MA32496B1 - Extration de l'uranium de l'acide phosphorique par voie humide - Google Patents
Extration de l'uranium de l'acide phosphorique par voie humideInfo
- Publication number
- MA32496B1 MA32496B1 MA33548A MA33548A MA32496B1 MA 32496 B1 MA32496 B1 MA 32496B1 MA 33548 A MA33548 A MA 33548A MA 33548 A MA33548 A MA 33548A MA 32496 B1 MA32496 B1 MA 32496B1
- Authority
- MA
- Morocco
- Prior art keywords
- phosphoric acid
- wet
- uranium
- wet phosphoric
- extration
- Prior art date
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 14
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 7
- 229910052770 Uranium Inorganic materials 0.000 title 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title 1
- 150000003671 uranium compounds Chemical class 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 238000000638 solvent extraction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G43/00—Compounds of uranium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/0278—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries by chemical methods
- C22B60/0282—Solutions containing P ions, e.g. treatment of solutions resulting from the leaching of phosphate ores or recovery of uranium from wet-process phosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/237—Selective elimination of impurities
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G43/00—Compounds of uranium
- C01G43/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G43/00—Compounds of uranium
- C01G43/01—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Removal Of Specific Substances (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
L'invention concerne un procédé permettant d'extraire des composés d'uranium à partir de l'acide phosphorique par voie humide, qui consiste notamment à abaisser la teneur en fer de l'acide phosphorique par voie humide et à réduire la valence de tout fer ferrique restant dans l'acide phosphorique par voie humide en fer ferreux, puis à extraire les composés d'uranium de l'acide phosphorique par voie humide. Le procédé peut consister notamment à séparer un flux latéral d'un flux d'alimentation de l'acide phosphorique par voie humide, le flux latéral présentant une teneur plus élevée en composés d'uranium que le flux d'alimentation par filtrage. L'extraction de composés d'uranium de l'acide phosphorique par voie humide peut se réaliser par un procédé d'échange ionique ou par extraction par solvant.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8517708P | 2008-07-31 | 2008-07-31 | |
| US16113309P | 2009-03-18 | 2009-03-18 | |
| PCT/US2009/051886 WO2010014562A2 (fr) | 2008-07-31 | 2009-07-28 | Extraction de l'uranium de l'acide phosphorique par voie humide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MA32496B1 true MA32496B1 (fr) | 2011-07-03 |
Family
ID=41608573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MA33548A MA32496B1 (fr) | 2008-07-31 | 2011-01-21 | Extration de l'uranium de l'acide phosphorique par voie humide |
Country Status (14)
| Country | Link |
|---|---|
| US (4) | US8226910B2 (fr) |
| KR (1) | KR101389877B1 (fr) |
| BR (1) | BRPI0916382A2 (fr) |
| CA (1) | CA2731170C (fr) |
| CL (1) | CL2011000128A1 (fr) |
| CO (1) | CO6362053A2 (fr) |
| IL (1) | IL210905A0 (fr) |
| JO (1) | JO2815B1 (fr) |
| MA (1) | MA32496B1 (fr) |
| MX (1) | MX2011000817A (fr) |
| PE (1) | PE20110691A1 (fr) |
| RU (1) | RU2011102292A (fr) |
| WO (1) | WO2010014562A2 (fr) |
| ZA (1) | ZA201100992B (fr) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8883096B2 (en) | 2008-07-31 | 2014-11-11 | Urtek, Llc | Extraction of uranium from wet-process phosphoric acid |
| MX2011000817A (es) | 2008-07-31 | 2011-06-01 | Urtek Llc | Extraccion de uranio a partir de acido fosforico de proceso humedo. |
| AU2013231161B2 (en) * | 2010-04-19 | 2014-04-10 | Areva Mines | Industrial extraction of uranium using ammonium carbonate and membrane separation |
| EA024078B1 (ru) * | 2010-04-19 | 2016-08-31 | Эвендж Экстракшн Текнолоджиз (Пти) Лтд. | Промышленная экстракция урана карбонатом аммония с применением мембранного разделения |
| WO2012156894A2 (fr) * | 2011-05-13 | 2012-11-22 | Synexus (Pty) Ltd | Procédé d'extraction par solvant à membrane |
| CA2854145A1 (fr) * | 2011-10-31 | 2013-05-10 | Urtek, Llc | Extraction de l'uranium de l'acide phosphorique produit par voie humide |
| US9702026B2 (en) | 2012-07-21 | 2017-07-11 | K-Technologies, Inc. | Processes for the recovery of uranium from industrial phosphoric acid using dual or single cycle continuous ion exchange approaches |
| CN103397184B (zh) * | 2013-07-31 | 2014-12-03 | 南昌航空大学 | 一种反萃取分离叔胺有机相中铀和铁的方法 |
| CN105181408A (zh) * | 2015-09-15 | 2015-12-23 | 中国原子能科学研究院 | 用于痕量铀样品预处理的双效浸取剂 |
| FR3044018B1 (fr) * | 2015-11-19 | 2017-12-22 | Areva Mines | Procedes d'extraction et de recuperation de l'uranium present dans une solution aqueuse comprenant de l'acide phosphorique |
| US11769906B2 (en) | 2017-09-14 | 2023-09-26 | Ampcera Inc. | Systems and methods for selectively extracting alkaline metals from metal-rich solutions using solid state ionic conductive electrolyte membrane |
| US11612847B2 (en) | 2018-01-31 | 2023-03-28 | Global Nuclear Fuel-Americas, Llc | Systems and methods for removing particulates of a fissile material |
| EP3623347A1 (fr) | 2018-09-17 | 2020-03-18 | Yara International ASA | Procédé d'élimination d'un contaminant à partir d'eaux usées provenant d'une installation industrielle et système permettant de mettre en uvre un tel procédé |
| EP3947286B1 (fr) * | 2019-03-29 | 2025-06-04 | The Board of Regents of The Nevada System of Higher Education on behalf of the University of Nevada, Las Vegas | Conversion d'hexafluorure d'uranium et récupération d'uranium à partir de liquides ioniques |
| EP4077219A4 (fr) | 2020-03-06 | 2024-02-21 | The Board of Regents of The Nevada System of Higher Education on behalf of the University of Nevada, Las Vegas | Récupération stoechiométrique d'uf4 à partir d'uf6 dissous dans des liquides ioniques |
| US11708286B2 (en) | 2020-08-19 | 2023-07-25 | Marmon Industrial Water Llc | High rate thickener and eductors therefor |
| WO2023083958A1 (fr) | 2021-11-12 | 2023-05-19 | Takhim For Technology And Business Services | Procédé de production d'une solution d'acide phosphorique purifiée et/ou de sels de phosphate dicalcique |
Family Cites Families (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2770520A (en) | 1950-04-11 | 1956-11-13 | Ray S Long | Recovery of uranium from phosphoric acid and phosphate solutions by ion exchange |
| US2756123A (en) | 1950-05-03 | 1956-07-24 | Richard H Bailes | Uranium-vanadium recovery and purification process |
| US2789879A (en) | 1950-11-15 | 1957-04-23 | Kaufman David | Recovery of uranium from phosphoric acid |
| US2767045A (en) | 1952-10-03 | 1956-10-16 | Robert F Mccullough | Treatment of phosphate rock to recover phosphorus and uranium values |
| US2859092A (en) | 1953-02-05 | 1958-11-04 | Richard H Bailes | Solvent extraction process for the recovery of metals from phosphoric acid |
| US2768059A (en) | 1953-06-03 | 1956-10-23 | Richard H Bailes | Process for recovery of uranium and the upgrading of alkali-uranium fluoride precipitates |
| US2743154A (en) | 1954-07-06 | 1956-04-24 | Kaufman David | Method of recovery of uranium by a resin-in-pulp process |
| US2882123A (en) | 1955-04-18 | 1959-04-14 | Ray S Long | Process for the recovery of uranium from phosphatic ore |
| US3044855A (en) | 1959-12-14 | 1962-07-17 | Collier Carbon & Chemical Co | Concentration of wet-process phosphoric acid |
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| US3711591A (en) | 1970-07-08 | 1973-01-16 | Atomic Energy Commission | Reductive stripping process for the recovery of uranium from wet-process phosphoric acid |
| US3770612A (en) | 1970-08-24 | 1973-11-06 | Allied Chem | Apparatus for electrolytic oxidation or reduction, concentration, and separation of elements in solution |
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| US3975178A (en) * | 1973-10-12 | 1976-08-17 | Tennessee Valley Authority | Purification of wet-process phosphoric acid with methanol and ammonia |
| JPS51143198A (en) | 1975-06-03 | 1976-12-09 | Asahi Chem Ind Co Ltd | New separation method |
| UST952002I4 (fr) | 1975-08-29 | 1976-11-02 | ||
| US4105741A (en) | 1976-03-08 | 1978-08-08 | Freeport Minerals Company | Process for recovery of uranium from wet process phosphoric acid |
| DE2719701C3 (de) * | 1976-05-06 | 1986-10-02 | W.R. Grace & Co., New York, N.Y. | Verfahren zur Überführung von Naßphosphorsäure in eine nicht zu Ausfällungen neigende konzentrierte Phosphorsäure |
| US4371504A (en) * | 1977-02-28 | 1983-02-01 | Uranium Recovery Corporation | Extractant and process for extracting uranium wet-process phosphoric acid |
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| US5787332A (en) | 1996-09-26 | 1998-07-28 | Fansteel Inc. | Process for recovering tantalum and/or niobium compounds from composites containing a variety of metal compounds |
| US5809394A (en) | 1996-12-13 | 1998-09-15 | Battelle Memorial Institute | Methods of separating short half-life radionuclides from a mixture of radionuclides |
| US5787322A (en) | 1997-04-11 | 1998-07-28 | Xerox Corporation | Multifunction customer replaceable unit latch |
| WO2000073539A1 (fr) * | 1999-05-28 | 2000-12-07 | Juzer Jangbarwala | Cellule d'extraction electrique comportant un appareil de filtrage des ions metalliques |
| US6303090B1 (en) | 2000-05-17 | 2001-10-16 | The United States Of America As Represented By The United States Department Of Energy | Conversion of depleted uranium hexafluoride to a solid uranium compound |
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| MX2011000817A (es) | 2008-07-31 | 2011-06-01 | Urtek Llc | Extraccion de uranio a partir de acido fosforico de proceso humedo. |
| US8883096B2 (en) * | 2008-07-31 | 2014-11-11 | Urtek, Llc | Extraction of uranium from wet-process phosphoric acid |
| US8506911B2 (en) | 2009-07-29 | 2013-08-13 | Battelle Memorial Institute | Compositions and methods for treating nuclear fuel |
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2009
- 2009-07-28 MX MX2011000817A patent/MX2011000817A/es active IP Right Grant
- 2009-07-28 KR KR1020117003952A patent/KR101389877B1/ko not_active Expired - Fee Related
- 2009-07-28 BR BRPI0916382A patent/BRPI0916382A2/pt not_active IP Right Cessation
- 2009-07-28 US US12/510,294 patent/US8226910B2/en active Active
- 2009-07-28 CA CA2731170A patent/CA2731170C/fr active Active
- 2009-07-28 RU RU2011102292/02A patent/RU2011102292A/ru not_active Application Discontinuation
- 2009-07-28 WO PCT/US2009/051886 patent/WO2010014562A2/fr not_active Ceased
- 2009-07-28 PE PE2011000081A patent/PE20110691A1/es not_active Application Discontinuation
- 2009-07-29 JO JO2009281A patent/JO2815B1/en active
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2011
- 2011-01-20 CL CL2011000128A patent/CL2011000128A1/es unknown
- 2011-01-21 MA MA33548A patent/MA32496B1/fr unknown
- 2011-01-27 IL IL210905A patent/IL210905A0/en unknown
- 2011-02-08 ZA ZA2011/00992A patent/ZA201100992B/en unknown
- 2011-02-15 CO CO11017744A patent/CO6362053A2/es not_active Application Discontinuation
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2012
- 2012-07-23 US US13/555,606 patent/US8703077B2/en active Active
- 2012-07-23 US US13/555,469 patent/US8685349B2/en active Active
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2014
- 2014-04-21 US US14/257,576 patent/US9217189B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2731170A1 (fr) | 2010-02-04 |
| MX2011000817A (es) | 2011-06-01 |
| WO2010014562A3 (fr) | 2010-04-15 |
| IL210905A0 (en) | 2011-04-28 |
| CL2011000128A1 (es) | 2012-01-20 |
| US8685349B2 (en) | 2014-04-01 |
| KR101389877B1 (ko) | 2014-04-29 |
| US20150010446A1 (en) | 2015-01-08 |
| US20130022520A1 (en) | 2013-01-24 |
| US8226910B2 (en) | 2012-07-24 |
| KR20110051201A (ko) | 2011-05-17 |
| ZA201100992B (en) | 2011-10-26 |
| JO2815B1 (en) | 2014-09-15 |
| CO6362053A2 (es) | 2012-01-20 |
| US8703077B2 (en) | 2014-04-22 |
| RU2011102292A (ru) | 2012-09-10 |
| US20100028226A1 (en) | 2010-02-04 |
| CA2731170C (fr) | 2014-05-27 |
| US20130022519A1 (en) | 2013-01-24 |
| US9217189B2 (en) | 2015-12-22 |
| PE20110691A1 (es) | 2011-10-23 |
| WO2010014562A2 (fr) | 2010-02-04 |
| BRPI0916382A2 (pt) | 2018-06-05 |
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