JPS62292746A - フタル酸ジメタリルエステルの製造法 - Google Patents

フタル酸ジメタリルエステルの製造法

Info

Publication number: JPS62292746A
Authority: JP; Japan
Prior art keywords: reaction; range; phthalic acid; chloride; dimethallyl
Prior art date: 1986-06-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP61134672A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0588697B2 (de

Inventor

Hidenori Ota

大田　英則

Toshihiro Sato

俊裕佐藤

Masao Kobayashi

雅夫小林

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Chemical Corp

Original Assignee

Mitsubishi Rayon Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-06-10

Filing date

1986-06-10

Publication date

1987-12-19

1986-06-10 Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd

1986-06-10 Priority to JP61134672A priority Critical patent/JPS62292746A/ja

1987-12-19 Publication of JPS62292746A publication Critical patent/JPS62292746A/ja

1993-12-24 Publication of JPH0588697B2 publication Critical patent/JPH0588697B2/ja

Status Granted legal-status Critical Current

Links

-1 dimethallyl phthalate Chemical compound 0.000 title claims description 21
238000004519 manufacturing process Methods 0.000 title claims description 7
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 27
238000006243 chemical reaction Methods 0.000 claims description 25
OHXAOPZTJOUYKM-UHFFFAOYSA-N 3-Chloro-2-methylpropene Chemical compound CC(=C)CCl OHXAOPZTJOUYKM-UHFFFAOYSA-N 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 9
238000000034 method Methods 0.000 claims description 4
239000000243 solution Substances 0.000 description 11
239000002253 acid Substances 0.000 description 7
150000001447 alkali salts Chemical class 0.000 description 5
229910021591 Copper(I) chloride Inorganic materials 0.000 description 4
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 4
229940045803 cuprous chloride Drugs 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 3
238000004821 distillation Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000003513 alkali Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
229960003280 cupric chloride Drugs 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
238000010992 reflux Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000005406 washing Methods 0.000 description 2
DSAYAFZWRDYBQY-UHFFFAOYSA-N 2,5-dimethylhexa-1,5-diene Chemical group CC(=C)CCC(C)=C DSAYAFZWRDYBQY-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
BYDRTKVGBRTTIT-UHFFFAOYSA-N 2-methylprop-2-en-1-ol Chemical compound CC(=C)CO BYDRTKVGBRTTIT-UHFFFAOYSA-N 0.000 description 1
OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
239000003518 caustics Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000011033 desalting Methods 0.000 description 1
HQWKKEIVHQXCPI-UHFFFAOYSA-L disodium;phthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C([O-])=O HQWKKEIVHQXCPI-UHFFFAOYSA-L 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000004448 titration Methods 0.000 description 1
238000000954 titration curve Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP61134672A 1986-06-10 1986-06-10 フタル酸ジメタリルエステルの製造法 Granted JPS62292746A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP61134672A JPS62292746A (ja)	1986-06-10	1986-06-10	フタル酸ジメタリルエステルの製造法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP61134672A JPS62292746A (ja)	1986-06-10	1986-06-10	フタル酸ジメタリルエステルの製造法

Publications (2)

Publication Number	Publication Date
JPS62292746A true JPS62292746A (ja)	1987-12-19
JPH0588697B2 JPH0588697B2 (de)	1993-12-24

Family

ID=15133867

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP61134672A Granted JPS62292746A (ja)	1986-06-10	1986-06-10	フタル酸ジメタリルエステルの製造法

Country Status (1)

Country	Link
JP (1)	JPS62292746A (de)

1986
- 1986-06-10 JP JP61134672A patent/JPS62292746A/ja active Granted

Also Published As

Publication number	Publication date
JPH0588697B2 (de)	1993-12-24

Publication	Publication Date	Title
DE69806832T2 (de)	2003-03-13	Verfahren zur Herstellung von Octaphenylcyclotetrasiloxan und Sym-Tetramethyltetraphenylcyclotetrasiloxan
EP0065770A1 (de)	1982-12-01	Verfahren zur Herstellung von p-Nitrophenetol
JPS6168446A (ja)	1986-04-08	ヒドロキシピバリン酸ネオペンチルグリコールエステルの製法
JPH0768166B2 (ja)	1995-07-26	メタクリル酸メチルの製法
JP2812792B2 (ja)	1998-10-22	色彩的に改善された純粋なグアニンの製造方法
US4983764A (en)	1991-01-08	Process for preparing N-phosphonomethyl-glycine
JPS62292746A (ja)	1987-12-19	フタル酸ジメタリルエステルの製造法
EP0044510B1 (de)	1984-03-07	Verfahren zur Herstellung von Diarylestern
US4499028A (en)	1985-02-12	Preparation of isethionic acid
US1584907A (en)	1926-05-18	Production of esters from amide acid sulphates
US3206510A (en)	1965-09-14	Process for making cyclohexanoneoxime
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CA1196014A (en)	1985-10-29	Process for producing n-phosphonomethylglycine
JPS62120332A (ja)	1987-06-01	２−パ−フルオロアルキルエタノ−ルの精製法
JPS6338983B2 (de)	1988-08-03
US3492344A (en)	1970-01-27	Process for producing cyclohexylsulfamic acid
JPS6115862A (ja)	1986-01-23	スクシノコハク酸ジアルキルの製法
JPS628419B2 (de)	1987-02-23
JP2501104B2 (ja)	1996-05-29	二酸化ゲルマニウムの回収方法
US3355485A (en)	1967-11-28	Preparation of sodium cyclohexyl sulfamate free of sulfate ions
JPH045657B2 (de)	1992-02-03
JPS6087281A (ja)	1985-05-16	ジオキサントリオ−ルの製造方法
US2477158A (en)	1949-07-26	Method of preparing veratraldehyde from opianic acid