KR890700549A - 치환된 방향족 화합물의 요오드화 방법 - Google Patents
치환된 방향족 화합물의 요오드화 방법Info
- Publication number
- KR890700549A KR890700549A KR1019880701530A KR880701530A KR890700549A KR 890700549 A KR890700549 A KR 890700549A KR 1019880701530 A KR1019880701530 A KR 1019880701530A KR 880701530 A KR880701530 A KR 880701530A KR 890700549 A KR890700549 A KR 890700549A
- Authority
- KR
- South Korea
- Prior art keywords
- aromatic compound
- catalyst
- group
- acid
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000001491 aromatic compounds Chemical class 0.000 title claims 9
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 7
- 239000003054 catalyst Substances 0.000 claims 5
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims 2
- 150000001555 benzenes Chemical class 0.000 claims 2
- 150000001768 cations Chemical class 0.000 claims 2
- -1 dephenyl Chemical compound 0.000 claims 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 2
- 150000002790 naphthalenes Chemical class 0.000 claims 2
- 239000010457 zeolite Substances 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- SBUKLPSBNFWJCU-UHFFFAOYSA-N ClIBr Chemical group ClIBr SBUKLPSBNFWJCU-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims 1
- 239000012965 benzophenone Substances 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 125000004093 cyano group Chemical group *C#N 0.000 claims 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 230000002083 iodinating effect Effects 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 229910052701 rubidium Inorganic materials 0.000 claims 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Quinoline Compounds (AREA)
- Pyridine Compounds (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- (a) 방향족 화합물이 벤젠, 바이페닐, 더페닐, 나프탈렌, 안트라센, 티오펜, 벤조티오펜 디페닐설폰, 디페닐설파이드, 디페닐에테르, 피리딘, 벤조피리딘 및 벤조페논으로 구성된 그룹으로부터 선택되고 (b) 방향족 화합물이 플루오로, 클로로, 브로모, 요오드, 하이드록실 또는 시아노로 구성된 그룹으로부터 선택된 최소한 하나의 치환체를 가지는 것으로 이루어진 산소 존재하, 산이 아닌 촉매에서 요오드 소오스를 방향족 화합물과 반응시키는 것으로 특징되어지는 방향족 화합물을 요오드화하는 방법.
- 제1항에 있어서, 전기한 산이 아닌 촉매가 제올라이트인 방법.
- 제2항에 있어서, 전기한 제올라이트가 최소한 하나의 칼륨, 루비듐 또는 세슘과 이온교환된 13X 타입인 방법.
- 제1항에 있어서, 전기한 방향족 화합물이 치환된 벤젠인 방법.
- 제1항에 있어서, 전기한 방향족 화합물이 치환된 나프탈렌인 방법.
- 제1항에 있어서, 전기한 산이 아닌 촉매가 염기성 부분을 포함하는 방법.
- 제6항에 있어서, 전기한 촉매가 알칼리 또는 알칼리 토류 양이온을 포함하는 방법.
- 제6항에 있어서, 전기한 산이 아닌 촉매가 비제올라이트 지지체상 알칼리 및 알칼리 토류 양이온으로 구성된 그룹으로부터 선택되는 방법.
- 제6항에 있어서, 전기한 방향족 화합물이 치환된 벤젠인 방법.
- 제6항에 있어서, 전기한 방향족 화합물이 치환된 나프탈렌인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US029897 | 1987-03-25 | ||
| US07/029,897 US4778940A (en) | 1987-03-25 | 1987-03-25 | Process for preparing iodinated substituted aromatic compounds |
| PCT/US1988/000800 WO1988007509A1 (en) | 1987-03-25 | 1988-03-16 | Process for preparing iodinated substituted aromatic compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR890700549A true KR890700549A (ko) | 1989-04-25 |
Family
ID=21851459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880701530A Withdrawn KR890700549A (ko) | 1987-03-25 | 1988-03-16 | 치환된 방향족 화합물의 요오드화 방법 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4778940A (ko) |
| EP (1) | EP0307447A1 (ko) |
| JP (1) | JPH01502819A (ko) |
| KR (1) | KR890700549A (ko) |
| CN (1) | CN88101781A (ko) |
| AU (1) | AU610879B2 (ko) |
| CA (1) | CA1314896C (ko) |
| DK (1) | DK656388D0 (ko) |
| ES (1) | ES2006391A6 (ko) |
| NO (1) | NO885192D0 (ko) |
| WO (1) | WO1988007509A1 (ko) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4855514A (en) * | 1988-08-17 | 1989-08-08 | Eastman Kodak Company | Oxidative iodination of phenol |
| US5026931A (en) * | 1990-09-10 | 1991-06-25 | Eastman Kodak Company | Process for preparing a product stream rich in naphthalene and 2-monoiodonaphthalene |
| US5138108A (en) * | 1990-12-03 | 1992-08-11 | Eastman Kodak Company | Process for regenerating a zeolite catalyst |
| US5386069A (en) * | 1993-05-07 | 1995-01-31 | Eastman Chemical Company | Process for preparation of difluoro-tetraiodobenzene |
| JP4332702B2 (ja) * | 2003-02-10 | 2009-09-16 | 三菱瓦斯化学株式会社 | ヨウ素化合物の製造方法 |
| EP1595862B1 (en) * | 2003-02-10 | 2010-11-17 | Mitsubishi Gas Chemical Company, Inc. | Process for production of iodine compounds and process for production of high-purity 5-iodo-2-methylbenzoic acid |
| KR101056563B1 (ko) * | 2003-07-03 | 2011-08-11 | 미츠비시 가스 가가쿠 가부시키가이샤 | 5요오도2메틸벤조산의 제조 방법 |
| JP4340858B2 (ja) * | 2003-07-03 | 2009-10-07 | 三菱瓦斯化学株式会社 | 5−ヨード−2−メチル安息香酸の製造方法 |
| CN100355710C (zh) * | 2005-12-15 | 2007-12-19 | 上海交通大学 | 芳烃碘代物的制备方法 |
| KR101123148B1 (ko) * | 2007-12-17 | 2012-03-19 | 에스케이케미칼주식회사 | 방향족 요오드화 화합물의 제조 방법 |
| KR101004369B1 (ko) | 2008-12-11 | 2010-12-27 | 에스케이케미칼주식회사 | 방향족 요오드화 화합물의 제조 방법 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3363010A (en) * | 1961-08-02 | 1968-01-09 | Pullman Inc | Halogenation process |
| US3600331A (en) * | 1968-06-18 | 1971-08-17 | Velsicol Chemical Corp | Catalyst containing copper phosphate and silver phosphate useful in the oxygenation of hydrogen halides |
| US3644542A (en) * | 1969-06-17 | 1972-02-22 | Hooker Chemical Corp | Benzene oxychlorination |
| US4240987A (en) * | 1979-10-29 | 1980-12-23 | Xerox Corporation | Chemical process |
| JPS5777631A (en) * | 1980-10-31 | 1982-05-15 | Kureha Chem Ind Co Ltd | Vapor-phase halogenation process |
| US4391785A (en) * | 1981-12-21 | 1983-07-05 | Mobil Oil Corporation | Preparation of ZSM-12 type zeolites |
| JPS59219241A (ja) * | 1983-05-30 | 1984-12-10 | Asahi Chem Ind Co Ltd | 芳香族化合物のオキシヨウ素化法 |
| US4513092A (en) * | 1984-01-04 | 1985-04-23 | Mobil Oil Corporation | Composite catalyst for halogenation and condensation of alkanes |
| IT1176856B (it) * | 1984-10-05 | 1987-08-18 | Montedipe Spa | Metodo per la sintesi di iodobenzene |
| IT1176981B (it) * | 1984-10-16 | 1987-08-26 | Montedipe Spa | Metodo per la sintesi di iodobenzene |
| US4746758A (en) * | 1986-09-29 | 1988-05-24 | Eastman Kodak Company | Processes for preparing iodinated aromatic compounds |
-
1987
- 1987-03-25 US US07/029,897 patent/US4778940A/en not_active Expired - Fee Related
-
1988
- 1988-02-15 CA CA000558888A patent/CA1314896C/en not_active Expired - Fee Related
- 1988-03-16 KR KR1019880701530A patent/KR890700549A/ko not_active Withdrawn
- 1988-03-16 WO PCT/US1988/000800 patent/WO1988007509A1/en not_active Ceased
- 1988-03-16 JP JP62507066A patent/JPH01502819A/ja active Pending
- 1988-03-16 AU AU15441/88A patent/AU610879B2/en not_active Ceased
- 1988-03-16 EP EP88903093A patent/EP0307447A1/en not_active Withdrawn
- 1988-03-25 CN CN198888101781A patent/CN88101781A/zh active Pending
- 1988-03-25 ES ES8800918A patent/ES2006391A6/es not_active Expired
- 1988-11-22 NO NO885192A patent/NO885192D0/no unknown
- 1988-11-24 DK DK656388A patent/DK656388D0/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DK656388A (da) | 1988-11-24 |
| AU1544188A (en) | 1988-11-02 |
| ES2006391A6 (es) | 1989-04-16 |
| NO885192L (no) | 1988-11-22 |
| DK656388D0 (da) | 1988-11-24 |
| EP0307447A1 (en) | 1989-03-22 |
| NO885192D0 (no) | 1988-11-22 |
| WO1988007509A1 (en) | 1988-10-06 |
| JPH01502819A (ja) | 1989-09-28 |
| AU610879B2 (en) | 1991-05-30 |
| CA1314896C (en) | 1993-03-23 |
| CN88101781A (zh) | 1988-11-02 |
| US4778940A (en) | 1988-10-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19881124 |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |