LV12016B - ANALYZE CESIA FOR SALT - Google Patents

ANALYZE CESIA FOR SALT Download PDF

Info

Publication number: LV12016B
Authority: LV; Latvia
Prior art keywords: cesium; less; calcium; parts; salt
Prior art date: 1995-04-06

Application number

LVP-97-213A

Other languages

English (en)

Latvian (lv)

Other versions

LV12016A (lv

Inventor

Bart F. BAKKE

Patrick M. Brown

Michael C. NORTHRUP

Original Assignee

Cabot Corporation

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-04-06

Filing date

1997-10-28

Publication date

1998-06-20

1997-10-28 Application filed by Cabot Corporation filed Critical Cabot Corporation

1998-04-20 Publication of LV12016A publication Critical patent/LV12016A/xx

1998-06-20 Publication of LV12016B publication Critical patent/LV12016B/en

Links

150000003839 salts Chemical class 0.000 title claims abstract description 15
MXBCYQUALCBQIJ-RYVPXURESA-N (8s,9s,10r,13s,14s,17r)-13-ethyl-17-ethynyl-11-methylidene-1,2,3,6,7,8,9,10,12,14,15,16-dodecahydrocyclopenta[a]phenanthren-17-ol;(8r,9s,13s,14s,17r)-17-ethynyl-13-methyl-7,8,9,11,12,14,15,16-octahydro-6h-cyclopenta[a]phenanthrene-3,17-diol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.C1CC[C@@H]2[C@H]3C(=C)C[C@](CC)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 MXBCYQUALCBQIJ-RYVPXURESA-N 0.000 title 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 121
-1 sulfate anions Chemical class 0.000 claims abstract description 111
238000000034 method Methods 0.000 claims abstract description 105
239000002253 acid Substances 0.000 claims abstract description 69
239000011575 calcium Substances 0.000 claims abstract description 53
239000012535 impurity Substances 0.000 claims abstract description 51
239000000203 mixture Substances 0.000 claims abstract description 51
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 47
VHUJINUACVEASK-UHFFFAOYSA-J aluminum;cesium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VHUJINUACVEASK-UHFFFAOYSA-J 0.000 claims abstract description 45
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 42
229910052791 calcium Inorganic materials 0.000 claims abstract description 41
229910001424 calcium ion Inorganic materials 0.000 claims abstract description 37
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims abstract description 35
229910052749 magnesium Inorganic materials 0.000 claims abstract description 30
229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 28
238000005553 drilling Methods 0.000 claims abstract description 20
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims abstract description 19
229910001863 barium hydroxide Inorganic materials 0.000 claims abstract description 17
239000000243 solution Substances 0.000 claims abstract 9
239000012266 salt solution Substances 0.000 claims abstract 4
229910052792 caesium Inorganic materials 0.000 claims description 134
ATZQZZAXOPPAAQ-UHFFFAOYSA-M caesium formate Chemical compound [Cs+].[O-]C=O ATZQZZAXOPPAAQ-UHFFFAOYSA-M 0.000 claims description 58
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 42
NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 claims description 40
239000011777 magnesium Substances 0.000 claims description 37
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 29
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 26
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 24
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 23
239000002244 precipitate Substances 0.000 claims description 23
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 21
235000010216 calcium carbonate Nutrition 0.000 claims description 21
XQPRBTXUXXVTKB-UHFFFAOYSA-M caesium iodide Chemical compound [I-].[Cs+] XQPRBTXUXXVTKB-UHFFFAOYSA-M 0.000 claims description 14
239000011734 sodium Substances 0.000 claims description 14
239000001569 carbon dioxide Substances 0.000 claims description 13
229910002092 carbon dioxide Inorganic materials 0.000 claims description 13
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 12
229910001425 magnesium ion Inorganic materials 0.000 claims description 12
AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 claims description 11
235000019253 formic acid Nutrition 0.000 claims description 11
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 10
LYQFWZFBNBDLEO-UHFFFAOYSA-M caesium bromide Chemical compound [Br-].[Cs+] LYQFWZFBNBDLEO-UHFFFAOYSA-M 0.000 claims description 10
239000004571 lime Substances 0.000 claims description 10
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 claims description 9
229910052708 sodium Inorganic materials 0.000 claims description 9
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
239000011591 potassium Substances 0.000 claims description 7
229910052700 potassium Inorganic materials 0.000 claims description 7
WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 claims description 5
239000004280 Sodium formate Substances 0.000 claims description 3
150000004675 formic acid derivatives Chemical class 0.000 claims description 3
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 3
235000019254 sodium formate Nutrition 0.000 claims description 3
229910021653 sulphate ion Inorganic materials 0.000 claims 10
235000012204 lemonade/lime carbonate Nutrition 0.000 claims 2
229910052751 metal Inorganic materials 0.000 claims 2
239000002184 metal Substances 0.000 claims 2
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 27
239000000920 calcium hydroxide Substances 0.000 abstract description 27
235000011116 calcium hydroxide Nutrition 0.000 abstract description 27
229910001861 calcium hydroxide Inorganic materials 0.000 abstract description 27
229910052782 aluminium Inorganic materials 0.000 abstract description 23
239000000463 material Substances 0.000 abstract description 21
229910052788 barium Inorganic materials 0.000 abstract description 19
239000012530 fluid Substances 0.000 abstract description 18
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 10
239000007787 solid Substances 0.000 abstract description 9
125000002091 cationic group Chemical group 0.000 abstract description 6
230000005484 gravity Effects 0.000 abstract description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 3
FLJPGEWQYJVDPF-UHFFFAOYSA-L caesium sulfate Chemical compound [Cs+].[Cs+].[O-]S([O-])(=O)=O FLJPGEWQYJVDPF-UHFFFAOYSA-L 0.000 description 91
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
239000002585 base Substances 0.000 description 26
238000004519 manufacturing process Methods 0.000 description 21
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 20
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 18
239000000706 filtrate Substances 0.000 description 16
150000001450 anions Chemical class 0.000 description 15
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 15
150000002500 ions Chemical class 0.000 description 15
150000001875 compounds Chemical class 0.000 description 14
239000003513 alkali Substances 0.000 description 13
150000007513 acids Chemical class 0.000 description 12
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 12
238000001914 filtration Methods 0.000 description 12
229910001744 pollucite Inorganic materials 0.000 description 12
238000000926 separation method Methods 0.000 description 11
239000002002 slurry Substances 0.000 description 11
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 10
239000000347 magnesium hydroxide Substances 0.000 description 10
229910001862 magnesium hydroxide Inorganic materials 0.000 description 10
235000012254 magnesium hydroxide Nutrition 0.000 description 10
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 10
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
229910001422 barium ion Inorganic materials 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 8
235000008733 Citrus aurantifolia Nutrition 0.000 description 8
235000011941 Tilia x europaea Nutrition 0.000 description 8
238000007792 addition Methods 0.000 description 8
229910000024 caesium carbonate Inorganic materials 0.000 description 8
230000029087 digestion Effects 0.000 description 8
239000000126 substance Substances 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000000292 calcium oxide Substances 0.000 description 6
238000002156 mixing Methods 0.000 description 6
229910000027 potassium carbonate Inorganic materials 0.000 description 6
230000001376 precipitating effect Effects 0.000 description 6
238000001556 precipitation Methods 0.000 description 6
239000000047 product Substances 0.000 description 6
229910000029 sodium carbonate Inorganic materials 0.000 description 6
YRAMACNQEYDINL-UHFFFAOYSA-J aluminum;cesium;disulfate Chemical group [Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YRAMACNQEYDINL-UHFFFAOYSA-J 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 5
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 5
230000001419 dependent effect Effects 0.000 description 5
230000000737 periodic effect Effects 0.000 description 5
FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 4
150000004649 carbonic acid derivatives Chemical class 0.000 description 4
238000004090 dissolution Methods 0.000 description 4
238000000605 extraction Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000005498 polishing Methods 0.000 description 4
238000000746 purification Methods 0.000 description 4
VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
229910052925 anhydrite Inorganic materials 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 2
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
239000004281 calcium formate Substances 0.000 description 2
229940044172 calcium formate Drugs 0.000 description 2
235000019255 calcium formate Nutrition 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
238000010586 diagram Methods 0.000 description 2
239000000284 extract Substances 0.000 description 2
229910001679 gibbsite Inorganic materials 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
235000010755 mineral Nutrition 0.000 description 2
239000011707 mineral Substances 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
229940102001 zinc bromide Drugs 0.000 description 2
ABJSOROVZZKJGI-OCYUSGCXSA-N (1r,2r,4r)-2-(4-bromophenyl)-n-[(4-chlorophenyl)-(2-fluoropyridin-4-yl)methyl]-4-morpholin-4-ylcyclohexane-1-carboxamide Chemical compound C1=NC(F)=CC(C(NC(=O)[C@H]2[C@@H](C[C@@H](CC2)N2CCOCC2)C=2C=CC(Br)=CC=2)C=2C=CC(Cl)=CC=2)=C1 ABJSOROVZZKJGI-OCYUSGCXSA-N 0.000 description 1
QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 1
101100381997 Danio rerio tbc1d32 gene Proteins 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
241000820057 Ithone Species 0.000 description 1
229910019440 Mg(OH) Inorganic materials 0.000 description 1
101100381999 Mus musculus Tbc1d32 gene Proteins 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
DAVHLQQWTZJAGY-UHFFFAOYSA-M [Br-].Br.[Cs+] Chemical compound [Br-].Br.[Cs+] DAVHLQQWTZJAGY-UHFFFAOYSA-M 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
238000000184 acid digestion Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000001553 barium compounds Chemical class 0.000 description 1
159000000009 barium salts Chemical class 0.000 description 1
UXFOSWFWQAUFFZ-UHFFFAOYSA-L barium(2+);diformate Chemical compound [Ba+2].[O-]C=O.[O-]C=O UXFOSWFWQAUFFZ-UHFFFAOYSA-L 0.000 description 1
229910001864 baryta Inorganic materials 0.000 description 1
238000009835 boiling Methods 0.000 description 1
NCMHKCKGHRPLCM-UHFFFAOYSA-N caesium(1+) Chemical compound [Cs+] NCMHKCKGHRPLCM-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
159000000006 cesium salts Chemical class 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
229940044170 formate Drugs 0.000 description 1
238000004442 gravimetric analysis Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000002386 leaching Methods 0.000 description 1
229910052808 lithium carbonate Inorganic materials 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
238000005580 one pot reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
235000007686 potassium Nutrition 0.000 description 1
229940088417 precipitated calcium carbonate Drugs 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000010909 process residue Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
229910000026 rubidium carbonate Inorganic materials 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
238000007514 turning Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/14—Clay-containing compositions
- C09K8/16—Clay-containing compositions characterised by the inorganic compounds other than clay
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Dispersion Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Compounds Of Unknown Constitution (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Cephalosporin Compounds (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Manufacture And Refinement Of Metals (AREA)
Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

LVP-97-213A 1995-04-06 1997-10-28 ANALYZE CESIA FOR SALT LV12016B (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US41756295A	1995-04-06	1995-04-06
US41756395A	1995-04-06	1995-04-06
PCT/US1996/004687 WO1996031435A1 (en)	1995-04-06	1996-04-05	Process for the production of cesium compounds

Publications (2)

Publication Number	Publication Date
LV12016A LV12016A (lv)	1998-04-20
LV12016B true LV12016B (en)	1998-06-20

Family

ID=27023771

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LVP-97-213A LV12016B (en)	1995-04-06	1997-10-28	ANALYZE CESIA FOR SALT

Country Status (15)

Country	Link
EP (2)	EP1254942A3 (de)
JP (1)	JP3920333B2 (de)
CN (2)	CN1295295C (de)
AT (1)	ATE246148T1 (de)
AU (1)	AU709994B2 (de)
BR (1)	BR9604937A (de)
CA (1)	CA2217343C (de)
CZ (1)	CZ296292B6 (de)
DE (1)	DE69629285T2 (de)
HU (1)	HU221823B1 (de)
LV (1)	LV12016B (de)
NO (2)	NO323650B1 (de)
PL (1)	PL322655A1 (de)
SK (1)	SK285016B6 (de)
WO (1)	WO1996031435A1 (de)

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US4734311A (en) *	1985-01-16	1988-03-29	Kimberly-Clark Corporation	Elasticized non-woven fabric and method of making the same
AU2590500A (en) *	1998-12-16	2000-07-03	Versitech, Inc.	Heavy liquids for use in separation processes
US20020033471A1 (en) *	2000-06-02	2002-03-21	Odle Thomas H.	Cesium formate containing coolant
US7211550B2 (en)	2000-07-14	2007-05-01	Cabot Corporation	Compositions for controlling scaling and completion fluids
US6818595B2 (en)	2001-02-14	2004-11-16	Cabot Specialty Fluids, Inc.	Drilling fluids containing an alkali metal formate
US6652820B2 (en) *	2001-04-02	2003-11-25	Cabot Corporation	Methods of making cesium salts and other alkali metal salts
WO2003018708A2 (en)	2001-08-10	2003-03-06	Cabot Specialty Fluids, Inc.	Alkali metal tungstate compositions and uses thereof
US6912898B2 (en) *	2003-07-08	2005-07-05	Halliburton Energy Services, Inc.	Use of cesium as a tracer in coring operations
US7407008B2 (en)	2006-05-10	2008-08-05	Cabot Specialty Fluids, Inc.	Weighted zero solids loss circulation, fluid loss and insulating annular space fluid systems
WO2009018273A1 (en) *	2007-08-02	2009-02-05	M-I Llc	Reclamation of halide-contaminated formate brines
MX344900B (es) *	2011-06-29	2017-01-09	Cabot Specialty Fluids Inc	Fluidos de perforacion de base hidrocarburos que contienen fosfato de cesio.
CA2932011C (en) *	2013-12-03	2019-12-31	Cabot Corporation	Methods to recover cesium formate from a mixed alkali metal formate blend
CN103803589B (zh) *	2014-03-04	2015-08-19	湖北百杰瑞新材料股份有限公司	一种高纯硫酸铯的制备方法
MY185382A (en)	2015-09-29	2021-05-16	Cabot Specialty Fluids Inc	Low solids oil based well fluid with particle-stabilized emulsion
CN105540621B (zh) *	2016-03-16	2017-05-03	江西东鹏新材料有限责任公司	一种生产氟化铯的方法
CN107140662B (zh) *	2017-05-05	2019-03-01	江西东鹏新材料有限责任公司	一种生产氢氧化铯的新方法
US11155895B2 (en) *	2017-07-11	2021-10-26	Albemarle Germany Gmbh	Method for obtaining cesium from aqueous starting solutions
EP3864182A4 (de) *	2018-10-10	2022-07-20	Li-Technology Pty Ltd.	Sole und verfahren zur herstellung davon
CN110256232B (zh) *	2019-06-28	2022-05-03	百杰瑞(荆门)新材料有限公司	一种甲酸铯生产方法
CN110902699B (zh) *	2019-12-27	2022-06-24	宜春市科远化工有限公司	从锂云母提锂后的废渣原料中制备高纯硫酸钾的方法
CN116375060B (zh) *	2023-02-27	2024-04-19	安徽泽升科技股份有限公司	一种碳酸铯的制备方法

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US3207571A (en) *	1962-04-09	1965-09-21	San Antonio Chemicals Inc	Process for preparing cesium compounds from cesium alum
US3489509A (en) *	1967-05-18	1970-01-13	Kewanee Oil Co	Process for recovery of cesium compounds of high purity
GB9211384D0 (en) *	1992-05-29	1992-07-15	Bp Chem Int Ltd	Aqueous brines
DE4313480C1 (de) *	1993-04-24	1994-04-14	Metallgesellschaft Ag	Verfahren zur Herstellung von Cäsiumsalzen aus Cäsium-Aluminium-Alaun

1996
- 1996-04-05 SK SK1356-97A patent/SK285016B6/sk not_active IP Right Cessation
- 1996-04-05 EP EP02016794A patent/EP1254942A3/de not_active Withdrawn
- 1996-04-05 PL PL96322655A patent/PL322655A1/xx unknown
- 1996-04-05 AT AT96912577T patent/ATE246148T1/de not_active IP Right Cessation
- 1996-04-05 CN CNB031067697A patent/CN1295295C/zh not_active Expired - Lifetime
- 1996-04-05 AU AU55350/96A patent/AU709994B2/en not_active Expired
- 1996-04-05 DE DE69629285T patent/DE69629285T2/de not_active Expired - Lifetime
- 1996-04-05 EP EP96912577A patent/EP0819098B1/de not_active Expired - Lifetime
- 1996-04-05 WO PCT/US1996/004687 patent/WO1996031435A1/en not_active Ceased
- 1996-04-05 CA CA002217343A patent/CA2217343C/en not_active Expired - Lifetime
- 1996-04-05 CZ CZ0315197A patent/CZ296292B6/cs not_active IP Right Cessation
- 1996-04-05 HU HU9900897A patent/HU221823B1/hu active IP Right Grant
- 1996-04-05 CN CN96194325A patent/CN1106345C/zh not_active Expired - Lifetime
- 1996-04-05 JP JP53049296A patent/JP3920333B2/ja not_active Expired - Fee Related
- 1996-04-05 BR BR9604937-5A patent/BR9604937A/pt not_active IP Right Cessation
1997
- 1997-10-03 NO NO19974590A patent/NO323650B1/no not_active IP Right Cessation
- 1997-10-28 LV LVP-97-213A patent/LV12016B/en unknown
2006
- 2006-02-17 NO NO20060801A patent/NO20060801L/no not_active Application Discontinuation

Also Published As

Publication number	Publication date
CZ296292B6 (cs)	2006-02-15
CN1515492A (zh)	2004-07-28
JPH11503169A (ja)	1999-03-23
DE69629285D1 (de)	2003-09-04
JP3920333B2 (ja)	2007-05-30
PL322655A1 (en)	1998-02-16
CN1106345C (zh)	2003-04-23
SK135697A3 (en)	1998-04-08
NO20060801L (no)	1997-12-03
DE69629285T2 (de)	2004-01-29
HU221823B1 (hu)	2003-01-28
BR9604937A (pt)	2000-10-24
EP1254942A2 (de)	2002-11-06
CN1186480A (zh)	1998-07-01
EP0819098B1 (de)	2003-07-30
EP1254942A3 (de)	2011-07-27
WO1996031435A1 (en)	1996-10-10
SK285016B6 (sk)	2006-04-06
NO974590D0 (no)	1997-10-03
CA2217343C (en)	2007-11-13
AU5535096A (en)	1996-10-23
CA2217343A1 (en)	1996-10-10
CZ315197A3 (cs)	1998-05-13
AU709994B2 (en)	1999-09-09
EP0819098A1 (de)	1998-01-21
ATE246148T1 (de)	2003-08-15
HUP9900897A2 (hu)	1999-07-28
NO323650B1 (no)	2007-06-18
NO974590L (no)	1997-12-03
HUP9900897A3 (en)	2000-04-28
CN1295295C (zh)	2007-01-17
LV12016A (lv)	1998-04-20

Publication	Publication Date	Title
LV12016B (en)	1998-06-20	ANALYZE CESIA FOR SALT
RU2176984C2 (ru)	2001-12-20	Способ выделения глинозема и кремнезема
US6436879B1 (en)	2002-08-20	Process for producing a predetermined cesium compound
US4215094A (en)	1980-07-29	Method for the removal of organic substances from alkali metal aluminate solution
US6113868A (en)	2000-09-05	Process for treating tungstate solutions to reduce molybdenum impurity and other impurity content
CN1042145C (zh)	1999-02-17	从含氧化铈和氟化物的固体混合物中回收铈的方法
US3760064A (en)	1973-09-18	Process for the production of neutral calcium hypochlorite crystals
US5728180A (en)	1998-03-17	Adsorbent combinations for enhanced removal of sodium oxalate from bayer process spent liquor
US4044095A (en)	1977-08-23	Process for recovery of alumina from high-silica ore
AU2003258077B2 (en)	2009-01-08	Aluminum hydroxide, made via the bayer process, with low organic carbon
US5171547A (en)	1992-12-15	Recovery of chromium in high purity state from waste materials of etching operations
JPS6036334A (ja)	1985-02-25	ポルサイトからセシウムの回収方法
US4430310A (en)	1984-02-07	Purification of impure Bayer process liquors
CA2597179C (en)	2008-06-17	Process for the production of cesium compounds
US4200618A (en)	1980-04-29	Preparation of magnesium chloride
JPS5839894B2 (ja)	1983-09-02	水溶性精錬スラグ中のリンおよびケイ素の除去方法
US3712838A (en)	1973-01-23	Regeneration of caustic liquor for etching aluminum
US3796789A (en)	1974-03-12	Removal of iron from sodium aluminate liquor
US3980754A (en)	1976-09-14	Purification of alkali carbonate containing a fluorine compound
US3211519A (en)	1965-10-12	Method of controlling sulfide concentration to prevent iron contamination in the processing of trona
JPS59199529A (ja)	1984-11-12	バイヤ−法液の精製
JPS585845B2 (ja)	1983-02-02	有機質不純物を含むアルミナ原料鉱石を処理する方法
JPS6036335A (ja)	1985-02-25	セシウムみようばんからのセシウムの回収方法
US6787120B1 (en)	2004-09-07	Volume reduction of aqueous waste by evaporative crystallization of burkeite and sodium salts
JPH0686297B2 (ja)	1994-11-02	オキシ塩化ジルコニウムの製造方法