MX2017006111A - Proceso para espumado de composiciones de poliolefina con el uso de mezcla de fluororesina/citrato como agente de nucleacion. - Google Patents

Proceso para espumado de composiciones de poliolefina con el uso de mezcla de fluororesina/citrato como agente de nucleacion.

Info

Publication number
MX2017006111A
MX2017006111A MX2017006111A MX2017006111A MX2017006111A MX 2017006111 A MX2017006111 A MX 2017006111A MX 2017006111 A MX2017006111 A MX 2017006111A MX 2017006111 A MX2017006111 A MX 2017006111A MX 2017006111 A MX2017006111 A MX 2017006111A
Authority
MX
Mexico
Prior art keywords
alkali metal
citrate
fluororesin
foam
mixture
Prior art date
Application number
MX2017006111A
Other languages
English (en)
Other versions
MX390558B (es
Inventor
J Kmiec Chester
Sun Gangwei
Esseghir Mohamed
Min XU Xian
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2017006111A publication Critical patent/MX2017006111A/es
Publication of MX390558B publication Critical patent/MX390558B/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22After-treatment of expandable particles; Forming foamed products
    • C08J9/228Forming foamed products
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C55/00Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
    • C07C55/22Tricarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0083Nucleating agents promoting the crystallisation of the polymer matrix
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H01B3/445Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/02CO2-releasing, e.g. NaHCO3 and citric acid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/262Alkali metal carbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

El proceso de espumado de una composición de poliolefina, por ejemplo polietileno, que utiliza como nucleador una combinación de (A) una fluororesina, y (B) una mezcla de (1) un primer componente que consiste de al menos uno de ácido cítrico y un citrato de metal alcalino y (2) un segundo componente que consiste de al menos uno de un citrato de metal alcalino, un citrato hidrógeno de metal di-alcalino, un citrato dihidrógeno de metal alcalino y un bicarbonato de metal alcalino con la condición de que si el primer componente de la mezcla es un citrato de metal alcalino, entonces el segundo componente de la mezcla no es un citrato de metal alcalino.
MX2017006111A 2014-11-28 2014-11-28 Proceso para espumado de composiciones de poliolefina con el uso de mezcla de fluororesina/citrato como agente de nucleacion. MX390558B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2014/092558 WO2016082212A1 (en) 2014-11-28 2014-11-28 Process for foaming polyolefin compositions using fluororesin/citrate mixture as nucleating agent

Publications (2)

Publication Number Publication Date
MX2017006111A true MX2017006111A (es) 2017-07-27
MX390558B MX390558B (es) 2025-03-20

Family

ID=56073403

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017006111A MX390558B (es) 2014-11-28 2014-11-28 Proceso para espumado de composiciones de poliolefina con el uso de mezcla de fluororesina/citrato como agente de nucleacion.

Country Status (9)

Country Link
US (1) US20170267828A1 (es)
EP (1) EP3224836B1 (es)
JP (1) JP6584505B2 (es)
KR (1) KR102306265B1 (es)
CN (1) CN107148654B (es)
BR (1) BR112017010189B1 (es)
CA (1) CA2969005C (es)
MX (1) MX390558B (es)
WO (1) WO2016082212A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10858492B2 (en) * 2016-09-13 2020-12-08 Dow Global Technologies Llc Nucleating agent for foamable cable insulation
EP3670600A1 (en) 2018-12-21 2020-06-24 Borealis AG Improved foaming behaviour of polymer compositions using passive nucleation
EP3670599A1 (en) * 2018-12-21 2020-06-24 Borealis AG Improved foaming behaviour of polymer compositions using blowing agent and nucleation agent
GB2585635B (en) 2019-05-28 2022-03-23 Kafrit Ind 1993 Ltd Compositions and methods for use in the preparation of hydrophobic surfaces

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US3808300A (en) * 1967-04-24 1974-04-30 Gas Chemical Co Inc Process for the preparation of closed-cellular shaped products of olefin polymers using a mixture of a citric acid salt and a carbonate or bicarbonate as the nucleation agent
EP0350969A3 (en) * 1984-10-11 1990-05-30 Daikin Industries, Limited Process for producing a foamed article of a fluorocarbon resin
JPS6191229A (ja) * 1984-10-11 1986-05-09 Daikin Ind Ltd フツ素樹脂発泡体の製法
US5225107A (en) * 1985-07-11 1993-07-06 Boehringer Ingelheim Gmbh Nucleating agents (pore regulators) for the preparation of directly gassed thermoplastic foams
US5405883A (en) * 1993-07-12 1995-04-11 The Dow Chemical Company Ethylene polymer foams blown with isobutane and 1,1-difluoroethane and a process for making
JPH07330935A (ja) * 1994-06-14 1995-12-19 Kanegafuchi Chem Ind Co Ltd 結晶性ポリオレフィン発泡体
JPH08157633A (ja) * 1994-12-01 1996-06-18 Kanegafuchi Chem Ind Co Ltd プロピレン系樹脂組成物押出発泡体およびその製法
US5688449A (en) * 1995-10-02 1997-11-18 Nitech Corporation Method of forming and extruding an additive-coated resin composition
EP0927288B1 (en) * 1996-09-04 2002-03-13 The Dow Chemical Company Floor, wall or ceiling covering
US6030696A (en) * 1997-09-30 2000-02-29 Sealed Air Corporation Extruded polyolefin foam in thicker grades and plank and process therefor
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US6069183A (en) * 1998-04-07 2000-05-30 Tenneco Packaging Inc. Foamable composition using high density polyethylene
US6207254B1 (en) * 1999-01-28 2001-03-27 Sealed Air Corporation Partially perforated foam
JP3461758B2 (ja) * 1999-07-19 2003-10-27 三菱電線工業株式会社 発泡用組成物および発泡同軸絶縁ケーブル
JP3520909B2 (ja) * 1999-09-30 2004-04-19 積水化成品工業株式会社 ポリオレフィン系樹脂発泡体とその製造方法
JP3883864B2 (ja) * 2001-12-28 2007-02-21 積水化成品工業株式会社 無架橋ポリオレフィン系樹脂発泡シート及びその製造方法
ES2300665T3 (es) * 2003-04-24 2008-06-16 National Research Council Of Canada Composicion de espuma de baja perdida y cable que contiene dicha espuma.
JP4728735B2 (ja) * 2004-08-04 2011-07-20 三井化学株式会社 オレフィン系熱可塑性エラストマー組成物及びその発泡体
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WO2014018768A1 (en) * 2012-07-27 2014-01-30 Reedy International Corporation Additives for low loss wire and cable dielectrics

Also Published As

Publication number Publication date
WO2016082212A1 (en) 2016-06-02
JP6584505B2 (ja) 2019-10-02
CA2969005A1 (en) 2016-06-02
US20170267828A1 (en) 2017-09-21
CN107148654A (zh) 2017-09-08
CA2969005C (en) 2021-12-14
KR102306265B1 (ko) 2021-09-29
CN107148654B (zh) 2020-03-10
EP3224836A4 (en) 2018-08-22
EP3224836A1 (en) 2017-10-04
EP3224836B1 (en) 2019-12-25
BR112017010189A2 (pt) 2018-02-06
KR20170095213A (ko) 2017-08-22
JP2017535656A (ja) 2017-11-30
MX390558B (es) 2025-03-20
BR112017010189B1 (pt) 2022-01-11

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