MX2009005391A - Proceso para elaborar (met) acrilatos de alquilo utilizando una hidrolisis de cianohidrina enzimatica. - Google Patents
Proceso para elaborar (met) acrilatos de alquilo utilizando una hidrolisis de cianohidrina enzimatica.Info
- Publication number
- MX2009005391A MX2009005391A MX2009005391A MX2009005391A MX2009005391A MX 2009005391 A MX2009005391 A MX 2009005391A MX 2009005391 A MX2009005391 A MX 2009005391A MX 2009005391 A MX2009005391 A MX 2009005391A MX 2009005391 A MX2009005391 A MX 2009005391A
- Authority
- MX
- Mexico
- Prior art keywords
- acrylates
- meth
- enzymatic
- preparing alkyl
- cyanohydrin
- Prior art date
Links
- 125000000217 alkyl group Chemical group 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 title 1
- 230000002255 enzymatic effect Effects 0.000 title 1
- 230000007062 hydrolysis Effects 0.000 title 1
- 238000006460 hydrolysis reaction Methods 0.000 title 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 2
- 102000004190 Enzymes Human genes 0.000 abstract 2
- 108090000790 Enzymes Proteins 0.000 abstract 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/62—Carboxylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/02—Amides, e.g. chloramphenicol or polyamides; Imides or polyimides; Urethanes, i.e. compounds comprising N-C=O structural element or polyurethanes
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
La presente invención se relaciona con un proceso para preparar (met)acrilatos de alquilo, caracterizado porque el proceso tiene un paso en el que una cianohidrina de hidroliza con una enzima cuya actividad residual después de la conversión de metacrilonitrilo en presencia de 20 mM iones de cianuro a 20ºC después de 30 minutos en por lo menos 90% de actividad residual de la enzima que se ha utilizado bajo condiciones idénticas de otra forma en ausencia de iones de cianuro.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006055426A DE102006055426A1 (de) | 2006-11-22 | 2006-11-22 | Verfahren zur Herstellung von Alkyl(meth)acrylaten unter Verwendung einer enzymatischen Cyanhydrinhydrolyse |
| PCT/EP2007/059033 WO2008061820A1 (de) | 2006-11-22 | 2007-08-30 | Verfahren zur herstellung von alkyl(meth)acrylaten unter verwendung einer enzymatischen cyanhydrinhydrolyse |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009005391A true MX2009005391A (es) | 2009-06-02 |
Family
ID=38740302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009005391A MX2009005391A (es) | 2006-11-22 | 2007-08-30 | Proceso para elaborar (met) acrilatos de alquilo utilizando una hidrolisis de cianohidrina enzimatica. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20100021977A1 (es) |
| CN (1) | CN101186935A (es) |
| AU (1) | AU2007324721A1 (es) |
| BR (1) | BRPI0718994A2 (es) |
| CA (1) | CA2670421A1 (es) |
| DE (1) | DE102006055426A1 (es) |
| MX (1) | MX2009005391A (es) |
| RU (1) | RU2009123373A (es) |
| TW (1) | TW200837195A (es) |
| WO (1) | WO2008061820A1 (es) |
| ZA (1) | ZA200903528B (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007015583A1 (de) * | 2007-03-29 | 2008-10-02 | Albert-Ludwigs-Universität Freiburg | Ein Enzym zur Herstellung von Methylmalonyl-Coenzym A oder Ethylmalonyl-Coenzym A sowie dessen Verwendung |
| AT506077B1 (de) * | 2008-01-29 | 2009-06-15 | Andritz Ag Maschf | Abwärmenutzung in der trockenpartie von papiermaschinen |
| DE102008002715A1 (de) * | 2008-06-27 | 2009-12-31 | Evonik Röhm Gmbh | 2-Hydroxyisobuttersäure produzierende rekombinante Zelle |
| DE102008040193A1 (de) * | 2008-07-04 | 2010-01-07 | Evonik Röhm Gmbh | Verfahren zur Herstellung freier Carbonsäuren |
| DE102008044218A1 (de) | 2008-12-01 | 2010-06-02 | Evonik Röhm Gmbh | Verfahren zur Herstellung von einem Carbonsäureamid aus einer Carbonylverbindung und Blausäure |
| DE102009046623A1 (de) | 2009-11-11 | 2011-05-12 | Evonik Röhm Gmbh | Verwendung eines zu einem MeaB-Protein homologen Proteins zur Erhöhung der enzymatischen Aktivität einer 3-Hydroxycarbonsäure-CoA-Mutase |
| DE102013000602A1 (de) | 2013-01-16 | 2014-07-17 | Evonik Industries Ag | Verfahren zur Herstellung von Acrylsäure |
| GB2524310A (en) * | 2014-03-20 | 2015-09-23 | Lucite Int Uk Ltd | A method of preventing polymer tar build-up in ACH production of MMA and MAA |
| US10392120B2 (en) * | 2016-04-19 | 2019-08-27 | General Electric Company | Propulsion engine for an aircraft |
| CA3026451A1 (en) * | 2016-06-03 | 2017-12-07 | Lutron Electronics Co., Inc. | User interface for a control device |
| DE102016210285A1 (de) | 2016-06-10 | 2017-12-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Methacrylaten und Methacrylsäure |
| GB201619827D0 (en) * | 2016-11-23 | 2017-01-04 | Lucite Int Uk Ltd | Process for the production of methyl methacrylate |
| FR3079498B1 (fr) | 2018-03-30 | 2020-06-19 | Airbus Operations | Unite de propulsion a helice comprenant un moteur thermique et un moteur electrique et aeronef comportant une telle unite de propulsion a helice |
| EP4105335A1 (en) | 2021-06-16 | 2022-12-21 | Evonik Operations GmbH | Enzymatic method for the production of l-glufosinate p-alkyl esters |
| MX2024011087A (es) | 2022-03-14 | 2024-09-23 | Evonik Operations Gmbh | Metodo enzimatico para la produccion de p-esteres de l-glufosinato. |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4529816A (en) * | 1984-02-13 | 1985-07-16 | E. I. Du Pont De Nemours And Company | Process for producing alkyl methacrylates |
| JPH05244968A (ja) * | 1991-08-16 | 1993-09-24 | Mitsui Toatsu Chem Inc | α−ヒドロキシイソブチルアミドの製造法 |
| DE69620847T3 (de) * | 1995-11-10 | 2008-11-27 | Mitsubishi Rayon Co., Ltd. | Verfahren zur Herstellung einer alpha-Hydroxy-säure oder eines alpha-Hydroxy-amids mittels Mikroorganismen |
| JPH11255710A (ja) * | 1998-03-11 | 1999-09-21 | Mitsubishi Gas Chem Co Inc | メタクリル酸メチルの製造方法 |
| DE10034194A1 (de) * | 2000-07-13 | 2003-09-11 | Roehm Gmbh | Verfahren zur Herstellung von Cyanwasserstoff |
| JP2002325587A (ja) * | 2001-03-02 | 2002-11-12 | Daicel Chem Ind Ltd | ニトリルヒドラターゼ、およびアミドの製造方法 |
| JP4672914B2 (ja) * | 2001-06-15 | 2011-04-20 | ダイセル化学工業株式会社 | アミド化合物の製造方法 |
| DE10200171A1 (de) * | 2002-01-04 | 2003-07-10 | Roehm Gmbh | Verfahren zur kontinuierlichen Herstellung von Alkyl(meth)acrylaten |
| US6582943B1 (en) * | 2002-02-05 | 2003-06-24 | E. I. Du Pont De Nemours And Company | Method for producing 2-hydroxyisobutyric acid and methacrylic acid from acetone cyanohydrin |
| DE10301007A1 (de) * | 2003-01-13 | 2004-07-22 | Röhm GmbH & Co. KG | Verbessertes Verfahren zur kontinuierlichen Herstellung von Alkyl(meth)acrylaten mit mehrfacher Katalysatorrezyklierung. |
| DE10347888A1 (de) * | 2003-10-10 | 2005-06-30 | Degussa Ag | Verfahren zur Herstellung von enantiomerenangereicherten alpha-Hydroxycarbonsäuren bzw. -amide |
| DE102004013824A1 (de) * | 2004-03-20 | 2005-10-13 | Degussa Ag | Nitrilhydratasen aus Rhodococcus opacus |
| DE102004013847A1 (de) * | 2004-03-20 | 2005-10-06 | Degussa Ag | Cyanidtolerante Nitrilhydratasen |
| DE102005023976A1 (de) * | 2005-05-20 | 2006-11-23 | Röhm Gmbh | Verfahren zur Umesterung |
| DE102005023975A1 (de) * | 2005-05-20 | 2006-11-23 | Röhm Gmbh | Verfahren zur Herstellung von Alkyl(meth)acrylaten |
| DE102005043719A1 (de) * | 2005-09-13 | 2007-03-15 | Röhm Gmbh | Vorrichtung und Verfahren für kontinuierlich durchgeführte Gleichgewichtsreaktionen |
| DE102006029318B3 (de) * | 2006-06-23 | 2007-10-11 | Röhm Gmbh | Verfahren zur kontinuierlichen Herstellung von ungesättigten Carbonsäureanhydriden |
-
2006
- 2006-11-22 DE DE102006055426A patent/DE102006055426A1/de not_active Withdrawn
-
2007
- 2007-01-18 CN CNA2007100020630A patent/CN101186935A/zh active Pending
- 2007-08-30 RU RU2009123373/04A patent/RU2009123373A/ru not_active Application Discontinuation
- 2007-08-30 BR BRPI0718994-0A patent/BRPI0718994A2/pt not_active IP Right Cessation
- 2007-08-30 MX MX2009005391A patent/MX2009005391A/es not_active Application Discontinuation
- 2007-08-30 AU AU2007324721A patent/AU2007324721A1/en not_active Abandoned
- 2007-08-30 WO PCT/EP2007/059033 patent/WO2008061820A1/de not_active Ceased
- 2007-08-30 CA CA002670421A patent/CA2670421A1/en not_active Abandoned
- 2007-08-30 US US12/441,145 patent/US20100021977A1/en not_active Abandoned
- 2007-11-19 TW TW096143711A patent/TW200837195A/zh unknown
-
2009
- 2009-05-21 ZA ZA200903528A patent/ZA200903528B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE102006055426A1 (de) | 2008-05-29 |
| ZA200903528B (en) | 2010-03-31 |
| WO2008061820A1 (de) | 2008-05-29 |
| US20100021977A1 (en) | 2010-01-28 |
| BRPI0718994A2 (pt) | 2014-02-11 |
| AU2007324721A1 (en) | 2008-05-29 |
| TW200837195A (en) | 2008-09-16 |
| CA2670421A1 (en) | 2008-05-29 |
| RU2009123373A (ru) | 2010-12-27 |
| CN101186935A (zh) | 2008-05-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |