JPS63199722A - 成形物品とその製法及びイソシアネート反応組成物 - Google Patents

成形物品とその製法及びイソシアネート反応組成物

Info

Publication number: JPS63199722A
Authority: JP; Japan
Prior art keywords: component; isocyanate; diamine; groups; weight
Prior art date: 1987-02-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP63027365A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0466887B2 (2

Inventor

クリスティアン・ヴェーバー

ヘルマン・シェーファー

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer AG

Original Assignee

Bayer AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-02-07

Filing date

1988-02-08

Publication date

1988-08-18

1988-02-08 Application filed by Bayer AG filed Critical Bayer AG

1988-08-18 Publication of JPS63199722A publication Critical patent/JPS63199722A/ja

1992-10-26 Publication of JPH0466887B2 publication Critical patent/JPH0466887B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 65
239000012948 isocyanate Substances 0.000 title claims description 15
150000002513 isocyanates Chemical class 0.000 title claims description 15
238000004519 manufacturing process Methods 0.000 title claims description 11
238000006243 chemical reaction Methods 0.000 title claims description 9
150000004985 diamines Chemical class 0.000 claims description 56
238000000034 method Methods 0.000 claims description 50
239000007795 chemical reaction product Substances 0.000 claims description 37
229920000647 polyepoxide Polymers 0.000 claims description 34
150000001875 compounds Chemical class 0.000 claims description 33
229920000570 polyether Polymers 0.000 claims description 28
-1 aliphatic monocarboxylic acid Chemical class 0.000 claims description 27
125000003277 amino group Chemical group 0.000 claims description 26
239000000047 product Substances 0.000 claims description 22
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 21
239000005056 polyisocyanate Substances 0.000 claims description 20
229920001228 polyisocyanate Polymers 0.000 claims description 20
239000006082 mold release agent Substances 0.000 claims description 18
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 18
125000003700 epoxy group Chemical group 0.000 claims description 17
229920000768 polyamine Polymers 0.000 claims description 17
150000003751 zinc Chemical class 0.000 claims description 15
239000004721 Polyphenylene oxide Substances 0.000 claims description 14
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 14
238000010107 reaction injection moulding Methods 0.000 claims description 14
239000011541 reaction mixture Substances 0.000 claims description 14
125000004432 carbon atom Chemical group C* 0.000 claims description 13
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 11
125000001931 aliphatic group Chemical group 0.000 claims description 10
150000004984 aromatic diamines Chemical class 0.000 claims description 10
229920005862 polyol Polymers 0.000 claims description 9
150000003077 polyols Chemical class 0.000 claims description 9
229920002396 Polyurea Polymers 0.000 claims description 8
239000004593 Epoxy Substances 0.000 claims description 7
239000003365 glass fiber Substances 0.000 claims description 7
125000001302 tertiary amino group Chemical group 0.000 claims description 7
PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical group CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 claims description 5
239000004814 polyurethane Substances 0.000 claims description 5
229920003226 polyurethane urea Polymers 0.000 claims description 3
RQEOBXYYEPMCPJ-UHFFFAOYSA-N 4,6-diethyl-2-methylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(C)=C1N RQEOBXYYEPMCPJ-UHFFFAOYSA-N 0.000 claims description 2
230000001476 alcoholic effect Effects 0.000 claims description 2
238000002360 preparation method Methods 0.000 description 18
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239000002253 acid Substances 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 6
238000000465 moulding Methods 0.000 description 6
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
150000001735 carboxylic acids Chemical class 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
150000004665 fatty acids Chemical class 0.000 description 5
239000000243 solution Substances 0.000 description 5
LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
238000006735 epoxidation reaction Methods 0.000 description 4
239000003822 epoxy resin Substances 0.000 description 4
150000002170 ethers Chemical class 0.000 description 4
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150000005846 sugar alcohols Polymers 0.000 description 4
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 4
JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
241000276425 Xiphophorus maculatus Species 0.000 description 3
239000003570 air Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
229910021529 ammonia Inorganic materials 0.000 description 3
230000001413 cellular effect Effects 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
125000005442 diisocyanate group Chemical group 0.000 description 3
150000002118 epoxides Chemical class 0.000 description 3
125000004185 ester group Chemical group 0.000 description 3
239000012765 fibrous filler Substances 0.000 description 3
239000004872 foam stabilizing agent Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
150000002989 phenols Chemical class 0.000 description 3
WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 3
229960003656 ricinoleic acid Drugs 0.000 description 3
FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
239000002344 surface layer Substances 0.000 description 3
MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 2
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
BSPRNZCEFZORPU-UHFFFAOYSA-N 4-[[[4-[bis(oxiran-2-ylmethyl)amino]phenyl]-(oxiran-2-yl)methoxy]-(oxiran-2-yl)methyl]-n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC(=CC=1)C(OC(C1OC1)C=1C=CC(=CC=1)N(CC1OC1)CC1OC1)C1OC1)CC1CO1 BSPRNZCEFZORPU-UHFFFAOYSA-N 0.000 description 2
ZRWNRAJCPNLYAK-UHFFFAOYSA-N 4-bromobenzamide Chemical compound NC(=O)C1=CC=C(Br)C=C1 ZRWNRAJCPNLYAK-UHFFFAOYSA-N 0.000 description 2
239000004970 Chain extender Substances 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
239000005062 Polybutadiene Substances 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
239000010425 asbestos Substances 0.000 description 2
150000001718 carbodiimides Chemical class 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
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238000010438 heat treatment Methods 0.000 description 2
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
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230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
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239000011261 inert gas Substances 0.000 description 2
238000002347 injection Methods 0.000 description 2
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125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
238000002156 mixing Methods 0.000 description 2
JAYXSROKFZAHRQ-UHFFFAOYSA-N n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC=CC=1)CC1CO1 JAYXSROKFZAHRQ-UHFFFAOYSA-N 0.000 description 2
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150000003512 tertiary amines Chemical class 0.000 description 2
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239000011701 zinc Substances 0.000 description 2
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ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
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239000002202 Polyethylene glycol Substances 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
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239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 description 1
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229930006000 Sucrose Natural products 0.000 description 1
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229910001315 Tool steel Inorganic materials 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
LNWBFIVSTXCJJG-UHFFFAOYSA-N [diisocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)(N=C=O)C1=CC=CC=C1 LNWBFIVSTXCJJG-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000004705 aldimines Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
238000005576 amination reaction Methods 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000004760 aramid Substances 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
229920003235 aromatic polyamide Polymers 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000012752 auxiliary agent Substances 0.000 description 1
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
239000010428 baryte Substances 0.000 description 1
229910052601 baryte Inorganic materials 0.000 description 1
238000005452 bending Methods 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
JRPRCOLKIYRSNH-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC2OC2)C=1C(=O)OCC1CO1 JRPRCOLKIYRSNH-UHFFFAOYSA-N 0.000 description 1
XFUOBHWPTSIEOV-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohexane-1,2-dicarboxylate Chemical group C1CCCC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 XFUOBHWPTSIEOV-UHFFFAOYSA-N 0.000 description 1
KBWLNCUTNDKMPN-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) hexanedioate Chemical compound C1OC1COC(=O)CCCCC(=O)OCC1CO1 KBWLNCUTNDKMPN-UHFFFAOYSA-N 0.000 description 1
RGAMPJYGTCSRAG-UHFFFAOYSA-N bis[2-(diethylamino)ethyl] hexanedioate Chemical compound CCN(CC)CCOC(=O)CCCCC(=O)OCCN(CC)CC RGAMPJYGTCSRAG-UHFFFAOYSA-N 0.000 description 1
238000007664 blowing Methods 0.000 description 1
230000031709 bromination Effects 0.000 description 1
238000005893 bromination reaction Methods 0.000 description 1
239000001273 butane Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
239000002666 chemical blowing agent Substances 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000000039 congener Substances 0.000 description 1
239000012084 conversion product Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000010431 corundum Substances 0.000 description 1
125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
150000001983 dialkylethers Chemical class 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
125000002228 disulfide group Chemical group 0.000 description 1
BRWZYZWZBMGMMG-UHFFFAOYSA-J dodecanoate tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BRWZYZWZBMGMMG-UHFFFAOYSA-J 0.000 description 1
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
125000006575 electron-withdrawing group Chemical group 0.000 description 1
150000002081 enamines Chemical class 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000003925 fat Substances 0.000 description 1
229910021485 fumed silica Inorganic materials 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
150000002391 heterocyclic compounds Chemical class 0.000 description 1
WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
229940091173 hydantoin Drugs 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
150000004658 ketimines Chemical class 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
239000000178 monomer Substances 0.000 description 1
BXYVQNNEFZOBOZ-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-n',n'-dimethylpropane-1,3-diamine Chemical compound CN(C)CCCNCCCN(C)C BXYVQNNEFZOBOZ-UHFFFAOYSA-N 0.000 description 1
SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
ZWRDBWDXRLPESY-UHFFFAOYSA-N n-benzyl-n-ethylethanamine Chemical compound CCN(CC)CC1=CC=CC=C1 ZWRDBWDXRLPESY-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229920003986 novolac Polymers 0.000 description 1
RWZYAGGXGHYGMB-UHFFFAOYSA-N o-aminobenzenecarboxylic acid Natural products NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 1
JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
229940049964 oleate Drugs 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
229910052628 phlogopite Inorganic materials 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006149 polyester-amide block copolymer Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920005903 polyol mixture Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
150000008442 polyphenolic compounds Chemical class 0.000 description 1
235000013824 polyphenols Nutrition 0.000 description 1
229920006295 polythiol Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000010454 slate Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
239000012974 tin catalyst Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
229920006305 unsaturated polyester Polymers 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4081—Mixtures of compounds of group C08G18/64 with other macromolecular compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
- C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6523—Compounds of group C08G18/3225 or C08G18/3271 or polyamines of C08G18/38
- C08G18/6529—Compounds of group C08G18/3225 or polyamines of C08G18/38
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0033—Foam properties having integral skins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Mechanical Engineering (AREA)
Polyurethanes Or Polyureas (AREA)

JP63027365A 1987-02-07 1988-02-08 成形物品とその製法及びイソシアネート反応組成物 Granted JPS63199722A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19873703739 DE3703739A1 (de)	1987-02-07	1987-02-07	Verfahren zur herstellung von formkoerpern, hierzu geeignete gemische von gegenueber isocyanatgruppen reaktionsfaehigen verbindungen und die nach dem verfahren erhaltenen formkoerper
DE3703739.0		1987-02-07

Publications (2)

Publication Number	Publication Date
JPS63199722A true JPS63199722A (ja)	1988-08-18
JPH0466887B2 JPH0466887B2 (2)	1992-10-26

Family

ID=6320442

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP63027365A Granted JPS63199722A (ja)	1987-02-07	1988-02-08	成形物品とその製法及びイソシアネート反応組成物

Country Status (9)

Country	Link
US (1)	US4777187A (2)
EP (1)	EP0278334B1 (2)
JP (1)	JPS63199722A (2)
KR (1)	KR880009758A (2)
AU (1)	AU594861B2 (2)
BR (1)	BR8800479A (2)
CA (1)	CA1312972C (2)
DE (2)	DE3703739A1 (2)
ZA (1)	ZA88815B (2)

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KR100898303B1 (ko) *	2001-08-24	2009-05-19	로저스 이노악 코포레이션	연마용 패드
KR20150079623A (ko) *	2012-10-24	2015-07-08	꽁빠니 제네날 드 에따블리세망 미쉘린	금속을 고무에 접착시키기 위한 접착 프라이머로서 특히 유용한 폴리우레아

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Publication number	Priority date	Publication date	Assignee	Title
DE3721058A1 (de) *	1987-06-26	1989-01-05	Bayer Ag	Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen
DE3732727A1 (de) *	1987-09-29	1989-04-06	Bayer Ag	Verfahren zur herstellung von kalthaertenden polyurethanharnstoff-elastomeren
DE3732726A1 (de) *	1987-09-29	1989-04-06	Bayer Ag	Verfahren zur herstellung von polyurethanharnstoff-elastomeren
US4870142A (en) *	1988-06-07	1989-09-26	Genesco Inc.	Novel urethane polymer alloys with reactive epoxy functional groups
US4904703A (en) *	1988-12-07	1990-02-27	Sms Associates	High temperature foam
JPH072826B2 (ja) *	1989-12-18	1995-01-18	日本ペイント株式会社	反応射出成形用樹脂組成物
US5348984A (en) *	1993-01-28	1994-09-20	Sealed Air Corporation	Expandable composition and process for extruded thermoplastic foams
DE10012394A1 (de) *	2000-03-15	2001-10-04	Ulrich Stieler	Verschluss für flaschenartige Behältnisse sowie Verfahren zu dessen Herstellung
CA2438773C (en)	2001-02-17	2008-12-30	Hehr International Inc.	Polyurea polymers prepared from polyamine epoxide adduct
DE10334875A1 (de) *	2003-07-29	2005-02-24	Behr Gmbh & Co. Kg	Werkstoff für Formteile
US7901762B2 (en)	2005-11-23	2011-03-08	Milgard Manufacturing Incorporated	Pultruded component
US8101107B2 (en)	2005-11-23	2012-01-24	Milgard Manufacturing Incorporated	Method for producing pultruded components
US8597016B2 (en)	2005-11-23	2013-12-03	Milgard Manufacturing Incorporated	System for producing pultruded components
US7875675B2 (en)	2005-11-23	2011-01-25	Milgard Manufacturing Incorporated	Resin for composite structures

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US4296212A (en) *	1980-08-27	1981-10-20	The Upjohn Company	Elastomeric polyurethane-polyurea polymer prepared from an organic polyisocyanate a polyol and an aromatic diamine having at least one of the ortho positions to each amine lower alkyl
US4324867A (en) *	1980-10-06	1982-04-13	Basf Wyandotte Corporation	Process for the preparation of molded polyurethane-polyurea elastomers and molded parts prepared thereby
US4374210A (en) *	1981-09-18	1983-02-15	The Upjohn Company	Polyurea-polyurethane from a mixture of a polyol, an aromatic diamine, and an isocyanate-terminated prepolymer
DE3147736A1 (de) *	1981-12-02	1983-06-09	Bayer Ag, 5090 Leverkusen	Verfahren zur herstellung von elastischen formkoerpern
US4519965A (en) *	1984-08-23	1985-05-28	Mobay Chemical Corporation	Internal mold release agent for use in reaction injection molding
US4540750A (en) *	1984-09-24	1985-09-10	Ciba-Geigy Corporation	Diethyl toluene diamine hardener systems
AU558999B2 (en) *	1984-10-11	1987-02-19	Air Products And Chemicals Inc.	Polyurethane-urea elastomer
US4569951A (en) *	1985-01-18	1986-02-11	The Dow Chemical Company	Polymers prepared by reaction of a polyisocyanate with a secondary amine terminated adduct of a primary amine compound and a polyepoxide
DE3520326A1 (de) *	1985-06-07	1986-12-11	Bayer Ag, 5090 Leverkusen	Verfahren zur herstellung von elastischen formkoerpern
US4748201A (en) *	1986-03-28	1988-05-31	Urylon Development, Inc.	Sprayable polyurethane composition and method of preparation
EP0257441A3 (en) *	1986-08-27	1988-09-14	The Dow Chemical Company	Flexible polyurethane foams based on difunctional polyols and mdi and method for preparing the same

1987
- 1987-02-07 DE DE19873703739 patent/DE3703739A1/de not_active Withdrawn
1988
- 1988-01-29 EP EP88101277A patent/EP0278334B1/de not_active Expired - Lifetime
- 1988-01-29 US US07/149,771 patent/US4777187A/en not_active Expired - Lifetime
- 1988-01-29 CA CA000557665A patent/CA1312972C/en not_active Expired - Fee Related
- 1988-01-29 DE DE8888101277T patent/DE3877220D1/de not_active Expired - Fee Related
- 1988-02-01 AU AU11134/88A patent/AU594861B2/en not_active Ceased
- 1988-02-05 ZA ZA880815A patent/ZA88815B/xx unknown
- 1988-02-05 BR BR8800479A patent/BR8800479A/pt unknown
- 1988-02-06 KR KR1019880001107A patent/KR880009758A/ko not_active Withdrawn
- 1988-02-08 JP JP63027365A patent/JPS63199722A/ja active Granted

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR100898303B1 (ko) *	2001-08-24	2009-05-19	로저스 이노악 코포레이션	연마용 패드
KR20150079623A (ko) *	2012-10-24	2015-07-08	꽁빠니 제네날 드 에따블리세망 미쉘린	금속을 고무에 접착시키기 위한 접착 프라이머로서 특히 유용한 폴리우레아
JP2016500736A (ja) *	2012-10-24	2016-01-14	コンパニーゼネラールデエタブリッスマンミシュラン	金属をゴムに接着させるための接着プライマーとして特に有用であるポリ尿素
US9845376B2 (en)	2012-10-24	2017-12-19	Compagnie Generale Des Establissements Michelin	Polyurea that is particularly useful as an adhesion primer for adhering metal to rubber

Also Published As

Publication number	Publication date
EP0278334A3 (en)	1989-07-26
JPH0466887B2 (2)	1992-10-26
KR880009758A (ko)	1988-10-05
CA1312972C (en)	1993-01-19
DE3703739A1 (de)	1988-08-18
EP0278334B1 (de)	1993-01-07
EP0278334A2 (de)	1988-08-17
ZA88815B (en)	1988-08-08
BR8800479A (pt)	1988-09-27
AU1113488A (en)	1988-08-11
US4777187A (en)	1988-10-11
DE3877220D1 (de)	1993-02-18
AU594861B2 (en)	1990-03-15

Publication	Publication Date	Title
CA1180146A (en)	1984-12-27	Reaction injection molded polyurethanes employing aliphatic amine chain extenders
US5212209A (en)	1993-05-18	Compatibilized internal mold release composition for preparations of foamed and fiber-reinforced polymeric articles
AU594861B2 (en)	1990-03-15	Process for the production of molded articles, mixtures of isocyanate reactive compounds suitable therefor and the molded articles obtained by the process
JPS58188643A (ja)	1983-11-04	反応射出成形エラストマ−の製造方法
US4495081A (en)	1985-01-22	Compositions containing polyether polyols and aliphatic primary amines
WO1990015835A1 (en)	1990-12-27	Process for preparing elastomeric polyurethane or polyurethane-urea polymers, and polyurethanes so prepared
US5350778A (en)	1994-09-27	Polyisocyanate based upon 4,4'- and 2,4'-diphenylmethane diisocyanates and use thereof in a rim process
US5563232A (en)	1996-10-08	Rim process utilizing isocyanates based upon 2,4'- and 4,4'-diphenylmethane diisocyanate
US4919878A (en)	1990-04-24	Process for the production of polyurethane-and/or polyurea-based moldings
JPH08169928A (ja)	1996-07-02	Ｒｉｍ用の線状ｈｄｉウレタンプレポリマー
JPH0331315A (ja)	1991-02-12	ポリ尿素エラストマー成形品の製法
JPS62275117A (ja)	1987-11-30	高分子量プレポリマ−からポリウレタンエラストマ−を製造する方法及びその方法で使用する半プレポリマ−
EP0650989B1 (en)	1999-01-13	Polyisocyanate based upon 4,4'-and 2,4'-diphenylmethane diisocyanates and use thereof in a RIM process
US4122058A (en)	1978-10-24	Rapid-setting polyurethanes prepared in the presence of a cyclic unsaturated aliphatic hydrocarbon
JPS6340812B2 (2)	1988-08-12
US5064600A (en)	1991-11-12	Process for production of moldings or films from polyisocyanate polyadducts by rim procedure
AU647554B2 (en)	1994-03-24	Compatibilized internal mold release compositions for preparation of foamed and fiber-reinforced polymeric articles
US5420186A (en)	1995-05-30	Internal mold release agents comprising metallic soaps compatibilized with liquid quaternary ammonium salts
EP0639614A1 (en)	1995-02-22	Process for the production of reinforced moldings and the resultant products
CA2111015C (en)	1996-10-15	Ionic siloxane as internal mold release agent for polyurethane, polyurethaneurea and polyurea elastomers
JPH01123816A (ja)	1989-05-16	成形体の製法
CN105377934A (zh)	2016-03-02	由增强的聚氨酯脲弹性体制成的模制件及其用途
JPH02232216A (ja)	1990-09-14	ポリウレタンの製法
US5312845A (en)	1994-05-17	Rim polyol blends containing acidic siloxane internal mold release agents and tin catalysts
US5324759A (en)	1994-06-28	RIM polyol blends containing acidic siloxane internal mold release agents and quaternary ammonium phenoxides