KR950000788A - 재 분산시킬 수 있는 분산분말 조성물 - Google Patents

재 분산시킬 수 있는 분산분말 조성물 Download PDF

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KR950000788A
KR950000788A KR1019940013536A KR19940013536A KR950000788A KR 950000788 A KR950000788 A KR 950000788A KR 1019940013536 A KR1019940013536 A KR 1019940013536A KR 19940013536 A KR19940013536 A KR 19940013536A KR 950000788 A KR950000788 A KR 950000788A
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polymer
vinyl
mol
base polymer
polyvinyl alcohol
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KR0145157B1 (ko
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슐체 요아힘
하레르츠쉘 라인하르트
피게 라이너
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에리히 프랑크·칼-하인즈 림뵉
와커-헤미게엠베하
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34Filling pastes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02Homopolymers or copolymers of esters of monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0042Powdery mixtures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Colloid Chemistry (AREA)

Abstract

이 발명은 (a) 비닐에스테르 폴리머, 스티렌 폴리머, 아크릴레이트 폴리머 및 비닐클로리드 폴리모로 구성되는 그룹에서 선택한 기재폴리머(base polymer)와, (b) 그 기재 폴리머를 기준으로 하여 가수분해도 85-95mol%와 회플러점도(Hoppler viscocity) 2-25mPaㆍs를 가진 폴리비닐 알코올 2-15wt%, (c) 폴리머성분 총중량을 기준으로 하여 미세한 앤티블록킹제(fine antiblocking agent) 3-30wt%, (d) 냉수에 용해시킬 수 있고 회플러점도 1-20mPaㆍs와 비누화와 0~250을 가지며 일반식 CH2=CH(CH2)x-NH2(x=0~4임)의 아미노기능 비닐단위를 구성하는 아미노기능 폴리비닐 알코올 1-15wt%로 구성한 재분산시킬수 있는 분산분말 조성물을 제공한다. 이 발명의 분산분말조성물은 전재, 특히 무기질바인더로서 포오트란드 시멘트로 구성되는 건조 모르타르의 사용에 특히 적합하며 이 모르타의 접착강도를 증가시킨다.

Description

재 분산시킬 수 있는 분산분말 조성물.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. (a) 비닐에스테르 폴리머, 스티렌 폴리머, 아크릴레이트 폴리머 및 비닐클로리드 폴리모로 구성되는 그룹에서 선택한 기재폴리머(base polymer)와, (b) 그 기재폴리머를 기재로 하여 가수분해도 85-95mol%, 회플러점도(Hoppler viscocity) 2-25mPaㆍs를 가진 폴리비닐 알코올 2-15wt%와, (c) 폴리머성분 총중량을 기준으로 하여 미세한 앤티블록킹제(fine antiblocking agent) 3-30wt%와, (d) 그 기재폴리머를 기준으로 하여 냉수에 용해할 수 있고 회플러점도 1-25mPaㆍs, 비누화가 (Saponification number) 0~250을 가지며 일반식 CH2=CH-(CH2)x-NH2(x=0~4)의 아미노기능 비닐단위를 구성하는 아미노기능 폴리비닐 알코올 1-15wt%로 구성함을 특징으로 하는 재분산시킬수 있는 분산분말 조성물.
  2. 제1항에 있어서, 위 기재폴리머(a)는 비닐아세테이트 호모폴리머; 비닐 아세테이트/에틸렌 코폴리며; 도는 포화 C3-~C8-알킬카르복실산 및/또는 비닐클로리드 또는, 스티렌함량 1-70wt%를 가진 스티렌/부틸 아크릴레이트 또는 스티렌/에틸 헥실아크릴레이트등 스티렌/아크릴레이트의 비닐에스테르로 구성되는 그룹에서 선택된 또 다른 비닐에스테르 0-40wt%와 에틸렌 1-40wt%로 구성되는 포화 C3-~C8-알킬 카르복실산과 에틸렌의 비닐에스테르 코폴리머로 구성되는 그룹에서 선택된 폴리머임을 특징으로 하는 위 조성물.
  3. 제1항에 있어서, 냉수에 용해시킬 수 있는 그 아미노기능 폴리비닐 알코올(d)은 비닐아세테이트 0~20mol%, 비닐알코올 35~95mol%, 일반식 CH2=CH-(CH2)x-NH2(X20~4)의 아미노기능 비닐단위1-15mol%, 1-메틸비닐 알코올 2-20mol%, 1-메틸비닐 아세테이트 0.01~3.0mol%로 구성되는 폴리머임을 특징으로 하는 위 조성물
  4. 제1항에 있어서, 냉수에 용해시킬 수 있는 그 아미노기능 폴리비닐 알코 올(d)은 비닐아세테이트 0.1~15mol%, 비닐알코올 70~95mol%, 일반식 CH2=CH-(CH2)x-NH2(x=1)의 아미노기능 비닐단위 2-10mol%, 1-메틸비닐 알코올 2-20mol%, 1-메틸비닐아세테이트 0.01~3.0mol%로 구성되는 폴리머임을 특징으로 하는 위 조성물
  5. 제1항에 있어서, 위 기재폴리머를 기준으로 하여, C1-~C4-알킬기와 비닐에스테르를 가지며 회플러점도 1-25mPaㆍs(4% 용액엣 측정)을 가진 1-알킬비닐에스테르의 완전비누화 코폴리머 10wt% 이내로 첨가함을 특징으로 하는 위 조성물.
  6. 제1항에 있어서, 그 기재폴리머를 기준으로 하여, 케톤 또는 멜라민 포름알데히드 및/또는 나프탈렌설폰산/포름알데히드의 설포네이트함유 축합생성물 및/또는 페놀설포네이트/포름알데히드 축합생성물등의 시멘트유동화제 30wt%이내 및/또는 그 기재폴리머를 기준으로 하여 유화제 또는 습윤제등의 계면활성제 2wt%이내 및/또는 그 기재폴리머를 기준으로 하여 아크릴산등 점도부여제(thickener) 3wt%이내 및/또는 그 기재폴리머를 기준으로하여 소포제 2wt% 이내로 첨가함을 특징으로 하는 위 조성물.
  7. 타일접착제, 나이핑 fillers(knifing fillers), 석고건재, 라임 모르타르, 시멘트모르타르, 애벌바르기 모르타르(rendering mortar) 및 건조 모르타르등 건재에 있어서, 위 청구범위 제1항 내지 제6항중 어느 한 항의 재분산시킬 수 있는 분산분말 조성물의 사용.
  8. 접착조성물 및 페인트에 있어서 위 청구범위 제1항 내지 제6항중 어느 한 항의 재분산시킬 수 있는 분산분말 조성물의 사용.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940013536A 1993-06-24 1994-06-15 재 분산시킬 수 있는 분산분말 조성물 Expired - Fee Related KR0145157B1 (ko)

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DE4321070A DE4321070A1 (de) 1993-06-24 1993-06-24 Redispergierbare Dispersionspulverzusammensetzung
DE93-P4321070.8 1993-06-24

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KR950000788A true KR950000788A (ko) 1995-01-03
KR0145157B1 KR0145157B1 (ko) 1998-07-15

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US (1) US5567750A (ko)
EP (1) EP0632096B1 (ko)
JP (1) JP2694422B2 (ko)
KR (1) KR0145157B1 (ko)
CN (1) CN1075826C (ko)
AT (1) ATE131849T1 (ko)
CA (1) CA2126586C (ko)
DE (2) DE4321070A1 (ko)
ES (1) ES2081723T3 (ko)
FI (1) FI942979A7 (ko)
TW (1) TW269703B (ko)

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FI942979A0 (fi) 1994-06-21
JPH0741632A (ja) 1995-02-10
DE4321070A1 (de) 1995-01-05
EP0632096A1 (de) 1995-01-04
JP2694422B2 (ja) 1997-12-24
US5567750A (en) 1996-10-22
CA2126586C (en) 2000-03-28
DE59400066D1 (de) 1996-02-01
ATE131849T1 (de) 1996-01-15
FI942979A7 (fi) 1994-12-25
EP0632096B1 (de) 1995-12-20
KR0145157B1 (ko) 1998-07-15
ES2081723T3 (es) 1996-03-16
CN1075826C (zh) 2001-12-05
CN1103876A (zh) 1995-06-21
TW269703B (ko) 1996-02-01
CA2126586A1 (en) 1994-12-25

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