MA38371B1 - Matériau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, ses procédés de préparation et ses utilisations - Google Patents

Matériau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, ses procédés de préparation et ses utilisations

Info

Publication number
MA38371B1
MA38371B1 MA38371A MA38371A MA38371B1 MA 38371 B1 MA38371 B1 MA 38371B1 MA 38371 A MA38371 A MA 38371A MA 38371 A MA38371 A MA 38371A MA 38371 B1 MA38371 B1 MA 38371B1
Authority
MA
Morocco
Prior art keywords
inorganic material
useful
preparation
methods
phosphoric acid
Prior art date
Application number
MA38371A
Other languages
English (en)
Other versions
MA38371A1 (fr
Inventor
Guilhem Arrachart
Stéphane Pellet-Rostaing
Raphaël Turgis
Mourabit Sabah El
Frédéric Goettmann
Agnès Grandjean
Original Assignee
Centre Nat Rech Scient
Commissariat L Energie Atomique Et Aux Energies Alternatives
Univ Montpellier 2 Sciences Et Techniques
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre Nat Rech Scient, Commissariat L Energie Atomique Et Aux Energies Alternatives, Univ Montpellier 2 Sciences Et Techniques filed Critical Centre Nat Rech Scient
Publication of MA38371A1 publication Critical patent/MA38371A1/fr
Publication of MA38371B1 publication Critical patent/MA38371B1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3251—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3259—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0265—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
    • C22B60/0269—Extraction by activated carbon containing adsorbents
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0265—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
    • C22B60/0273—Extraction by titanium containing adsorbents, e.g. by hydrous titanium oxide
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0278—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries by chemical methods
    • C22B60/0282—Solutions containing P ions, e.g. treatment of solutions resulting from the leaching of phosphate ores or recovery of uranium from wet-process phosphoric acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Nanotechnology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

L'invention se rapporte à un matériau hybride organique-inorganique qui comprend un support solide inorganique sur lequel sont greffées des molécules organiques de formule générale (i) ci-après dans laquelle : x, y et z = 0 ou 1, avec l'un au moins de x, y et z différent de 0; m = 1 à 6; v et w = 0 ou 1, avec v = 1 quand w = 0, et v = 0 quand w = 1; si x = 0, r
MA38371A 2013-02-25 2013-11-08 Matériau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, ses procédés de préparation et ses utilisations MA38371B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1351639A FR3002463B1 (fr) 2013-02-25 2013-02-25 Materiau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux contenant de l'acide phosphorique, ses procedes de preparation et ses utilisations
PCT/EP2013/073429 WO2014127860A1 (fr) 2013-02-25 2013-11-08 Matériau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, ses procédés de préparation et ses utilisations

Publications (2)

Publication Number Publication Date
MA38371A1 MA38371A1 (fr) 2016-09-30
MA38371B1 true MA38371B1 (fr) 2017-04-28

Family

ID=48140081

Family Applications (1)

Application Number Title Priority Date Filing Date
MA38371A MA38371B1 (fr) 2013-02-25 2013-11-08 Matériau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, ses procédés de préparation et ses utilisations

Country Status (7)

Country Link
US (1) US10130932B2 (fr)
AU (1) AU2013379406B2 (fr)
BR (1) BR112015019799B1 (fr)
FR (1) FR3002463B1 (fr)
MA (1) MA38371B1 (fr)
TN (1) TN2015000334A1 (fr)
WO (1) WO2014127860A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3013059B1 (fr) * 2013-11-08 2016-01-01 Commissariat Energie Atomique Utilisation d'un materiau hybride organique-inorganique pour extraire l'uranium(vi) d'une solution aqueuse d'acide sulfurique, issue notamment de la lixiviation sulfurique d'un minerai uranifere
FR3014336B1 (fr) 2013-12-05 2016-01-22 Commissariat Energie Atomique Utilisation d'un gel alcalin oxydant pour eliminer un biofilm sur une surface d'un substrat solide.
FR3025115B1 (fr) 2014-09-03 2018-12-07 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede d'extraction selectif de platinoides, a partir d'un support les contenant, avec un milieu d'extraction comprenant un fluide supercritique et un ligand organique.
FR3025799B1 (fr) 2014-09-12 2016-10-14 Commissariat Energie Atomique Procede de preparation d'un materiau solide nanocomposite a base d'hexa- et octacyanometallates de metaux alcalins.
FR3034417B1 (fr) 2015-04-03 2019-03-15 Commissariat A L'energie Atomique Et Aux Energies Alternatives Composes a fonctions oxyde de phosphine et amine, utiles comme ligands de l'uranium(vi), et leurs utilisations, notamment pour extraire l'uranium(vi) de solutions aqueuses d'acide sulfurique
FR3044018B1 (fr) 2015-11-19 2017-12-22 Areva Mines Procedes d'extraction et de recuperation de l'uranium present dans une solution aqueuse comprenant de l'acide phosphorique
FR3044006B1 (fr) 2015-11-19 2020-03-06 Orano Mining Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique
FR3060006B1 (fr) * 2016-12-13 2020-02-28 Orano Mining Materiau organique mesoporeux, utile notamment pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, et ses utilisations
CN107163079B (zh) * 2017-05-09 2019-07-16 凯莱英生命科学技术(天津)有限公司 一种烃基膦酸酯的制备方法
EP3441396A1 (fr) * 2017-08-07 2019-02-13 Université de Montpellier Procé?dé? de sé?paration d'uranium et/ou de thorium
DE102018005069A1 (de) 2018-06-26 2020-01-02 Skw Stickstoffwerke Piesteritz Gmbh Verfahren zur Herstellung von harnstoffbasierten Düngemitteln mit elementaren Schwefel und Produkte davon

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4396556A (en) * 1981-03-02 1983-08-02 Occidental Research Corporation Process of preparing organophosphorus compounds by phase transfer catalysis
IL69384A0 (en) 1983-08-01 1983-11-30 Israel Atomic Energy Comm Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange
FR2896705B1 (fr) 2006-01-30 2008-12-05 Commissariat Energie Atomique Procede de separation en milieu aqueux d'au moins un element actinide d'elements lanthanides par complexation et filtration membranaire
US8343450B2 (en) * 2007-10-09 2013-01-01 Chemnano Materials, Ltd. Functionalized carbon nanotubes, recovery of radionuclides and separation of actinides and lanthanides
US8357628B2 (en) * 2008-08-29 2013-01-22 Agilent Technologies, Inc. Inorganic/organic hybrid totally porous metal oxide particles, methods for making them and separation devices using them
EP2437882A4 (fr) * 2009-06-01 2016-11-23 Waters Technologies Corp Matériau hybride pour des séparations chromatographiques
US20110110985A1 (en) * 2009-11-06 2011-05-12 Battelle Memorial Institute Functionalized nanomaterials for chelation therapies and sorbent dialysis of toxins
FR2990206B1 (fr) 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations

Also Published As

Publication number Publication date
FR3002463B1 (fr) 2016-08-19
BR112015019799A2 (pt) 2017-07-18
BR112015019799B1 (pt) 2022-03-08
TN2015000334A1 (fr) 2017-01-03
MA38371A1 (fr) 2016-09-30
WO2014127860A1 (fr) 2014-08-28
US20160016150A1 (en) 2016-01-21
US10130932B2 (en) 2018-11-20
FR3002463A1 (fr) 2014-08-29
AU2013379406B2 (en) 2017-03-09
AU2013379406A1 (en) 2015-09-03

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