ
ニル−５−メルカプトテトラゾール２０．０ｍｇを加え
赤感性高感度乳剤を作製した。更にハロゲン化銀１モル
当りシアンカプラーとして、１−ヒドロキシ−１’ｍ−
［δ−（２゜４−ジー ［−アミルフェノキシ）ブチル
１−２−ナフ］〜アミド５０（１、カラードシアンカプ
ラーどして１−ヒドロキシ−４−［４，−（１−ヒト［
１キシ−８−アセ］・アミド−３，６−ジスルホ−２−
ナフチルアゾ）フェノキシ］ −Ｎ−［δ−（２゜４−
ジー ｔ−アミルフェノキシ）ブチル１−２−ナラ１〜
アミドジナトリウム塩１＋、ＤＩＲ化合物として２−〈
１−フェニル−５−テトラゾールヂオ）−４−オクタデ
シルザクシンイミド−１−インダノン１．７ｇ、またド
デシルガレ−１〜０．３９を添加し、トリクレジルフォ
スフニー１〜６５（］及び酢酸エチル１３６ｄの混合物
を加熱溶解し、トリイソプロピルナフタレンスルホン酸
ソーダ５ｇを含む７．５％Ｕラチン水溶液５５０−中に
加えてコロイドミルにて乳化分散した分散物を加えて赤
感性低感度乳剤を作製し乾燥膜厚４．０μｍ１塗布銀吊
３０ ｍｇ／ ｄｍ’になるように塗布した。（ハロゲ
ン化銀１モル当り１００ｇのゼラチンを含む）第４層：
赤感性高感度ハロゲン化銀乳剤層沃臭化銀乳剤（平均粒
子サイズ０．８０ ！１ｍ 、沃化銀７モル％を含む）
を金および硫黄増感剤で化学増感し、更に赤感性増感色
素として、無水９−エチル−３，３′−ジー（３−スル
ホプロピル）−４，，５，１，５’ −ジベンゾチアカ
ルボシアニンヒドロキシド、無水５．５′−ジクロロ−
９−エチル−３，３′−ジー（３−スルボブチル）チア
カルボシアニンヒト［ｌキシド：および無水５゜５１−
ジクロロ−３′、９−ジエヂル−３−（４−スルボブプ
ル）オキシチアカルボシアニンヒドロキシドを加えたの
ちに４−ヒドロキシ−６−メヂルー１．３，３ａ、７−
テ１ヘラザインゲン１．０ｇおよび１−フェニル−５−
メルカプトテトラゾール１０．０ｍｇを加え赤感性高感
度乳剤を作製した。更にハロゲン化銀１モル当りシアン
カプラーどして、１−ヒドロキシ−Ｎ−［δ−（２，４
−ジ−ｔ−アミルフェノキシ）ブチル］−２−ナフトア
ミド１０ｇ、カラードシアンカプラーとして１−ヒドロ
キシ−１［４−（１−ヒドロキシ−８−アセトアミド−
３，６−ジスルホ−２−ナフチルアゾ）フェノキシ］
−Ｎ−［δ−（２，４＝ジー １−アミルフェノキシ）
ブチル］−２−ナフトアミド・ジナトリウム塩１、Ｄｒ
Ｒ化合物として２−（１−フェニル−５−テトラゾリル
チオ）−４−オクタデシルザクシンイミド−１−インダ
ノン１．６（］ 、またドデシルガレート０．５ｇを添
加し、トリクレジルフォスフェート２０ｇ及び酢酸エチ
ル６０１Ｑの混合物を加熱溶解し、トリイソプロピルナ
フタレンスルホン酸ソーダ１．５ｇを含む７．５％ゼラ
チン水溶液３０ｎ（２中に加えてコロイドミルにて乳化
分散した分散物を加えて赤感性高感度乳剤を作製し、乾
燥膜厚２．０μｌ、塗布銀量２０ ｍｇ／ ｄｔ’にな
るように塗布した。（ハロゲン化銀１モル当り１００ｇ
のゼラチンを含む。）第５層：中間層
第２層と同じ
第６層：緑感性低感度ハロゲン化銀乳剤層沃臭化銀乳剤
（平均粒子サイズ０．５２μｍ、沃化銀８モル％を含む
沃臭化銀乳剤）を金および硫黄増感剤で化学増感し、更
に緑感性増感色素どして無水５．５′−ジクロロ−９−
エチル−３゜３′−ジー（３−スルホブチル）オキサカ
ルポシアニンヒドロギシド；無水５．５′−ジフェニル
−〇−エチルー３．３′−ジー（３−スルボブデル）オ
゛キサカルボシアニンヒドロキシドおよび無水９−エチ
ル−３，３′−ジー（３−スルホプロピル） −５，６
，５’ 、６’ −ジベンゾオキザ力ルポシアニンヒド
ロキシドを加えついで４−ヒドロキシ−６−メチル−１
，３，３ａ、７−チトラザインデン１．Ｏｇおよび１−
フェニル−５−メルカプトテトラゾール２０．０ｍｇを
加え、緑感性低感度ハロゲン化銀乳剤を作製した。更に
ハロゲン化銀１モル当り、マゼンタカプラーとして、”
ｌ（２゜４．６−１−ジクロロ）フェニル−３−［３−
（２゜４−ジーｔｅｒｔ−アミルフェノキシ）アセトア
ミド］ベンゾアミドー５−ピラゾロン５０ｇ、カラード
マゼンタカプラーとして、１− （２，４，６−トジク
ロロフェニル）−４−（１−ナフチルアゾ）−３−（２
−クロロ−５−オクタデセニルスクシンイミドアニリノ
）−５−ピラゾロン１０ｑ、ＤＩＲ化合物として、β−
（４−［”ｌ （１１−二］−口フェニル１ｆ−（１−
フェニル−５−テトラゾリル）チオメチル−３−ウンデ
シル−５−ピラゾリルオキシ］−１−ヒドロキシ−２−
ナフトアミド）プロピオンｌ １．５（ｌを添加し、ト
リクレジルフォスフェート６０（ｌ及び酢酸エチル２０
０鑓の混合物を加熱溶解し、１〜リイソプロビルナフク
レンスルホン酸ソーダを含むゼラチン水溶液中に加えコ
ロイドミルにて乳化分散した分散物を加えて緑感性低感
度乳剤を作製し、乾燥膜厚４．０μｍ、塗布銀ｆＡ ２
０ ｍ！］／ ６ｍ２になるように塗布した。3rd layer: red-sensitive, low-sensitivity silver halide emulsion layer A silver iodobromide emulsion (average grain size 0.45 μm, silver iodobromide emulsion containing 4 mol% silver iodide) is chemically sensitized with gold and sulfur sensitizers. Furthermore, as a red-sensitive sensitizing dye, anhydrous 9-ethyl-3,3'-
Di(3-sulfopropyl i4.5.4', 5'-
Dibenzodia lupocyanine hydroxide; Anhydrous 5.5
'-dichloro-9-ethyl-3,3'-di(3-sulfobdel)thiacarbocyanine hydroxide: and anhydrous 5,5'-dichloro-3',9-diethyl-3-(
After adding 4-sulfobutyl)oxythiacarbocyanine hydroxide, 4-hydroxy-6-methyl-1,
3,3a,7-tetrazaindene 1.0(1,1-)J
20.0 mg of nyl-5-mercaptotetrazole was added to prepare a red-sensitive emulsion. Furthermore, as a cyan coupler per mole of silver halide, 1-hydroxy-1'm-
[δ-(2゜4-di[-amylphenoxy)butyl 1-2-naph] ~ amide 50 (1, colored cyan coupler to 1-hydroxy-4-[4,-(1-human [
1x-8-ace]amide-3,6-disulfo-2-
naphthylazo)phenoxy] -N-[δ-(2゜4-
G t-amylphenoxy)butyl 1-2-nara 1~
Amide disodium salt 1+, 2- as DIR compound
1.7 g of 1-phenyl-5-tetrazoldio)-4-octadecylsuccinimide-1-indanone and dodecyl galley-1-0.39 were added, and tricresylphosphny 1-65 (] and ethyl acetate were added. A red-sensitive, low-sensitivity emulsion was prepared by heating and dissolving the mixture of 136d, adding it to a 7.5% U latin aqueous solution 550 containing 5 g of sodium triisopropylnaphthalene sulfonate, and adding the dispersion that had been emulsified and dispersed in a colloid mill. The film was coated to give a dry film thickness of 4.0 μm and a coating weight of 30 mg/dm'. (Contains 100 g of gelatin per mole of silver halide) 4th layer:
Red-sensitive high-sensitivity silver halide emulsion layer Silver iodobromide emulsion (average grain size 0.80!1m, containing 7 mol% silver iodide)
was chemically sensitized with gold and sulfur sensitizers, and anhydrous 9-ethyl-3,3'-di(3-sulfopropyl)-4,,5,1,5'-dibenzo was added as a red-sensitizing dye. Thiacarbocyanine hydroxide, anhydrous 5,5'-dichloro-
9-ethyl-3,3'-di(3-sulbutyl)thiacarbocyanine human [l oxide: and anhydrous 5°51-
After adding dichloro-3',9-diedyl-3-(4-sulbobupur)oxythiacarbocyanine hydroxide, 4-hydroxy-6-medyyl-1.3,3a,7-
1.0 g of green beans and 1-phenyl-5-
10.0 mg of mercaptotetrazole was added to prepare a red-sensitive emulsion. Further, per mole of silver halide, cyan coupler etc., 1-hydroxy-N-[δ-(2,4
-di-t-amylphenoxy)butyl]-2-naphthamide 10 g, as colored cyan coupler 1-hydroxy-1[4-(1-hydroxy-8-acetamide-
3,6-disulfo-2-naphthylazo)phenoxy]
-N-[δ-(2,4=di-1-amylphenoxy)
butyl]-2-naphthamide disodium salt 1, Dr
As the R compound, 1.6 (2-(1-phenyl-5-tetrazolylthio)-4-octadecylsuccinimide-1-indanone) and 0.5 g of dodecyl gallate were added, and 20 g of tricresyl phosphate and ethyl acetate were added. 601Q mixture was heated and dissolved, and 30n of a 7.5% aqueous gelatin solution containing 1.5g of sodium triisopropylnaphthalene sulfonate (added to 2 and the dispersion emulsified and dispersed in a colloid mill was added to form a red-sensitive high-sensitivity emulsion). It was prepared and coated to give a dry film thickness of 2.0 μl and a coated silver amount of 20 mg/dt' (100 g per mole of silver halide).
Contains gelatin. ) 5th layer: Intermediate layer Same as 2nd layer 6th layer: Green-sensitive, low-sensitivity silver halide emulsion layer Silver iodobromide emulsion (average grain size 0.52 μm, silver iodobromide containing 8 mol% silver iodide) The emulsion) was chemically sensitized with gold and sulfur sensitizers, and then anhydrous 5,5'-dichloro-9-
Ethyl-3゜3'-di(3-sulfobutyl)oxacarpocyanine hydroxide; Anhydrous 9-ethyl-3,3'-di(3-sulfopropyl)-5,6
, 5', 6'-dibenzooxalpocyanine hydroxide and then 4-hydroxy-6-methyl-1
,3,3a,7-chitrazaindene1. Og and 1-
20.0 mg of phenyl-5-mercaptotetrazole was added to prepare a green-sensitive, low-sensitivity silver halide emulsion. Furthermore, per mole of silver halide, as a magenta coupler,
l(2゜4.6-1-dichloro)phenyl-3-[3-
(2゜4-di-tert-amylphenoxy)acetamido]benzamide 5-pyrazolone 50 g, as colored magenta coupler, 1-(2,4,6-todichlorophenyl)-4-(1-naphthylazo)-3-(2
-Chloro-5-octadecenylsuccinimideanilino)-5-pyrazolone 10q, as a DIR compound, β-
(4-[”l (11-bi]-phenyl 1f-(1-
phenyl-5-tetrazolyl)thiomethyl-3-undecyl-5-pyrazolyloxy]-1-hydroxy-2-
Add 1.5 (l) of naphthamide) propion, 60 (l) of tricresyl phosphate and 20 (l) of ethyl acetate.
A green-sensitive, low-sensitivity emulsion was prepared by heating and dissolving a mixture of 0 and 1 and adding the dispersion that was emulsified and dispersed in a colloid mill into an aqueous gelatin solution containing 1 to lyisoprobylnafucrene sodium sulfonate. 4.0 μm, coated silver fA 2
0 m! ] / It was applied to a total area of 6m2.
（ハロゲン化銀１モル当り１００ｇのゼラチンを含む。(Contains 100 g of gelatin per mole of silver halide.
）
第７層：緑感性高感度ハロゲン化銀乳剤層沃臭化銀乳剤
（平均粒子サイズ０．８５μｍ１沃化銀１０モル％を含
む）を金および硫黄増感剤で化学増感し、さらには緑感
性増感色素として無水５．５′−ジクロロ−９−エチル
−３，３′−ジー（３−スルホブチル）オキサカルボシ
アニンヒドロキシド；無水５．５′−ジフェニル−９−
エチル−３，３′−ジー（３−スルボブチル）オキサカ
ルボシアニンヒドロキシドおよび無水−９−エチル−３
，３′−ジー（３−スルホプロピル）−５，６，５’
、６’ −ジベンゾオキサカルボシアニンヒドロキシド
を加え、ついで４−ヒドロキシ−６−メチル−１，３，
３ａ、フーチトラザインデン１．Ｏｇおよび１−フェニ
ル−５−メルカプトテトラゾール１０．０ｍｇを加えて
緑感性高感度ハロゲン化銀乳剤を作製した。更にハロゲ
ン化銀１モル当りマゼンタカプラーとして、１− （２
，４゜６−トリクロロ）フェニル−３−［３−２，４，
−ジーｔｅｒｔ−アミルフェノキシアセトアミド］ベン
ゾアミド−５−ピラゾロン５（１，カラードマゼンタカ
プラーとして、１−（２，４，６−トリクロロフエニル
）−４−（１〜ナフヂルアゾ）−３−（２−クロロ−５
−オクタデセニルスクシンイミドアニリノ）−５−ピラ
ゾロン２．５（１，２，５−ジー ｔ−オクチルハイド
ロキノン１．５（＋ 、またＤＩＲ化合物として、β−
（４−［１−（ｐ−二トロフェニル）−４−（１−フェ
ニル−５−テトラゾリル）チオメチル−３−ウンデシル
−５〜ピラゾリルオキシ］−１−ヒドロキシ−２−ナフ
トアミド）プロピオンＩＩ Ｏ，５（Ｉを添加し、１〜
リクレジルフオスフ工−ト２０ｇ及び酢酸エチル３０ｍ
１２の混合物を加熱溶解し、トリイソプロピルナフタレ
ンスルホン酸ソーダを含むゼラチン水溶液中に加えコロ
イドミルにて乳化分散した分散物を加えて緑感性低感度
乳剤を作製し、乾燥膜厚２，０μｍ１塗布銀ｍ １５
ｍ（１／ ｄ１’になるように塗布した。) 7th layer: Green-sensitive, high-sensitivity silver halide emulsion layer A silver iodobromide emulsion (average grain size 0.85 μm, containing 10 mol% of silver iodide) is chemically sensitized with gold and sulfur sensitizers, and further Anhydrous 5,5'-dichloro-9-ethyl-3,3'-di(3-sulfobutyl)oxacarbocyanine hydroxide as a green-sensitive sensitizing dye; anhydrous 5,5'-diphenyl-9-
Ethyl-3,3'-di(3-sulbutyl)oxacarbocyanine hydroxide and anhydrous-9-ethyl-3
,3'-di(3-sulfopropyl)-5,6,5'
, 6'-dibenzoxacarbocyanine hydroxide, then 4-hydroxy-6-methyl-1,3,
3a, Fuchitra Zainden 1. A green-sensitive and highly sensitive silver halide emulsion was prepared by adding Og and 10.0 mg of 1-phenyl-5-mercaptotetrazole. Furthermore, 1-(2
,4゜6-trichloro)phenyl-3-[3-2,4,
-di-tert-amylphenoxyacetamide]benzamide-5-pyrazolone 5 (1, as a colored magenta coupler, 1-(2,4,6-trichlorophenyl)-4-(1-naphdylazo)-3-(2-chloro -5
-octadecenyl succinimide anilino)-5-pyrazolone 2.5 (1,2,5-di t-octylhydroquinone 1.5 (+, also as a DIR compound, β-
(4-[1-(p-nitrophenyl)-4-(1-phenyl-5-tetrazolyl)thiomethyl-3-undecyl-5-pyrazolyloxy]-1-hydroxy-2-naphthamido)propion II O,5( Add I, 1~
20g of Likresil fluorocarbonate and 30m of ethyl acetate
A green-sensitive low-sensitivity emulsion was prepared by heating and dissolving the mixture of No. 12 in an aqueous gelatin solution containing sodium triisopropylnaphthalene sulfonate, and adding the dispersion that had been emulsified and dispersed in a colloid mill. m 15
m(1/d1').
（ハロゲン化銀１モル当り１００ｇのゼラチンを含む。(Contains 100 g of gelatin per mole of silver halide.
）
第８層：中間層
第２層と同じ
第９層：黄色フィルタ一層
黄色コロイド銀を分散せしめたゼラチン水溶液中に、２
，５−ジー 【−オクチルハイドロキノン３ｇとジー２
−エチルへキシルフタレート １．５ｑを酢酸エチル１
０１Ｑで溶解し、トリイソプロピルナフタレンスルホン
酸ソーダ０．３ｇを含むゼラチン水溶液中に分散せしめ
た分散液を加え、これをゼラチン０．９ｑ ／プ、２，
５−ジー ｔ−オクチルハイドロキノン０．１０（＋／
Ｔ！’の割合で乾燥膜厚１，２μｍになるように塗布し
た。) 8th layer: Intermediate layer Same as the 2nd layer 9th layer: Yellow filter 2 layers in a gelatin aqueous solution in which yellow colloidal silver is dispersed.
,5-G [-octylhydroquinone 3g and G2
- Ethylhexyl phthalate 1.5q to ethyl acetate 1
01Q and dispersed in an aqueous gelatin solution containing 0.3 g of sodium triisopropylnaphthalene sulfonate were added, and this was added to 0.9 q/p of gelatin, 2,
5-G t-octylhydroquinone 0.10 (+/
T! It was coated at a ratio of 1 to 2 μm to give a dry film thickness of 1.2 μm.
第１０層：青感性低感度ハロゲン化銀乳剤層沃臭化銀乳
剤（平均粒子サイズ０．６μｍ、沃化銀６モル％を含む
）を金および硫黄増感剤で化学増感し、さらには増感色
素として無水５．５’ −ジメトキシ−３，３１−ジー
（３−スルホプロピル）チアシアニンヒドロキシドを加
え、ついで４−ヒドロキシ−６−メチル−１，３，３８
，７−チトラザインデンｉ、ｏｇ 、 １−フェニル−
５−メルカプトテトラゾール２０．０ｍｇを加えて青感
性低感度ハロゲン化銀乳剤を作製した。更にハロゲン化
銀１モル当りイエローカプラーどして、α−ピバロイル
−α−（１−ベンジル−２−フェニル−３゜５−ジオキ
ソ−１，２，４−１−リアシリジン−４−イル）−２′
−クロロ−５′−［α−（ドデシルオキシカルボニル）
ペントキシカルボニル］アセトアニリド２５０９を添加
し、ジブチルフタレ−１〜１２０ｇ、酢酸エチル３００
ｄの混合物を加熱溶解し、トリイソプロピルナフタレン
スルホン酸ソーダを含むゼラチン水溶液中に加えてコロ
イドミルにて乳化分散した分散物を加えて青感性低感度
ハロゲン化銀乳剤を作製し、乾燥膜厚４，０μｍ、塗布
銀ｍ ５ ｍｑ／ ｄｍ’になるように塗布した。（ハ
ロゲン化銀１モル当り２４０ｇのゼラチンを含む。）第
１１層：青感性高感度ハロゲン化銀乳剤層沃臭化銀乳剤
（平均粒子サイズ１．２μｍ、沃化銀７モル％を含む）
を金および硫黄増感剤で化学増感し、さらには増感色素
として無水５．５’ −ジメトキシ−３，３′−ジー（
３−スルボブロビル）チアシアニンヒドロキシドを加え
、ついで４−ヒドロキシ−６−メチル−１，３，３ａ
、７−テトラずインデン１．０ｇおよび１−フェニル−
５−メルカプミルテトラゾール１０．０ｍｇを加えて青
感性高感度ハロゲン化銀乳剤を作製した。更にハロゲン
化銀１モル当りイエローカプラーとして、α−ピバロイ
ル−α−（１−ベンジル−２−）■ニルー３．５−ジオ
キソー１．２．４−トリアシリジン−４−イル）−２′
−クロロ−５′−［α−（ドデシルオキシカルボニル
ル
タレート４０ｇ、酢酸エチル２４０ｗｌ）の混合物を加
熱溶解し、ｌ−リイソプロピルナフタレンスルホン酸ソ
ーダを含むゼラチン水溶液中に加えてコロイドミルにて
乳化分散した分散物を加えて青感性高感度ハロゲン化銀
乳剤を作製し、乾燥膜厚２．０μｍ１塗布銀聞５ｍＯ／
ｄ，２になるように塗布した。10th layer: blue-sensitive, low-sensitivity silver halide emulsion layer A silver iodobromide emulsion (average grain size 0.6 μm, containing 6 mol% silver iodide) is chemically sensitized with gold and sulfur sensitizers, and further Anhydrous 5,5'-dimethoxy-3,31-di(3-sulfopropyl)thiacyanine hydroxide was added as a sensitizing dye, and then 4-hydroxy-6-methyl-1,3,38
,7-chitrazaindene i,og, 1-phenyl-
A blue-sensitive, low-sensitivity silver halide emulsion was prepared by adding 20.0 mg of 5-mercaptotetrazole. Further, per mole of silver halide, as a yellow coupler, α-pivaloyl-α-(1-benzyl-2-phenyl-3°5-dioxo-1,2,4-1-lyasiridin-4-yl)-2 ′
-Chloro-5'-[α-(dodecyloxycarbonyl)
Add 2509 g of pentoxycarbonyl]acetanilide, 1 to 120 g of dibutyl phthalate, and 300 g of ethyl acetate.
The mixture d was dissolved by heating, added to an aqueous gelatin solution containing sodium triisopropylnaphthalene sulfonate, and the dispersion was emulsified and dispersed in a colloid mill to prepare a blue-sensitive, low-sensitivity silver halide emulsion, and the dry film thickness was 4. , 0 μm, coated silver m 5 mq/dm'. (Contains 240 g of gelatin per mole of silver halide.) Eleventh layer: Blue-sensitive, high-sensitivity silver halide emulsion layer Silver iodobromide emulsion (average grain size 1.2 μm, containing 7 mole % of silver iodide)
was chemically sensitized with gold and sulfur sensitizers, and anhydrous 5,5'-dimethoxy-3,3'-di(
3-sulbobrovir) thiacyanine hydroxide, then 4-hydroxy-6-methyl-1,3,3a
, 1.0 g of 7-tetrazuindene and 1-phenyl-
A blue-sensitive and highly sensitive silver halide emulsion was prepared by adding 10.0 mg of 5-mercapmyltetrazole. Further, as a yellow coupler per mole of silver halide, α-pivaloyl-α-(1-benzyl-2-)■nilu-3,5-dioxo1,2,4-triacyridin-4-yl)-2'
-Chloro-5'-[α-(40 g of dodecyloxycarbonyl rutalate, 240 wl of ethyl acetate) was dissolved by heating, added to an aqueous gelatin solution containing sodium l-lyisopropylnaphthalenesulfonate, and emulsified and dispersed in a colloid mill. A blue-sensitive, high-sensitivity silver halide emulsion was prepared by adding the dispersion obtained, and the dry film thickness was 2.0 μm.
It was applied so that it became d.2.
（ハロゲン化銀１′ｆニル当り１６０ｇのゼラチンを含
む。）
第１２層：中間層
ジー２−■ヂルヘキシルフタレー１〜２ｏ，２−［３−
シアノ−３−（ｎ−ドデシルアミノカルボニル）アリリ
デン］−１−エヂルビ口リジン２。(Contains 160 g of gelatin per 1'f silver halide.) 12th layer: Intermediate layer
Cyano-3-(n-dodecylaminocarbonyl)allylidene]-1-edylbilysine 2.
と酢酸エチル２ｍｆｆｉを混合し、トリイソプロピルナ
フタレンスルホン酸ソーダ０．６ｇを含むゼラチン水溶
液中に分散せしめた分散液をゼラチン水溶液中に加え、
これをゼラチン１．０ｇ／ｎ２の割合で乾燥膜厚１４０
μｍになるように塗布した。and 2 mffi of ethyl acetate were mixed and dispersed in an aqueous gelatin solution containing 0.6 g of sodium triisopropylnaphthalene sulfonate, and a dispersion was added to the aqueous gelatin solution.
The dry film thickness was 140 at a ratio of gelatin of 1.0 g/n2.
It was coated to a thickness of μm.
第１３Ｅ：保護層
１００ｍＲ当りゼラチン４（１，１．２−ビスビニルス
ルホニルエタン０．２ｇを含むゼラチン水溶液をゼラチ
ン１．３Ｑ／１２の割合で乾燥膜厚１．２μｍになるよ
うに塗布した。13th E: An aqueous gelatin solution containing 4 g of gelatin (0.2 g of 1,1.2-bisvinylsulfonylethane) per 100 mR of the protective layer was applied at a ratio of 1.3 Q/12 gelatin to give a dry film thickness of 1.2 μm.
［フィルムＢの作製］
上記で作製したフィルムＡにおいて、第１３層の保護層
に帯電防止剤としてポリエチレンオキサイド系帯電防止
剤を４０ｍ（１／ｎ’、潤滑剤どしてＤ（、−８６エマ
ルジヨン（ダウコーティング社製）を５０ｍ（１／１２
とそれぞれなるように添加し、フィルムの裏面にアルミ
ナゾルＡ Ｓ − ２００を０．８（］ ／１２となる
よう塗工した。[Production of Film B] In the film A produced above, 40 m (1/n') of a polyethylene oxide-based antistatic agent was added to the protective layer of the 13th layer as a lubricant, and D (-86 emulsion) was added as an antistatic agent. (manufactured by Dow Coating Co., Ltd.) for 50 m (1/12
and alumina sol AS-200 was applied to the back side of the film so that the ratio was 0.8(]/12).
上記通過口を通したフィルムを露光後現像処理した後、
フィルム表面のスタチックマークを目視で判定した。判
定基準は以下のとおりである。After exposing and developing the film that has passed through the passage port,
Static marks on the film surface were visually determined. The judgment criteria are as follows.
◎ ：フィルム通過１．０ ｍでスタチックマーク発生
なし。◎: No static marks were generated when the film passed through 1.0 m.
Ｏ ：フィルム通過１．０ｍでスタチックマー９１個。O: 91 static mer when the film passed 1.0m.
○Δ：フィルム通過１，Ｏｍでスタチックマー９２個。○Δ: Film passing 1, Om, 92 static mer.
Δ ：フィルム通過１．０ｍでスタチックマーク３〜５
個。Δ: Static mark 3-5 at 1.0m film passage
Individual.
× ：フィルム通過１．０ｍでスタチックマーク６〜１
０個。×: Static mark 6-1 at 1.0m film passage
0 pieces.
結果を表−３に示す。The results are shown in Table-3.
なお、上記判定結果に従ったフィルムをプリントし、さ
らにフィルムの実用性を調べた結果は以下のとおりであ
る。In addition, the results of printing a film according to the above judgment results and further examining the practicality of the film are as follows.
◎，Ｏニブリントでの影響はなかった。◎, O Niblint had no effect.
ＯΔ ニブリントでシーンによっては川われるが、商品
価値上はほどんど問題とはな
ない。OΔ Niblint may be damaged depending on the scene, but it is not a problem in terms of commercial value.
Δ ニブリント上にかなり現われ、商品価値」二問題
のレベル。Δ niblint appears considerably, and the level of commercial value' two problems.
× ：商品価値は全くない。×: There is no commercial value at all.
表−３の結果から明らかなように、リン酸化合物系帯電
防止剤および潤滑剤で処理しない遮光部材を用いたもの
は、フィルムが帯電防止剤および潤滑剤で処理されてい
ても、上記通過条件（自動巻き上げ、巻き戻し条件と同
程度）ではスタチックマークの発生が認められるが、一
方、本発明の構成となるリン酸化合物系帯電防止剤およ
び潤滑剤で処理した遮光部材では、フィルムが処理され
ていないものもスタチックマークの発生が良好に抑えら
れていることがわかる。As is clear from the results in Table 3, when using a light shielding member that is not treated with a phosphoric acid compound antistatic agent and a lubricant, even if the film is treated with an antistatic agent and a lubricant, the above passing conditions (same level as automatic winding and rewinding conditions), the occurrence of static marks is observed, but on the other hand, in the light-shielding member treated with the phosphoric acid compound-based antistatic agent and lubricant that constitutes the present invention, the film is It can be seen that the generation of static marks is well suppressed even in the case where no static marks are formed.
さらに試料１において、帯電防止剤として、サンスタッ
１〜２３０− Ｄに代えて、表−２のＮ０１８〜１３を
それぞれ用いても同様の結果を得た。Furthermore, in Sample 1, similar results were obtained when each of N018 to 13 in Table 2 was used as an antistatic agent in place of Sunstat 1 to 230-D.
なお、本発明の遮光部材を用いて、サクラカラ−Ｓ Ｒ
−１６００を装填した写真フィルムマガジンを作成して
ニコンＦ３モータドライブ付きで連続囮影したフィルム
においては、すべてスタチックマークが発生していない
ことを確認した。In addition, using the light shielding member of the present invention, Sakura Color-SR
It was confirmed that no static marks were produced in any of the films that were made using a photographic film magazine loaded with -1600 and subjected to continuous exposure using a Nikon F3 motor drive.
実施例−２ 以下の条件にて遮光部材を帯電防止処理を施しｌご 。Example-2 Apply antistatic treatment to the light shielding member under the following conditions.
（Ｂ−１＞遮光部材：
基布用ｍ紺：レーヨン
パイル用繊維：ポリエステル
（Ｂ−２）帯電防止剤おにび潤滑剤処理条件：帯電防止
剤の種類および乾燥時の付ぎ量、並びに潤滑剤の種類お
よび乾燥時の付き缶が、下記表−４の如くなるＪ：うに
帯電防止剤および潤滑剤を同一の添加液に添加し浸漬法
で処理した。また乾燥は処理後以下の表−５に示す条件
で行った。(B-1> Light shielding member: Navy blue for base fabric: Rayon fiber for pile: Polyester (B-2) Antistatic agent and lubricant processing conditions: Type of antistatic agent and amount applied during drying, The type of lubricant and the drying capacity are as shown in Table 4 below.J: Sea urchin antistatic agent and lubricant were added to the same additive solution and treated by dipping.Drying was done as shown in the table below after treatment. The test was carried out under the conditions shown in -5.
以下余白
表−４
上記の遮光部材を用いて、実施例−１と同様の方法によ
りフィルムテストを行ない、同様にスタヂックマーク発
生の度合を評価した。Margin Table 4 Below: Using the above light shielding member, a film test was conducted in the same manner as in Example 1, and the degree of static mark generation was evaluated in the same manner.
結果を表−６に示す。The results are shown in Table-6.
以下余白
表−６
表−６の結果から明らかなように、遮光部月の種類を代
え、帯電防止剤および潤滑剤を同一の液として用いて処
理することによっても、実施例−１と同様にスタチック
マークの発生が良好に防１トされていることがわかる。Margin Table 6 below As is clear from the results in Table 6, the same results as in Example 1 can be obtained by changing the type of light shielding part and using the same antistatic agent and lubricant. It can be seen that the generation of static marks is effectively prevented.
なお、上記遮光部材試料を用いてサクシカラー１６００
フイルムを装填した写真フィルムマガジンを作成し、ニ
コンＦ３モータドライブ付ぎで連続撤影したフィルムに
おいては、すべてスタチックマークが発生していないこ
とを確認した。In addition, using the above light shielding member sample, Sakshi Color 1600
A photographic film magazine loaded with film was created, and it was confirmed that no static marks were generated on the film that was continuously removed using a Nikon F3 motor drive.
実施例−３
実施例−２で作成した遮光部材試料ＮＯ，３４゜３５．
３６，３７，４０，４．２，４３，４．４゜４５．４８
．＝１９および５０を用いて、実施例−２と同様にして
実験を行った。但し、用いたフィルムは電算写植用の仕
様であり、フィルム通過口の高さも電算写植用写真フィ
ルムマガジンのものと同程度にした。Example-3 Light shielding member sample No. 34°35. created in Example-2.
36, 37, 40, 4.2, 43, 4.4° 45.48
．． An experiment was conducted in the same manner as in Example-2 using =19 and 50. However, the film used was of a specification for computerized phototypesetting, and the height of the film passage opening was also made to be similar to that of a photographic film magazine for computerized phototypesetting.
フィルム通過口高さ＋ １．８ｍｍ
用いた電算写植用フィルムはそれぞれ帯電防止剤処理な
しをフィルムＣとし、帯電防止剤処理布をフィルムＤど
して用いた。Height of film passage port + 1.8 mm The computer phototypesetting films used were those without antistatic agent treatment (Film C) and antistatic agent treated cloth (Film D).
［フィルムＣの作製コ
下記処方の（Ａ）液を３４℃に保ちながら、（Ｂ）液お
よび（Ｃ）ｉを１分間に亘って加える同時混合法にＪ：
り平均粒径０．３３μｍの立方体の沃臭化銀乳剤（組成
：臭化銀９９．５モル％、沃化銀０．５モル％）を調製
した。物理熟成終了後、ｐＨ−６，０どし、脱塩水洗を
２回繰り返した後、分散用ゼラチンを加え５５℃、３０
分間分散し７ｊ Ｉ！、５００ｃｃに仕上げた。[Preparation of film C] A simultaneous mixing method in which solution (B) and (C)i are added for 1 minute while keeping solution (A) of the following formulation at 34° C.J:
A cubic silver iodobromide emulsion (composition: silver bromide 99.5 mol %, silver iodide 0.5 mol %) having an average grain size of 0.33 μm was prepared. After physical ripening, the pH was adjusted to -6.0, and washing with demineralized water was repeated twice, then gelatin for dispersion was added and the mixture was heated at 55℃ for 30 minutes.
Dispersed for 7j I! , finished to 500cc.
（Ａ）液 Ｋ Ｂ ｒ ２（］ゼゼラチン
１２（Ｉ
Ｈ２０６００ＣＣ仕上げ
（Ｂ）液 Ｋ Ｂ ｒ ８４ｇＫ Ｉ
ｏ、６ｇ
ゼラチン ４ｇ
１」２０ ６００ｃｃ仕上げ（Ｃ）液 Ａ（
ＩＮＯｓ １２０（＋２８％ＮＨ４ＯＨ１７８
ＣＣ
８２０６００ＣＣ仕」二げ
このようにして得られた沃臭化銀乳剤を各２５ＣＣ分割
採取して、チオ硫酸ナトリウム０．１２５ｍｇ。(A) Liquid K B r 2 (] Zegelatin 12 (I H20600CC finish (B) Liquid K B r 84g K I
o, 6g gelatin 4g 1"20 600cc finishing (C) liquid A (
INOs 120 (+28%NH4OH178
The silver iodobromide emulsion thus obtained was divided into 25 CC portions and 0.125 mg of sodium thiosulfate was collected.
塩化金酸０．１ｍｇ、チオシアン酸アンモニウム１．５
ｍｇを加え６６℃、５０分間の化学熟成を行ない、４−
ヒドロキシ−６−メチル−１，３，３ａ、７−チトラザ
インデンを０．７５（］および１１０％ゼラチン水溶を
１２ｃｃ添加し化学熟成を終了した。Chloroauric acid 0.1 mg, ammonium thiocyanate 1.5
4-mg and chemically ripened at 66°C for 50 minutes.
Chemical ripening was completed by adding 0.75 ml of hydroxy-6-methyl-1,3,3a,7-chitrazaindene and 12 cc of 110% aqueous gelatin.
化学熟成終了後、増感色素を４．５ｍｇ加え、更に塗布
助剤としてサポニン（２０％） １．７ＣＣ，スヂレ
ンーマレイン酸共重合ポリマー０．１４（ｌを加え硬膜
剤としてポルマリンを添加して乳剤を調製し、保護膜液
としてサポニンどホルマリンおよびマット剤として二酸
化ケイ素を添加したゼラチン液を調製し、乳剤層として
銀量が３．８ｇ ／ｍ２、ゼラチン量が３．００ ／
＊’ 、保護層のゼラチン量が１，５ｇ／ｌＩ２になる
ようにフィルムベース（ポリエステル、厚さ１００μｍ
）支持体上に塗布し乾燥した。但し、乳剤層の膜厚４μ
ｍ１保護層の膜厚１μｍである。After chemical ripening, 4.5 mg of sensitizing dye was added, and 1.7 CC of saponin (20%) was added as a coating aid, and 0.14 L of styrene-maleic acid copolymer was added, and Polmarine was added as a hardening agent. A gelatin solution was prepared by adding saponin and formalin as a protective film solution and silicon dioxide as a matting agent.As an emulsion layer, the amount of silver was 3.8 g/m2, and the amount of gelatin was 3.00 g/m2.
*', film base (polyester, thickness 100 μm) so that the amount of gelatin in the protective layer is 1.5 g/lI
) It was coated on a support and dried. However, the thickness of the emulsion layer is 4μ.
The thickness of the m1 protective layer is 1 μm.
さらに非感光性裏面層（バック層）として、上記乳剤層
で用いたものと同じゼラチン、増粘剤、塗布助剤、柔軟
剤、硬膜剤等を含有した層を設けた。Furthermore, a layer containing the same gelatin, thickener, coating aid, softener, hardener, etc. as used in the emulsion layer was provided as a non-photosensitive back layer.
また、該バック層には染料およびマット剤としてポリメ
タクリル酸メチルを含有させた。Further, the back layer contained polymethyl methacrylate as a dye and a matting agent.
［フィルムＤの作Ｆ！！］
上記フィルムＣにおいて、保護層に帯電防止剤としてポ
リエチレンオーキザイド系化合物を３５ｎ＋。[Film D's creation F! ! ] In the above film C, 35n+ of a polyethylene oxidide compound was added as an antistatic agent to the protective layer.
／１２となるように添加し、フィルムの裏面にアルミナ
ゾルＡ Ｓ−２００を０．８（１／ｉ２どなるように塗
工した。/12, and alumina sol A S-200 was applied to the back side of the film at a ratio of 0.8 (1/i2).
上記で実験したフィルムをザクラドール６１１珈像液（
小西六写真工業［Ｊ）を用いてサクラオートマチックプ
ロセツザーＱＳ−２５（小西六写真工業■製）で３８℃
、２０秒視像を行ない定着、水洗、乾燥をした。スリキ
ズの判定を実施例−１と同様にして行ない、得られた結
果を表−７に示す。The film tested above was mixed with Zacrador 611 photographic solution (
Using Sakura Automatic Processor QS-25 (manufactured by Konishiroku Photo Industry ■) at 38℃ using Konishiroku Photo Industry [J]
After visual imaging for 20 seconds, the film was fixed, washed with water, and dried. The judgment of scratches was carried out in the same manner as in Example-1, and the obtained results are shown in Table-7.
以下余白
表−７
表−７の結果から明らかなように、本発明の遮光部材を
用いたものは他のフィルムにおいても開襟にスタチック
マークの発生が良好に防止されることが確認された。Margin Table 7 Below: As is clear from the results in Table 7, it was confirmed that the use of the light shielding member of the present invention effectively prevented the generation of static marks on the open collar of other films as well.
なお、本発明の遮光部材を用いて、電篩写植用の写真フ
ィルムマガジンを作成し、電算写植機でテストを行った
フィルムにおいては、すべてスタチックマークが良好に
防止されていることを確認した。In addition, it was confirmed that static marks were well prevented in all of the films that were created using the light-shielding member of the present invention to create a photographic film magazine for electronic sieve typesetting, and tested with a computerized typesetting machine. .
Claims (1)
された写真フィルムマガジンにおいて、前記遮光部材が
リン酸化合物系帯電防止剤および潤滑剤で処理されてい
ることを特徴とする写真フィルムマガジン。1. A photographic film magazine in which a light shielding member having a pile is attached to a photographic film entrance/exit portion, wherein the light shielding member is treated with a phosphoric acid compound-based antistatic agent and a lubricant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61129881A JPH0610748B2 (en) | 1986-06-04 | 1986-06-04 | Photo film magazine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61129881A JPH0610748B2 (en) | 1986-06-04 | 1986-06-04 | Photo film magazine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62286041A true JPS62286041A (en) | 1987-12-11 |
| JPH0610748B2 JPH0610748B2 (en) | 1994-02-09 |
Family
ID=15020634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61129881A Expired - Lifetime JPH0610748B2 (en) | 1986-06-04 | 1986-06-04 | Photo film magazine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0610748B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01312537A (en) * | 1988-06-13 | 1989-12-18 | Konica Corp | Cartridge for photographic film |
| JPH0293456A (en) * | 1988-09-29 | 1990-04-04 | Konica Corp | Magazine for photographic sensitive material |
| JPH02161427A (en) * | 1988-12-15 | 1990-06-21 | Konica Corp | Magazine for photographic sensitive material |
| US5508775A (en) * | 1993-09-08 | 1996-04-16 | Fuji Photo Film Co., Ltd. | Method and apparatus for finishing pile fabric |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2336230A (en) * | 1941-08-15 | 1943-12-07 | Eastman Kodak Co | Surface-active agent |
| US2345734A (en) * | 1939-07-18 | 1944-04-04 | Eastman Kodak Co | Self-emulsifying phosphated and phosphited oils as antistatic lubricants |
| JPS4946391A (en) * | 1972-07-07 | 1974-05-02 | ||
| JPS53292A (en) * | 1976-06-23 | 1978-01-05 | Monsanto Co | Polyester filament formable polymer and preparation thereof |
| JPS60208751A (en) * | 1984-04-02 | 1985-10-21 | Kuraray Co Ltd | Fabric structure for shading photosensitive film box |
| JPS60246866A (en) * | 1984-05-16 | 1985-12-06 | 東レ株式会社 | Yarn making fiber treating agent |
-
1986
- 1986-06-04 JP JP61129881A patent/JPH0610748B2/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2345734A (en) * | 1939-07-18 | 1944-04-04 | Eastman Kodak Co | Self-emulsifying phosphated and phosphited oils as antistatic lubricants |
| US2336230A (en) * | 1941-08-15 | 1943-12-07 | Eastman Kodak Co | Surface-active agent |
| JPS4946391A (en) * | 1972-07-07 | 1974-05-02 | ||
| JPS53292A (en) * | 1976-06-23 | 1978-01-05 | Monsanto Co | Polyester filament formable polymer and preparation thereof |
| JPS60208751A (en) * | 1984-04-02 | 1985-10-21 | Kuraray Co Ltd | Fabric structure for shading photosensitive film box |
| JPS60246866A (en) * | 1984-05-16 | 1985-12-06 | 東レ株式会社 | Yarn making fiber treating agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01312537A (en) * | 1988-06-13 | 1989-12-18 | Konica Corp | Cartridge for photographic film |
| JPH0293456A (en) * | 1988-09-29 | 1990-04-04 | Konica Corp | Magazine for photographic sensitive material |
| JPH02161427A (en) * | 1988-12-15 | 1990-06-21 | Konica Corp | Magazine for photographic sensitive material |
| US5508775A (en) * | 1993-09-08 | 1996-04-16 | Fuji Photo Film Co., Ltd. | Method and apparatus for finishing pile fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0610748B2 (en) | 1994-02-09 |
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