LU82905A1 - Procede et compositions pour la preparation de polymeres et de copolymeres de chlorure de vinyle - Google Patents

Procede et compositions pour la preparation de polymeres et de copolymeres de chlorure de vinyle Download PDF

Info

Publication number: LU82905A1
Authority: LU; Luxembourg
Prior art keywords: polymerization; vinyl chloride; chloride; butyl; peroxyesters
Prior art date: 1979-12-21

Application number

LU82905A

Other languages

English (en)

French (fr)

Inventor

N Gaylord

Original Assignee

Dart Ind Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-21

Filing date

1980-10-31

Publication date

1981-03-24

1980-10-31 Application filed by Dart Ind Inc filed Critical Dart Ind Inc

1981-03-24 Publication of LU82905A1 publication Critical patent/LU82905A1/fr

Links

BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 31
238000000034 method Methods 0.000 title claims description 21
229920000642 polymer Polymers 0.000 title claims description 12
230000008569 process Effects 0.000 title claims description 10
239000000203 mixture Substances 0.000 title claims description 8
229920001577 copolymer Polymers 0.000 title claims description 5
238000002360 preparation method Methods 0.000 title claims description 5
238000006116 polymerization reaction Methods 0.000 claims description 28
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims description 21
229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 21
239000001119 stannous chloride Substances 0.000 claims description 21
235000011150 stannous chloride Nutrition 0.000 claims description 21
150000001875 compounds Chemical class 0.000 claims description 14
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 12
238000010557 suspension polymerization reaction Methods 0.000 claims description 11
239000012933 diacyl peroxide Substances 0.000 claims description 10
230000003197 catalytic effect Effects 0.000 claims description 6
-1 aromatic carboxylic acids Chemical class 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims 1
125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 23
239000003638 chemical reducing agent Substances 0.000 description 14
238000006243 chemical reaction Methods 0.000 description 13
239000000178 monomer Substances 0.000 description 10
239000000243 solution Substances 0.000 description 10
239000003054 catalyst Substances 0.000 description 9
229960000583 acetic acid Drugs 0.000 description 8
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
150000002978 peroxides Chemical class 0.000 description 5
229920000915 polyvinyl chloride Polymers 0.000 description 5
239000004800 polyvinyl chloride Substances 0.000 description 5
150000003254 radicals Chemical class 0.000 description 5
239000000725 suspension Substances 0.000 description 5
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 5
125000000217 alkyl group Chemical group 0.000 description 4
125000003710 aryl alkyl group Chemical group 0.000 description 4
FWPIDFUJEMBDLS-UHFFFAOYSA-L tin(II) chloride dihydrate Chemical compound O.O.Cl[Sn]Cl FWPIDFUJEMBDLS-UHFFFAOYSA-L 0.000 description 4
239000004342 Benzoyl peroxide Substances 0.000 description 3
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
235000019400 benzoyl peroxide Nutrition 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
239000003999 initiator Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 3
238000003860 storage Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000000375 suspending agent Substances 0.000 description 3
238000004448 titration Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
108010010803 Gelatin Proteins 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000012662 bulk polymerization Methods 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000011790 ferrous sulphate Substances 0.000 description 2
239000012634 fragment Substances 0.000 description 2
239000008273 gelatin Substances 0.000 description 2
229920000159 gelatin Polymers 0.000 description 2
235000019322 gelatine Nutrition 0.000 description 2
235000011852 gelatine desserts Nutrition 0.000 description 2
150000002430 hydrocarbons Chemical group 0.000 description 2
230000006698 induction Effects 0.000 description 2
229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
RQHGZNBWBKINOY-PLNGDYQASA-N (z)-4-tert-butylperoxy-4-oxobut-2-enoic acid Chemical compound CC(C)(C)OOC(=O)\C=C/C(O)=O RQHGZNBWBKINOY-PLNGDYQASA-N 0.000 description 1
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
AYMDJPGTQFHDSA-UHFFFAOYSA-N 1-(2-ethenoxyethoxy)-2-ethoxyethane Chemical compound CCOCCOCCOC=C AYMDJPGTQFHDSA-UHFFFAOYSA-N 0.000 description 1
WMKGMCCZGTXXQU-UHFFFAOYSA-N 2,3-benzodioxine-1,4-dione Chemical compound C1=CC=C2C(=O)OOC(=O)C2=C1 WMKGMCCZGTXXQU-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 1
SZFABAXZLWVKDV-UHFFFAOYSA-N 2-methyloctanoyl 2-methyloctaneperoxoate Chemical compound CCCCCCC(C)C(=O)OOC(=O)C(C)CCCCCC SZFABAXZLWVKDV-UHFFFAOYSA-N 0.000 description 1
FITCNIVIIJXTTC-UHFFFAOYSA-N 2-tert-butylperoxycarbonylbenzenecarboperoxoic acid Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)OO FITCNIVIIJXTTC-UHFFFAOYSA-N 0.000 description 1
HYKDWGUFDOYDGV-UHFFFAOYSA-N 4-anilinobenzenesulfonic acid Chemical compound C1=CC(S(=O)(=O)O)=CC=C1NC1=CC=CC=C1 HYKDWGUFDOYDGV-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
229920003091 Methocel™ Polymers 0.000 description 1
229920001214 Polysorbate 60 Polymers 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
JUIBLDFFVYKUAC-UHFFFAOYSA-N [5-(2-ethylhexanoylperoxy)-2,5-dimethylhexan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C(CC)CCCC JUIBLDFFVYKUAC-UHFFFAOYSA-N 0.000 description 1
TVGUQRIOHQCGEW-UHFFFAOYSA-N [Co].CCC(C)=O Chemical compound [Co].CCC(C)=O TVGUQRIOHQCGEW-UHFFFAOYSA-N 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
229940037003 alum Drugs 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000000872 buffer Substances 0.000 description 1
NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
UPIWXMRIPODGLE-UHFFFAOYSA-N butyl benzenecarboperoxoate Chemical group CCCCOOC(=O)C1=CC=CC=C1 UPIWXMRIPODGLE-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Substances Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
229960003280 cupric chloride Drugs 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 description 1
XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
229910001448 ferrous ion Inorganic materials 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
QTNBSPSKSFNSNU-UHFFFAOYSA-N hexyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOCCCCCC QTNBSPSKSFNSNU-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000009434 installation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
150000002506 iron compounds Chemical class 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
150000002976 peresters Chemical class 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
229940099427 potassium bisulfite Drugs 0.000 description 1
235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
239000001230 potassium iodate Substances 0.000 description 1
JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 description 1
229940093930 potassium iodate Drugs 0.000 description 1
235000006666 potassium iodate Nutrition 0.000 description 1
239000000047 product Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
229940001584 sodium metabisulfite Drugs 0.000 description 1
JXHZRQHZVYDRGX-UHFFFAOYSA-M sodium;hydrogen sulfate;hydrate Chemical compound [OH-].[Na+].OS(O)(=O)=O JXHZRQHZVYDRGX-UHFFFAOYSA-M 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
239000001587 sorbitan monostearate Substances 0.000 description 1
235000011076 sorbitan monostearate Nutrition 0.000 description 1
229940035048 sorbitan monostearate Drugs 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
UWNNZXDNLPNGQJ-UHFFFAOYSA-N tert-butyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC(C)(C)C UWNNZXDNLPNGQJ-UHFFFAOYSA-N 0.000 description 1
NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Polymerisation Methods In General (AREA)

LU82905A 1979-12-21 1980-10-31 Procede et compositions pour la preparation de polymeres et de copolymeres de chlorure de vinyle LU82905A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/106,333 US4269958A (en)	1979-12-21	1979-12-21	Peroxygen compound-stannous chloride redox catalyst system for suspension polymerization of vinyl chloride
US10633379		1979-12-21

Publications (1)

Publication Number	Publication Date
LU82905A1 true LU82905A1 (fr)	1981-03-24

Family

ID=22310856

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LU82905A LU82905A1 (fr)	1979-12-21	1980-10-31	Procede et compositions pour la preparation de polymeres et de copolymeres de chlorure de vinyle

Country Status (14)

Country	Link
US (1)	US4269958A (es)
JP (1)	JPS5693714A (es)
BE (1)	BE886228A (es)
BR (1)	BR8007777A (es)
CA (1)	CA1167199A (es)
DE (1)	DE3048080A1 (es)
ES (1)	ES8200907A1 (es)
FR (1)	FR2471989A1 (es)
GB (1)	GB2065680B (es)
IT (1)	IT1151046B (es)
LU (1)	LU82905A1 (es)
NL (1)	NL8006906A (es)
NO (1)	NO803575L (es)
SE (1)	SE8009014L (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
MY166897A (en) *	2011-09-09	2018-07-24	Gaba Int Holding Ag	Stable compositions and methods for preparing the same
CN110128593A (zh) *	2019-05-28	2019-08-16	桂林理工大学	离子液体中合成蔗渣木聚糖香草酸酯-g-HEMA/MAA的方法

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US3487062A (en) *	1966-11-16	1969-12-30	Du Pont	Synergistic accelerator for t-butyl permaleic acid in methacrylate polymerization
US3668194A (en) *	1966-12-14	1972-06-06	Borden Inc	Suspension polymerization of pvc polymers and copolymers at reduced temperatures
FR2029113A6 (en) *	1969-01-10	1970-10-16	Pechiney Saint Gobain	Vinyl chloride based polymers prodn - using organo Al or organo Ti based catalyst
NL7101997A (es) *	1970-02-16	1971-08-18

1979
- 1979-12-21 US US06/106,333 patent/US4269958A/en not_active Expired - Lifetime
1980
- 1980-10-30 FR FR8023235A patent/FR2471989A1/fr active Granted
- 1980-10-31 CA CA000363676A patent/CA1167199A/en not_active Expired
- 1980-10-31 LU LU82905A patent/LU82905A1/fr unknown
- 1980-11-18 BE BE0/202848A patent/BE886228A/fr not_active IP Right Cessation
- 1980-11-26 NO NO803575A patent/NO803575L/no unknown
- 1980-11-27 BR BR8007777A patent/BR8007777A/pt unknown
- 1980-12-16 GB GB8040204A patent/GB2065680B/en not_active Expired
- 1980-12-16 JP JP17663280A patent/JPS5693714A/ja active Pending
- 1980-12-19 SE SE8009014A patent/SE8009014L/xx not_active Application Discontinuation
- 1980-12-19 DE DE19803048080 patent/DE3048080A1/de not_active Withdrawn
- 1980-12-19 IT IT26833/80A patent/IT1151046B/it active
- 1980-12-19 ES ES497961A patent/ES8200907A1/es not_active Expired
- 1980-12-19 NL NL8006906A patent/NL8006906A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
IT1151046B (it)	1986-12-17
DE3048080A1 (de)	1981-09-24
NO803575L (no)	1981-06-22
ES497961A0 (es)	1981-11-16
SE8009014L (sv)	1981-06-22
BR8007777A (pt)	1981-06-23
US4269958A (en)	1981-05-26
GB2065680A (en)	1981-07-01
ES8200907A1 (es)	1981-11-16
NL8006906A (nl)	1981-07-16
JPS5693714A (en)	1981-07-29
FR2471989A1 (fr)	1981-06-26
BE886228A (fr)	1981-03-16
GB2065680B (en)	1983-09-28
FR2471989B1 (es)	1983-02-11
IT8026833A0 (it)	1980-12-19
CA1167199A (en)	1984-05-08

Publication	Publication Date	Title
US2911398A (en)	1959-11-03	Polymer hydroperoxides
US3637633A (en)	1972-01-25	Peroxy compounds
NO138336B (no)	1978-05-08	Analogifremgangsmaate for fremstilling av terapeutisk aktive benzofuranderivater
EP1383809B1 (fr)	2005-07-06	Polymerisation en suspension aqueuse de chlorure de vinyle
LU82891A1 (fr)	1981-03-24	Compositions et procede pour la preparation de polymeres et de copolymeres de monomeres ethyleniquement insatures
FR2471989A1 (fr)	1981-06-26	Procede et compositions pour la preparation de polymeres et de copolymeres de chlorure de vinyle
US3652522A (en)	1972-03-28	Process for the polymerization of vinyl chloride
US5145923A (en)	1992-09-08	Process for the preparation of ethylene/vinyl ester copolymers
FR2471988A1 (fr)	1981-06-26	Catalyseurs et procede pour la preparation de polymeres et de copolymeres de monomeres ethyleniquement insatures
LU82908A1 (fr)	1981-03-24	Catalyseurs et procede pour la preparation de polymeres et de copolymeres de chlorure de vinyle
US4543401A (en)	1985-09-24	Peroxygen compound-isoascorbic acid redox catalyst system for suspension polymerization of vinyl chloride
FR2471987A1 (fr)	1981-06-26	Catalyseurs et procede pour la preparation de polymeres et de copolymeres d'halogenures de vinyle
LU82920A1 (fr)	1981-03-26	Compositions et procede de preparation de polymeres et de copolymeres de chlorure de vinyle
US3141010A (en)	1964-07-14	Process for the manufacture of vinyl ester polymers and copolymers
US3637623A (en)	1972-01-25	Polymerization of vinyl chloride in bulk and at low temperatures
US6649788B2 (en)	2003-11-18	Preparation of polyethylene waxes
US3232922A (en)	1966-02-01	Novel diacyl peroxides and polymerization processes employing same
RU2026307C1 (ru)	1995-01-09	Способ получения сополимеров изобутилена и полярного винилового мономера
US3127383A (en)	1964-03-31	x xocor
US7741524B2 (en)	2010-06-22	Iodinated organic substances of low molecular mass and process for preparing them
JPH1025310A (ja)	1998-01-27	重合開始剤組成物及びそれを用いるビニル系単量体の重合方法
US3645998A (en)	1972-02-29	Method of producing polyvinyl fluoride in an aqueous medium in the presence of a catalyst system of tri-alkyl boron and hydrogen peroxide
CA1178747A (en)	1984-11-27	Vinyl halide polymer of enhanced plasticizer uptake
EP4630461A1 (fr)	2025-10-15	Utilisation d'au moins un perester pour amorcer la polymerisation ou la copolymerisation d'ethylene sous haute pression
FR2858319A1 (fr)	2005-02-04	Procede de preparation de substances organiques iodees de faible masse moleculaire et substances organiques iodees de faible masse moleculaire