JPS6420218A - Curable graft polymer and its production - Google Patents
Curable graft polymer and its productionInfo
- Publication number
- JPS6420218A JPS6420218A JP17491387A JP17491387A JPS6420218A JP S6420218 A JPS6420218 A JP S6420218A JP 17491387 A JP17491387 A JP 17491387A JP 17491387 A JP17491387 A JP 17491387A JP S6420218 A JPS6420218 A JP S6420218A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- group
- component
- unsaturated polyester
- polybasic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000578 graft copolymer Polymers 0.000 title 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
PURPOSE:To obtain inexpensively the title polymer excellent in hardness, strength and toughness, by reacting a specified polymer with an OH group- containing unsaturated polyester. CONSTITUTION:2-30mol.% unsaturated polybasic acid anhydride (a) (e.g., maleic anhydride) is copolymerized with a vinyl monomer (b) (e.g., styrene) in the presence of a polymerization modifier (e.g., mercaptan) to obtain a polymer (A) having an acid anhydride group as a side chain. Component A is reacted with an OH group-containing unsaturated polyester (B) obtained by sterifying a polybasic acid mixture containing an alpha,beta-unsaturated polybasic acid as a component and other polybasic acids as modifying components with a polyhydric alcohol at a eight ratio (A:B) of 20-80:80-20 in component (b) in the presence of an acid, an amine and a polymerization inhibitor in the presence of air to obtain the title polymer in which an unsaturated polyester is grafted onto a polymer main chain comprising C-C bonds through an ester bond and a COOH group is present in the vicinal position.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17491387A JPH0657750B2 (en) | 1987-07-15 | 1987-07-15 | Process for producing curable graft polymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17491387A JPH0657750B2 (en) | 1987-07-15 | 1987-07-15 | Process for producing curable graft polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6420218A true JPS6420218A (en) | 1989-01-24 |
| JPH0657750B2 JPH0657750B2 (en) | 1994-08-03 |
Family
ID=15986891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17491387A Expired - Lifetime JPH0657750B2 (en) | 1987-07-15 | 1987-07-15 | Process for producing curable graft polymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0657750B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012102302A1 (en) | 2012-03-19 | 2013-09-19 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Extruding device for manufacturing double walled hollow section, has separator that is provided in region of stamper tools and die arrangement such that material of exterior wall is disconnected from material of inside wall |
| WO2018080250A1 (en) * | 2016-10-31 | 2018-05-03 | 롯데첨단소재(주) | Thermoplastic resin composition, method for producing same, and molded product formed therefrom |
| WO2024247573A1 (en) * | 2023-05-26 | 2024-12-05 | 日清紡ホールディングス株式会社 | Marine biodegradable polymer compound having aliphatic unsaturated carbon-carbon bond and method for producing same |
-
1987
- 1987-07-15 JP JP17491387A patent/JPH0657750B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012102302A1 (en) | 2012-03-19 | 2013-09-19 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Extruding device for manufacturing double walled hollow section, has separator that is provided in region of stamper tools and die arrangement such that material of exterior wall is disconnected from material of inside wall |
| WO2018080250A1 (en) * | 2016-10-31 | 2018-05-03 | 롯데첨단소재(주) | Thermoplastic resin composition, method for producing same, and molded product formed therefrom |
| KR20180047496A (en) * | 2016-10-31 | 2018-05-10 | 롯데첨단소재(주) | Thermoplastic resin composition, method for preparing the same and article produced therefrom |
| US10995208B2 (en) | 2016-10-31 | 2021-05-04 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition, method for producing same, and molded product formed therefrom |
| WO2024247573A1 (en) * | 2023-05-26 | 2024-12-05 | 日清紡ホールディングス株式会社 | Marine biodegradable polymer compound having aliphatic unsaturated carbon-carbon bond and method for producing same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0657750B2 (en) | 1994-08-03 |
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