JPS63745Y2 - - Google Patents
Info
- Publication number
- JPS63745Y2 JPS63745Y2 JP4115582U JP4115582U JPS63745Y2 JP S63745 Y2 JPS63745 Y2 JP S63745Y2 JP 4115582 U JP4115582 U JP 4115582U JP 4115582 U JP4115582 U JP 4115582U JP S63745 Y2 JPS63745 Y2 JP S63745Y2
- Authority
- JP
- Japan
- Prior art keywords
- ink layer
- fluoride
- transfer material
- glass surface
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000002378 acidificating effect Effects 0.000 claims description 21
- 238000012546 transfer Methods 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 16
- 238000012545 processing Methods 0.000 claims description 12
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229910001610 cryolite Inorganic materials 0.000 claims description 7
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 2
- 235000013024 sodium fluoride Nutrition 0.000 claims description 2
- 239000011775 sodium fluoride Substances 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 9
- 239000012790 adhesive layer Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 210000003298 dental enamel Anatomy 0.000 description 4
- 150000002222 fluorine compounds Chemical group 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
- Surface Treatment Of Glass (AREA)
Description
【考案の詳細な説明】
本考案はガラス表面加工用転写材に関するもの
であり、その目的は安全な作業でガラス、タイ
ル、ホーロー等の表面を腐食加工できる転写材を
提供することにある。[Detailed Description of the Invention] The present invention relates to a transfer material for glass surface processing, and its purpose is to provide a transfer material that can corrode the surfaces of glass, tiles, enamel, etc. in a safe manner.
従来、ガラス、タイル、ホーロー等の表面を腐
食することにより艷消し加工を施す方法としては
ガラス腐食性溶液を用いる所謂湿式の腐食方法に
よつていた。しかしながら湿式の腐食方法におい
てはフツ酸等の毒性の強い溶液を取扱うため作業
が非常に危険であつた。 BACKGROUND ART Conventionally, a so-called wet corrosion method using a glass corrosive solution has been used to apply a dulling process to the surface of glass, tile, enamel, etc. by corroding it. However, the wet corrosion method is extremely dangerous because it involves highly toxic solutions such as hydrofluoric acid.
本考案者はこのような従来法の問題を解消せん
として種々考察、工夫を重ねた結果、本考案を完
成するに至つたものである。 The inventor of the present invention has made various considerations and efforts to solve the problems of the conventional method, and as a result has completed the present invention.
即ち本考案は、剥離性を有する基体シート上
に、フツ化ナトリウム、フツ化カルシウム、クリ
オライト、カリクリオライトおよびアンモニウム
クリオライトよりなる群より選ばれた少なくとも
一つのフツ化物を含有するインキ組成物よりなる
第１インキ層、及び加熱により前記フツ化物と反
応してフツ化水素を生成する酸性硫酸ナトリウ
ム、酸性硫酸カリウム、酸性リン酸ナトリウム、
塩化アンモニウムおよびスルフアミン酸よりなる
群より選ばれた少なくとも一つの弱酸性物質を含
有するインキ組成物よりなる第２インキ層を設
け、その上に必要に応じて接着剤層を設けたこと
を特徴とするガラス表面加工用転写材である。 That is, the present invention provides an ink composition containing at least one fluoride selected from the group consisting of sodium fluoride, calcium fluoride, cryolite, challicryolite, and ammonium cryolite on a base sheet having release properties. a first ink layer consisting of; and acidic sodium sulfate, acidic potassium sulfate, and acidic sodium phosphate that react with the fluoride to generate hydrogen fluoride when heated.
A second ink layer made of an ink composition containing at least one weakly acidic substance selected from the group consisting of ammonium chloride and sulfamic acid is provided, and an adhesive layer is provided thereon as necessary. This is a transfer material for glass surface processing.
以下、図面に基づいて本考案について更に詳し
く説明する。 Hereinafter, the present invention will be explained in more detail based on the drawings.
第１図は本考案にかかる転写材の一実施例を示
す。１は基体シート、２は第１インキ層、３は第
２インキ層、４は接着剤層、５は被転写体であ
る。基体シート１としては例えばポリエチレンテ
レフタレートフイルムにポリプロピレンフイルム
をラミネートしたフイルムのように剥離性を有す
るものを用いる。剥離性を有するものとしてはそ
の他に、熱可塑性アクリル樹脂等を塗布したもの
を用いてもよい。 FIG. 1 shows an embodiment of a transfer material according to the present invention. 1 is a base sheet, 2 is a first ink layer, 3 is a second ink layer, 4 is an adhesive layer, and 5 is a transfer target. As the base sheet 1, a material having releasability, such as a polyethylene terephthalate film laminated with a polypropylene film, is used. In addition to the releasable material, a material coated with thermoplastic acrylic resin or the like may also be used.
基体シート１の上に第１インキ層２及び第２イ
ンキ層３を設ける。第１インキ層２はフツ化物を
含有し、溶剤、樹脂バインダーを適宜混合してな
るインキ組成物を用いて、塗布又は印刷手段にて
設けられる。溶剤としては例えばトルエン、キシ
レン等を、樹脂バインダーとしては例えばアクリ
ル樹脂等を適用できる。フツ化物としては、フツ
化ナトリウム（NaF）、フツ化カルシウム
（CaF2）、クリオライト（Na3AlF6）、カリクリオ
ライト（K3AlF6）およびアンモニウムクリオラ
イト〔（NH4）3AlF6〕より選ばれた少なくとも一
つのフツ化物を用いる。第１インキ層が網点状に
印刷形成されたものであれば、より均一な凹凸状
態の艷消し加工を施す転写材が得られる。 A first ink layer 2 and a second ink layer 3 are provided on the base sheet 1. The first ink layer 2 is provided by coating or printing using an ink composition containing a fluoride and appropriately mixed with a solvent and a resin binder. For example, toluene, xylene, etc. can be used as the solvent, and acrylic resin, etc. can be used as the resin binder. Fluorides include sodium fluoride (NaF), calcium fluoride (CaF 2 ), cryolite (Na 3 AlF 6 ), calycriolite (K 3 AlF 6 ), and ammonium cryolite [(NH 4 ) 3 AlF 6 ] At least one fluoride selected from the above is used. If the first ink layer is printed in the form of halftone dots, it is possible to obtain a transfer material that can be subjected to the erasing process with more uniform unevenness.
第２インキ層３は弱酸性物質を含有するインキ
組成物を用いて設けられる。弱酸性物質として
は、前記フツ化物と反応してフツ化水素を生成す
る酸性硫酸ナトリウム（NaHSO4）、酸性硫酸カ
リウム（KHSO4）、酸性リン酸ナトリウム
（NaH2PO4またはNa2HPO4）、塩化アンモニウ
ム（NH4Cl）およびスルフアミン酸
（NH4SO3H）よりなる群より選ばれた少なくと
も一つの弱酸性物質であり、第１インキ層２に含
有されるフツ化物に応じて最も適したものを選択
して構成されるのが好ましい。その例としては、
クリオライト（Na3AlF6）及びフツ化カルシウ
ム（CaF2）に対しては酸性硫酸ナトリウム
（NaHSO4）が、フツ化ナトリウム（NaF）に対
しては塩化アンモニウム（NH4Cl）がそれぞれ
好ましい。又、第１インキ層２及び第２インキ層
３は何れが上又は下に置して形成されていてもよ
い。更に第１インキ層２及び／又は第２インキ層
３を構成するインキ組成物の樹脂バインダーとし
て接着性を有するものを用いた場合は、該二層は
接着性を有するものとなる。この場合はその上に
接着剤層４は不要である（第２図参照）。 The second ink layer 3 is provided using an ink composition containing a weakly acidic substance. Examples of weakly acidic substances include acidic sodium sulfate (NaHSO 4 ), acidic potassium sulfate (KHSO 4 ), and acidic sodium phosphate (NaH 2 PO 4 or Na 2 HPO 4 ), which react with the fluoride to generate hydrogen fluoride. , at least one weakly acidic substance selected from the group consisting of ammonium chloride (NH 4 Cl) and sulfamic acid (NH 4 SO 3 H), which is most suitable depending on the fluoride contained in the first ink layer 2. It is preferable that the configuration is selected from the following. For example,
Acidic sodium sulfate (NaHSO 4 ) is preferred for cryolite (Na 3 AlF 6 ) and calcium fluoride (CaF 2 ), and ammonium chloride (NH 4 Cl) is preferred for sodium fluoride (NaF). Furthermore, either the first ink layer 2 or the second ink layer 3 may be formed on top or on the bottom. Furthermore, when a resin binder having adhesive properties is used in the ink composition constituting the first ink layer 2 and/or the second ink layer 3, the two layers have adhesive properties. In this case there is no need for an adhesive layer 4 thereon (see FIG. 2).
第１インキ層２及び第２インキ層３の上に必要
に応じて接着剤層４を設ける。接着剤層４は例え
ばアクリル樹脂、ビニル樹脂等を用いて構成され
る。 An adhesive layer 4 is provided on the first ink layer 2 and the second ink layer 3, if necessary. The adhesive layer 4 is made of, for example, acrylic resin, vinyl resin, or the like.
本考案は以上のような構成のガラス表面加工用
転写材であり、次にその使用方法について説明す
る（第３図参照）。本考案にかかる転写材はその
対象物はガラスのみでなくタイル、ホーロー製品
にも及ぶものである。まず被転写材５表面に転写
材をその接着剤層４が接するように載置した後、
基体シート１を剥離し、第１インキ層２及び第２
インキ層３を転写する。次に被転写体５を加熱処
理する。加熱は前記フツ化物及び前記弱酸性物質
が反応してフツ化水素ガスを生成するような温度
で行う。前記のようなフツ化物及び弱酸性物質で
あれば約300℃〜800℃において加熱すればよい。
この加熱によつてフツ化水素ガスが発生し、第１
インキ層２及び第２インキ層３を設けた部分の被
転写体５表面は腐食され、艷消し加工が施され
る。加熱後、残存物を適宜の手段にて洗浄除去す
る。 The present invention is a transfer material for glass surface processing having the above-mentioned structure, and the method of using the same will be explained next (see FIG. 3). The transfer material according to the present invention is applicable not only to glass but also to tiles and enamel products. First, a transfer material is placed on the surface of the transfer material 5 so that its adhesive layer 4 is in contact with the surface, and then
The base sheet 1 is peeled off, and the first ink layer 2 and the second ink layer are removed.
Transfer the ink layer 3. Next, the transfer target 5 is subjected to a heat treatment. Heating is performed at a temperature such that the fluoride and the weakly acidic substance react to generate hydrogen fluoride gas. Fluorides and weakly acidic substances such as those mentioned above may be heated at about 300°C to 800°C.
Hydrogen fluoride gas is generated by this heating, and the first
The surface of the transferred object 5 in the portion where the ink layer 2 and the second ink layer 3 are provided is corroded and subjected to a fade-out process. After heating, the residue is washed and removed by an appropriate means.
上記のフツ化物は単独ではガラス表面を速やか
に加工できるものではないが、前記の弱酸性物質
と組み合わされるときには300〜800℃、特に好ま
しくは350〜600℃において、第１インキ層と第２
インキ層の分解・溶融反応が惹起しガラス表面を
腐食するフツ化水素ガスが発生する。この場合、
各層の厚みは５〜100μｍの程度で普通行われる
が、加工精度を向上させ、図柄を鮮明にするため
には各層の厚みを10〜50μｍの範囲にすることが
好ましい。これらの各層に含まれるフツ化物と弱
酸性物質の含有量は、フツ化物中のフツ素のモル
数を基準にするならば、弱酸性物質の使用モル数
は0.5〜3.0モル、特に好ましくは0.9〜1.5モルの
範囲にすることが実際上有利である。これらのフ
ツ化物または弱酸性物質を含む各層は、０〜100
℃では互いに接触していても反応を起こすことが
なく、反応の開始は300℃以上で急速にかつ顕著
に認められる。もし、加熱温度が100〜300℃であ
るならば、反応は非常に緩慢に進行し、目的とす
る反応の達成に数分〜数十分間を有する。しかも
図柄の周辺が拡散したようになつて美しい表面加
工を行うことが容易ではない。このようなことか
ら、本考案における加工操作は所定の温度におい
て数秒〜数分間という短時間内に終了することが
有利である。 The above-mentioned fluoride alone cannot quickly process the glass surface, but when combined with the above-mentioned weak acidic substance, the first ink layer and the second
The decomposition and melting reaction of the ink layer causes hydrogen fluoride gas to be generated which corrodes the glass surface. in this case,
The thickness of each layer is usually in the range of 5 to 100 .mu.m, but in order to improve processing accuracy and make the pattern clear, it is preferable that the thickness of each layer be in the range of 10 to 50 .mu.m. The content of the fluoride and the weakly acidic substance contained in each of these layers is based on the number of moles of fluorine in the fluoride, and the number of moles of the weakly acidic substance used is 0.5 to 3.0 moles, particularly preferably 0.9. A range of 1.5 mol is of practical advantage. Each layer containing these fluorides or weakly acidic substances has a range of 0 to 100
At 300°C, no reaction occurs even when they are in contact with each other, and the initiation of the reaction is rapid and noticeable at temperatures above 300°C. If the heating temperature is 100 to 300°C, the reaction proceeds very slowly, and it takes several minutes to several tens of minutes to achieve the desired reaction. Moreover, the periphery of the design becomes diffused, making it difficult to achieve a beautiful surface finish. For this reason, it is advantageous for the processing operation in the present invention to be completed within a short time of several seconds to several minutes at a predetermined temperature.
本考案は以上のようなガラス表面加工用転写材
であるから、これを適用することによつて安全な
作業によつてガラス表面加工を施すことができ
る。又、第１インキ層及び第２インキ層を構成す
る各各のインキ組成物は無害であるから、転写材
の製造時においても安全な作業で行うことができ
る。更に任意の形状のマツト部分を形成するに際
してもマスキング等の複雑な手間を要することな
く行うことが容易であり、繊細な絵柄、文字を形
成するのも容易である。従つて種々のガラス、タ
イル、ホーロー製品等の表面の加工技術において
広く利用されることが期待される。 Since the present invention is a transfer material for glass surface processing as described above, by applying this, glass surface processing can be performed in a safe manner. Further, since each ink composition constituting the first ink layer and the second ink layer is harmless, the production of the transfer material can be carried out safely. Further, it is easy to form matte portions of arbitrary shapes without requiring complicated labor such as masking, and it is also easy to form delicate patterns and letters. Therefore, it is expected that it will be widely used in surface processing techniques for various glasses, tiles, enamel products, etc.
第１図及び第２図は本考案に係るガラス表面加
工用転写材の各々実施例の部分拡大断面図を、第
３図は第１図に示す転写材を用いた転写工程の部
分拡大断面図を各々示す。
図中、１……基体シート、２……第１インキ
層、３……第２インキ層、４……接着剤層、５…
…被転写体。
1 and 2 are partially enlarged sectional views of respective examples of the transfer material for glass surface processing according to the present invention, and FIG. 3 is a partially enlarged sectional view of the transfer process using the transfer material shown in FIG. 1. are shown respectively. In the figure, 1... Base sheet, 2... First ink layer, 3... Second ink layer, 4... Adhesive layer, 5...
...Transferred object.
Claims (1)
リウム、フツ化カルシウム、クリオライト、カ
リクリオライトおよびアンモニウムクリオライ
トよりなる群より選ばれた少なくとも一つのフ
ツ化物を含有するインキ組成物よりなる第１イ
ンキ層、及び加熱により前記フツ化物と反応し
てフツ化水素を生成する酸性硫酸ナトリウム、
酸性硫酸カリウム、酸性リン酸ナトリウム、塩
化アンモニウムおよびスルフアミン酸よりなる
群より選ばれた少なくとも一つの弱酸性物質を
含有するインキ組成物よりなる第２インキ層を
設け、その上に必要に応じて接着剤層を設けた
ことを特徴とするガラス表面加工用転写材。 (2) 第１インキ層が網点状に印刷形成されたこと
を特徴とする実用新案登録請求の範囲第１項に
記載のガラス表面加工用転写材。 (3) 第１インキ層及び／又は第２インキ層が接着
性を有するものであることを特徴とする実用新
案登録請求の範囲第１項に記載のガラス表面加
工用転写材。[Claims for Utility Model Registration] (1) At least one fluoride selected from the group consisting of sodium fluoride, calcium fluoride, cryolite, challicryolite, and ammonium cryolite on a releasable base sheet. a first ink layer consisting of an ink composition containing; and acidic sodium sulfate that reacts with the fluoride to generate hydrogen fluoride when heated;
A second ink layer made of an ink composition containing at least one weakly acidic substance selected from the group consisting of acidic potassium sulfate, acidic sodium phosphate, ammonium chloride, and sulfamic acid is provided, and if necessary, adhesive is applied thereon. A transfer material for glass surface processing characterized by being provided with an agent layer. (2) The transfer material for glass surface processing according to claim 1, wherein the first ink layer is printed in the form of halftone dots. (3) The transfer material for glass surface processing according to claim 1, wherein the first ink layer and/or the second ink layer have adhesive properties.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4115582U JPS58143840U (en) | 1982-03-23 | 1982-03-23 | Transfer material for glass surface processing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4115582U JPS58143840U (en) | 1982-03-23 | 1982-03-23 | Transfer material for glass surface processing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58143840U JPS58143840U (en) | 1983-09-28 |
| JPS63745Y2 true JPS63745Y2 (en) | 1988-01-09 |
Family
ID=30052344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4115582U Granted JPS58143840U (en) | 1982-03-23 | 1982-03-23 | Transfer material for glass surface processing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58143840U (en) |
-
1982
- 1982-03-23 JP JP4115582U patent/JPS58143840U/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58143840U (en) | 1983-09-28 |
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