JPS64999B2 - - Google Patents

Info

Publication number: JPS64999B2
Authority: JP; Japan
Prior art keywords: phosphor; copper; gold; weight; cerium
Prior art date: 1981-08-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP12467881A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5827777A (ja

Inventor

Kyoshi Inoe

Mitsuhiro Oikawa

Tomoharu Tomura

Takamitsu Kawamata

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Toshiba Corp

Original Assignee

Tokyo Shibaura Electric Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-08-11

Filing date

1981-08-11

Publication date

1989-01-10

1981-08-11 Application filed by Tokyo Shibaura Electric Co Ltd filed Critical Tokyo Shibaura Electric Co Ltd

1981-08-11 Priority to JP12467881A priority Critical patent/JPS5827777A/ja

1983-02-18 Publication of JPS5827777A publication Critical patent/JPS5827777A/ja

1989-01-10 Publication of JPS64999B2 publication Critical patent/JPS64999B2/ja

Status Granted legal-status Critical Current

Links

OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 38
229910052684 Cerium Inorganic materials 0.000 claims description 13
229910052802 copper Inorganic materials 0.000 claims description 13
239000010949 copper Substances 0.000 claims description 13
229910052737 gold Inorganic materials 0.000 claims description 13
239000010931 gold Substances 0.000 claims description 13
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 12
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
229910052691 Erbium Inorganic materials 0.000 claims description 11
UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 11
229910052782 aluminium Inorganic materials 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 8
239000005083 Zinc sulfide Substances 0.000 claims description 6
229910052984 zinc sulfide Inorganic materials 0.000 claims description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
239000012190 activator Substances 0.000 claims description 5
239000000460 chlorine Substances 0.000 claims description 5
229910052801 chlorine Inorganic materials 0.000 claims description 5
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
239000011159 matrix material Substances 0.000 claims 1
239000002245 particle Substances 0.000 description 16
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 11
239000013078 crystal Substances 0.000 description 10
NYZGMENMNUBUFC-UHFFFAOYSA-N P.[S-2].[Zn+2] Chemical class P.[S-2].[Zn+2] NYZGMENMNUBUFC-UHFFFAOYSA-N 0.000 description 9
-1 copper-activated zinc cadmium sulfide Chemical class 0.000 description 8
QRJOYPHTNNOAOJ-UHFFFAOYSA-N copper gold Chemical compound [Cu].[Au] QRJOYPHTNNOAOJ-UHFFFAOYSA-N 0.000 description 6
238000000034 method Methods 0.000 description 6
239000002253 acid Substances 0.000 description 5
229910000365 copper sulfate Inorganic materials 0.000 description 5
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 5
239000000203 mixture Substances 0.000 description 5
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
230000004913 activation Effects 0.000 description 4
HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 4
VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 3
229940107816 ammonium iodide Drugs 0.000 description 3
230000006866 deterioration Effects 0.000 description 3
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
239000002994 raw material Substances 0.000 description 3
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
235000019270 ammonium chloride Nutrition 0.000 description 2
229910000420 cerium oxide Inorganic materials 0.000 description 2
QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 description 2
238000010894 electron beam technology Methods 0.000 description 2
SYDXSHCNMKOQFW-UHFFFAOYSA-H erbium(3+);trisulfate Chemical compound [Er+3].[Er+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O SYDXSHCNMKOQFW-UHFFFAOYSA-H 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
238000010304 firing Methods 0.000 description 2
230000004907 flux Effects 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
238000000879 optical micrograph Methods 0.000 description 2
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
239000001103 potassium chloride Substances 0.000 description 2
235000011164 potassium chloride Nutrition 0.000 description 2
239000000843 powder Substances 0.000 description 2
WFUBYPSJBBQSOU-UHFFFAOYSA-M rubidium iodide Chemical compound [Rb+].[I-] WFUBYPSJBBQSOU-UHFFFAOYSA-M 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
229910004631 Ce(NO3)3.6H2O Inorganic materials 0.000 description 1
239000005749 Copper compound Substances 0.000 description 1
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
238000005273 aeration Methods 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
239000011324 bead Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
150000001785 cerium compounds Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000011109 contamination Methods 0.000 description 1
150000001880 copper compounds Chemical class 0.000 description 1
PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000010130 dispersion processing Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002123 erbium compounds Chemical class 0.000 description 1
YBYGDBANBWOYIF-UHFFFAOYSA-N erbium(3+);trinitrate Chemical compound [Er+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YBYGDBANBWOYIF-UHFFFAOYSA-N 0.000 description 1
150000002344 gold compounds Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000001678 irradiating effect Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
QGJSAGBHFTXOTM-UHFFFAOYSA-K trifluoroerbium Chemical compound F[Er](F)F QGJSAGBHFTXOTM-UHFFFAOYSA-K 0.000 description 1

Landscapes

Luminescent Compositions (AREA)

JP12467881A 1981-08-11 1981-08-11 緑色発光螢光体 Granted JPS5827777A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP12467881A JPS5827777A (ja)	1981-08-11	1981-08-11	緑色発光螢光体

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP12467881A JPS5827777A (ja)	1981-08-11	1981-08-11	緑色発光螢光体

Publications (2)

Publication Number	Publication Date
JPS5827777A JPS5827777A (ja)	1983-02-18
JPS64999B2 true JPS64999B2 (fr)	1989-01-10

Family

ID=14891355

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP12467881A Granted JPS5827777A (ja)	1981-08-11	1981-08-11	緑色発光螢光体

Country Status (1)

Country	Link
JP (1)	JPS5827777A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6254785A (ja) *	1985-09-03	1987-03-10	Nichia Kagaku Kogyo Kk	硫化物螢光体
KR100326442B1 (ko) *	1994-12-09	2002-07-02	김순택	형광슬러리조성물

1981
- 1981-08-11 JP JP12467881A patent/JPS5827777A/ja active Granted

Also Published As

Publication number	Publication date
JPS5827777A (ja)	1983-02-18

Publication	Publication Date	Title
US4208299A (en)	1980-06-17	Method of preparing zinc sulfide phosphor coactivated with copper and gold
EP0091184B1 (fr)	1987-09-23	Matériaux luminescents et leur utilisation dans les dispositifs d'affichage fluorescent excités par des électrons
JP2000319649A (ja)	2000-11-21	緑色発光蛍光体組成物及びこれを用いて製造された蛍光膜を備えた陰極線管
US3691088A (en)	1972-09-12	Process for preparing phosphors
JPS64999B2 (fr)	1989-01-10
EP0358078B1 (fr)	1993-05-05	Matières luminescentes contenant des whiskers d'oxyde de zinc
US5185553A (en)	1993-02-09	Green emitting phosphor and cathode ray tube using said phosphor
JP2506980B2 (ja)	1996-06-12	蛍光体
JPS6248716B2 (fr)	1987-10-15
JP2001329261A (ja)	2001-11-27	低駆動電圧で高効率発光する硫化亜鉛系蛍光体の製造方法
KR930003383B1 (ko)	1993-04-26	ZnS : Ag, Al계 청색발광 형광체의 제조방법
JPH11349937A (ja)	1999-12-21	青色発光蛍光体
JPH0625350B2 (ja)	1994-04-06	硫化物螢光体
JP2598586B2 (ja)	1997-04-09	緑色発光蛍光体
KR920004166B1 (ko)	1992-05-30	녹색 발광 형광체
JP2762846B2 (ja)	1998-06-04	青色発光蛍光体およびその製造方法
JPH0629421B2 (ja)	1994-04-20	青色発光蛍光体及びそれを用いたカラー投写型映像装置用青色発光ブラウン管
KR100286934B1 (ko)	2001-04-16	녹색발광 형광체
KR910002681B1 (ko)	1991-05-03	녹색 발광 형광체
US3052638A (en)	1962-09-04	Preparation of recalcined zinc sulfide phosphors
US2882238A (en)	1959-04-14	Barium phosphate phosphor
KR950011230B1 (ko)	1995-09-29	녹색 발광형광체의 제조방법
JP2001064639A (ja)	2001-03-13	低電圧用青色蛍光体及びその製造方法
KR19980019750A (ko)	1998-06-25	Y2o3s계 소립자 형광체의 제조방법
JPH044287A (ja)	1992-01-08	青色発光蛍光体及び陰極線管