KR970061802A - 흑색 유리 프릿, 이의 제조방법 및 이의 용도 - Google Patents

흑색 유리 프릿, 이의 제조방법 및 이의 용도 Download PDF

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KR970061802A
KR970061802A KR1019970004336A KR19970004336A KR970061802A KR 970061802 A KR970061802 A KR 970061802A KR 1019970004336 A KR1019970004336 A KR 1019970004336A KR 19970004336 A KR19970004336 A KR 19970004336A KR 970061802 A KR970061802 A KR 970061802A
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mol
glass frit
less
glass
sulfur
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KR100478551B1 (ko
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게르하르트 튄커
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메르크 볼프강, 빈더 폴커
체르덱 아크티엔게젤샤프트 케라미쉐 파르벤
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Assigned to 페로 게엠베하 reassignment 페로 게엠베하 권리의 전부이전등록 Assignors: 우미코레 아게 운트 코 카게
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00—Glasses, glazes or enamels with special properties

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

흑색 유리 도료 조성물 제조를 위해 일반적인 유리 프릿을 사용하는 경우 상당히 다량의 흑색 안료를 사용해야 한다. 본 발명에 따르는 흑색 유리 프릿을 사용하여 사용되는 안료의 양을 감소시킬 수 있는데, 흑색 유리 프릿의 박층은 투과도가 낮다.
본 발명에 따르는 유리 프릿은 흑색이며, 유리 조성물에는 다음 성분이 함유도된다: K2O 10 내지 17몰%, B2O310 내지 25몰%, TiO215 내지 30몰%, SiO230 내지 55몰%,Al2O30 내지 5몰%, Bi2O30 내지 5몰%, Fe2O3(전체 철) 0.05 내지 3몰% 및 황(전체 황) 0.1 내지 3몰%.

Description

흑색 유리 프릿, 이의 제조방법 및 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 유리 조성물 속에K2O 10 내지 17몰%, B2O310 내지 25몰%, TiO215 내지 30몰%, SiO230 내지 55몰%,Al2O30 내지 5몰%, Bi2O30 내지 5몰%, Fe2O30.05 내지 3(전체 철)몰% 및 S 0.1 내지 3(전체 황)몰%와 PbO, CdO, ZnO,Li2O, Na2O, MgO, CaO, SrO, BaO 및 P2O5(이들 각각의 양은 0.5중량% 미만이다)로부터 선택된 산화물을 함유하는 흑색 유리 프릿.
  2. 제1항에 있어서, Fe2O30.1 내지 1몰%와 S 0.1 내지 2몰%를 함유함을 특징으로 하는 유리 프릿.
  3. 제1항 또는 제2항에 있어서, K2O 13 내지 16몰%, B2O318 내지 23몰%, TiO217 내지 25몰%, SiO235 내지 50몰%, Fe2O30.1 내지 1몰%, S 0.1 내지 2몰% 및 Bi2O30 내지 3몰%와 3중량%미만의 기타 금속 산화물을 특징으로 하는 유리 프릿.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 4분 동안 소성시키는 동안에 최저 용융 온도 TS가 650℃미만, 바람직하게는 590 내지 620℃의 범위임을 특징으로 하는 유리 프릿.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 30㎛두께의 소부처리된 유리 층에 대한 투과도가 2%미만임을 특징으로 하는 유리 프릿.
  6. K2O 10 내지 17몰%, B2O310 내지 25몰%, TiO215 내지 30몰%, SiO230 내지 55몰%, Al2O30 내지 5몰%, Bi2O30 내지 5몰% 및 Fe2O30.05 내지 3몰%와 PbO, CdO, ZnO, Li2O, Na2O, MgO, CaO, SrO, BaO 및 P2O5로부터 선택된 산화물 (이들 각각의 양은 유리 프릿의 0.5중량% 미만이다)을 함유하는 통상의 금속 산화물 형성 유리 원료와 추가로 유리 프릿 속에 잔류하는 양을 초과하는 0.1 내지 3몰%의 황 공급원과의 혼합물을 1000 내지 1200℃에서 환원 조건하에서 용융시키고, 용융물을 급냉시킨 후, 수득한 취성 재료를 분쇄함을 특징으로 하여, 제1항에 따르는 조성물을 포함하는 흑색 유리 프릿을 제조하는 방법.
  7. 제6항에 있어서, 용융되는 혼합물이 황 공급원으로서 원소 황을 함유하고 용융 장치 내의 기체가 환원됨을 특징으로 하는 제조방법.
  8. 제6항 또는 제7항에 있어서, 용융되는 혼합물이 탄소를 추가로 함유함을 특징으로 하는 방법.
  9. 소부성 기재 위의 유리 에나멜 또는 화장 마무리층을 형성시키기 위한, 제1항에 따르는 흑색 유리 프릿의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970004336A 1996-02-15 1997-02-14 흑색유리프릿,이의제조방법및이를사용하는유리에나멜또는장식용마감층의형성방법 Expired - Lifetime KR100478551B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19605617A DE19605617A1 (de) 1996-02-15 1996-02-15 Schwarze Glasfritte, Verfahren zu ihrer Herstellung und deren Verwendung
DE19605617.9 1996-02-15

Publications (2)

Publication Number Publication Date
KR970061802A true KR970061802A (ko) 1997-09-12
KR100478551B1 KR100478551B1 (ko) 2005-08-05

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KR1019970004336A Expired - Lifetime KR100478551B1 (ko) 1996-02-15 1997-02-14 흑색유리프릿,이의제조방법및이를사용하는유리에나멜또는장식용마감층의형성방법

Country Status (7)

Country Link
US (1) US5710081A (ko)
EP (1) EP0790220B1 (ko)
JP (1) JP4014684B2 (ko)
KR (1) KR100478551B1 (ko)
AT (1) ATE171925T1 (ko)
DE (2) DE19605617A1 (ko)
ES (1) ES2125112T3 (ko)

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WO2021107707A1 (en) * 2019-11-29 2021-06-03 Saint-Gobain Glass France Chemically durable, low-e coating compatible black enamel compositions

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DE19502653A1 (de) * 1995-01-28 1996-08-01 Cerdec Ag Bleifreie Glaszusammensetzung und deren Verwendung
GB9713169D0 (en) * 1997-06-23 1997-08-27 Cookson Matthey Ceramics Plc Glass frit
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US6534340B1 (en) * 1998-11-18 2003-03-18 Analog Devices, Inc. Cover cap for semiconductor wafer devices
US6105394A (en) * 1999-01-12 2000-08-22 Ferro Corporation Glass enamel for automotive applications
ES2161193B1 (es) * 2000-03-30 2002-06-16 Vidres S A Vidresa Formulacion y procedimiento para la obtencion de efectos metalicos en baldosas ceramicas y sus aplicaciones.
JP2003083689A (ja) * 2001-09-13 2003-03-19 Alstom (Swiss) Ltd 回転再生式熱交換装置
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US7832233B2 (en) * 2005-05-18 2010-11-16 Ferro Corporation Method of making staged burnout enamels for second surface firing of multilayer glass structures
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CN103011605A (zh) * 2012-12-10 2013-04-03 彩虹集团公司 一种汽车玻璃油墨用无铅玻璃粉及其制备方法
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JP6258976B2 (ja) 2013-02-26 2018-01-10 コーニング インコーポレイテッド イオン交換プロセスに適合した装飾用多孔性無機層を表面に有する強化ガラス物品
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JP7117928B2 (ja) * 2018-07-27 2022-08-15 日本山村硝子株式会社 結晶性ガラス封止材及びその製造方法
JP6897704B2 (ja) * 2019-03-29 2021-07-07 Tdk株式会社 黒色マーク組成物およびこれを用いた電子部品
CN113924278A (zh) 2019-04-16 2022-01-11 康宁公司 用于离子交换和汽车玻璃的填充孔装饰层
KR102602111B1 (ko) * 2019-04-24 2023-11-13 쌩-고벵 글래스 프랑스 유리 프릿, 이로부터 형성된 흑색 에나멜 코팅을 포함하는 코팅 물품, 및 코팅 물품의 제조 방법
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Publication number Priority date Publication date Assignee Title
WO2021107707A1 (en) * 2019-11-29 2021-06-03 Saint-Gobain Glass France Chemically durable, low-e coating compatible black enamel compositions
KR20210067331A (ko) * 2019-11-29 2021-06-08 쌩-고벵 글래스 프랑스 화학적 내구성이 있고 로이(Low-E) 코팅과 사용하기에 적합한 흑색 에나멜 조성물

Also Published As

Publication number Publication date
US5710081A (en) 1998-01-20
ES2125112T3 (es) 1999-02-16
JP4014684B2 (ja) 2007-11-28
DE59700025D1 (de) 1998-11-12
ATE171925T1 (de) 1998-10-15
EP0790220A1 (de) 1997-08-20
KR100478551B1 (ko) 2005-08-05
DE19605617A1 (de) 1997-08-21
EP0790220B1 (de) 1998-10-07
JPH09221337A (ja) 1997-08-26

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