JPS633655B2 - - Google Patents

Info

Publication number: JPS633655B2
Authority: JP; Japan
Prior art keywords: catalyst; smectite; montmorillonite; reaction; silicon
Prior art date: 1981-10-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP56165496A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5867340A (ja

Inventor

Shigemitsu Shin

Yoshimichi Kyozumi

Kunio Suzuki

Kazuo Hashimoto

Hideo Watanabe

Yoshinari Kawamura

Juji Shimazaki

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-10-16

Filing date

1981-10-16

Publication date

1988-01-25

1981-10-16 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1981-10-16 Priority to JP56165496A priority Critical patent/JPS5867340A/ja

1983-04-21 Publication of JPS5867340A publication Critical patent/JPS5867340A/ja

1988-01-25 Publication of JPS633655B2 publication Critical patent/JPS633655B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 claims description 29
229910021647 smectite Inorganic materials 0.000 claims description 15
150000001336 alkenes Chemical class 0.000 claims description 13
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
230000015572 biosynthetic process Effects 0.000 claims description 6
238000003786 synthesis reaction Methods 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
239000002994 raw material Substances 0.000 claims description 5
229910052814 silicon oxide Inorganic materials 0.000 claims description 5
150000001983 dialkylethers Chemical class 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 15
238000006243 chemical reaction Methods 0.000 description 14
229910052901 montmorillonite Inorganic materials 0.000 description 14
150000001875 compounds Chemical class 0.000 description 9
238000010438 heat treatment Methods 0.000 description 8
239000010410 layer Substances 0.000 description 8
238000000034 method Methods 0.000 description 8
229910052710 silicon Inorganic materials 0.000 description 8
239000010703 silicon Substances 0.000 description 8
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
238000009830 intercalation Methods 0.000 description 6
-1 silicon ion Chemical class 0.000 description 6
238000002441 X-ray diffraction Methods 0.000 description 5
230000002687 intercalation Effects 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
238000005342 ion exchange Methods 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
229910004298 SiO 2 Inorganic materials 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
229910020163 SiOCl Inorganic materials 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
239000012159 carrier gas Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000004927 clay Substances 0.000 description 2
239000002734 clay mineral Substances 0.000 description 2
239000011229 interlayer Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
BDLWRIAFNYVGTC-UHFFFAOYSA-N 2-[bis(2-chloroethyl)amino]ethyl 3-(acridin-9-ylamino)propanoate Chemical compound C1=CC=C2C(NCCC(=O)OCCN(CCCl)CCCl)=C(C=CC=C3)C3=NC2=C1 BDLWRIAFNYVGTC-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
102000051619 SUMO-1 Human genes 0.000 description 1
108700038981 SUMO-1 Proteins 0.000 description 1
229910003902 SiCl 4 Inorganic materials 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000005215 alkyl ethers Chemical class 0.000 description 1
150000001449 anionic compounds Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000011161 development Methods 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
229910000271 hectorite Inorganic materials 0.000 description 1
238000001027 hydrothermal synthesis Methods 0.000 description 1
229910001412 inorganic anion Inorganic materials 0.000 description 1
230000001678 irradiating effect Effects 0.000 description 1
229930014626 natural product Natural products 0.000 description 1
229910000273 nontronite Inorganic materials 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000002891 organic anions Chemical class 0.000 description 1
QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000010992 reflux Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910000275 saponite Inorganic materials 0.000 description 1
229910000276 sauconite Inorganic materials 0.000 description 1
230000001568 sexual effect Effects 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000002424 x-ray crystallography Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP56165496A 1981-10-16 1981-10-16 オレフイン合成用多孔性結晶質触媒 Granted JPS5867340A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP56165496A JPS5867340A (ja)	1981-10-16	1981-10-16	オレフイン合成用多孔性結晶質触媒

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP56165496A JPS5867340A (ja)	1981-10-16	1981-10-16	オレフイン合成用多孔性結晶質触媒

Publications (2)

Publication Number	Publication Date
JPS5867340A JPS5867340A (ja)	1983-04-21
JPS633655B2 true JPS633655B2 (fr)	1988-01-25

Family

ID=15813496

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP56165496A Granted JPS5867340A (ja)	1981-10-16	1981-10-16	オレフイン合成用多孔性結晶質触媒

Country Status (1)

Country	Link
JP (1)	JPS5867340A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4753908A (en) *	1985-12-10	1988-06-28	Agency Of Industrial Science	Method for production of microporous separating material from smectite type mineral

1981
- 1981-10-16 JP JP56165496A patent/JPS5867340A/ja active Granted

Also Published As

Publication number	Publication date
JPS5867340A (ja)	1983-04-21

Publication	Publication Date	Title
Yamanaka et al.	1984	High surface area solids obtained by intercalation of iron oxide pillars in montmorillonite
CA1093278A (fr)	1981-01-13	Procede d'obtention de silice polymorphe
JP2554685B2 (ja)	1996-11-13	層間カルコゲン化合物を含有する層状金属カルコゲン化合物およびそれらの合成
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CA2477713C (fr)	2010-09-21	Preparation d'une zeolite aluminosilicate cristalline de type mfi
DE2924870C2 (de)	1984-12-13	Verfahren zur Herstellung von Aluminium-modifizierter Kieselsäure und deren Verwendung
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