JPS6479213A - Polymerizable composition and polymerized molded item - Google Patents
Polymerizable composition and polymerized molded itemInfo
- Publication number
- JPS6479213A JPS6479213A JP3154188A JP3154188A JPS6479213A JP S6479213 A JPS6479213 A JP S6479213A JP 3154188 A JP3154188 A JP 3154188A JP 3154188 A JP3154188 A JP 3154188A JP S6479213 A JPS6479213 A JP S6479213A
- Authority
- JP
- Japan
- Prior art keywords
- compd
- polymerizable
- thiophosphite
- group
- phosphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE:To prevent the reaction from being inhibited by the action of dissolved oxygen and to make it possible both to speed up of the polymn. reaction and to prevent the occurrence of gelation, by adding a phosphite compd. or a thiophosphite compd. CONSTITUTION:This polymerizable compsn. is preped. by adding a phosphite compd. or a thiophosphite compd. in an unsatd. radical-polymerizable compsn. A copolymerized molded item is obd. by irradiating this polymerizable compsn. with a radiation such as light, electron beam and the like. The above described polymerizable compsn. is preped. by using radical-polymerizable prepolymer, oligomer and monomer as the main component, adding a polymerization initiator in case of photopolymn. or if necessary, compounding a sensitizer, an antioxidant, a pigment, a filler, etc. The phosphite compd. or the thiophosphite compd. and compd. having at least one structure of formula I (wherein P is a trivalent phosphorus; Y is S or O; R is alkyl group, phenyl group, acrylate group, aryl group, hydroxyl group. etc.).
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63031541A JP2536894B2 (en) | 1987-06-18 | 1988-02-12 | Radiation Radical Polymerizable Composition and Polymerized Molded Product |
| DE1989615561 DE68915561T2 (en) | 1988-02-12 | 1989-02-08 | Polymerizable composition and polymer made from it. |
| EP19890102135 EP0328058B1 (en) | 1988-02-12 | 1989-02-08 | Polymerizable composition and polymer obtaining from the same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-153009 | 1987-06-18 | ||
| JP15300987 | 1987-06-18 | ||
| JP63031541A JP2536894B2 (en) | 1987-06-18 | 1988-02-12 | Radiation Radical Polymerizable Composition and Polymerized Molded Product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6479213A true JPS6479213A (en) | 1989-03-24 |
| JP2536894B2 JP2536894B2 (en) | 1996-09-25 |
Family
ID=26370028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63031541A Expired - Lifetime JP2536894B2 (en) | 1987-06-18 | 1988-02-12 | Radiation Radical Polymerizable Composition and Polymerized Molded Product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2536894B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016117871A (en) * | 2014-12-22 | 2016-06-30 | 荒川化学工業株式会社 | Modified phenolic resin having polymerizable double bond and hydroxyl group in molecule, actinic ray-curable resin composition, cured product, actinic ray-curable printing ink, and printed matter |
| JP2017036383A (en) * | 2015-08-10 | 2017-02-16 | 東洋インキScホールディングス株式会社 | Active energy ray-polymerizable resin composition for optical three-dimensional modeling, and three-dimensional modeling |
| JP2017197652A (en) * | 2016-04-27 | 2017-11-02 | 株式会社菱晃 | Curable resin composition, cured product thereof, and coating material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4910988A (en) * | 1972-05-30 | 1974-01-30 | ||
| JPS5091688A (en) * | 1973-12-17 | 1975-07-22 | ||
| JPS52140590A (en) * | 1976-05-18 | 1977-11-24 | Toyobo Co Ltd | Urethane-modified acrylate resin compositions |
| JPS52151380A (en) * | 1976-06-11 | 1977-12-15 | Japan Synthetic Rubber Co Ltd | Preparation of conjugated diolefin polymers |
| JPS5474892A (en) * | 1977-11-05 | 1979-06-15 | Degussa | Method of making glycydillgrouppcontaining acryl resin suitable for making powder lacquer binder by mixing with aliphatic carboxylic acid and same binder containing same resin |
-
1988
- 1988-02-12 JP JP63031541A patent/JP2536894B2/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4910988A (en) * | 1972-05-30 | 1974-01-30 | ||
| JPS5091688A (en) * | 1973-12-17 | 1975-07-22 | ||
| JPS52140590A (en) * | 1976-05-18 | 1977-11-24 | Toyobo Co Ltd | Urethane-modified acrylate resin compositions |
| JPS52151380A (en) * | 1976-06-11 | 1977-12-15 | Japan Synthetic Rubber Co Ltd | Preparation of conjugated diolefin polymers |
| JPS5474892A (en) * | 1977-11-05 | 1979-06-15 | Degussa | Method of making glycydillgrouppcontaining acryl resin suitable for making powder lacquer binder by mixing with aliphatic carboxylic acid and same binder containing same resin |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016117871A (en) * | 2014-12-22 | 2016-06-30 | 荒川化学工業株式会社 | Modified phenolic resin having polymerizable double bond and hydroxyl group in molecule, actinic ray-curable resin composition, cured product, actinic ray-curable printing ink, and printed matter |
| JP2017036383A (en) * | 2015-08-10 | 2017-02-16 | 東洋インキScホールディングス株式会社 | Active energy ray-polymerizable resin composition for optical three-dimensional modeling, and three-dimensional modeling |
| JP2017197652A (en) * | 2016-04-27 | 2017-11-02 | 株式会社菱晃 | Curable resin composition, cured product thereof, and coating material |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2536894B2 (en) | 1996-09-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 12 Free format text: PAYMENT UNTIL: 20080708 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 12 Free format text: PAYMENT UNTIL: 20080708 |