MX2019012006A - Proceso para la recuperacion de litio. - Google Patents
Proceso para la recuperacion de litio.Info
- Publication number
- MX2019012006A MX2019012006A MX2019012006A MX2019012006A MX2019012006A MX 2019012006 A MX2019012006 A MX 2019012006A MX 2019012006 A MX2019012006 A MX 2019012006A MX 2019012006 A MX2019012006 A MX 2019012006A MX 2019012006 A MX2019012006 A MX 2019012006A
- Authority
- MX
- Mexico
- Prior art keywords
- lithium
- aluminum
- recovery
- precipitate
- compositions
- Prior art date
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052744 lithium Inorganic materials 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- 238000011084 recovery Methods 0.000 title abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 4
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 2
- 239000002893 slag Substances 0.000 abstract 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 238000003723 Smelting Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/02—Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action including acoustic waves
- C22B9/023—By filtering
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Secondary Cells (AREA)
Abstract
La presente invención se refiere a un proceso mejorado para la recuperación de litio de composiciones que también contienen aluminio. Un ejemplo de tales composiciones metalúrgicas es la escoria metalúrgica que se obtiene cuando se reciclan baterías de iones de litio o sus productos derivados usando un proceso de fundición pirometalúrgica. La lixiviación ácida de tal escoria, seguida por neutralización para precipitar aluminio lleva a pobres rendimientos de litio ya que el litio tiende a co-precipitar con aluminio. Se presenta un proceso en donde se precipita aluminio selectivamente usando una fuente de fosfato en un pH controlado preferiblemente entre 3 y 4.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17165533 | 2017-04-07 | ||
| PCT/EP2018/057569 WO2018184876A1 (en) | 2017-04-07 | 2018-03-26 | Process for the recovery of lithium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019012006A true MX2019012006A (es) | 2019-11-11 |
Family
ID=58501374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019012006A MX2019012006A (es) | 2017-04-07 | 2018-03-26 | Proceso para la recuperacion de litio. |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US20210123119A1 (es) |
| EP (1) | EP3607099B1 (es) |
| JP (1) | JP7128836B2 (es) |
| KR (1) | KR102514227B1 (es) |
| CN (1) | CN110494575B (es) |
| AU (1) | AU2018248786B2 (es) |
| BR (1) | BR112019020836B1 (es) |
| CA (1) | CA3057755C (es) |
| CL (1) | CL2019002809A1 (es) |
| EA (1) | EA201992236A1 (es) |
| ES (1) | ES2882605T3 (es) |
| MX (1) | MX2019012006A (es) |
| MY (1) | MY190885A (es) |
| PE (1) | PE20191742A1 (es) |
| PL (1) | PL3607099T3 (es) |
| PT (1) | PT3607099T (es) |
| RS (1) | RS62158B1 (es) |
| TW (1) | TWI746818B (es) |
| WO (1) | WO2018184876A1 (es) |
| ZA (1) | ZA201906584B (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE543505C2 (en) | 2019-04-15 | 2021-03-09 | Northvolt Ab | Process for the recovery of cathode materials in the recycling of lithium ion batteries |
| KR102680508B1 (ko) | 2020-08-24 | 2024-07-01 | 그린 라이온 피티이. 리미티드 | 리튬이온 배터리의 재활용에서의 불순물 제거 공정 |
| JP7166653B2 (ja) * | 2020-10-02 | 2022-11-08 | 株式会社アサカ理研 | 高純度リチウム塩水溶液の製造方法 |
| CN116323998A (zh) * | 2020-10-19 | 2023-06-23 | 关东电化工业株式会社 | 锂的回收方法及碳酸锂的制造方法 |
| JP7634980B2 (ja) * | 2020-12-14 | 2025-02-25 | Ｊｘ金属サーキュラーソリューションズ株式会社 | リチウムイオン電池廃棄物の処理方法 |
| JP2024524935A (ja) | 2021-06-23 | 2024-07-09 | ハー．ツェー．スタルク タングステン ゲゼルシャフト ミット ベシュレンクテル ハフツング | 湿式冶金還元処理による電池材料のリサイクルプロセス |
| MX2023015161A (es) | 2021-06-23 | 2024-01-22 | H C Starck Tungsten Gmbh | Proceso de reciclaje de materiales de baterias mediante tratamiento hidrometalurgico. |
| JP7472406B2 (ja) | 2022-01-17 | 2024-04-22 | グリーン リチウム－イオン プライベート リミテッド | リン酸鉄リチウム電池の再利用処理 |
| US12297520B2 (en) * | 2022-02-23 | 2025-05-13 | Green Li-Ion Pte. Ltd. | Processes and systems for purifying and recycling lithium-ion battery waste streams |
| JP2023143116A (ja) * | 2022-03-25 | 2023-10-06 | 株式会社アサカ理研 | 低濃度リチウム塩水溶液の濃縮方法 |
| WO2023204761A1 (en) | 2022-04-18 | 2023-10-26 | Green Li-Ion Pte. Ltd | Process and system for recovering lithium from lithium-ion batteries |
| CN116002736B (zh) * | 2022-12-29 | 2024-06-11 | 四川顺应锂材料科技有限公司 | 一种黏土锂矿有压浸出分离铝和锂制备氢氧化铝的方法 |
| FR3151045A1 (fr) | 2023-07-13 | 2025-01-17 | Eramet | Procédé de purification d’un filtrat de lixiviation de la masse noire de batteries lithium-ion usagées |
| AU2024327911A1 (en) | 2023-08-23 | 2026-04-09 | Green Li-Ion Pte. Ltd. | Processes and systems for purifying independent streams of manganese, nickel, and cobalt from lithium-ion battery waste streams |
| KR102742452B1 (ko) * | 2023-12-15 | 2024-12-16 | 고려아연 주식회사 | 유가 금속 회수 방법 |
| DE102024116277A1 (de) * | 2024-06-11 | 2025-01-16 | cylib GmbH | Zementation |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4402919A (en) | 1981-03-19 | 1983-09-06 | Kerr-Mcgee Corporation | Process for the regeneration of mineral acids used to solubilize phosphate ores |
| JP3452769B2 (ja) * | 1997-09-18 | 2003-09-29 | 株式会社東芝 | 電池の処理方法 |
| CN100503849C (zh) * | 2006-11-24 | 2009-06-24 | 江西赣锋锂业股份有限公司 | 硫酸法锂云母提锂工艺中精硫酸锂溶液的生产方法 |
| US8936770B2 (en) * | 2010-01-22 | 2015-01-20 | Molycorp Minerals, Llc | Hydrometallurgical process and method for recovering metals |
| WO2011141297A1 (en) | 2010-05-12 | 2011-11-17 | Umicore | Lithium-bearing slag as aggregate in concrete |
| JP5533700B2 (ja) * | 2011-01-27 | 2014-06-25 | 住友金属鉱山株式会社 | 有価金属の浸出方法及びこの浸出方法を用いた有価金属の回収方法 |
| CN103173611B (zh) * | 2011-12-23 | 2016-09-28 | 贵州大学 | 从铝质岩中提取金属锂的方法 |
| JP5958316B2 (ja) | 2012-12-07 | 2016-07-27 | 住友金属鉱山株式会社 | アルミニウムの分離除去方法、並びにリチウムイオン電池からの有価金属の回収方法 |
| WO2014098357A1 (ko) * | 2012-12-21 | 2014-06-26 | 재단법인 포항산업과학연구원 | 리튬 함유 용액으로부터 리튬을 추출하는 방법 |
| CN103131873B (zh) * | 2013-01-31 | 2014-07-16 | 贵州大学 | 利用混酸分离铝质岩中的锂元素并制备碳酸锂的方法 |
| CN103219561B (zh) * | 2013-03-28 | 2015-08-19 | 四川天齐锂业股份有限公司 | 锰酸锂电池正极材料回收方法 |
| CN103199320B (zh) * | 2013-03-28 | 2015-05-27 | 四川天齐锂业股份有限公司 | 镍钴锰三元正极材料回收利用的方法 |
| JP6480235B2 (ja) * | 2015-03-30 | 2019-03-06 | Ｊｘ金属株式会社 | リチウムイオン電池スクラップからの鉄及びアルミニウムの除去方法 |
| CN105039699B (zh) * | 2015-06-03 | 2018-01-02 | 江西合纵锂业科技有限公司 | 锂云母固氟重构提取碱金属渣处理与资源化利用方法 |
| JP6622998B2 (ja) | 2015-08-10 | 2019-12-18 | Ｊｘ金属株式会社 | リチウムイオン電池スクラップからの鉄及びアルミニウムの除去方法及び、有価金属の回収方法 |
| CN105244564B (zh) * | 2015-11-14 | 2017-07-04 | 福州大学 | 一种磷酸铁锂动力电池的回收利用方法 |
| CN105907983A (zh) * | 2016-04-20 | 2016-08-31 | 天齐锂业股份有限公司 | 从火法回收锂电池产生的炉渣中提取锂的方法 |
| CN106505270B (zh) * | 2016-09-28 | 2018-07-27 | 荆门市格林美新材料有限公司 | 从废旧锂离子电池正极片中回收钴和锂的方法 |
| CN106532172B (zh) * | 2016-12-23 | 2019-05-21 | 江西合纵锂业科技有限公司 | 一种从失效磷酸铁锂电池正极材料中选择性浸出锂的方法 |
-
2018
- 2018-03-12 TW TW107108241A patent/TWI746818B/zh active
- 2018-03-26 KR KR1020197031321A patent/KR102514227B1/ko active Active
- 2018-03-26 ES ES18722894T patent/ES2882605T3/es active Active
- 2018-03-26 WO PCT/EP2018/057569 patent/WO2018184876A1/en not_active Ceased
- 2018-03-26 JP JP2019554763A patent/JP7128836B2/ja active Active
- 2018-03-26 US US16/500,127 patent/US20210123119A1/en active Pending
- 2018-03-26 RS RS20210941A patent/RS62158B1/sr unknown
- 2018-03-26 EA EA201992236A patent/EA201992236A1/ru unknown
- 2018-03-26 PT PT187228945T patent/PT3607099T/pt unknown
- 2018-03-26 AU AU2018248786A patent/AU2018248786B2/en active Active
- 2018-03-26 CA CA3057755A patent/CA3057755C/en active Active
- 2018-03-26 MY MYPI2019005880A patent/MY190885A/en unknown
- 2018-03-26 EP EP18722894.5A patent/EP3607099B1/en active Active
- 2018-03-26 MX MX2019012006A patent/MX2019012006A/es unknown
- 2018-03-26 PE PE2019001969A patent/PE20191742A1/es unknown
- 2018-03-26 BR BR112019020836-4A patent/BR112019020836B1/pt active IP Right Grant
- 2018-03-26 CN CN201880023623.7A patent/CN110494575B/zh active Active
- 2018-03-26 PL PL18722894T patent/PL3607099T3/pl unknown
-
2019
- 2019-10-02 CL CL2019002809A patent/CL2019002809A1/es unknown
- 2019-10-07 ZA ZA2019/06584A patent/ZA201906584B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA3057755C (en) | 2024-05-14 |
| EA201992236A1 (ru) | 2020-04-02 |
| KR20190138807A (ko) | 2019-12-16 |
| EP3607099A1 (en) | 2020-02-12 |
| ZA201906584B (en) | 2021-01-27 |
| KR102514227B1 (ko) | 2023-03-24 |
| ES2882605T3 (es) | 2021-12-02 |
| TWI746818B (zh) | 2021-11-21 |
| MY190885A (en) | 2022-05-17 |
| CN110494575B (zh) | 2021-12-21 |
| CA3057755A1 (en) | 2018-10-11 |
| PL3607099T3 (pl) | 2021-11-02 |
| TW201842198A (zh) | 2018-12-01 |
| CN110494575A (zh) | 2019-11-22 |
| PT3607099T (pt) | 2021-07-28 |
| AU2018248786B2 (en) | 2023-11-23 |
| PE20191742A1 (es) | 2019-12-12 |
| RS62158B1 (sr) | 2021-08-31 |
| WO2018184876A1 (en) | 2018-10-11 |
| JP2020516769A (ja) | 2020-06-11 |
| US20210123119A1 (en) | 2021-04-29 |
| BR112019020836A2 (pt) | 2020-05-12 |
| JP7128836B2 (ja) | 2022-08-31 |
| AU2018248786A1 (en) | 2019-10-31 |
| EP3607099B1 (en) | 2021-05-12 |
| CL2019002809A1 (es) | 2020-03-06 |
| BR112019020836B1 (pt) | 2022-12-06 |
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