KR910014331A - 알킬-치환된 방향족 탄화수소의 제조방법 - Google Patents

알킬-치환된 방향족 탄화수소의 제조방법 Download PDF

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KR910014331A
KR910014331A KR1019900015078A KR900015078A KR910014331A KR 910014331 A KR910014331 A KR 910014331A KR 1019900015078 A KR1019900015078 A KR 1019900015078A KR 900015078 A KR900015078 A KR 900015078A KR 910014331 A KR910014331 A KR 910014331A
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alkaline earth
compound
group
alkali metal
alumina
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KR0150795B1 (ko
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마사미 후까오
다꾸오 히비
기요시 이끼미
고오후 스즈까모
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원본미기재
스미또모 가가꾸고오교 가부시끼가이샤
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/72—Addition to a non-aromatic carbon atom of hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

알킬-치환된 방향족 탄화수소의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 200내지 800℃의 온도에서 알루미나를 하나 이상의 알칼리토금속의 화합물로 처리한 다음 200내지 800℃의 온도에서 불활성 기체하에서 알칼리금속 및 알칼리금속 수소화물로 구성된 군으로 부터 선택된 하나 이상의 화합물로 처리하여 수득할수 있는 고체 염기의 존재하에서, 측쇄내의 알파탄소에 하나 이상의 수수원자를 가지는 알킬 방향족 탄화수소를 올레핀으로 알킬화 시킴을 특징으로 하는 알킬-치환된 방향족 탄화수소의 제조방법.
  2. 제1항에 있어서, 고체염기는 알루미나를 하나 이상의 상기 알칼리토금속의 화합물로 처리한후 알칼리금속으로 처리하여 수득하는 방법.
  3. 제1항에 있어서, 고체 염기는 알루미나를 하나 이상의 상기 알칼리토금속의 화합물로 처리한후 알칼리금속수소화물로 처리하여 수득하는 방법.
  4. 제1항에 있어서, 고체 염기는 알루미나를 하나 이상의 상기 알칼리토금속의 화합물로 처리한 음 200내지 450℃의 온도에서 알칼리금속 및 알칼리금속 수소화물로 구성된 군으로 부터 선택된 하나 이상의 화합물로 처리하여 수득하는 방법.
  5. 제1항에 있어서, 하나 이상의 상기 상기 알칼리토금속의 화합물은 알칼리토금속의 산화물, 수산화물, 알콕시드 및 아세테이트로 구성된 군으로 선택되는 방법.
  6. 제1항에 있어서, 하나 이상의 상기 알칼리토금속의 화합물은 알칼리 토금속의 산화물 및 수산화물로 구성된 군에서 선택되는 방법.
  7. 제1항에 있어서, 고체염기는 250내지 600℃의 온도에서 알루미나를 하나 이상의 상기 알칼리토금속의 화합물로 처리 하여 수득하는 방법.
  8. 제1항에 있어서, 하나 이상의 상기 알칼리토금속의 화합물의 양은 알루미나의 중량을 기준으로 5내지 40중량%인 방법.
  9. 제1항에 있어서, 알칼리금속 및 알칼리금속 수소화물로 구성된 군에서 선택된 하나 이상의 상기 화합물의 양은 알루미나의 중량을 기준으로 2내지 15중량%인 방법.
  10. 제1항에 있어서, 하나 이상의 상기 알칼리토금속의 화합물은 산화 마그네슘, 수산화마그네슘, 수산화칼슘, 수산화바륨 및 마그네슘 아세테이트로 구성된 군에서 선택되는 방법.
  11. 제1항에 있어서, 알칼리금속은 나트륨 및 칼륨으로 구성된 군에서 하나 이상 선택되는 방법.
  12. 제11항에 있어서, 알칼리금속이 칼륨인 방법.
  13. 제1항에 있어서, 알리금속 수소화물은 수소화나트륨 및 수소화칼륨으로 구성된 군으로 부터 하나 이상 선택되는 방법.
  14. 제13항에 있어서, 알칼리금속 수호화물이 수소화칼륨인 방법.
  15. 제1항에 있어서, 축쇄내의 알파 탄소에 수소원자를 가지는 알킬 방향족 탄화수소는 그 측쇄에 1내지 10탄소원자를 가지는 방법.
  16. 제15항에 있어서, 알킬 방향족 탄화수소는 톨루엔 및 이소프로필벤젠으로 구성된 군에서 하나 선택되는 방법.
  17. 제1항에 있어서, 올레핀은 2내지 20탄소원자를 가지는 방법.
  18. 제17항에 있어서, 올레핀은 에틸렌 및 프로필렌으로 구성된 군에서 선택되는 방법.
  19. 제1항에 있어서, 알킬화 반응온도는 20내지 200℃인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900015078A 1990-01-30 1990-09-22 알킬-치환된 방향족 탄화수소의 제조방법 Expired - Fee Related KR0150795B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP20989/1990 1990-01-30
JP2-20989/90 1990-01-30
JP2020989A JP2748631B2 (ja) 1990-01-30 1990-01-30 アルキル置換芳香族炭化水素の製造方法

Publications (2)

Publication Number Publication Date
KR910014331A true KR910014331A (ko) 1991-08-31
KR0150795B1 KR0150795B1 (ko) 1998-10-15

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Country Status (5)

Country Link
US (1) US5097088A (ko)
EP (1) EP0439679B1 (ko)
JP (1) JP2748631B2 (ko)
KR (1) KR0150795B1 (ko)
DE (1) DE69020131T2 (ko)

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JP3250899B2 (ja) * 1993-12-27 2002-01-28 日石三菱株式会社 アルキル置換芳香族炭化水素の側鎖アルキル化方法
JP3548599B2 (ja) * 1994-04-14 2004-07-28 新日本石油株式会社 アルキル置換芳香族炭化水素の側鎖アルキル化方法
DE19715203A1 (de) * 1997-04-11 1998-10-15 Basf Ag Katalysator und Verfahren zur Seitenkettenalkylierung
US6262325B1 (en) 1998-09-29 2001-07-17 Basf Aktiengessellschaft Basic catalyst based on titanates, zirconates and hafnates
DE19845293A1 (de) * 1998-10-01 2000-04-06 Basf Ag Herstellung eines basischen Katalysators unter Vermeidung hoher Temperaturen
FI20000183A0 (fi) * 2000-01-28 2000-01-28 Optatech Oy Alkylointimenetelmä
WO2010002792A2 (en) 2008-06-30 2010-01-07 Kior, Inc. Co-processing solid biomass in a conventional petroleum refining process unit
US8524959B1 (en) 2009-02-18 2013-09-03 Kior, Inc. Biomass catalytic conversion process and apparatus for use therein
US8558043B2 (en) * 2009-03-04 2013-10-15 Kior, Inc. Modular biomass treatment unit
CN102438969A (zh) * 2009-05-22 2012-05-02 科伊奥股份有限公司 利用氢源处理生物质
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Also Published As

Publication number Publication date
EP0439679A2 (en) 1991-08-07
DE69020131T2 (de) 1995-09-21
JP2748631B2 (ja) 1998-05-13
US5097088A (en) 1992-03-17
EP0439679A3 (en) 1991-11-06
JPH03227944A (ja) 1991-10-08
KR0150795B1 (ko) 1998-10-15
DE69020131D1 (de) 1995-07-20
EP0439679B1 (en) 1995-06-14

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