JPS6228802B2 - - Google Patents

Info

Publication number: JPS6228802B2
Authority: JP; Japan
Prior art keywords: weight; parts; monomers; polymerization; persulfate
Prior art date: 1979-11-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP14410679A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5667317A (en

Inventor

Norio Yagi

Yutaka Mitsuta

Tomoyuki Kitsunai

Yasuaki Sakano

Masaki Aikawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Denka Co Ltd

Original Assignee

Denki Kagaku Kogyo KK

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-11-07

Filing date

1979-11-07

Publication date

1987-06-23

1979-11-07 Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK

1979-11-07 Priority to JP14410679A priority Critical patent/JPS5667317A/ja

1981-06-06 Publication of JPS5667317A publication Critical patent/JPS5667317A/ja

1987-06-23 Publication of JPS6228802B2 publication Critical patent/JPS6228802B2/ja

Status Granted legal-status Critical Current

Links

239000000178 monomer Substances 0.000 claims description 31
229920002554 vinyl polymer Polymers 0.000 claims description 12
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 10
229910019142 PO4 Inorganic materials 0.000 claims description 9
238000000034 method Methods 0.000 claims description 9
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 9
239000010452 phosphate Substances 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
229910052783 alkali metal Inorganic materials 0.000 claims description 7
-1 alkali metal sulfonate Chemical class 0.000 claims description 6
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 6
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical group [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 6
239000002585 base Substances 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
239000001506 calcium phosphate Substances 0.000 claims description 4
229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
235000011010 calcium phosphates Nutrition 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 4
238000007720 emulsion polymerization reaction Methods 0.000 claims description 4
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical group [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
150000001340 alkali metals Chemical class 0.000 claims 1
125000003118 aryl group Chemical class 0.000 claims 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
229920005992 thermoplastic resin Polymers 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 description 24
239000003505 polymerization initiator Substances 0.000 description 7
229920001577 copolymer Polymers 0.000 description 5
239000003995 emulsifying agent Substances 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
150000003923 2,5-pyrrolediones Chemical class 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 description 2
238000007664 blowing Methods 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 description 1
HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910001870 ammonium persulfate Inorganic materials 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000006698 induction Effects 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
239000004137 magnesium phosphate Substances 0.000 description 1
229910000157 magnesium phosphate Inorganic materials 0.000 description 1
229960002261 magnesium phosphate Drugs 0.000 description 1
235000010994 magnesium phosphates Nutrition 0.000 description 1
125000005395 methacrylic acid group Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
239000007787 solid Substances 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1

Landscapes

Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP14410679A 1979-11-07 1979-11-07 Production of thermoplastic resin Granted JPS5667317A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP14410679A JPS5667317A (en)	1979-11-07	1979-11-07	Production of thermoplastic resin

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP14410679A JPS5667317A (en)	1979-11-07	1979-11-07	Production of thermoplastic resin

Publications (2)

Publication Number	Publication Date
JPS5667317A JPS5667317A (en)	1981-06-06
JPS6228802B2 true JPS6228802B2 (fr)	1987-06-23

Family

ID=15354319

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP14410679A Granted JPS5667317A (en)	1979-11-07	1979-11-07	Production of thermoplastic resin

Country Status (1)

Country	Link
JP (1)	JPS5667317A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS61162507A (ja) *	1985-01-11	1986-07-23	Sumitomo Naugatuck Co Ltd	耐熱性ならびに流動性に優れる共重合体の製造法

1979
- 1979-11-07 JP JP14410679A patent/JPS5667317A/ja active Granted

Also Published As

Publication number	Publication date
JPS5667317A (en)	1981-06-06

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US4001163A (en)	1977-01-04	Styrene-butadiene copolymer latices containing carboxyl groups
JPH07316208A (ja)	1995-12-05	アクリルポリマーの製造方法
JPH0250923B2 (fr)	1990-11-05
US4129703A (en)	1978-12-12	Free-radical polymerizations using mixed initiator systems at two thermally distinct polymerization stages
JPS6236044B2 (fr)	1987-08-05
US3255164A (en)	1966-06-07	Redox polymerization incorporating step of dissolving reducing agent in monomer
KR20010014182A (ko)	2001-02-26	자유 라디칼 개시 수성 유화 중합에 의한 수성 중합체분산액의 제조 방법
US5510399A (en)	1996-04-23	Aqueous, high-solids synthetic rubber emulsion and its preparation
US3470146A (en)	1969-09-30	Suspension polymerization of vinyl aromatic monomers
JPS6228802B2 (fr)	1987-06-23
JPH0124805B2 (fr)	1989-05-15
US4169828A (en)	1979-10-02	Bead size distribution in the suspension polymerization of vinyl aromatic monomers
JPS6261048B2 (fr)	1987-12-19
US3915942A (en)	1975-10-28	Process for producing acrylonitrile polymers
GB944266A (en)	1963-12-11	Process for the production of acrylonitrile copolymers
US5266642A (en)	1993-11-30	Process for the preparation of alpha-methylstyrene polymers
US3769251A (en)	1973-10-30	Process for the preparation of aqueous styrene/acrylic acid ester copolymer dispersions
US4004072A (en)	1977-01-18	Process for producing acrylonitrile polymers
CN101591404B (zh)	2011-03-30	1-卤代羧酸-n-(2或3-磺酸基羧酸)二元醇二酯的应用
JPH09188706A (ja)	1997-07-22	水性懸濁液中でのアクリル系モノマーの重合方法
GB1005377A (en)	1965-09-22	Aqueous emulsions of acrylic ester copolymers
JPH08245706A (ja)	1996-09-24	機械的安定性に優れた水性エマルジョンの製造方法
JPS617309A (ja)	1986-01-14	アクリル酸またはメタクリル酸のエステル類の重合方法
JPS5871901A (ja)	1983-04-28	ビニル糸重合体粒子の製造方法