JPS6465111A - Actinic ray-curable composition for cast polymerization - Google Patents
Actinic ray-curable composition for cast polymerizationInfo
- Publication number
- JPS6465111A JPS6465111A JP62313267A JP31326787A JPS6465111A JP S6465111 A JPS6465111 A JP S6465111A JP 62313267 A JP62313267 A JP 62313267A JP 31326787 A JP31326787 A JP 31326787A JP S6465111 A JPS6465111 A JP S6465111A
- Authority
- JP
- Japan
- Prior art keywords
- meth
- photopolymn
- oligomer
- acrylate
- curable composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 abstract 1
- ILBBNQMSDGAAPF-UHFFFAOYSA-N 1-(6-hydroxy-6-methylcyclohexa-2,4-dien-1-yl)propan-1-one Chemical compound CCC(=O)C1C=CC=CC1(C)O ILBBNQMSDGAAPF-UHFFFAOYSA-N 0.000 abstract 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- ZNAAXKXXDQLJIX-UHFFFAOYSA-N bis(2-cyclohexyl-3-hydroxyphenyl)methanone Chemical compound C1CCCCC1C=1C(O)=CC=CC=1C(=O)C1=CC=CC(O)=C1C1CCCCC1 ZNAAXKXXDQLJIX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE:To obtain the title compsn. which is improved in deep cure property, optical strain, mechanical residual strain and yellowing, by blending an oligomer having a terminal (meth)acryloyl group, a reactive dilute monomer and a specified photopolymn. initiator. CONSTITUTION:A hydroxylated (meth)acrylate [e.g., 2-hydroxyethyl (meth) acrylate] and an isocyanate compd. having at least two isocyanate groups in the molecule (e.g., tetramethylene diisocyanate) are reacted in the presence of a catalyst at 50-90 deg.C to give an oligomer having a terminal (meth)acryloyl group A. 100pts.wt. mixture consisting of 30-99wt.% A and 1-70wt.% reactive dilute monomer B having a b.p. of at least 100 deg.C (e.g., methyl methacrylate) is blended with 0.005-0.2pt.wt. of at least one member of photopolymn. initiators selected from among 2-hydroxy-2-methyl-phenylpropan-1-one, hydroxycyclohexyl phenyl ketone and 2,4,6-trimethylbenzoyldiphenylphosphine oxide.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62313267A JP2615180B2 (en) | 1987-05-01 | 1987-12-11 | Actinic ray curable composition for cast polymerization |
| US07/273,338 US4985472A (en) | 1987-05-01 | 1988-04-28 | Actinic ray curable composition for casting polymerization and casting polymerization molded products |
| AU16897/88A AU597830B2 (en) | 1987-05-01 | 1988-04-28 | Actinic radiation-curable composition for cast polymerization and product of cast polymerization |
| EP88903947A EP0313665B1 (en) | 1987-05-01 | 1988-04-28 | Actinic radiation-curable composition for cast polymerization and product of cast polymerization |
| DE8888903947T DE3878139T2 (en) | 1987-05-01 | 1988-04-28 | COMPOSITE COMPOSITION FOR CASTING POLYMERIZATION AND CASTING POLYMERIZATION PRODUCTS. |
| PCT/JP1988/000432 WO1988008434A1 (en) | 1987-05-01 | 1988-04-28 | Actinic radiation-curable composition for cast polymerization and product of cast polymerization |
| KR1019880701419A KR930003464B1 (en) | 1987-05-01 | 1988-04-28 | Active Light Curable Composition for Mold Polymerization and Mold Polymerization Molded Product |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10866287 | 1987-05-01 | ||
| JP62-108662 | 1987-05-01 | ||
| JP62313267A JP2615180B2 (en) | 1987-05-01 | 1987-12-11 | Actinic ray curable composition for cast polymerization |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13672396A Division JP2855424B2 (en) | 1996-05-30 | 1996-05-30 | Actinic ray curable composition for optical article, and optical article |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6465111A true JPS6465111A (en) | 1989-03-10 |
| JP2615180B2 JP2615180B2 (en) | 1997-05-28 |
Family
ID=26448493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62313267A Expired - Lifetime JP2615180B2 (en) | 1987-05-01 | 1987-12-11 | Actinic ray curable composition for cast polymerization |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2615180B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007070395A (en) * | 2005-09-05 | 2007-03-22 | Denki Kagaku Kogyo Kk | Antistatic hard coat resin composition and use thereof |
| JP2011503543A (en) * | 2007-11-01 | 2011-01-27 | ザ・リージエンツ・オブ・ザ・ユニバーシテイー・オブ・カリフオルニア | Collection tube apparatus, system, and method |
| JP2012529979A (en) * | 2009-06-12 | 2012-11-29 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Multi-layer coating method |
| JP2015111125A (en) * | 2008-12-09 | 2015-06-18 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | Polymers for use in centrifugal separation of liquids |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5513794A (en) * | 1978-07-14 | 1980-01-30 | Basf Ag | Photocurable molding material*impregnating and coating materials*molding products and coated layer therfrom |
| JPS5515471A (en) * | 1978-07-14 | 1980-02-02 | Basf Ag | Acylphosphine oxide compound*its manufacture and its use |
| JPS59161422A (en) * | 1982-09-20 | 1984-09-12 | チオコ−ル・コ−ポレ−シヨン | Radiation curable coating for photographic laminate |
| JPS6114212A (en) * | 1984-06-30 | 1986-01-22 | Yokohama Rubber Co Ltd:The | Ultraviolet-curable resin composition |
| JPS6114210A (en) * | 1984-06-30 | 1986-01-22 | Yokohama Rubber Co Ltd:The | Ultraviolet-curable resin composition |
| JPS62104817A (en) * | 1985-10-31 | 1987-05-15 | Nitto Electric Ind Co Ltd | Ultraviolet-sensitive resin composition |
| JPS63199302A (en) * | 1987-02-16 | 1988-08-17 | Pioneer Electronic Corp | Fresnel lens |
-
1987
- 1987-12-11 JP JP62313267A patent/JP2615180B2/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5513794A (en) * | 1978-07-14 | 1980-01-30 | Basf Ag | Photocurable molding material*impregnating and coating materials*molding products and coated layer therfrom |
| JPS5515471A (en) * | 1978-07-14 | 1980-02-02 | Basf Ag | Acylphosphine oxide compound*its manufacture and its use |
| JPS59161422A (en) * | 1982-09-20 | 1984-09-12 | チオコ−ル・コ−ポレ−シヨン | Radiation curable coating for photographic laminate |
| JPS6114212A (en) * | 1984-06-30 | 1986-01-22 | Yokohama Rubber Co Ltd:The | Ultraviolet-curable resin composition |
| JPS6114210A (en) * | 1984-06-30 | 1986-01-22 | Yokohama Rubber Co Ltd:The | Ultraviolet-curable resin composition |
| JPS62104817A (en) * | 1985-10-31 | 1987-05-15 | Nitto Electric Ind Co Ltd | Ultraviolet-sensitive resin composition |
| JPS63199302A (en) * | 1987-02-16 | 1988-08-17 | Pioneer Electronic Corp | Fresnel lens |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007070395A (en) * | 2005-09-05 | 2007-03-22 | Denki Kagaku Kogyo Kk | Antistatic hard coat resin composition and use thereof |
| JP2011503543A (en) * | 2007-11-01 | 2011-01-27 | ザ・リージエンツ・オブ・ザ・ユニバーシテイー・オブ・カリフオルニア | Collection tube apparatus, system, and method |
| JP2015111125A (en) * | 2008-12-09 | 2015-06-18 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | Polymers for use in centrifugal separation of liquids |
| JP2012529979A (en) * | 2009-06-12 | 2012-11-29 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Multi-layer coating method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2615180B2 (en) | 1997-05-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080311 Year of fee payment: 11 |