MX2009005127A - Composicion para separacion de hidrogeno. - Google Patents

Composicion para separacion de hidrogeno.

Info

Publication number
MX2009005127A
MX2009005127A MX2009005127A MX2009005127A MX2009005127A MX 2009005127 A MX2009005127 A MX 2009005127A MX 2009005127 A MX2009005127 A MX 2009005127A MX 2009005127 A MX2009005127 A MX 2009005127A MX 2009005127 A MX2009005127 A MX 2009005127A
Authority
MX
Mexico
Prior art keywords
alkyl
cycloalkyl
aryl
forms
substituent
Prior art date
Application number
MX2009005127A
Other languages
English (en)
Inventor
Douglas W Stephan
Preston A Chase
Gregory C Welch
Original Assignee
Stephan Consulting Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stephan Consulting Corp filed Critical Stephan Consulting Corp
Publication of MX2009005127A publication Critical patent/MX2009005127A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5022—Aromatic phosphines (P-C aromatic linkage)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un compuesto que tiene la fórmula (I) donde cada uno de R1, R2, R3 y R4 es independientemente arilo- de C6-C18, cicloalquilo- de C5-C8, arilo de C6-C18 que tiene por lo menos un sustituyente alquilo de C1-C20, cicloalquilo de C5-C8 que tiene por lo menos un sustituyente alquilo de C1-C20, alquilo-ramificado de C4-C20, alquilo- lineal de C16-C20, RO-, -NRR´, -PRR´, -SR, formas sustituidas de fluoro de los mismos, y formas de perfluoro de los mismos: y R5 es arilo- de C6-C18, cicloalquilo- de C5-C8, arilo de C6-C18 que tiene por lo menos un sustituyente alquilo de C1-C20, cicloalquilo de C5-C8 que tiene por lo menos un sustituyente alquilo de C1-C20, alquilo- ramificado de C3-C20, alquilo- lineal de C2-C30, formas sustituidas de fluoro de los mismos, y formas de perfluoro de los mismos; donde R y R´ son cada uno independientemente arilo- de C6-C18, cicloalquilo- de C5-C8, arilo de C6-C18 que tiene por lo menos un sustituyente alquilo de C1-C20, cicloalquilo de C5-C8 que tiene por lo menos un sustituyente alquilo de C1-C20, alquilo- ramificado de C4-C20, alquilo lineal de C2-C30, formas sustituidas de fluoro de los mismos, y formas de perfluoro de los mismos; A es N, P, S u O con la condición de que cuando A es S, R2 es una nulidad; y M es B, Al, Ga o In.
MX2009005127A 2006-11-14 2007-11-14 Composicion para separacion de hidrogeno. MX2009005127A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US86568406P 2006-11-14 2006-11-14
US89655707P 2007-03-23 2007-03-23
PCT/IB2007/004577 WO2008125911A2 (en) 2006-11-14 2007-11-14 Hydrogen splitting composition

Publications (1)

Publication Number Publication Date
MX2009005127A true MX2009005127A (es) 2009-07-03

Family

ID=39864421

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009005127A MX2009005127A (es) 2006-11-14 2007-11-14 Composicion para separacion de hidrogeno.

Country Status (10)

Country Link
US (2) US8299284B2 (es)
EP (1) EP2091957A4 (es)
JP (1) JP2010509393A (es)
KR (1) KR20090078835A (es)
CN (1) CN102066390A (es)
AU (1) AU2007350983A1 (es)
CA (1) CA2669545C (es)
MX (1) MX2009005127A (es)
SG (1) SG176482A1 (es)
WO (1) WO2008125911A2 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9624154B2 (en) 2012-12-07 2017-04-18 University Of Central Florida Research Foundation, Inc. Heterogeneously catalyzed chemical reduction of carbon dioxide
WO2014089537A1 (en) * 2012-12-07 2014-06-12 University Of Central Florida Research Foundation, Inc. Heterogeneous metal-free catalyst
GB2522858A (en) * 2014-02-05 2015-08-12 Imp Innovations Ltd Fuel cell and battery
WO2016097734A1 (en) * 2014-12-16 2016-06-23 Isis Innovation Limited Solid-phase catalysts comprising supported frustrated lewis pairs
KR101979575B1 (ko) 2015-04-13 2019-05-17 갈모어 인코포레이티드 콘크리트 또는 아스팔트와 같은 호스트 중의 그래파이트 옥사이드 강화된 섬유
US10988488B2 (en) 2015-04-23 2021-04-27 UNIVERSITé LAVAL Process for the functionalization of sp2-H carbons using frustrated lewis pair catalysts
US10821429B2 (en) 2015-12-15 2020-11-03 UNIVERSITé LAVAL Precatalysts and process for the metal-free functionalization of SP2 carbons using the same
US10258976B2 (en) 2015-12-15 2019-04-16 UNIVERSITé LAVAL Precatalysts and process for the metal-free functionalization of SP2 carbons using the same
JP7079696B2 (ja) * 2018-08-29 2022-06-02 株式会社日本触媒 ホウ素化合物、およびそれを用いた水素化物、重合体ならびに付加体の製造方法
WO2020247329A1 (en) 2019-06-04 2020-12-10 Dow Silicones Corporation Thermally initiated acid catalyzed reaction between silyl hydride and siloxane
WO2020247335A1 (en) 2019-06-04 2020-12-10 Dow Silicones Corporation BRIDGED FRUSTRATED LEWIS PAIRS AS THERMAL TRIGGER FOR REACTIONS BETWEEN Si-H AND ALPHA-BETA UNSATURATED ESTERS
CN113924344B (zh) 2019-06-04 2023-07-14 美国陶氏有机硅公司 作为用于Si-H和Si-O-Si之间的反应的热触发剂的桥联受阻路易斯对
EP3980428B1 (en) 2019-06-04 2023-04-26 Dow Silicones Corporation Thermally initiated acid catalyzed reaction between silyl hydride and alpha-beta unsaturated esters
KR20220016902A (ko) 2019-06-04 2022-02-10 다우 실리콘즈 코포레이션 Si-H와 Si-OR의 반응을 위한 열 트리거로서의 가교된 불완전 루이스 쌍
EP3980432B1 (en) 2019-06-04 2023-04-26 Dow Silicones Corporation Bridged frustrated lewis pairs as thermal trigger for reactions between si-h and epoxide
CN113924330B (zh) 2019-06-04 2023-01-24 美国陶氏有机硅公司 甲硅烷基氢化物与甲硅烷基醚和/或硅烷醇之间的热引发的酸催化反应
WO2021146093A1 (en) * 2020-01-14 2021-07-22 University Of Vermont And State Agricultural College Methods of preparing primary phosphine products using lewis acid catalysts

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4522932A (en) * 1982-09-27 1985-06-11 Exxon Research & Engineering Co. Phosphine and phosphonium compounds and catalysts
ID23037A (id) * 1997-08-01 2000-01-06 Dow Chemical Co Aktivator katalis ion zwitter
US6395847B2 (en) 1999-11-19 2002-05-28 Exxonmobil Chemical Patents Inc. Supported organometallic catalysts and their use in olefin polymerization
GB0314220D0 (en) 2003-06-19 2003-07-23 Univ Durham Bifunctional catalyst

Also Published As

Publication number Publication date
WO2008125911A3 (en) 2011-03-03
KR20090078835A (ko) 2009-07-20
CA2669545C (en) 2016-01-05
AU2007350983A8 (en) 2009-06-25
SG176482A1 (en) 2011-12-29
AU2007350983A1 (en) 2008-10-23
CN102066390A (zh) 2011-05-18
WO2008125911A8 (en) 2009-04-23
CA2669545A1 (en) 2008-10-23
EP2091957A4 (en) 2012-03-21
WO2008125911A2 (en) 2008-10-23
EP2091957A2 (en) 2009-08-26
US20130018207A1 (en) 2013-01-17
US20100048949A1 (en) 2010-02-25
US8299284B2 (en) 2012-10-30
JP2010509393A (ja) 2010-03-25
US8642812B2 (en) 2014-02-04

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