MA43711A - Procédés de production de l-glufosinate - Google Patents

Procédés de production de l-glufosinate

Info

Publication number
MA43711A
MA43711A MA043711A MA43711A MA43711A MA 43711 A MA43711 A MA 43711A MA 043711 A MA043711 A MA 043711A MA 43711 A MA43711 A MA 43711A MA 43711 A MA43711 A MA 43711A
Authority
MA
Morocco
Prior art keywords
production processes
glufosinate
glufosinate production
processes
production
Prior art date
Application number
MA043711A
Other languages
English (en)
Inventor
Michelle Lorraine Gradley
Brian Michael Green
Original Assignee
Agrimetis Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=58267184&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MA43711(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Agrimetis Llc filed Critical Agrimetis Llc
Publication of MA43711A publication Critical patent/MA43711A/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00Preparation of nitrogen-containing organic compounds
    • C12P13/04Alpha- or beta- amino acids
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/10Transferases (2.)
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00Microorganisms; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/20Bacteria; Culture media therefor
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/0004Oxidoreductases (1.)
    • C12N9/0012Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7)
    • C12N9/0014Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7) acting on the CH-NH2 group of donors (1.4)
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/0004Oxidoreductases (1.)
    • C12N9/0012Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7)
    • C12N9/0014Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7) acting on the CH-NH2 group of donors (1.4)
    • C12N9/0022Oxidoreductases (1.) acting on nitrogen containing compounds as donors (1.4, 1.5, 1.6, 1.7) acting on the CH-NH2 group of donors (1.4) with oxygen as acceptor (1.4.3)
    • C12N9/0024D-Amino acid oxidase (1.4.3.3)
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00Preparation of nitrogen-containing organic compounds
    • C12P13/02Amides, e.g. chloramphenicol or polyamides; Imides or polyimides; Urethanes, i.e. compounds comprising N-C=O structural element or polyurethanes
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P41/00Processes using enzymes or microorganisms to separate optical isomers from a racemic mixture
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P9/00Preparation of organic compounds containing a metal or atom other than H, N, C, O, S or halogen
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12YENZYMES
    • C12Y104/00Oxidoreductases acting on the CH-NH2 group of donors (1.4)
    • C12Y104/03Oxidoreductases acting on the CH-NH2 group of donors (1.4) with oxygen as acceptor (1.4.3)
    • C12Y104/03003D-Amino-acid oxidase (1.4.3.3)
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12YENZYMES
    • C12Y206/00Transferases transferring nitrogenous groups (2.6)
    • C12Y206/01Transaminases (2.6.1)
    • C12Y206/010194-Aminobutyrate—2-oxoglutarate transaminase (2.6.1.19)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Toxicology (AREA)
  • Virology (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Catching Or Destruction (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Peptides Or Proteins (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
MA043711A 2016-03-02 2017-02-28 Procédés de production de l-glufosinate MA43711A (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662302421P 2016-03-02 2016-03-02
US201662336989P 2016-05-16 2016-05-16
US201662413240P 2016-10-26 2016-10-26

Publications (1)

Publication Number Publication Date
MA43711A true MA43711A (fr) 2018-11-28

Family

ID=58267184

Family Applications (1)

Application Number Title Priority Date Filing Date
MA043711A MA43711A (fr) 2016-03-02 2017-02-28 Procédés de production de l-glufosinate

Country Status (14)

Country Link
US (11) US9834802B2 (fr)
EP (2) EP3423585A1 (fr)
JP (3) JP7041066B2 (fr)
KR (2) KR20250156185A (fr)
CN (3) CN116121315A (fr)
AU (2) AU2017227553B2 (fr)
BR (1) BR112018067523A8 (fr)
CA (1) CA3015081A1 (fr)
CL (2) CL2018002454A1 (fr)
IL (2) IL316333A (fr)
MA (1) MA43711A (fr)
MX (2) MX388774B (fr)
WO (1) WO2017151573A1 (fr)
ZA (1) ZA201805680B (fr)

Families Citing this family (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2017227553B2 (en) 2016-03-02 2021-03-25 Basf Se Methods for making L-glufosinate
CN111065270A (zh) 2017-07-18 2020-04-24 阿格里麦蒂斯有限责任公司 L-草胺膦的生产方法
US20210127681A1 (en) * 2017-07-27 2021-05-06 Basf Se Use of herbicidal compositions based on l-glufosinate in tolerant field crops
BR122023021519A2 (pt) 2017-08-09 2024-01-09 Basf Se Mistura de herbicidas, composição pesticida e método de controle de vegetação
KR20240113610A (ko) * 2017-08-09 2024-07-22 바스프 에스이 L-글루포시네이트 또는 이의 염 및 하나 이상의 vlcfa 저해제를 포함하는 제초제 혼합물
EP3440937A1 (fr) * 2017-08-09 2019-02-13 Basf Se Mélanges herbicides comprenant du l-glufosinate ou son sel et un second herbicide
BR122023021512A2 (pt) * 2017-08-09 2024-03-05 Basf Se Mistura herbicida, composição pesticida e método para controlar vegetação indesejável
US11363818B2 (en) * 2017-08-09 2022-06-21 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in soybean cultures
BR122024002212A2 (pt) * 2017-08-09 2024-03-12 Basf Se Mistura pesticida sinergística
EP3440939A1 (fr) * 2017-08-09 2019-02-13 Basf Se Mélanges herbicides comprenant du l-glufosinate
CN107502647B (zh) * 2017-09-15 2020-12-15 浙江大学 一种生物酶法去消旋化制备l-草铵膦的方法
CN110055289B (zh) * 2018-01-19 2020-05-29 上海弈柯莱生物医药科技有限公司 一种l-草铵膦的制备方法
CN110343676B (zh) 2018-04-03 2020-06-23 上海弈柯莱生物医药科技有限公司 一种l-谷氨酸脱氢酶突变体及其应用
TWI851589B (zh) 2018-07-31 2024-08-11 德商拜耳廠股份有限公司 編碼改良之轉胺酶蛋白質之核酸
CN108912167B (zh) * 2018-08-08 2020-07-07 河北威远生物化工有限公司 一种从水解反应液中分离纯化草铵膦的方法
CN112739822A (zh) * 2018-09-05 2021-04-30 巴斯夫欧洲公司 改善l-草胺膦产率的方法
CN111019916B (zh) * 2018-11-23 2020-12-08 弈柯莱生物科技(上海)股份有限公司 一种d-氨基酸氧化酶突变体及其应用
CN109609475B (zh) * 2018-12-28 2020-10-09 浙江工业大学 草铵膦脱氢酶突变体及其合成l-草铵膦的应用
CN109576236B (zh) * 2018-12-28 2019-12-17 浙江工业大学 一种d-氨基酸氧化酶突变体及其应用
CN109609474B (zh) * 2018-12-28 2020-07-28 浙江工业大学 一种氨基酸脱氢酶突变体及其在合成l-草铵膦中的应用
KR102582675B1 (ko) * 2019-01-11 2023-09-25 씨제이제일제당 주식회사 글루포시네이트 제조 방법
EP3909962B1 (fr) 2019-01-11 2025-05-21 CJ CheilJedang Corporation Procédé de production de l-glufosinate
CN109609477B (zh) * 2019-01-14 2022-02-18 浙江工业大学 一种α-转氨酶突变体及其在不对称合成L-草铵膦中的应用
CN111172125B (zh) * 2019-03-05 2023-08-08 上海七洲紫岳生物科技有限公司 一种固定化d-氨基酸氧化酶及其制备方法和应用
MX2021012680A (es) 2019-04-16 2021-11-12 Basf Se Metodos para la produccion de monohidrato de l-glufosinato de amonio cristalino.
CN111979208B (zh) 2019-05-23 2023-01-10 弈柯莱生物科技(上海)股份有限公司 一种l-谷氨酸脱氢酶突变体及其应用
CN112391438B (zh) * 2019-08-13 2023-01-13 四川利尔生物科技有限公司 一种l-草铵膦或其盐的生产方法
CA3155389A1 (fr) * 2019-11-20 2021-05-27 Philip Pentland Composition herbicide a base de glufosinate
CN113825841B (zh) 2019-12-09 2022-08-09 湖南利尔生物科技有限公司 经修饰的daao酶及其应用
WO2021151745A1 (fr) 2020-01-31 2021-08-05 Basf Se Combinaisons herbicides comprenant du glufosinate et de l'oxadiazon
US20230054749A1 (en) * 2020-01-31 2023-02-23 Basf Se Herbicide Combinations Comprising Glufosinate and Flumiclorac-pentyl
US12557815B2 (en) 2020-01-31 2026-02-24 Basf Se Herbicide combinations comprising glufosinate and pyraflufen-ethyl
BR112022014824A2 (pt) 2020-01-31 2022-12-13 Basf Se Combinação de herbicidas, composição, métodos de produção de combinações herbicidas, de tratamento ou proteção de plantas produtoras em fileiras e de tratamento ou proteção de plantas especializadas e uso da composição herbicida
US20230075365A1 (en) 2020-01-31 2023-03-09 Basf Se Herbicide combinations comprising glufosinate and selected ppo inhibitors
BR112022014758A2 (pt) 2020-01-31 2022-10-11 Basf Se Combinação de herbicidas, composição, métodos para produzir uma combinação de herbicidas, para controlar o crescimento indesejado das plantas e para tratar ou proteger culturas e uso da combinação de herbicidas
BR112022014952A2 (pt) 2020-01-31 2022-09-20 Basf Se Combinação de herbicidas, composição, métodos de produção de combinações de herbicidas, de controle do crescimento vegetal indesejado e de tratamento ou proteção de plantas e uso da combinação de herbicidas
BR112022015061A2 (pt) * 2020-01-31 2022-09-20 Basf Se Combinação de herbicidas, composição, métodos para produzir uma combinação de herbicidas, para controlar o crescimento indesejado das plantas, para tratar ou proteger culturas e uso de uma combinação de herbicidas
WO2021151737A1 (fr) 2020-01-31 2021-08-05 Basf Se Combinaisons herbicides comprenant du glufosinate et de la flumioxazine
US20230076646A1 (en) 2020-01-31 2023-03-09 Basf Se Herbicide combinations comprising glufosinate and sulfentrazone
WO2021151735A1 (fr) * 2020-01-31 2021-08-05 Basf Se Combinaisons herbicides comprenant du glufosinate et du carfentrazone-éthyle
BR112022014831A2 (pt) 2020-01-31 2022-09-27 Basf Se Combinação de herbicidas, composição, métodos para produzir uma combinação de herbicidas, para controlar o crescimento de plantas indesejadas e para tratar ou proteger culturas e uso de uma combinação de herbicidas
WO2021151733A1 (fr) 2020-01-31 2021-08-05 Basf Se Combinaisons herbicides comprenant du glufosinate et du saflufénacil
BR112022014971A2 (pt) 2020-01-31 2022-09-20 Basf Se Combinação herbicida, composição, métodos para produzir uma combinação herbicida, para controlar o crescimento indesejado das plantas e para tratar ou proteger culturas e uso de combinações herbicidas
US12262715B2 (en) 2020-02-05 2025-04-01 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and at least one protoporphyrinogen-IX oxidase inhibitor
CN111321193B (zh) * 2020-03-18 2020-11-10 浙江工业大学 一种生物多酶偶联法氧化还原不对称制备l-草铵膦的方法
CN111574559A (zh) * 2020-04-30 2020-08-25 河北威远生物化工有限公司 L-草铵膦酶水解液的后处理方法
WO2022007881A1 (fr) 2020-07-09 2022-01-13 四川利尔生物科技有限公司 Glutamate déshydrogénase modifiée et son utilisation
CN112553285B (zh) * 2020-12-25 2022-10-28 浙江大学杭州国际科创中心 一种ω-转氨酶的应用及生物酶法去消旋化制备L-草铵膦的方法
CN117120625A (zh) 2021-04-01 2023-11-24 巴斯夫欧洲公司 制备l-草铵膦的方法
US12146167B2 (en) 2021-04-01 2024-11-19 Evonik Operations Gmbh Enzymatic method for producing L-glufosinate and its phosphoesters
CN113969269B (zh) * 2021-04-29 2024-05-03 永农生物科学有限公司 D-氨基酸氧化酶突变体及其在制备l-草铵膦中的应用
CN113295783A (zh) * 2021-05-08 2021-08-24 青岛谱尼测试有限公司 一种精草铵膦衍生转化的检测方法
CN114805433B (zh) * 2021-05-13 2023-11-28 永农生物科学有限公司 不含结晶水的l-草铵膦铵盐晶体形式及固体粉末
EP4105335A1 (fr) 2021-06-16 2022-12-21 Evonik Operations GmbH Procédé enzymatique pour la production d'esters p-alkyl du l-glufosinate
EP4151643A1 (fr) 2021-09-16 2023-03-22 Evonik Operations GmbH Procédé amélioré pour la production de phosphoesters de précurseurs du glufosinate
KR20240125984A (ko) 2021-12-31 2024-08-20 후난 라이어 바이오테크 씨오., 엘티디. 변형된 글루타메이트 탈수소효소 및 이의 용도
CN116555206A (zh) * 2022-01-30 2023-08-08 弈柯莱生物科技(上海)股份有限公司 一种d-氨基酸氧化酶及其在制备l-草铵膦或其中间体中的应用
CN114540440B (zh) * 2022-03-01 2024-09-27 浙江工业大学 一种加压催化制备2-羰基-4-(羟基甲基膦酰基)丁酸的方法
CA3245643A1 (fr) 2022-03-14 2023-09-21 Evonik Operations Gmbh Procede enzymatique de production de p-esters de l-glufosinate
CN115074403B (zh) * 2022-05-18 2025-04-22 湖北泰盛化工有限公司 L-草铵膦的关键中间体4-(甲基羟基磷酰基)-2-羰基丁酸
WO2023222227A1 (fr) 2022-05-19 2023-11-23 Evonik Operations Gmbh Procédé enzymatique de production de l-glufosinate
WO2023222226A1 (fr) 2022-05-19 2023-11-23 Evonik Operations Gmbh Procédé enzymatique pour la production de l-glufosinate
WO2023232225A1 (fr) 2022-05-31 2023-12-07 Evonik Operations Gmbh Procédé enzymatique de production diastéréosélective de p-esters de l-glufosinate
US20250380702A1 (en) * 2022-06-29 2025-12-18 Basf Se Herbicidal mixtures comprising l-glufosinate or its salt and a second herbicide
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