KR950000788A - 재 분산시킬 수 있는 분산분말 조성물 - Google Patents
재 분산시킬 수 있는 분산분말 조성물 Download PDFInfo
- Publication number
- KR950000788A KR950000788A KR1019940013536A KR19940013536A KR950000788A KR 950000788 A KR950000788 A KR 950000788A KR 1019940013536 A KR1019940013536 A KR 1019940013536A KR 19940013536 A KR19940013536 A KR 19940013536A KR 950000788 A KR950000788 A KR 950000788A
- Authority
- KR
- South Korea
- Prior art keywords
- polymer
- vinyl
- mol
- base polymer
- polyvinyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0042—Powdery mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
Claims (8)
- (a) 비닐에스테르 폴리머, 스티렌 폴리머, 아크릴레이트 폴리머 및 비닐클로리드 폴리모로 구성되는 그룹에서 선택한 기재폴리머(base polymer)와, (b) 그 기재폴리머를 기재로 하여 가수분해도 85-95mol%, 회플러점도(Hoppler viscocity) 2-25mPaㆍs를 가진 폴리비닐 알코올 2-15wt%와, (c) 폴리머성분 총중량을 기준으로 하여 미세한 앤티블록킹제(fine antiblocking agent) 3-30wt%와, (d) 그 기재폴리머를 기준으로 하여 냉수에 용해할 수 있고 회플러점도 1-25mPaㆍs, 비누화가 (Saponification number) 0~250을 가지며 일반식 CH2=CH-(CH2)x-NH2(x=0~4)의 아미노기능 비닐단위를 구성하는 아미노기능 폴리비닐 알코올 1-15wt%로 구성함을 특징으로 하는 재분산시킬수 있는 분산분말 조성물.
- 제1항에 있어서, 위 기재폴리머(a)는 비닐아세테이트 호모폴리머; 비닐 아세테이트/에틸렌 코폴리며; 도는 포화 C3-~C8-알킬카르복실산 및/또는 비닐클로리드 또는, 스티렌함량 1-70wt%를 가진 스티렌/부틸 아크릴레이트 또는 스티렌/에틸 헥실아크릴레이트등 스티렌/아크릴레이트의 비닐에스테르로 구성되는 그룹에서 선택된 또 다른 비닐에스테르 0-40wt%와 에틸렌 1-40wt%로 구성되는 포화 C3-~C8-알킬 카르복실산과 에틸렌의 비닐에스테르 코폴리머로 구성되는 그룹에서 선택된 폴리머임을 특징으로 하는 위 조성물.
- 제1항에 있어서, 냉수에 용해시킬 수 있는 그 아미노기능 폴리비닐 알코올(d)은 비닐아세테이트 0~20mol%, 비닐알코올 35~95mol%, 일반식 CH2=CH-(CH2)x-NH2(X20~4)의 아미노기능 비닐단위1-15mol%, 1-메틸비닐 알코올 2-20mol%, 1-메틸비닐 아세테이트 0.01~3.0mol%로 구성되는 폴리머임을 특징으로 하는 위 조성물
- 제1항에 있어서, 냉수에 용해시킬 수 있는 그 아미노기능 폴리비닐 알코 올(d)은 비닐아세테이트 0.1~15mol%, 비닐알코올 70~95mol%, 일반식 CH2=CH-(CH2)x-NH2(x=1)의 아미노기능 비닐단위 2-10mol%, 1-메틸비닐 알코올 2-20mol%, 1-메틸비닐아세테이트 0.01~3.0mol%로 구성되는 폴리머임을 특징으로 하는 위 조성물
- 제1항에 있어서, 위 기재폴리머를 기준으로 하여, C1-~C4-알킬기와 비닐에스테르를 가지며 회플러점도 1-25mPaㆍs(4% 용액엣 측정)을 가진 1-알킬비닐에스테르의 완전비누화 코폴리머 10wt% 이내로 첨가함을 특징으로 하는 위 조성물.
- 제1항에 있어서, 그 기재폴리머를 기준으로 하여, 케톤 또는 멜라민 포름알데히드 및/또는 나프탈렌설폰산/포름알데히드의 설포네이트함유 축합생성물 및/또는 페놀설포네이트/포름알데히드 축합생성물등의 시멘트유동화제 30wt%이내 및/또는 그 기재폴리머를 기준으로 하여 유화제 또는 습윤제등의 계면활성제 2wt%이내 및/또는 그 기재폴리머를 기준으로 하여 아크릴산등 점도부여제(thickener) 3wt%이내 및/또는 그 기재폴리머를 기준으로하여 소포제 2wt% 이내로 첨가함을 특징으로 하는 위 조성물.
- 타일접착제, 나이핑 fillers(knifing fillers), 석고건재, 라임 모르타르, 시멘트모르타르, 애벌바르기 모르타르(rendering mortar) 및 건조 모르타르등 건재에 있어서, 위 청구범위 제1항 내지 제6항중 어느 한 항의 재분산시킬 수 있는 분산분말 조성물의 사용.
- 접착조성물 및 페인트에 있어서 위 청구범위 제1항 내지 제6항중 어느 한 항의 재분산시킬 수 있는 분산분말 조성물의 사용.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4321070A DE4321070A1 (de) | 1993-06-24 | 1993-06-24 | Redispergierbare Dispersionspulverzusammensetzung |
| DE93-P4321070.8 | 1993-06-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR950000788A true KR950000788A (ko) | 1995-01-03 |
| KR0145157B1 KR0145157B1 (ko) | 1998-07-15 |
Family
ID=6491171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019940013536A Expired - Fee Related KR0145157B1 (ko) | 1993-06-24 | 1994-06-15 | 재 분산시킬 수 있는 분산분말 조성물 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5567750A (ko) |
| EP (1) | EP0632096B1 (ko) |
| JP (1) | JP2694422B2 (ko) |
| KR (1) | KR0145157B1 (ko) |
| CN (1) | CN1075826C (ko) |
| AT (1) | ATE131849T1 (ko) |
| CA (1) | CA2126586C (ko) |
| DE (2) | DE4321070A1 (ko) |
| ES (1) | ES2081723T3 (ko) |
| FI (1) | FI942979A7 (ko) |
| TW (1) | TW269703B (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100440678B1 (ko) * | 2001-12-21 | 2004-07-21 | 재단법인 포항산업과학연구원 | 산화제가 첨가된 밀스케일을 사용한 하드 페라이트의제조방법 |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4443738A1 (de) * | 1994-12-08 | 1996-06-13 | Wacker Chemie Gmbh | Holzleimpulver |
| DE19502435A1 (de) * | 1995-01-26 | 1996-08-01 | Elotex Ag | Chemische Zusammensetzung mit einem Gehalt an a) einem Copolymer auf Basis von Styrol und/oder Alkyl(meth)acrylat sowie mindestens eines weiteren Comonomers und b) an einem Schutzkolloid, deren wäßrige Polymerdispersion, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5563187A (en) * | 1995-02-16 | 1996-10-08 | Rohm And Haas Company | Grafted polymer composition |
| DE19512744A1 (de) * | 1995-04-05 | 1996-10-10 | Jan Hendrik Peters | Lösungsmittelfreier und lösungsmittelarmer Dispersionsklebstoff, dessen Basisstoff (vorwiegend Polystyrol und Polyvinylchlorid) aus Kunststoffabfällen gewonnen wird |
| DE19523115A1 (de) * | 1995-06-26 | 1997-01-02 | Hoechst Ag | Dispersionspulver mit erhöhter Selbstentzündungstemperatur |
| DE19549084A1 (de) * | 1995-12-29 | 1997-07-03 | Wacker Chemie Gmbh | Pulverförmige, redispergierbare Bindemittel |
| DE19620817A1 (de) * | 1996-05-23 | 1997-11-27 | Wacker Chemie Gmbh | Flexible Baustoffmassen |
| DE19623412B4 (de) * | 1996-06-12 | 2008-05-29 | Basf Se | Verfahren zur Herstellung von Polymerisatpulver |
| DE19639897A1 (de) * | 1996-09-27 | 1998-04-02 | Sun Chemical Corp | Wasserlösliche und sauerstoffsperrende Polymerschichten und deren Verwendung für lichtempfindliche Materialien |
| DE19709254A1 (de) | 1997-03-06 | 1998-09-10 | Wacker Chemie Gmbh | Verfahren zur Herstellung von schutzkolloidfreien Dispersionen und Dispersionspulvern |
| DE19710381A1 (de) * | 1997-03-13 | 1998-09-17 | Buna Sow Leuna Olefinverb Gmbh | Redispergierbare Dispersionspulver auf Basis von Polyacrylaten |
| GB2328627A (en) * | 1997-08-19 | 1999-03-03 | Dean James Clowes | Building elements |
| DE19757298A1 (de) * | 1997-12-22 | 1999-06-24 | Basf Ag | Verfahren zur Herstellung von Polymerpulvern |
| DE19853420A1 (de) * | 1998-11-19 | 2000-05-25 | Wacker Chemie Gmbh | Verwendung von Dispersionspulver-Zusammensetzungen auf der Basis von Vinylaromat-1,3-Dien-Mischpolymerisaten in selbstverlaufenden Bodenspachtelmassen und Estrichen |
| DE19901307C1 (de) | 1999-01-15 | 2000-06-21 | Clariant Gmbh | Dispersionspulver enthaltend teilacetalisierte, wasserlösliche Polyvinylalkohole, Verfahren zu deren Herstellung sowie deren Verwendung |
| DE19964153B4 (de) | 1999-03-10 | 2006-06-01 | Wacker Chemie Ag | Verwendung von Fällungsmittel-Konzentrat zur Herstellung von schnell trocknenden Putzmassen |
| DE10109841C2 (de) * | 2001-03-22 | 2003-10-30 | Wacker Polymer Systems Gmbh | Trockenmörtel mit verbesserten Verarbeitungseigenschaften, Verfahren zu deren Herstellung, sowie deren Verwendung |
| AU785048B2 (en) * | 2001-03-21 | 2006-09-07 | Rohm And Haas Company | Method for preparing storage-stable fast-drying multi-component aqueous coating compositions and coatings derived therefrom |
| AU2002256076A1 (en) * | 2001-04-10 | 2002-10-28 | Interlock Industries, Inc. | Water based adhesive |
| DE10140130A1 (de) * | 2001-08-16 | 2003-03-06 | Wacker Polymer Systems Gmbh | Polyvinylacetale mit verbesserter Haftung |
| DE10316079A1 (de) * | 2003-04-08 | 2004-11-11 | Wacker Polymer Systems Gmbh & Co. Kg | Polyvinylalkohol-stabilisierte Redispersionspulver mit verflüssigenden Eigenschaften |
| DE10317882A1 (de) * | 2003-04-17 | 2004-11-11 | Wacker Polymer Systems Gmbh & Co. Kg | Redispersionspulver-Zusammensetzung mit abbindebeschleunigender Wirkung |
| ES2366785T3 (es) * | 2003-09-01 | 2011-10-25 | Acquos Pty Ltd. | Agentes redispersantes para polvos de polímeros redispersables y polvos de polímeros redispersables que incluyen los mismos. |
| DE102004023374A1 (de) * | 2004-05-12 | 2005-12-08 | Celanese Emulsions Gmbh | Konservierungsmittelfreie Beschichtungsmittel, Verfahren zu deren Herstellung und deren Verwendung |
| DE102004026610A1 (de) * | 2004-06-01 | 2005-12-22 | Wacker Polymer Systems Gmbh & Co. Kg | Verwendung von Vinylchlorid-Ethylen-Mischpolymerisaten zur Hydrophobierung von Baustoffmassen |
| US7288581B2 (en) * | 2004-12-15 | 2007-10-30 | Wacker Polymer Systems Gmbh & Co. Kg | Process for the stabilization of dusting surfaces |
| CA2598102C (en) * | 2005-03-03 | 2010-09-21 | Wacker Polymer Systems Gmbh & Co. Kg | Use of silicon oxide compounds as free-flow agents in the production of solid polyvinyl acetate resins |
| DE102005054905A1 (de) * | 2005-11-17 | 2007-05-24 | Wacker Polymer Systems Gmbh & Co. Kg | Schutzkolloidstabilisiertes Dispersionspulver |
| DE602006013874D1 (de) * | 2005-11-24 | 2010-06-02 | Nippon Synthetic Chem Ind | Wässrige emulsion und klebstofffzusammensetzung |
| DE102006007282A1 (de) * | 2006-02-16 | 2007-08-23 | Wacker Polymer Systems Gmbh & Co. Kg | Verfahren zur Herstellung von kationisch stabilisierten und in Wasser redispergierbaren Polymerpulverzusammensetzungen |
| US20110160336A1 (en) * | 2006-10-05 | 2011-06-30 | Roland Reichenbach-Klinke | Method of use of a polyvinyl alcohol-based composition |
| DE102006047091A1 (de) * | 2006-10-05 | 2008-04-10 | Basf Construction Polymers Gmbh | Neue Zusammensetzung auf Polyvinylalkohol-Basis |
| WO2008101297A1 (en) * | 2007-02-22 | 2008-08-28 | Acquos Pty Ltd | Redispersible polymers including a protective colloid system |
| EP2055686A1 (en) * | 2007-10-30 | 2009-05-06 | PRAD Research and Development N.V. | Additive for controlliing cement slurry rheology |
| DE102010011180A1 (de) * | 2010-03-12 | 2011-09-15 | Ardex Gmbh | Verfahren zur Verlegung von Fliesen |
| DE102010063470A1 (de) * | 2010-12-17 | 2012-06-21 | Wacker Chemie Ag | Papierstreichmassen enthaltend eine Kombination aus Styrol-Butadien-Copolymer und/oder Styrol-Acrylsäureester-Copolymer und Vinylacetat-Ethylen-Copolymer |
| DE102011076407A1 (de) * | 2011-05-24 | 2012-11-29 | Wacker Chemie Ag | Verfahren zur Herstellung von Schutzkolloid-stabilisierten Polymerisaten |
| DE102012223620A1 (de) | 2012-12-18 | 2014-06-18 | Wacker Chemie Ag | Verwendung von Hybridcopolymeren als Schutzkolloide für Polymere |
| DE102012223614A1 (de) | 2012-12-18 | 2014-06-18 | Wacker Chemie Ag | Verwendung von Polyvinylalkohol stabilisierten Polymerisaten in mineralischen Baustoffmassen |
| CN104403603A (zh) * | 2014-10-22 | 2015-03-11 | 上海大学 | 阻燃交联型聚乙烯醇粘结剂及其制备方法 |
| JP6874154B2 (ja) * | 2017-04-28 | 2021-05-19 | ハンワ ソリューションズ コーポレイションHanwha Solutions Corporation | 塩化ビニル系樹脂ラテックス組成物およびその製造方法 |
| WO2023098983A1 (de) | 2021-11-30 | 2023-06-08 | Wacker Chemie Ag | Verfahren zur herstellung von in wasser redispergierbaren polymerpulvern |
| WO2024051929A1 (de) | 2022-09-06 | 2024-03-14 | Wacker Chemie Ag | In wasser redispergierbare polymerpulver für baustofftrockenformulierungen |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2748103A (en) * | 1952-06-10 | 1956-05-29 | Eastman Kodak Co | Copolymers of vinyl esters with nu-allyl urethanes and hydrolysis products thereof |
| DE2049114C3 (de) * | 1970-10-06 | 1974-03-21 | Wacker-Chemie Gmbh, 8000 Muenchen | Herstellen freifließender, blockfester,redispergierbarer Kunststoffpulver |
| US3784648A (en) * | 1971-10-01 | 1974-01-08 | Wacker Chemie Gmbh | Process for the preparation of free-flowing,lump-free,redispersible,synthetic resin powders |
| US4704416A (en) * | 1985-12-19 | 1987-11-03 | Wacker-Chemie Gmbh | Aqueous redispersible powders which contain a water-soluble polymer and at least one organic silicon compound and a process for preparing the same |
| CA1330684C (en) * | 1988-04-15 | 1994-07-12 | Robert Krantz Pinschmidt Jr. | Method for preparing poly(vinyl alcohol)- co-poly(vinylamine) via a two-phase process |
| US5155167A (en) * | 1988-04-15 | 1992-10-13 | Air Products And Chemicals, Inc. | Vinyl alcohol copolymers containing allylamine functionality |
| DE4016979A1 (de) * | 1990-05-25 | 1991-11-28 | Hoechst Ag | Verdickersystem fuer wasserhaltige baustoffgemische |
| DE4030638A1 (de) * | 1990-09-27 | 1992-04-02 | Wacker Chemie Gmbh | Dispersionspulverzusammensetzung |
-
1993
- 1993-06-24 DE DE4321070A patent/DE4321070A1/de not_active Withdrawn
-
1994
- 1994-06-03 TW TW083105066A patent/TW269703B/zh active
- 1994-06-15 KR KR1019940013536A patent/KR0145157B1/ko not_active Expired - Fee Related
- 1994-06-21 FI FI942979A patent/FI942979A7/fi unknown
- 1994-06-22 US US08/263,465 patent/US5567750A/en not_active Expired - Fee Related
- 1994-06-23 DE DE59400066T patent/DE59400066D1/de not_active Expired - Fee Related
- 1994-06-23 ES ES94109707T patent/ES2081723T3/es not_active Expired - Lifetime
- 1994-06-23 AT AT94109707T patent/ATE131849T1/de not_active IP Right Cessation
- 1994-06-23 EP EP94109707A patent/EP0632096B1/de not_active Expired - Lifetime
- 1994-06-23 CA CA002126586A patent/CA2126586C/en not_active Expired - Fee Related
- 1994-06-24 JP JP6164794A patent/JP2694422B2/ja not_active Expired - Lifetime
- 1994-06-24 CN CN94107822A patent/CN1075826C/zh not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100440678B1 (ko) * | 2001-12-21 | 2004-07-21 | 재단법인 포항산업과학연구원 | 산화제가 첨가된 밀스케일을 사용한 하드 페라이트의제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| FI942979A0 (fi) | 1994-06-21 |
| JPH0741632A (ja) | 1995-02-10 |
| DE4321070A1 (de) | 1995-01-05 |
| EP0632096A1 (de) | 1995-01-04 |
| JP2694422B2 (ja) | 1997-12-24 |
| US5567750A (en) | 1996-10-22 |
| CA2126586C (en) | 2000-03-28 |
| DE59400066D1 (de) | 1996-02-01 |
| ATE131849T1 (de) | 1996-01-15 |
| FI942979A7 (fi) | 1994-12-25 |
| EP0632096B1 (de) | 1995-12-20 |
| KR0145157B1 (ko) | 1998-07-15 |
| ES2081723T3 (es) | 1996-03-16 |
| CN1075826C (zh) | 2001-12-05 |
| CN1103876A (zh) | 1995-06-21 |
| TW269703B (ko) | 1996-02-01 |
| CA2126586A1 (en) | 1994-12-25 |
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