JPS627669A - Member for semiconductor - Google Patents

Member for semiconductor

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Publication number
JPS627669A
JPS627669A JP60142496A JP14249685A JPS627669A JP S627669 A JPS627669 A JP S627669A JP 60142496 A JP60142496 A JP 60142496A JP 14249685 A JP14249685 A JP 14249685A JP S627669 A JPS627669 A JP S627669A
Authority
JP
Japan
Prior art keywords
weight
parts
sic
oxygen
strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60142496A
Other languages
Japanese (ja)
Other versions
JPH0583513B2 (en
Inventor
玉水 照康
幸文 酒井
恭一 岡本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coorstek KK
Original Assignee
Toshiba Ceramics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Ceramics Co Ltd filed Critical Toshiba Ceramics Co Ltd
Priority to JP60142496A priority Critical patent/JPS627669A/en
Publication of JPS627669A publication Critical patent/JPS627669A/en
Publication of JPH0583513B2 publication Critical patent/JPH0583513B2/ja
Granted legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 産業[の不1用 この発明は、半導体拡散炉の炉芯管、ボート、フォーク
のごとき半導体用部材、とくに高強度材料でつくられた
半導体用部材に関するものである。
DETAILED DESCRIPTION OF THE INVENTION This invention relates to semiconductor components such as core tubes, boats, and forks of semiconductor diffusion furnaces, and particularly to semiconductor components made of high-strength materials.

mi記 従来のセラミック焼結体でつくられた半導体用部材たと
えば半導体用炉芯管は、強度が150MPa程度にすぎ
なかった。
A conventional semiconductor member made of a ceramic sintered body, such as a semiconductor furnace core tube, has a strength of only about 150 MPa.

ところが、最近−半導体ウェハは大型化する傾向が強く
、ウェハの寸法おJ:び干出が大きくなっている。たと
えば、5インチのウェハは15グラム、6インチのウェ
ハは20グラム、8インチのウェハは36グラムである
。
However, recently, there has been a strong tendency for semiconductor wafers to become larger, and the wafer dimensions and wafer size have increased. For example, a 5-inch wafer weighs 15 grams, a 6-inch wafer weighs 20 grams, and an 8-inch wafer weighs 36 grams.

また、これらのウェハを熱処理する炉芯管の直径は、6
インチのウェハで235mm、8インチのウェハで30
0mmである。また、1つのボートには25〜50枚の
ウェハを載置するのが一般的である。そのため、ウェハ
の大型化に伴って、ボートが支持づべき重石は著しく増
加する。フォークは4つのボートを支持(ることもあり
、より一段と大きな重量に耐えるようにしなければなら
ない。
In addition, the diameter of the furnace core tube for heat-treating these wafers is 6
235mm for inch wafer, 30mm for 8 inch wafer
It is 0 mm. Moreover, it is common to place 25 to 50 wafers on one boat. Therefore, as the size of the wafer increases, the weight that the boat must support increases significantly. The fork may support four boats, so it must be able to withstand even more weight.

、 が ゛しようと る[ 1 従来のセラミック焼結体でつくられた半導体用部材にお
いては、ウェハの大型化に十分に対処できない。たとえ
ば、炉芯管の場合、肉厚を大きくしなければならず、耐
スポーリングの問題が生じるばかりでなく、炉内の湿度
降下速度が低く、ランニングコストが高くなる。
[1] Conventional semiconductor components made of ceramic sintered bodies cannot adequately cope with the increasing size of wafers. For example, in the case of a furnace core tube, the wall thickness must be increased, which not only causes the problem of spalling resistance, but also reduces the rate of humidity drop in the furnace, increasing running costs.

また、ボートやフォークの場合、割れや変形等のトラブ
ルが発生しやすくなる。
Furthermore, in the case of boats and forks, problems such as cracking and deformation are more likely to occur.

11丸l立 この発明は、前述のような従来技術の欠点を解消して、
高強度の半導体用部材を提供することを目的としている
。
This invention solves the drawbacks of the prior art as mentioned above,
The purpose is to provide high-strength semiconductor members.

ル1悲11 したがって、この目的を達成するために、第1の発明は
、5iC50〜97”1m部と、△9N1〜10重量部
と、C1〜10工猶部とを成形焼成してなる半導体用部
材を要旨としている。
Therefore, in order to achieve this object, the first invention provides a semiconductor formed by molding and firing 1 m part of 5iC50-97'', 1-10 parts by weight of Δ9N, and a C1-10 process part. The main points are the parts and materials used.

また、第2の発明は、Si 050〜97重分部と、A
’2N1〜10重邑部と、C1〜10重量部と、A’)
2031〜30重量部を成形焼成してなる半導体用部材
を要旨としている。
Further, the second invention provides a Si 050-97 overlapped portion and an A
'2N1~10 parts by weight, C1~10 parts by weight, A')
The gist is a semiconductor member formed by molding and firing 2031 to 30 parts by weight.

IJ   を ′ ゛るための 本発明者等は炭化ケイ素質焼結体のひずみの発生につい
てその原因を究明したところ、原IIのSiCにおける
含有酸素量によって焼結体の特性が大きく影響されるこ
とを発見しlこ 。
In order to improve IJ, the present inventors investigated the cause of distortion in silicon carbide sintered bodies and found that the properties of the sintered bodies were greatly affected by the amount of oxygen contained in the SiC of original II. I discovered this.

炭化ケイ素はその粒子表面が常温であっても空気によっ
て酸化され、特に1μm以下のような超微粒子の場合は
酸化の度合が著しい。
Silicon carbide is oxidized by air even if its particle surface is at room temperature, and the degree of oxidation is particularly significant in the case of ultrafine particles of 1 μm or less.

一般的にいって、SiC中の酸素量は表面積に比例して
増大する。換言すれば、粒子径が小になれば、それだけ
SiC中の酸素量が大きくなるのである。
Generally speaking, the amount of oxygen in SiC increases in proportion to the surface area. In other words, the smaller the particle size, the larger the amount of oxygen in SiC.

このような炭化ケイ素中の酸素による影響について説明
すれば1.l Nは、5iC−AQ N−C系において
液相で反応が進むため、均質性の点でホウ素にりも好ま
しい焼結助剤であるが、SiC中の酸素による妨害を受
けやすい。そのため、従来は含有酸素量が比較的多い5
iC(例えば約1重量%の酸素を含むSi C)の場合
は、SiC中の酸素による妨害の度合が大きく、Δ9N
を焼結助剤として用いても優れた効果が19られなかっ
た。
The effects of oxygen in silicon carbide can be explained as follows: 1. Since lN reacts in the liquid phase in the 5iC-AQ N-C system, boron is also a preferred sintering aid in terms of homogeneity, but it is susceptible to interference by oxygen in SiC. Therefore, in the past, the amount of oxygen contained was relatively high.
In the case of iC (for example, SiC containing about 1% by weight of oxygen), the degree of interference by oxygen in SiC is large, and Δ9N
Even when used as a sintering aid, no excellent effect was obtained.

このような観点から、従来、SiC中の含有酸素量は、
少なくともA[Nを焼結助剤、とじて使用する場合は、
小さいほど好ましいとされてきたのである。AQ Nを
添加する場合は、SiC中の酸素量を小さく設定するこ
と、つまりSiCの粒径を大きく設定することが必要で
あった。それゆえ、他の諸点では3iC粉末の粒径は小
さいほど好ましいことがわかっていても、そのような超
微粒子は実際には1吏用できなかった。
From this point of view, conventionally, the amount of oxygen contained in SiC is
When using at least A[N as a sintering aid,
It has been believed that the smaller the size, the better. When adding AQN, it was necessary to set the amount of oxygen in SiC small, that is, to set the particle size of SiC large. Therefore, even though it is known that the smaller the particle size of 3iC powder is in other respects, it has not been possible to actually use such ultrafine particles.

しかしながら、本発明者等は反応系の中にCを含有せし
めることによって前述のごときSiC中の含有酸素によ
る妨害を副部できることを解明した。
However, the present inventors have discovered that the above-mentioned interference caused by the oxygen contained in SiC can be reduced by incorporating C into the reaction system.

そこで、この発明は、このような複数成分の相互関係を
巧みに生かし、まずCの添加により炭化ケイ素を無酸素
状態にし、しかるのちΔ9Nを焼結助剤として焼結させ
るものである。それゆえ反応が理想的な状態で行なわれ
る。
Therefore, the present invention skillfully takes advantage of the interrelationships among a plurality of components to first render silicon carbide in an oxygen-free state by adding C, and then sinter it using Δ9N as a sintering aid. Therefore, the reaction takes place under ideal conditions.

SIC中の酸素の影響をうけずに、I Nは、例えば2
000℃以上の焼結温度において液相となり、△9がS
iと均一に買換されやすい。したがって焼結体は均質と
なり、高強度となる。
Without the influence of oxygen in the SIC, I N is, for example, 2
It becomes a liquid phase at a sintering temperature of 000℃ or higher, and △9 is S
It is easy to exchange with i. Therefore, the sintered body becomes homogeneous and has high strength.

また、第2発明にあっては、炭化ケイ素をA9203−
AQ N−C系の焼結助剤で焼結させ、高強度の自焼結
炭化ケイ素をつくる。その場合、5iC−A9Nは全律
固溶する。したがってSi C−AQzO3−AQ N
−C系では炭化ケイ素は自焼結する。この系にあっては
液相焼結であり、そのため、同相焼結のものに比べて均
一な焼結組織を作り易い。
Moreover, in the second invention, silicon carbide is A9203-
Sintered with AQ N-C based sintering aid to create high strength self-sintered silicon carbide. In that case, 5iC-A9N is completely dissolved in solid solution. Therefore, Si C-AQzO3-AQ N
-C-based silicon carbide self-sinters. This system uses liquid phase sintering, which makes it easier to create a uniform sintered structure compared to in-phase sintering.

また、A Q203を添加すると、A 9203の一部
がCにより還元され、活性なA!2が生成し、他の酸化
物の不純物が焼結炭化ケイ素の粒界にα−△Il!20
3として存在する。炭化ケイ素と、炭化ケイ素焼結組織
に存在するAl2O3との熱膨張の差によって焼結体の
歪みを除く作用をする。このため焼結体の強度は900
MPaにも達する。また、ワイブル係数は15となり、
きわめて信頼性が高くなる。
Furthermore, when AQ203 is added, a part of A9203 is reduced by C, resulting in active A! 2 is generated, and other oxide impurities are present at the grain boundaries of sintered silicon carbide. 20
It exists as 3. The difference in thermal expansion between silicon carbide and Al2O3 present in the silicon carbide sintered structure acts to remove distortion in the sintered body. Therefore, the strength of the sintered body is 900
It also reaches MPa. Also, the Weibull coefficient is 15,
Extremely reliable.

このようなことを勘案して、この発明にあっては、組成
を次のとおり限定した。すなわち、第1発明ではSi 
050〜97重分部と、Ail N1〜101最部、!
:、01〜10重量部にし、第2発明では、ざらに、A
Q 2031〜30重量部、C加したのである。
Taking these matters into consideration, in this invention, the composition is limited as follows. That is, in the first invention, Si
050-97 overlapped part and Ail N1-101 most part,!
:, 01 to 10 parts by weight, and in the second invention, Zara, A
Q: 2031 to 30 parts by weight of C was added.

組成をそのように限定した理由を以下詳細に説明する。The reason for limiting the composition in this way will be explained in detail below.

AQ Nは、1重量部より小だと焼結助剤としての十分
な効果が得られず、10重量部より大だと強度が著しく
低下する。
When AQN is less than 1 part by weight, sufficient effect as a sintering aid cannot be obtained, and when it is more than 10 parts by weight, the strength is significantly reduced.

Cは、1重量部より小だと焼結助剤として添加した窒化
物が焼結助剤として作用しなくなって強度の低下を沼き
、10重量部より大だと焼結体としての耐酸化性が悪化
し、強度も低下する。
If C is less than 1 part by weight, the nitride added as a sintering aid will no longer function as a sintering aid, resulting in a decrease in strength, and if it is more than 10 parts by weight, the oxidation resistance of the sintered body will deteriorate. The properties deteriorate and the strength also decreases.

AQ 203は1重量部より小だと強度の向上が認めら
れず、30重量部より大だと強度の低下が著しくなる。
If AQ 203 is less than 1 part by weight, no improvement in strength will be observed, and if it is more than 30 parts by weight, the strength will be significantly reduced.

本発明の好ましい実M態様では、炭化ケイ素の比表面積
を20m2/F以上(好しくは約45ff12/g)に
するか、又は酸素を1.51母%以上含む炭化ケイ素を
使用して、焼結体の特性を一段と優れたものにする。
In a preferred embodiment M of the present invention, the specific surface area of silicon carbide is set to 20 m2/F or more (preferably about 45 ff12/g), or silicon carbide containing 1.51% or more of oxygen is used. Improve the properties of the body.

支克乱上 平均粒径の1μmのSiC粉末79重量部と、A!22
0315重量部と、C4重量部と、AlN2重伍部を配
合し、フェノールレジンを粘結剤として添加して混練成
形し、アルゴン雰囲気下で1800℃の温度で常圧焼結
を行なって、理論密度に対し98〜80%の緻密体を得
た。その20℃における曲げ強さは900MPaであっ
た。
79 parts by weight of SiC powder with an average particle diameter of 1 μm and A! 22
0315 parts by weight, C4 parts by weight, and 2 parts by weight of AlN were mixed, kneaded and molded with the addition of phenol resin as a binder, and pressureless sintered at a temperature of 1800°C in an argon atmosphere. A dense body with a density of 98 to 80% was obtained. Its bending strength at 20°C was 900 MPa.

11糺り 平均粒径10μmのSiC粉末に4重量部のCと2車a
部のA9Nを配合し、フェノールレジンを粘結剤として
使用して混練成形し、アルゴン雰囲気下で21QO℃の
常圧焼結を行って、理論密度に対し98〜80重量%の
緻密体を得た。その20’Cにおける曲げ強さは850
MPaであった。
11 SiC powder with an average particle diameter of 10 μm, 4 parts by weight of C and 2 wheels a
A9N was mixed and molded using phenol resin as a binder, and pressureless sintering was performed at 21QO℃ in an argon atmosphere to obtain a dense body with a density of 98 to 80% by weight based on the theoretical density. Ta. Its bending strength at 20'C is 850
It was MPa.

支1JLIL 平均粒径1μmのSiC粉末をポットミルに入れて、水
を含まないアセトンを使用して平均粒径0.5μmにな
るまで粉砕した。
Support 1 JLIL SiC powder with an average particle size of 1 μm was placed in a pot mill and ground using water-free acetone until the average particle size was 0.5 μm.

このような超微粒のSiC粉末を常温で空気にさらし、
SiCの粒子表面積を一部酸化させた。その際、それら
の酸化を管理して、SiC内の酸素含有量を0.51量
%、1重層%、1.5重量%、2重量%、4重M%にし
たものを得た。
Such ultra-fine SiC powder is exposed to air at room temperature,
Part of the SiC particle surface area was oxidized. At that time, the oxidation was controlled to obtain SiC with an oxygen content of 0.51% by weight, 1% by weight, 1.5% by weight, 2% by weight, and 4% by weight.

そのように一部間化された各SiC粉末に3重量部のC
と1重は部の△9Nを配合し、フェノールレジンを粘結
剤として使用して混練成形し、アルゴン雰囲気下で21
00℃の常圧焼結を行って、理論密度に対し98〜80
重」%のm密林を得た。これらのものの20℃における
曲げ強さは表1に示す通りであった。表1からも明らか
なように、SiC中の酸素量が1.5重量%を超えると
、曲げ強さが増加する。
3 parts by weight of C was added to each SiC powder so partially oxidized.
and 1 part △9N were mixed and molded using phenol resin as a binder, and 21 parts were mixed in an argon atmosphere.
Perform pressureless sintering at 00℃ to achieve a density of 98 to 80 compared to the theoretical density.
% m dense forest was obtained. The bending strength of these products at 20° C. was as shown in Table 1. As is clear from Table 1, when the amount of oxygen in SiC exceeds 1.5% by weight, the bending strength increases.

支11上 平均粒径1μmのSiC粉末にA 9203、Cおよび
A9Nを配合し、フェノールレジンを粘結剤として添加
して混練成形し、アルゴン雰囲気下で1800℃の温度
で常圧焼結を行なって、理論密度に対し98〜80重最
%の単口体を17だ。これらのものの20’Cにおける
曲げ強1立は表2に示すとおりであった。
A9203, C and A9N were blended with SiC powder with an average particle size of 1 μm on support 11, and phenol resin was added as a binder, kneaded and molded, and pressureless sintered at a temperature of 1800°C in an argon atmosphere. So, the single mouth material with the maximum weight of 98 to 80% of the theoretical density is 17. The bending strength of these materials at 20'C was as shown in Table 2.

表2からも明らかなように、SiC粉末の比表面積が2
0m2/gを超えると、曲げ強度が増加する。
As is clear from Table 2, the specific surface area of SiC powder is 2
When it exceeds 0 m2/g, the bending strength increases.

l肚灸立1 以上の説明からも明らかなように、本発明によれば、従
来のものに比較して高強度の半。
1 As is clear from the above explanation, according to the present invention, the intensity is half that of the conventional one.

導体用部材が19られる。とくに最適の条件にすれば、
900MPaの高強度のものが得られる。
A conductor member 19 is provided. Especially under optimal conditions,
A high strength of 900 MPa can be obtained.

それゆえ、本発明によれば、半導体用部材を2〜3mm
の薄肉にしても十分に実用に洪しえることになり、耐ス
ポーリング性が格段に向上し、とくに大型の炉芯管に適
用した場合、肉薄により炉内の温度降下速度を大きくで
き、ランニングコストを大幅に低減できるという実務上
きわめて顕著な効果を奏する。
Therefore, according to the present invention, the thickness of the semiconductor member is 2 to 3 mm.
Even if the wall is thin, it can be put to practical use, and the spalling resistance is greatly improved.Especially when applied to a large furnace core tube, the thin wall makes it possible to increase the rate of temperature drop in the furnace, and the running This has an extremely significant practical effect in that costs can be significantly reduced.

また、′本発明によれば、従来のものに比較して比較的
低温で焼結できる。とくに従来は実際上全く不可能とさ
れていた1 900℃以下の温度でも所望の焼結が実施
できる。したがって製造コストの低減がはかれる。
Furthermore, according to the present invention, sintering can be performed at a relatively low temperature compared to conventional methods. In particular, desired sintering can be performed at temperatures below 1900°C, which was previously considered to be completely impossible. Therefore, manufacturing costs can be reduced.

さらに、本発明にあっては、焼結体が気孔率1%以下で
緻密であるため、3iの含浸が不要である。
Furthermore, in the present invention, since the sintered body is dense with a porosity of 1% or less, impregnation with 3i is not necessary.

表  1 酸素含有量〈重量%)      曲げ強度(MPa 
)
Table 1 Oxygen content (wt%) Bending strength (MPa
)

Claims (4)

【特許請求の範囲】[Claims] (1)SiC50〜97重量部と、AlN 1〜10重量部と、C1〜10重量部とを成形焼成して
なる半導体用部材。
(1) A semiconductor member formed by molding and firing 50 to 97 parts by weight of SiC, 1 to 10 parts by weight of AlN, and 1 to 10 parts by weight.
(2)SiC50〜97重量部と、AlN 1〜10重量部と、C1〜10重量部と、Al_2O_
31〜30重量部を成形焼成してなる半導体用部材。
(2) 50 to 97 parts by weight of SiC, 1 to 10 parts by weight of AlN, 1 to 10 parts by weight of C, and Al_2O_
A semiconductor member formed by molding and firing 31 to 30 parts by weight.
(3)酸素を1.5重量%以上含むSiC を使用した特許請求の範囲第1項または第2項に記載の
半導体用部材。
(3) The semiconductor member according to claim 1 or 2, which uses SiC containing 1.5% by weight or more of oxygen.
(4)比表面積が20m^2/g以上であるSiCを使
用した特許請求の範囲第1項または第2項に記載の半導
体用部材。
(4) The semiconductor member according to claim 1 or 2, which uses SiC having a specific surface area of 20 m^2/g or more.
JP60142496A 1985-07-01 1985-07-01 Member for semiconductor Granted JPS627669A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60142496A JPS627669A (en) 1985-07-01 1985-07-01 Member for semiconductor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60142496A JPS627669A (en) 1985-07-01 1985-07-01 Member for semiconductor

Publications (2)

Publication Number Publication Date
JPS627669A true JPS627669A (en) 1987-01-14
JPH0583513B2 JPH0583513B2 (en) 1993-11-26

Family

ID=15316680

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60142496A Granted JPS627669A (en) 1985-07-01 1985-07-01 Member for semiconductor

Country Status (1)

Country Link
JP (1) JPS627669A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63257218A (en) * 1987-03-30 1988-10-25 ノートン カンパニー Component of diffusion furnace
JPH01119560A (en) * 1987-10-31 1989-05-11 Toshiba Ceramics Co Ltd Electrically conductive silicon carbide sintered body
JPH01131059A (en) * 1987-11-17 1989-05-23 Toshiba Ceramics Co Ltd Production of furnace core tube of silicon carbide
JP2012180230A (en) * 2011-02-28 2012-09-20 Tokyo Yogyo Co Ltd Conductive ceramic sintered compact

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS553396A (en) * 1978-06-15 1980-01-11 Carborundum Co Silicon carbideealuminum nitride sintered product and its manugacture
JPS57148344A (en) * 1981-03-10 1982-09-13 Nec Corp Manufacturing equipment for semiconductor
JPS5950086A (en) * 1982-09-17 1984-03-22 南九州化学工業株式会社 Coated granular potassium fertilizer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS553396A (en) * 1978-06-15 1980-01-11 Carborundum Co Silicon carbideealuminum nitride sintered product and its manugacture
JPS57148344A (en) * 1981-03-10 1982-09-13 Nec Corp Manufacturing equipment for semiconductor
JPS5950086A (en) * 1982-09-17 1984-03-22 南九州化学工業株式会社 Coated granular potassium fertilizer

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63257218A (en) * 1987-03-30 1988-10-25 ノートン カンパニー Component of diffusion furnace
JPH01119560A (en) * 1987-10-31 1989-05-11 Toshiba Ceramics Co Ltd Electrically conductive silicon carbide sintered body
JPH01131059A (en) * 1987-11-17 1989-05-23 Toshiba Ceramics Co Ltd Production of furnace core tube of silicon carbide
JP2012180230A (en) * 2011-02-28 2012-09-20 Tokyo Yogyo Co Ltd Conductive ceramic sintered compact

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