NL1006200C2 - Werkwijze en systeem voor het selectief verwijderen van verontreinigingen uit gasstromen. - Google Patents
Werkwijze en systeem voor het selectief verwijderen van verontreinigingen uit gasstromen. Download PDFInfo
- Publication number
- NL1006200C2 NL1006200C2 NL1006200A NL1006200A NL1006200C2 NL 1006200 C2 NL1006200 C2 NL 1006200C2 NL 1006200 A NL1006200 A NL 1006200A NL 1006200 A NL1006200 A NL 1006200A NL 1006200 C2 NL1006200 C2 NL 1006200C2
- Authority
- NL
- Netherlands
- Prior art keywords
- metal
- gas
- gas stream
- sulfate
- solution
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 70
- 239000000356 contaminant Substances 0.000 title abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 63
- 239000002184 metal Substances 0.000 claims abstract description 63
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 17
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002244 precipitate Substances 0.000 claims abstract description 9
- 150000003839 salts Chemical class 0.000 claims abstract description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 28
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 22
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical group [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 16
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 15
- 239000011701 zinc Substances 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 11
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 11
- 239000012266 salt solution Substances 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 230000008929 regeneration Effects 0.000 claims description 8
- 238000011069 regeneration method Methods 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 239000011133 lead Substances 0.000 claims description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- 238000011109 contamination Methods 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 230000001172 regenerating effect Effects 0.000 claims description 2
- 239000010944 silver (metal) Substances 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 150000002826 nitrites Chemical class 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 5
- 239000005864 Sulphur Substances 0.000 abstract 2
- 150000005323 carbonate salts Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 99
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 88
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
- 239000000243 solution Substances 0.000 description 42
- 238000006243 chemical reaction Methods 0.000 description 31
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 30
- 239000007788 liquid Substances 0.000 description 20
- 229910002092 carbon dioxide Inorganic materials 0.000 description 16
- 235000011121 sodium hydroxide Nutrition 0.000 description 16
- 238000010521 absorption reaction Methods 0.000 description 15
- 239000001569 carbon dioxide Substances 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 15
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 14
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 13
- 238000001556 precipitation Methods 0.000 description 13
- 239000007791 liquid phase Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000009792 diffusion process Methods 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 238000012856 packing Methods 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 230000002745 absorbent Effects 0.000 description 6
- 239000002250 absorbent Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
- 150000002500 ions Chemical group 0.000 description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910000010 zinc carbonate Inorganic materials 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 description 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000005083 Zinc sulfide Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003034 coal gas Substances 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 235000004416 zinc carbonate Nutrition 0.000 description 3
- 239000011667 zinc carbonate Substances 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 230000007850 degeneration Effects 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 150000004698 iron complex Chemical class 0.000 description 2
- 229910000358 iron sulfate Inorganic materials 0.000 description 2
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 2
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 2
- 238000005184 irreversible process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 235000009529 zinc sulphate Nutrition 0.000 description 2
- 239000011686 zinc sulphate Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004277 Ferrous carbonate Substances 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 239000005569 Iron sulphate Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FMEHGPQTMOPUGM-UHFFFAOYSA-N Tddf Natural products C1=C(O)C(OC)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)OC)=C1 FMEHGPQTMOPUGM-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- OVFCVRIJCCDFNQ-UHFFFAOYSA-N carbonic acid;copper Chemical compound [Cu].OC(O)=O OVFCVRIJCCDFNQ-UHFFFAOYSA-N 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 229910000009 copper(II) carbonate Inorganic materials 0.000 description 1
- BQJTUDIVKSVBDU-UHFFFAOYSA-L copper;sulfuric acid;sulfate Chemical compound [Cu+2].OS(O)(=O)=O.[O-]S([O-])(=O)=O BQJTUDIVKSVBDU-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000011646 cupric carbonate Substances 0.000 description 1
- 235000019854 cupric carbonate Nutrition 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000006196 drop Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000019268 ferrous carbonate Nutrition 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/20—Methods for preparing sulfides or polysulfides, in general
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Separation Of Gases By Adsorption (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1006200A NL1006200C2 (nl) | 1997-06-02 | 1997-06-02 | Werkwijze en systeem voor het selectief verwijderen van verontreinigingen uit gasstromen. |
| AU77914/98A AU7791498A (en) | 1997-06-02 | 1998-05-29 | Method and system for selective removal of contamination from gas flows |
| PCT/NL1998/000312 WO1998055209A1 (en) | 1997-06-02 | 1998-05-29 | Method and system for selective removal of contamination from gas flows |
| DE69828784T DE69828784T2 (de) | 1997-06-02 | 1998-05-29 | Verfahren und anlage zur selektiven beseitigung von verunreinigung aus gasströmen |
| AT98925979T ATE287758T1 (de) | 1997-06-02 | 1998-05-29 | Verfahren und anlage zur selektiven beseitigung von verunreinigung aus gasströmen |
| EP98925979A EP0986432B1 (de) | 1997-06-02 | 1998-05-29 | Verfahren und anlage zur selektiven beseitigung von verunreinigung aus gasströmen |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1006200 | 1997-06-02 | ||
| NL1006200A NL1006200C2 (nl) | 1997-06-02 | 1997-06-02 | Werkwijze en systeem voor het selectief verwijderen van verontreinigingen uit gasstromen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL1006200C2 true NL1006200C2 (nl) | 1998-12-03 |
Family
ID=19765074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL1006200A NL1006200C2 (nl) | 1997-06-02 | 1997-06-02 | Werkwijze en systeem voor het selectief verwijderen van verontreinigingen uit gasstromen. |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0986432B1 (de) |
| AT (1) | ATE287758T1 (de) |
| AU (1) | AU7791498A (de) |
| DE (1) | DE69828784T2 (de) |
| NL (1) | NL1006200C2 (de) |
| WO (1) | WO1998055209A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007009943A1 (en) * | 2005-07-22 | 2007-01-25 | Shell Internationale Research Maatschappij B.V. | Process for producing a gas stream depleted of hydrogen sulphide and of mercaptans |
| EP2484427B1 (de) * | 2011-02-08 | 2017-07-19 | Neste Oyj | Zweistufiges Gasreinigungsverfahren |
| WO2012164467A1 (en) * | 2011-05-27 | 2012-12-06 | Frames Biogas Processing B.V. | Method for regenerating absorption liquid |
| EP2564918B1 (de) * | 2011-08-31 | 2018-03-07 | Neste Oyj | Zweistufiges Gasreinigungsverfahren mit Sulfidausfällung und Alkaliabsorption |
| EP2695660B1 (de) * | 2012-08-08 | 2018-01-10 | Neste Oyj | Verfahren zur Reinigung von Gasströmen resultierend aus einer Hydrierung, Hydrodeoxygenation oder Hydrocracking von Fettsäuren, deren Estern und Glyceriden |
| EP2808079B1 (de) | 2013-05-27 | 2016-12-14 | King Saud University | Absorbierendes Material, Herstellungsverfahren dafür und Verwendung davon |
| CN103432872B (zh) * | 2013-09-10 | 2015-05-27 | 南京大学 | 一种湿式选择性脱硫系统及其脱硫方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1225628A (fr) * | 1956-07-18 | 1960-07-01 | Pintsch Bamag Ag | Procédé et dispositif pour la purification des gaz |
| DE2304497A1 (de) * | 1973-01-31 | 1974-08-08 | Norddeutsche Affinerie | Verfahren zum entfernen von schwefelwasserstoff aus diesen enthaltenden gasen |
| US4202864A (en) * | 1978-09-01 | 1980-05-13 | Deuterium Corporation | Process for controlling environmental pollution from steam containing hydrogen sulfide |
| DE3300402A1 (de) * | 1983-01-07 | 1984-10-11 | Hoechst Ag, 6230 Frankfurt | Verfahren zur entfernung von schwefelwasserstoff aus gasen oder fluessigkeiten sowie mikroorganismus zur durchfuehrung des verfahrens |
| US5147620A (en) * | 1989-06-08 | 1992-09-15 | Linko Enterprises, Inc. | Process for the purification of gaseous streams |
| EP0628339A1 (de) * | 1993-06-14 | 1994-12-14 | VESTERAGER, Niels Ole | Verfahren zur Extraktion von unerwünschten Stoffen aus einem Gas |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4192854A (en) * | 1976-09-03 | 1980-03-11 | Eic Corporation | Process for removing hydrogen sulfide and ammonia from gaseous streams |
-
1997
- 1997-06-02 NL NL1006200A patent/NL1006200C2/nl not_active IP Right Cessation
-
1998
- 1998-05-29 AT AT98925979T patent/ATE287758T1/de not_active IP Right Cessation
- 1998-05-29 EP EP98925979A patent/EP0986432B1/de not_active Expired - Lifetime
- 1998-05-29 WO PCT/NL1998/000312 patent/WO1998055209A1/en not_active Ceased
- 1998-05-29 AU AU77914/98A patent/AU7791498A/en not_active Abandoned
- 1998-05-29 DE DE69828784T patent/DE69828784T2/de not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1225628A (fr) * | 1956-07-18 | 1960-07-01 | Pintsch Bamag Ag | Procédé et dispositif pour la purification des gaz |
| DE2304497A1 (de) * | 1973-01-31 | 1974-08-08 | Norddeutsche Affinerie | Verfahren zum entfernen von schwefelwasserstoff aus diesen enthaltenden gasen |
| US4202864A (en) * | 1978-09-01 | 1980-05-13 | Deuterium Corporation | Process for controlling environmental pollution from steam containing hydrogen sulfide |
| DE3300402A1 (de) * | 1983-01-07 | 1984-10-11 | Hoechst Ag, 6230 Frankfurt | Verfahren zur entfernung von schwefelwasserstoff aus gasen oder fluessigkeiten sowie mikroorganismus zur durchfuehrung des verfahrens |
| US5147620A (en) * | 1989-06-08 | 1992-09-15 | Linko Enterprises, Inc. | Process for the purification of gaseous streams |
| EP0628339A1 (de) * | 1993-06-14 | 1994-12-14 | VESTERAGER, Niels Ole | Verfahren zur Extraktion von unerwünschten Stoffen aus einem Gas |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69828784D1 (de) | 2005-03-03 |
| EP0986432A1 (de) | 2000-03-22 |
| DE69828784T2 (de) | 2006-04-06 |
| AU7791498A (en) | 1998-12-21 |
| EP0986432B1 (de) | 2005-01-26 |
| WO1998055209A1 (en) | 1998-12-10 |
| ATE287758T1 (de) | 2005-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2267565C (en) | A method for removing mercury and sulphur dioxide from gases | |
| EP3434353B1 (de) | Steuerung von quecksilberemissionen | |
| Ter Maat et al. | The removal of hydrogen sulfide from gas streams using an aqueous metal sulfate absorbent: Part I. The absorption of hydrogen sulfide in metal sulfate solutions | |
| CN104692579B (zh) | 一种冶炼烟气制酸废水资源化深度处理的方法 | |
| NO148962B (no) | Fremgangsmaate ved ekstraksjon og utvinning av kvikksoelv fra gasser. | |
| WO2010017652A1 (es) | Proceso y sistema para la separación, reciclado y estabilización ambiental sustentable de efluentes ácidos con arsénico (as) y/o metales pesados que forman sulfuros insolubles | |
| CN106731629B (zh) | 一种利用铜冶炼厂尾矿渣浆液脱硫脱砷汞的方法 | |
| CS277304B6 (en) | Process of microbiological conversion of sulfur-containing noxious substances in waste gases | |
| NL1006200C2 (nl) | Werkwijze en systeem voor het selectief verwijderen van verontreinigingen uit gasstromen. | |
| CN106868544A (zh) | 一种从硫酸体系电解液中选择性去除一价阴离子杂质的方法 | |
| Mazurek et al. | Application of sulphate and magnesium enriched waste rapeseed cake biochar for recovery of Cu (II) and Zn (II) from industrial wastewater generated in sulphuric acid plants | |
| CN115652114A (zh) | 一种含铊溶液中铊的资源化回收工艺 | |
| JPH08206452A (ja) | 水銀を含むガス中の水銀を同時に捕集、沈殿させる連続処理方法 | |
| CN105399182B (zh) | 一种高效去除污酸中重金属的方法 | |
| AU775117B2 (en) | Process for removing selenium and mercury from aqueous solutions | |
| CN106076083A (zh) | 一种协同催化氧化体系脱除硫化氢回收硫磺的工艺 | |
| WO1996030299A1 (en) | Method of regeneration of iron chelates in nitric oxide scrubbing | |
| US20050211631A1 (en) | Method for the separation of zinc and a second metal which does not form an anionic complex in the presence of chloride ions | |
| EP0409480A2 (de) | Methode zum Entfernen von Schwefelwasserstoff aus einem Gas | |
| PL146522B1 (en) | Method of recovering elementary sulfur from sulfur dioxide or sulfur dioxide and hydrohen sulfide containing gases | |
| JP2014161802A (ja) | セレン除去装置及び除去方法 | |
| CN105582759A (zh) | 一种工业烟气除尘脱硫脱砷一体化方法 | |
| PL235943B1 (pl) | Sposób usuwania metali ze ścieków instalacji mokrego odsiarczania spalin | |
| CN1546209A (zh) | 一种高效处理含h2s废气的方法 | |
| RU2804317C2 (ru) | Способ удаления сероводорода |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PD2B | A search report has been drawn up | ||
| VD1 | Lapsed due to non-payment of the annual fee |
Effective date: 20070101 |