KR940702902A - 할로겐화 발포제를 함유하는 미세 기포 플라스틱 발포물(Fine-celled plasitc foam containing halogenated blowing agent) - Google Patents

할로겐화 발포제를 함유하는 미세 기포 플라스틱 발포물(Fine-celled plasitc foam containing halogenated blowing agent)

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Publication number
KR940702902A
KR940702902A KR1019940701037A KR19940701037A KR940702902A KR 940702902 A KR940702902 A KR 940702902A KR 1019940701037 A KR1019940701037 A KR 1019940701037A KR 19940701037 A KR19940701037 A KR 19940701037A KR 940702902 A KR940702902 A KR 940702902A
Authority
KR
South Korea
Prior art keywords
blowing agent
agent emulsion
low boiling
boiling point
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1019940701037A
Other languages
English (en)
Inventor
루돌프 제이. 댐즈
리차드 엠. 폴린
코엔 포켓트
존. 지. 오웬즈
Original Assignee
게리 리 그리스월드
미네소타 미이닝 앤드 매뉴팩츄어링 컴패니(Minnesota Mining and Manufacturing Company)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/771,442 external-priority patent/US5210106A/en
Application filed by 게리 리 그리스월드, 미네소타 미이닝 앤드 매뉴팩츄어링 컴패니(Minnesota Mining and Manufacturing Company) filed Critical 게리 리 그리스월드
Publication of KR940702902A publication Critical patent/KR940702902A/ko
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 (1)하나이상의 저 비점, 히드로클로카본, (2)하나이상의 저비점, 염소가 제거된 퍼플루오르화 화합물 및 (3)하나이상의 저 비점, 히드로클로로플루오로카본, 하나이상의 저 비점, 히드로플루오로카본, 하나이상의 저 비점 히드로카본 또는 이의 혼합물을 부가로 포함하는 발포제 혼합물을 포함하는 발포제 유탁액; 발포성 중합성 반응 혼합물 및 플루오로화합물 계면활성제, 임의로, 실리콘 계면활성제 및 촉매; 발포 플라스틱; 및 이의 제조 방법에 관한 것이다.

Description

할로겐화 발포제를 함유하는 미세 기포 플라스틱 발포물(Fine-celled plasitc foam containing halogenated blowing agent)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. (a)둘 이상의 반응성 수소 원자를 갖는 하나이상의 고분자량 화합물; (b)(1) 하나이상의 저 비점, 히드로클로로카본 및 (2)하나이상의 저 비점, 염소가 제거된 퍼플루오르화 화합물을 포함하는 발포제 혼합물; 및 (c)플루오로화합물 계면활성제를 포함하는 발포제 유탁액.
  2. 제1항에 있어서, 하나이상의 저 비점, 히드로클로로플루오로카본, 하나이상의 저 비점, 히드로플로오로카본, 하나이상의 저 비점, 히드로카본, 또는 이의 혼합물을 부가로 포함하는 발포제 유탁액.
  3. 제1항에 있어서, 실리콘 계면활성제를 부가로 포함하는 발포제 유탁액.
  4. 제1항에 있어서, 사슬 연장제 및/또는 가교제를 부가로 포함하는 발포제 유탁액.
  5. 제1항에 있어서, 하나 이상의 촉매를 가로 포함하는 발포제 유탁액.
  6. 제5항에 있어서, (a)둘이상의 반응성 수소 원자를 갖는 80내지 300중량부의 고분자량 화합물, (b)제1항 또는 제2항에 따른 0.1 내지 150중량부의 발포제 혼합물, (c)0.01내지 10중량부의 플로오로화합물 계면활성제, (d)0내지 10중량부의 실리콘 계면활성제, (e)0내지 50중량부의 물 및 (f)촉매적으로 유효한 함량의 촉매를 포함하는 발포제 유탁액.
  7. 제2항에 있어서, 상기 발포제 혼합물이 이소프로필클로라이드 및 퍼플로오로 N-메틸모르폴린을 포함하는 발포제 유탁액.
  8. 제2항에 있어서, 상기 발포제 혼합물이 이소프로필클로라이드 및 퍼플로오로헥산을 포함하는 발포제 유탁액.
  9. 제5항의 발포제 유탁액 및 유기 및/또는 변성 유기 폴리이소시아네이트 또는 폴리아소시아누레이트의 반응 생성물을 포함하는 발포 플라스틱.
  10. (a)(1)(i) 하나 이상의 저 비점 히드로클로로카본 및 (ii)하나 이상의 저 비점, 염소가 제거된 퍼플루오로화 화합물을 포함하는 발포제 혼합물, (2)촉매 및 (3)플로오로화합물 계면활성제의 존재하에 유기 및/또는 변성 규기 폴리이소시아네이트 및 둘이상의 반응성 수소 원자를 갖는 하나이상의 고분자량 화합물과 혼합하는 단계를 포함하는 플라스틱의 제조 방법.
  11. 하나 이상의 저 비점, 히드로클로로플루오로카본, 하나이상의 저 비점, 히드로플로오로카본, 하나이상의 저 비점, 히드로카본 또는 이의 화합물을 부가로 포함하는 제10항에 따른 발포제 유탁액.
  12. 제10항에 있어서, (a)하나이상의 상기 고분자량 화합물을 둘이상의 수소원자, 상기 발포제 혼합물, 상기 촉매 및 상기 플로오로화합물 계면활성제를 유화시키고, (b)상기 유화된 혼합물을 상기 유기 또는 변성 유기 폴리이소시아네이트에 첨가하는 단계를 부가로 포함하는 방법.
  13. 제9항의 발포 플라스틱에 의해 절연된 제품.
  14. 트리플로오로디클로로에탄, 퍼플루오로 N-메틸모르폴린 및 플루오로 계면활성제를 포함하는 발포제 유탁액으로 제조된 발포 플라스틱.
  15. 실리콘 계면활성제를 부가로 포함하는 제14항에 따른 발포제 유탁액.
  16. 트리플로오로디클로로에탄, 퍼플루오로 N-이소프로필모르폴린 및 플루오로 계면활성제를 포함하는 발포제 유탁액으로 제조된 발포 플라스틱.
  17. 실리콘 계면활성제를 부가로 포함하는 제16항에 따른 발포제 유탁액.
  18. 트리플로오로디클로로에탄, 퍼플루오로 N-메틸모르폴린 및 플루오로 계면활성제를 포함하는 발포제 유탁액.
  19. 제18항에 있어서, 실리콘 계면활성제를 부가로 포함하는 발포제 유탁액.
  20. 1, 1, 2, 2-테트라플루오로시클로부탄, 퍼플루오로 N-메틸모르폴린 및 플루오로계면활성제를 포함하는 발포제 유탁액.
  21. 제20항에 있어서, 실리콘 계면활성제를 부가로 포함하는 발포제 유탁액.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940701037A 1991-10-04 1992-08-26 할로겐화 발포제를 함유하는 미세 기포 플라스틱 발포물(Fine-celled plasitc foam containing halogenated blowing agent) Ceased KR940702902A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US07/771,442 US5210106A (en) 1991-10-04 1991-10-04 Fine-celled plastic foam containing fluorochemical blowing agent
US771.442 1991-10-04
US07/918,207 US5211873A (en) 1991-10-04 1992-07-21 Fine-celled plastic foam containing fluorochemical blowing agent
US918.207 1992-07-21
PCT/US1992/007225 WO1993007201A2 (en) 1991-10-04 1992-08-26 Fine-celled plastic foam containing halogenated blowing agent

Publications (1)

Publication Number Publication Date
KR940702902A true KR940702902A (ko) 1994-09-17

Family

ID=27118465

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940701037A Ceased KR940702902A (ko) 1991-10-04 1992-08-26 할로겐화 발포제를 함유하는 미세 기포 플라스틱 발포물(Fine-celled plasitc foam containing halogenated blowing agent)

Country Status (9)

Country Link
US (1) US5211873A (ko)
EP (1) EP0606252A1 (ko)
JP (1) JPH06511274A (ko)
KR (1) KR940702902A (ko)
AU (1) AU2518892A (ko)
BR (1) BR9206579A (ko)
CA (1) CA2116857A1 (ko)
MX (1) MX9205431A (ko)
WO (1) WO1993007201A2 (ko)

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DE3941871A1 (de) * 1989-12-19 1991-06-20 Basf Ag Neue fluorkohlenstoff- und oxypropylenalkylethergruppen gebunden enthaltende ester, diese ester enthaltende emulsionen und deren verwendung zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren
GB9001368D0 (en) * 1990-01-20 1990-03-21 Bp Chem Int Ltd Blowing agents
US4997706A (en) * 1990-02-09 1991-03-05 The Dow Chemical Company Foaming system for closed-cell rigid polymer foam
US5162384A (en) * 1991-09-13 1992-11-10 Minnesota Mining And Manufacturing Company Making foamed plastic containing perfluorinated heterocyclic blowing agent

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WO1993007201A2 (en) 1993-04-15
BR9206579A (pt) 1995-05-30
JPH06511274A (ja) 1994-12-15
CA2116857A1 (en) 1993-04-15
AU2518892A (en) 1993-05-03
EP0606252A1 (en) 1994-07-20
US5211873A (en) 1993-05-18
WO1993007201A3 (en) 1993-05-13
MX9205431A (es) 1994-03-31

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