JPS6467261A - Liquid cation-exchange material, weakly acidic cation-exchange resin and method for manufacturing them - Google Patents
Liquid cation-exchange material, weakly acidic cation-exchange resin and method for manufacturing themInfo
- Publication number
- JPS6467261A JPS6467261A JP63089170A JP8917088A JPS6467261A JP S6467261 A JPS6467261 A JP S6467261A JP 63089170 A JP63089170 A JP 63089170A JP 8917088 A JP8917088 A JP 8917088A JP S6467261 A JPS6467261 A JP S6467261A
- Authority
- JP
- Japan
- Prior art keywords
- beads
- cation exchange
- functional group
- emulsion
- cation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005341 cation exchange Methods 0.000 title abstract 5
- 230000002378 acidificating effect Effects 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 title abstract 2
- 239000000463 material Substances 0.000 title abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title 1
- 239000003729 cation exchange resin Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000011324 bead Substances 0.000 abstract 6
- 229920001577 copolymer Polymers 0.000 abstract 5
- 125000000524 functional group Chemical group 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- 239000000839 emulsion Substances 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 238000007306 functionalization reaction Methods 0.000 abstract 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To facilitate direct functionalization by preparing a liquid cation exchange material with an emulsion of beads of a crosslinked copolymer having a spherical shape of 0.1 to 1.5 μ in diameter and having a cation exchange functional group of a specific group. CONSTITUTION: The crosslinked acrylate copolymer beads are formed by emulsion polymn. of the majority ratio of an acrylate monomer and a small ratio of an ethylenically unsatd. monomer. The ester bond of the beads is hydrolyzed by a strong acid to form the carboxylic acid cation exchange functional group of a free acid type and similarly to form the coagulum of the functionalized copolymer beads and thereafter, the coagulum is resuspended, by which the emulsion of the copolymer beads is prepd. The functionalized copolymer beads have the spherical shape having a diameter of 0.01 to 1.5 μm and have the cation exchange functional group in the free acid form of the weakly acidic functional group of 0.7 to 1.5 per monomer unit.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/943,889 US4380590A (en) | 1978-09-19 | 1978-09-19 | Emulsion copolymer cation exchange resins |
| US05/944,052 US4359537A (en) | 1978-09-19 | 1978-09-19 | Emulsion copolymer anion exchange resins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6467261A true JPS6467261A (en) | 1989-03-13 |
| JPH0131936B2 JPH0131936B2 (en) | 1989-06-28 |
Family
ID=27130187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63089170A Granted JPS6467261A (en) | 1978-09-19 | 1988-04-13 | Liquid cation-exchange material, weakly acidic cation-exchange resin and method for manufacturing them |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6467261A (en) |
-
1988
- 1988-04-13 JP JP63089170A patent/JPS6467261A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0131936B2 (en) | 1989-06-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR830000921A (en) | Manufacturing method of ultra-microscopic cation exchange resin particles | |
| JPS5265597A (en) | Preparation of high polimeric materials with improved water absorption | |
| ES8703897A1 (en) | Process for producing a water-absorbent resin. | |
| ES375295A1 (en) | Process for the production of microcapsules | |
| GB1102746A (en) | Process for the production of copolymers of vinyl esters and ethylene | |
| KR900004814A (en) | Ion Exchange Resin with Short Diffusion Path | |
| JPS6467261A (en) | Liquid cation-exchange material, weakly acidic cation-exchange resin and method for manufacturing them | |
| JPS5592135A (en) | Production of microcapsule | |
| FR2318665B1 (en) | ||
| KR850000476A (en) | Bead phase polymer and its preparation method | |
| JPS55137105A (en) | Suspension stabilizer | |
| GB778104A (en) | Process for the production of cation exchange resins of the carboxylic type | |
| JPS5655403A (en) | Suspension stabilizer for vinyl compound | |
| JPS5529579A (en) | Polymerization of vinyl chloride | |
| JPS5227455A (en) | Process for preparing a high polymer material having water absorption properties | |
| GB752265A (en) | Manufacture of polyvinyl chloride resin | |
| US2860109A (en) | Cross-linked acrylic anhydride terpolymer cation exchanger | |
| JPS6443343A (en) | Microcapsules and their production | |
| JPS56102934A (en) | Manufacture of micro capsule | |
| JPS5643305A (en) | Production of maleinized polyvinyl alcohol | |
| JPS5541804A (en) | Amphoteric ion exchanger and preparation thereof | |
| SU134833A1 (en) | The method of obtaining cation exchange resin | |
| ATE38786T1 (en) | DEVICE FOR THE PRODUCTION OF SPHERICAL PARTICLES. | |
| JPS5386792A (en) | Production of modified polyolefin resin | |
| GB781400A (en) | Improvements in or relating to ion-exchange resins |