MX2013013256A - Proceso para la preparacion de beta-santalol. - Google Patents

Proceso para la preparacion de beta-santalol.

Info

Publication number
MX2013013256A
MX2013013256A MX2013013256A MX2013013256A MX2013013256A MX 2013013256 A MX2013013256 A MX 2013013256A MX 2013013256 A MX2013013256 A MX 2013013256A MX 2013013256 A MX2013013256 A MX 2013013256A MX 2013013256 A MX2013013256 A MX 2013013256A
Authority
MX
Mexico
Prior art keywords
santalol
preparation
alkyl
compound
beta
Prior art date
Application number
MX2013013256A
Other languages
English (en)
Inventor
Anthony A Birkbeck
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Publication of MX2013013256A publication Critical patent/MX2013013256A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/26—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/283—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62—Halogen-containing esters
    • C07C69/63—Halogen-containing esters of saturated acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se relaciona con un proceso para la preparación de un compuesto de la fórmula (I) en la forma de cualquiera de sus estereoisómeros o mezclas de los mismos, y en donde R representa un grupo C2-C10 de la fórmula CORa, en donde Ra es un grupo alquilo o alquenilo que comprende opcionalmente uno o dos grupos funcionales o es un grupo fenilo o bencilo opcionalmente sustituido por uno a tres grupos alquilo, alcoxilo, carboxilo, acilo, amino o nitro o átomos de halógeno. La invención también se relaciona con el uso del compuesto (I) para la síntesis de ß-santalol o de sus derivados.
MX2013013256A 2011-06-30 2012-06-28 Proceso para la preparacion de beta-santalol. MX2013013256A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161503224P 2011-06-30 2011-06-30
EP11172037 2011-06-30
PCT/EP2012/062614 WO2013001026A1 (en) 2011-06-30 2012-06-28 Process for the preparation of beta-santalol

Publications (1)

Publication Number Publication Date
MX2013013256A true MX2013013256A (es) 2013-12-16

Family

ID=44584802

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013013256A MX2013013256A (es) 2011-06-30 2012-06-28 Proceso para la preparacion de beta-santalol.

Country Status (9)

Country Link
US (1) US9056826B2 (es)
EP (1) EP2726447B1 (es)
JP (1) JP5901757B2 (es)
CN (1) CN103596910B (es)
BR (1) BR112013029840A2 (es)
ES (1) ES2547922T3 (es)
IL (1) IL230125A (es)
MX (1) MX2013013256A (es)
WO (1) WO2013001026A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017207707A1 (en) * 2016-06-03 2017-12-07 Firmenich Sa Process for the preparation of polysantol-type compounds
CN108707073A (zh) * 2018-04-18 2018-10-26 帕潘纳(北京)科技有限公司 一种亚丙烯双乙酯的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3662008A (en) 1969-05-21 1972-05-09 Procter & Gamble Process for preparing beta-santalol from 3-methylnorcamphor
US3679756A (en) 1969-05-21 1972-07-25 Procter & Gamble Process for preparing {62 -santalol from 3-methylnorcamphor
US4223167A (en) * 1978-02-14 1980-09-16 Fritzsche Dodge & Olcott Inc. Processes for preparing β-santalol, β-santalene dihydro-β-santalol and related compounds
DE2843838A1 (de) 1978-10-07 1980-04-24 Basf Ag Bicyclische verbindungen, verfahren zu deren herstellung und deren verwendung
JPS5738730A (en) * 1980-08-14 1982-03-03 Kuraray Co Ltd Cis-pentene derivative and its preparation
DE10348062A1 (de) 2003-10-16 2005-05-19 Symrise Gmbh & Co. Kg Kurzkettige Enolester als Riechstoff-Prekursoren
WO2006120639A2 (en) * 2005-05-11 2006-11-16 Firmenich Sa Catalytic scriabine reaction
JP5387401B2 (ja) * 2007-03-07 2014-01-15 宇部興産株式会社 ２−メチル−３−（３，４−メチレンジオキシフェニル）プロパナールの品質保持方法、及びその製造方法
WO2008120175A1 (en) 2007-04-03 2008-10-09 Firmenich Sa 1,4-hydrogenation of dienes with ru complexes
US7902393B2 (en) * 2008-05-20 2011-03-08 Firmenich Sa Process for the preparation of β-santalol and derivatives thereof

Also Published As

Publication number Publication date
JP2014522825A (ja) 2014-09-08
US20140213818A1 (en) 2014-07-31
US9056826B2 (en) 2015-06-16
EP2726447B1 (en) 2015-08-12
BR112013029840A2 (pt) 2016-12-06
IL230125A (en) 2016-06-30
CN103596910B (zh) 2015-11-25
CN103596910A (zh) 2014-02-19
JP5901757B2 (ja) 2016-04-13
ES2547922T3 (es) 2015-10-09
EP2726447A1 (en) 2014-05-07
WO2013001026A1 (en) 2013-01-03

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