MX340954B - Procedimiento para producir acido acetico. - Google Patents
Procedimiento para producir acido acetico.Info
- Publication number
- MX340954B MX340954B MX2013006882A MX2013006882A MX340954B MX 340954 B MX340954 B MX 340954B MX 2013006882 A MX2013006882 A MX 2013006882A MX 2013006882 A MX2013006882 A MX 2013006882A MX 340954 B MX340954 B MX 340954B
- Authority
- MX
- Mexico
- Prior art keywords
- concentration
- iodide
- acetic acid
- reactor
- methyl
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 9
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 230000006315 carbonylation Effects 0.000 abstract 3
- 238000005810 carbonylation reaction Methods 0.000 abstract 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 3
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 3
- 239000003863 metallic catalyst Substances 0.000 abstract 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- -1 lithium iodide) Chemical compound 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
- C07C51/46—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by azeotropic distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se produce ácido acético mientras al mismo tiempo se inhibe un aumento en la concentración o la producción de yoduro de hidrógeno en un reactor de carbonilación o la corrosión del reactor de carbonilación; un procedimiento de producción de ácido acético comprende un paso de reacción para permitir continuamente que metanol reaccione con monóxido de carbono en la presencia de un sistema de catalizador que comprende un catalizador metálico (por ejemplo, un catalizador de rodio), un yoduro iónico (por ejemplo, yoduro de litio), y yoduro de metilo en un reactor de carbonilación; y en el procedimiento, (i) la concentración del catalizador metálico se mantiene en no menor que 860 ppm en base al peso, la concentración de agua se mantiene en 0.8 a 15% en peso, la concentración de yoduro de metilo se mantiene en no mayor que 13.9% en peso, y la concentración de acetato de metilo se mantienen en no menor que 0.1% en peso, en una fase líquida completa en el reactor, y/o (ii) la concentración del catalizador metálico se mantiene en no menor que 660 ppm en base al peso, la concentración de agua se mantiene en 0.8 a 3.9% en peso, la concentración del yoduro iónico se mantiene en no mayor que 13% en peso, la concentración de yoduro de metilo se mantiene en no mayor que 13.9% en peso, y la concentración de acetato de metilo se mantiene en no menor que 0.1% en peso, en una fase líquida completa en el reactor.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010279797 | 2010-12-15 | ||
| PCT/JP2011/077844 WO2012081416A1 (ja) | 2010-12-15 | 2011-12-01 | 酢酸の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013006882A MX2013006882A (es) | 2013-07-05 |
| MX340954B true MX340954B (es) | 2016-07-29 |
Family
ID=46244525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013006882A MX340954B (es) | 2010-12-15 | 2011-12-01 | Procedimiento para producir acido acetico. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9115071B2 (es) |
| EP (1) | EP2653459B2 (es) |
| JP (1) | JP5823981B2 (es) |
| KR (1) | KR101879006B1 (es) |
| CN (1) | CN103370297B (es) |
| BR (1) | BR112013014801B1 (es) |
| ES (1) | ES2688801T5 (es) |
| MX (1) | MX340954B (es) |
| MY (1) | MY160900A (es) |
| SG (1) | SG190939A1 (es) |
| TW (1) | TWI529156B (es) |
| WO (1) | WO2012081416A1 (es) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY161174A (en) * | 2010-12-15 | 2017-04-14 | Daicel Corp | Process for producing acetic acid |
| MX340954B (es) | 2010-12-15 | 2016-07-29 | Daicel Corp | Procedimiento para producir acido acetico. |
| US10988432B2 (en) | 2013-03-07 | 2021-04-27 | Ineos Acetyls Uk Limited | Process for the co-production of acetic acid and acetic anhydride |
| JP2014240057A (ja) * | 2013-06-12 | 2014-12-25 | 千代田化工建設株式会社 | アルデヒド吸着材、アルデヒドの除去方法、酢酸の製造方法及びアルデヒド吸着材の再生方法 |
| KR102465649B1 (ko) | 2014-11-14 | 2022-11-11 | 셀라니즈 인터내셔날 코포레이션 | 낮은 요오드화에틸 함량을 갖는 반응 매질로부터 아세트산을 제조하기 위한 방법 |
| US9458077B2 (en) | 2014-11-14 | 2016-10-04 | Celanese International Corporation | Reducing hydrogen iodide content in carbonylation processes |
| US9540304B2 (en) | 2014-11-14 | 2017-01-10 | Celanese International Corporation | Processes for producing an acetic acid product having low butyl acetate content |
| KR102439491B1 (ko) * | 2014-11-14 | 2022-09-01 | 셀라니즈 인터내셔날 코포레이션 | 아세트산리튬을 포함하는 반응 매질을 플래싱하기 위한 방법 |
| US9233907B1 (en) | 2014-11-14 | 2016-01-12 | Celanese International Corporation | Reducing hydrogen iodide content in carbonylation processes |
| KR102397552B1 (ko) | 2014-11-14 | 2022-05-12 | 셀라니즈 인터내셔날 코포레이션 | 디캔터 제어를 수반하는 아세트산을 제조하기 위한 방법 |
| CN107108434A (zh) | 2014-11-14 | 2017-08-29 | 国际人造丝公司 | 通过去除铁改进乙酸产率的方法 |
| WO2016076971A1 (en) * | 2014-11-14 | 2016-05-19 | Celanese International Corporation | Process for producing acetic acid by introducing a lithium compound |
| US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
| US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9540302B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| MX2017009867A (es) | 2015-01-30 | 2017-11-15 | Celanese Int Corp | Procedimientos para producir acido acetico. |
| US9512056B2 (en) * | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9382186B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for producing acetic acid |
| RS63644B1 (sr) | 2015-10-02 | 2022-10-31 | Celanese Int Corp | Postupak za proizvodnju sirćetne kiseline recikliranjem vode |
| US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| BR112018074026A2 (pt) | 2016-07-07 | 2019-02-26 | Daicel Corporation | processos para separação ou remoção de compostos redutores de permanganato (prc?s) de uma primeira mistura e para produção de ácido acético |
| MX370246B (es) | 2016-10-28 | 2019-12-04 | Daicel Corp | Metodo para la produccion de acido acetico. |
| BR112019014638A2 (pt) * | 2017-01-18 | 2020-07-07 | Daicel Corporation | método para produzir ácido acético |
| US10246399B2 (en) * | 2017-02-07 | 2019-04-02 | Daicel Corporation | Process for producing acetic acid |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| US5391821A (en) | 1983-09-02 | 1995-02-21 | Daicel Chemical Industries, Ltd. | Process for producing carboxylic acids |
| JPH05140024A (ja) | 1983-09-02 | 1993-06-08 | Daicel Chem Ind Ltd | 酢酸の製造法 |
| CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
| US5334755A (en) | 1992-04-24 | 1994-08-02 | Chiyoda Corporation | Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst |
| GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
| JP3308392B2 (ja) | 1994-06-02 | 2002-07-29 | ダイセル化学工業株式会社 | カルボニル化反応方法 |
| JPH08277244A (ja) | 1995-04-05 | 1996-10-22 | Daicel Chem Ind Ltd | カルボン酸の製造方法及びカルボニル化反応用触媒系 |
| GB9626429D0 (en) | 1996-12-19 | 1997-02-05 | Bp Chem Int Ltd | Process |
| US6211405B1 (en) | 1998-10-23 | 2001-04-03 | Celanese International Corporation | Addition of iridium to the rhodium/inorganic iodide catalyst system |
| US6303813B1 (en) | 1999-08-31 | 2001-10-16 | Celanese International Corporation | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
| US6420304B1 (en) * | 2000-04-20 | 2002-07-16 | China Petrochemical Development Corporation | Polymer-supported carbonylation catalyst and its use |
| US6657078B2 (en) * | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
| DE10225686B4 (de) * | 2002-06-10 | 2005-08-04 | Siemens Ag | Hubübertragungselement für ein Einspritzventil |
| GB0213485D0 (en) | 2002-06-12 | 2002-07-24 | Bp Chem Int Ltd | Process |
| US7005541B2 (en) | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
| JP4732743B2 (ja) | 2004-12-06 | 2011-07-27 | ダイセル化学工業株式会社 | 蒸留方法 |
| JP5075336B2 (ja) * | 2004-12-20 | 2012-11-21 | 株式会社ダイセル | 酢酸の製造方法 |
| EP1912926A2 (en) | 2005-07-14 | 2008-04-23 | Daicel Chemical Industries, Ltd. | Process for producing carboxylic acid |
| US20090082593A1 (en) | 2005-10-03 | 2009-03-26 | Hidetaka Kojima | Process for the Production of Acetic Acid |
| US7989659B2 (en) | 2007-05-17 | 2011-08-02 | Celanese International Corporation | Method and apparatus for making acetic acid with improved light ends column productivity |
| CN102131758A (zh) | 2008-06-28 | 2011-07-20 | Aa保费投资公司 | 用于生产羧酸的组合物及其制备方法和使用方法 |
| US20100113827A1 (en) | 2008-11-03 | 2010-05-06 | Wei Wang | Removing iodobenzene compounds from acetic acid |
| US8957248B2 (en) | 2010-07-26 | 2015-02-17 | Daicel Corporation | Process for producing acetic acid |
| JP5116821B2 (ja) | 2010-09-24 | 2013-01-09 | 株式会社藤商事 | 遊技機 |
| MX340954B (es) | 2010-12-15 | 2016-07-29 | Daicel Corp | Procedimiento para producir acido acetico. |
-
2011
- 2011-12-01 MX MX2013006882A patent/MX340954B/es active IP Right Grant
- 2011-12-01 SG SG2013042015A patent/SG190939A1/en unknown
- 2011-12-01 KR KR1020137018275A patent/KR101879006B1/ko active Active
- 2011-12-01 BR BR112013014801-2A patent/BR112013014801B1/pt not_active IP Right Cessation
- 2011-12-01 JP JP2012548726A patent/JP5823981B2/ja active Active
- 2011-12-01 CN CN201180067612.7A patent/CN103370297B/zh not_active Ceased
- 2011-12-01 ES ES11849332T patent/ES2688801T5/es active Active
- 2011-12-01 MY MYPI2013002218A patent/MY160900A/en unknown
- 2011-12-01 US US13/994,373 patent/US9115071B2/en active Active
- 2011-12-01 WO PCT/JP2011/077844 patent/WO2012081416A1/ja not_active Ceased
- 2011-12-01 EP EP11849332.9A patent/EP2653459B2/en active Active
- 2011-12-14 TW TW100146094A patent/TWI529156B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| JP5823981B2 (ja) | 2015-11-25 |
| WO2012081416A1 (ja) | 2012-06-21 |
| TW201231449A (en) | 2012-08-01 |
| ES2688801T3 (es) | 2018-11-07 |
| ES2688801T5 (es) | 2022-03-29 |
| CN103370297A (zh) | 2013-10-23 |
| SG190939A1 (en) | 2013-07-31 |
| TWI529156B (zh) | 2016-04-11 |
| EP2653459B1 (en) | 2018-08-22 |
| US9115071B2 (en) | 2015-08-25 |
| CN103370297B (zh) | 2015-10-07 |
| MX2013006882A (es) | 2013-07-05 |
| BR112013014801B1 (pt) | 2019-04-02 |
| EP2653459B2 (en) | 2021-12-08 |
| KR20130127491A (ko) | 2013-11-22 |
| JPWO2012081416A1 (ja) | 2014-05-22 |
| BR112013014801A2 (pt) | 2016-09-27 |
| EP2653459A1 (en) | 2013-10-23 |
| US20130310603A1 (en) | 2013-11-21 |
| KR101879006B1 (ko) | 2018-07-16 |
| MY160900A (en) | 2017-03-31 |
| EP2653459A4 (en) | 2016-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |