NL1002526C2 - Katalysatorvrije ozonoxydatie van zetmeel. - Google Patents

Katalysatorvrije ozonoxydatie van zetmeel. Download PDF

Info

Publication number: NL1002526C2
Authority: NL; Netherlands
Prior art keywords: starch; ozone; reaction; oxidation; suspension
Prior art date: 1996-03-04

Application number

NL1002526A

Other languages

English (en)

Dutch (nl)

Inventor

Ido Pieter Bleeker

Ronald Peter Wilhel Kesselmans

Original Assignee

Avebe Coop Verkoop Prod

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-04

Filing date

1996-03-04

Publication date

1997-09-05

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19762439&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NL1002526(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1996-03-04 Application filed by Avebe Coop Verkoop Prod filed Critical Avebe Coop Verkoop Prod

1996-03-04 Priority to NL1002526A priority Critical patent/NL1002526C2/nl

1997-03-04 Priority to DE69700835T priority patent/DE69700835T2/de

1997-03-04 Priority to AT97905508T priority patent/ATE186915T1/de

1997-03-04 Priority to AU22362/97A priority patent/AU2236297A/en

1997-03-04 Priority to EP97905508A priority patent/EP0885245B1/de

1997-03-04 Priority to PCT/NL1997/000106 priority patent/WO1997035890A1/en

1997-03-04 Priority to IDP970661A priority patent/ID16116A/id

1997-09-05 Application granted granted Critical

1997-09-05 Publication of NL1002526C2 publication Critical patent/NL1002526C2/nl

Links

CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 74
229920002472 Starch Polymers 0.000 title claims abstract description 57
235000019698 starch Nutrition 0.000 title claims abstract description 57
239000008107 starch Substances 0.000 title claims abstract description 45
238000007254 oxidation reaction Methods 0.000 title claims abstract description 33
230000003647 oxidation Effects 0.000 title claims abstract description 32
238000000034 method Methods 0.000 claims abstract description 31
229920001592 potato starch Polymers 0.000 claims abstract description 23
229920002261 Corn starch Polymers 0.000 claims abstract description 20
240000003183 Manihot esculenta Species 0.000 claims abstract description 7
235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims abstract description 7
238000006243 chemical reaction Methods 0.000 claims description 31
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 27
239000000725 suspension Substances 0.000 claims description 16
239000008120 corn starch Substances 0.000 claims description 15
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 11
239000000243 solution Substances 0.000 claims description 10
239000007900 aqueous suspension Substances 0.000 claims description 7
230000001590 oxidative effect Effects 0.000 claims description 6
239000003054 catalyst Substances 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 4
239000002518 antifoaming agent Substances 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 claims description 2
238000009958 sewing Methods 0.000 claims 1
235000019759 Maize starch Nutrition 0.000 abstract description 4
235000013339 cereals Nutrition 0.000 abstract description 4
229920000881 Modified starch Polymers 0.000 abstract description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
235000019426 modified starch Nutrition 0.000 abstract description 2
239000012736 aqueous medium Substances 0.000 abstract 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 60
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
239000007789 gas Substances 0.000 description 15
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
239000001301 oxygen Substances 0.000 description 10
229910052760 oxygen Inorganic materials 0.000 description 10
230000008569 process Effects 0.000 description 9
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 7
239000007800 oxidant agent Substances 0.000 description 7
238000004448 titration Methods 0.000 description 7
230000008901 benefit Effects 0.000 description 6
239000004575 stone Substances 0.000 description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
150000004676 glycans Chemical class 0.000 description 5
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 5
229920001282 polysaccharide Polymers 0.000 description 5
239000005017 polysaccharide Substances 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
125000003172 aldehyde group Chemical group 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
229920000945 Amylopectin Polymers 0.000 description 3
RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
235000013305 food Nutrition 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
238000010626 work up procedure Methods 0.000 description 3
229920000856 Amylose Polymers 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
229920002085 Dialdehyde starch Polymers 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
240000008042 Zea mays Species 0.000 description 2
235000002017 Zea mays subsp mays Nutrition 0.000 description 2
150000001241 acetals Chemical class 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
239000012159 carrier gas Substances 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
230000000694 effects Effects 0.000 description 2
235000013312 flour Nutrition 0.000 description 2
238000005187 foaming Methods 0.000 description 2
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
150000002466 imines Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 2
150000002632 lipids Chemical class 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000012429 reaction media Substances 0.000 description 2
239000000523 sample Substances 0.000 description 2
229910001923 silver oxide Inorganic materials 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000004370 Bleached starch Substances 0.000 description 1
244000000626 Daucus carota Species 0.000 description 1
235000002767 Daucus carota Nutrition 0.000 description 1
229920002245 Dextrose equivalent Polymers 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
239000012431 aqueous reaction media Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229920000704 biodegradable plastic Polymers 0.000 description 1
235000019428 bleached starch Nutrition 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
229910001919 chlorite Inorganic materials 0.000 description 1
QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 description 1
229910052619 chlorite group Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
235000005822 corn Nutrition 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
239000006066 glass batch Substances 0.000 description 1
239000008103 glucose Substances 0.000 description 1
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
125000000468 ketone group Chemical group 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
235000009973 maize Nutrition 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
239000000203 mixture Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000001254 oxidized starch Substances 0.000 description 1
235000013808 oxidized starch Nutrition 0.000 description 1
KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000000546 pharmaceutical excipient Substances 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
238000004886 process control Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000004044 response Effects 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000002351 wastewater Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Biochemistry (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Catalysts (AREA)

NL1002526A 1996-03-04 1996-03-04 Katalysatorvrije ozonoxydatie van zetmeel. NL1002526C2 (nl)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
NL1002526A NL1002526C2 (nl)	1996-03-04	1996-03-04	Katalysatorvrije ozonoxydatie van zetmeel.
DE69700835T DE69700835T2 (de)	1996-03-04	1997-03-04	Katalysatorfreie ozon-oxidation von stärke
AT97905508T ATE186915T1 (de)	1996-03-04	1997-03-04	Katalysatorfreie ozon-oxidation von stärke
AU22362/97A AU2236297A (en)	1996-03-04	1997-03-04	Catalyst-free ozone oxidation of starch
EP97905508A EP0885245B1 (de)	1996-03-04	1997-03-04	Katalysatorfreie ozon-oxidation von stärke
PCT/NL1997/000106 WO1997035890A1 (en)	1996-03-04	1997-03-04	Catalyst-free ozone oxidation of starch
IDP970661A ID16116A (id)	1996-03-04	1997-03-04	Oksidasi pati dengan ozon yang bebas katalis

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL1002526A NL1002526C2 (nl)	1996-03-04	1996-03-04	Katalysatorvrije ozonoxydatie van zetmeel.
NL1002526		1996-03-04

Publications (1)

Publication Number	Publication Date
NL1002526C2 true NL1002526C2 (nl)	1997-09-05

Family

ID=19762439

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL1002526A NL1002526C2 (nl)	1996-03-04	1996-03-04	Katalysatorvrije ozonoxydatie van zetmeel.

Country Status (7)

Country	Link
EP (1)	EP0885245B1 (de)
AT (1)	ATE186915T1 (de)
AU (1)	AU2236297A (de)
DE (1)	DE69700835T2 (de)
ID (1)	ID16116A (de)
NL (1)	NL1002526C2 (de)
WO (1)	WO1997035890A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SE515725C2 (sv) *	1999-11-29	2001-10-01	Sveriges Staerkelseproduct Foe	Oxidation av stärkelse
US6322632B1 (en)	2000-02-18	2001-11-27	Archer-Daniels-Midland Corporation	Method for producing oxidized starch
US9376648B2 (en)	2008-04-07	2016-06-28	The Procter & Gamble Company	Foam manipulation compositions containing fine particles
KR20170134349A (ko)	2015-02-04	2017-12-06	알스트롬-문크스조 데팅겐 게엠바하	바이오폴리머 나노입자를 포함하는 사전-함침된 장식 원지를 제조하기 위한 조성물 및 방법
CN105504075B (zh) *	2015-12-11	2018-09-18	武汉轻工大学	一种干法降低淀粉分子量的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6140301A (ja) *	1984-07-31	1986-02-26	Hokuetsu Seishi Kk	オゾンによる酸化澱粉の製造法

1996
- 1996-03-04 NL NL1002526A patent/NL1002526C2/nl not_active IP Right Cessation
1997
- 1997-03-04 WO PCT/NL1997/000106 patent/WO1997035890A1/en not_active Ceased
- 1997-03-04 EP EP97905508A patent/EP0885245B1/de not_active Expired - Lifetime
- 1997-03-04 AT AT97905508T patent/ATE186915T1/de active
- 1997-03-04 DE DE69700835T patent/DE69700835T2/de not_active Expired - Lifetime
- 1997-03-04 AU AU22362/97A patent/AU2236297A/en not_active Abandoned
- 1997-03-04 ID IDP970661A patent/ID16116A/id unknown

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6140301A (ja) *	1984-07-31	1986-02-26	Hokuetsu Seishi Kk	オゾンによる酸化澱粉の製造法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
C. D. SZYMANSKI: "Ozone Oxidation of Corn Starch", JOURNAL OF APPLIED POLYMER SCIENCE, vol. 8, no. 4, 1964, US, pages 1597 - 1606, XP002017225 *
DATABASE WPI Week 86, Derwent World Patents Index; Class 15, AN 86-096640, XP002017226 *
P. ANGIBEAUD ET AL.: "Cellulose and Starch Reactivity with Ozone", CELLULOSE AND ITS DERIVATIVES, CHEMISTRY, BIOCHEMISTRY AND APPLICATIONS, 1985, UK, pages 161 - 171, XP000607692 *

Also Published As

Publication number	Publication date
EP0885245B1 (de)	1999-11-24
DE69700835T2 (de)	2000-05-18
EP0885245A1 (de)	1998-12-23
ATE186915T1 (de)	1999-12-15
ID16116A (id)	1997-09-04
DE69700835D1 (de)	1999-12-30
AU2236297A (en)	1997-10-17
WO1997035890A1 (en)	1997-10-02

Legal Events

Date	Code	Title	Description
1997-11-03	PD2B	A search report has been drawn up
2006-10-02	TD	Modifications of names of proprietors of patents	Owner name: COOEPERATIE AVEBE U.A. Effective date: 20060711
2012-08-22	PLEX	Lifting of former pledge	Effective date: 20120814
2012-10-10	V1	Lapsed because of non-payment of the annual fee	Effective date: 20121001

Publication	Publication Date	Title
AU672869B2 (en)	1996-10-17	Purification of polysaccharides
US4035235A (en)	1977-07-12	Method of making lipophilic starch derivatives
Chattopadhyay et al.	1997	Optimisation of conditions of synthesis of oxidised starch from corn and amaranth for use in film-forming applications
JP3685517B2 (ja)	2005-08-17	デンプン生成物の製造方法
CA2302567C (en)	2007-04-17	Modified starch
CA2412491C (fr)	2012-04-10	Utilisation papetiere et non papetiere d'une composition amylacee contenant une matiere amylacee cationique selectionnee
FI105690B (fi)	2000-09-29	Menetelmä hapetetun tärkkelyksen valmistamiseksi
EP1969014B1 (de)	2010-01-27	Verfahren zur modifizierung von stärke
NL1002526C2 (nl)	1997-09-05	Katalysatorvrije ozonoxydatie van zetmeel.
AU723782B2 (en)	2000-09-07	Process for oxidising starch
NL1007158C2 (nl)	1999-03-30	Enzymatische modificatie.
RU2160805C2 (ru)	2000-12-20	Отделочный агент
NL1004793C2 (nl)	1998-06-17	Werkwijze voor de oxidatie van zetmeel met perjodaat.
NL1002525C2 (nl)	1997-09-05	Werkwijze voor het oxideren van droog zetmeel onder toepassing van ozon.
NL1002527C2 (nl)	1997-09-05	Werkwijze voor het oxyderen van polysacchariden onder toepassing van ozon in aanwezigheid van een halogeniden bevattende katalysator.
Satmalawati et al.	2020	Physicochemical properties of ozone-oxidized cassava starch under different slurry concentration
Besemer et al.	1994	The relation between calcium sequestering capacity and oxidation degree of dicarboxy‐starch and dicarboxy‐inulin
EP0630906A1 (de)	1994-12-28	Verflüssigung von körniger Stärke
JP5209256B2 (ja)	2013-06-12	増粘効果の高い澱粉及びその製造方法
EP1242462B1 (de)	2005-05-18	Oxidation von stärke
US8552178B2 (en)	2013-10-08	Process for modification of biopolymers
JPH11140101A (ja)	1999-05-25	カルボキシ多糖類の製造方法
JPH11310601A (ja)	1999-11-09	高濃度トリカルボキシ多糖類水溶液の製造方法
JPS6210242B2 (de)	1987-03-05